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Figure 6
Experimental L-edge XAS spectrum (de Groot et al., 2005BB10) compared with calculation and with corresponding projections of transitions into metal-3d based orbitals of t2 and e symmetries in an octahedral Fe3+ complex (10Dq = 1.5 eV and 90% of reduction in the atomic values of Slater integrals). Contrary to Ti4+ and based on the large number of multiplets in the case of Fe3+, the t2:e proportion in this case is closer to the expected 3:2 value (based on 3d-occupation).

Journal logoJOURNAL OF
SYNCHROTRON
RADIATION
ISSN: 1600-5775
Volume 23| Part 5| September 2016| Pages 1264-1271
https://doi.org/10.1107/S1600577516012443
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