Figure 1
New high-pressure structures of sulfur found by high-pressure powder diffraction. The eight-member rings (S-I, top) break down at 1.5 GPa to form first a triangular chain structure (S-II; left), a novel square chain structure (S-III; right), and then, above 86 GPa, an incommensurate phase (bottom), which is superconducting. A similar sequence is found in Se (Degtyareva, Gregoryanz, Somayazulu, Dera et al., 2005; Degtyareva, Gregoryanz, Somayazulu, Mao & Hemley, 2005). |