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Figure 8
Corrected and normalized XAS of the (i-pr Ni) isomer determined from the attenuations of 15 mM solutions following the solvent subtraction as illustrated in Fig. 6[link]. The modelled background (Fig. 6[link]) was subtracted from the corrected (dark-current and scattering effect) attenuations of the solutions (shown in Fig. 3[link] by the diamond symbols; sample detail: #1, Table 3[link]). The corresponding uncertainty was propagated from the uncertainty contributions of experimental systematics, and from the variance of repeated measurements with both the solution and the solvent. The defined accuracy will allow the reliable structural analysis of (i-pr Ni) using XAFS. At each of the energies, three aperture-dependent measurements are in excellent agreement.

Journal logoJOURNAL OF
SYNCHROTRON
RADIATION
ISSN: 1600-5775
Volume 22| Part 4| July 2015| Pages 1008-1021
https://doi.org/10.1107/S1600577515006190
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