Figure 1
Schematic illustration of conventional normalization (a–c) and MBACK normalization (d–f). (a) Measured data (black) are first fitted by a pre-edge polynomial (green) which is then extrapolated over the data range. The vertical line marks the end of the pre-edge fit region. (b) A post-edge spline (red) is then fitted to the pre-edge subtracted data (black) and extrapolated to E0 (vertical line) in order to determine the appropriate scale factor. (c) Conventionally normalized data. (d) In the MBACK procedure, a single background function (red), consisting of a complementary error function (green) plus a polynomial (pink), is used to fit the data both below and above the edge in order to maximize the agreement with the corresponding region of tabulated X-ray cross section, shown in (e). The vertical lines in (d) and (e) mark the edge region that is excluded from the fit. (f) MBACK normalized spectrum. |