Figure 8
The effect of pressure on Hg10Sn90 (Degtyareva et al., 1999). Au is the pressure marker. Diffraction peaks in EDXD spectra (2θ = 9.52°) are fitted to the tI2 structure, indexing is given for the lower pattern at 41.1 GPa. Additional diffraction peaks observed above ∼55 GPa have been interpreted as orthorhombic distortion; indexing is given for the upper pattern (shaded). In the light of later results on the In–Sn system, a two-phase mixture of bct-tI2 and hcp-hP2 is suggested; re-indexing is given in the upper panel. This assumption explains all diffraction peaks including previously unexplained ones (marked by asterisks). |