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Figure 5
(a) Structure of molecule A of (3). H atoms of the dimethylglyoximato and pyridine ligands are omitted for clarity. The thermal ellipsoids are drawn at the 30% probability level. The occupancy factors of the D and H atoms of the (R)-1-cyanoethyl-dα group are 100%. (b) Structure of molecule B of (3). The 1-cyanoethyl group is disordered. The black area (50%) shows the initial (S)-1-cyanoethyl group and the gray area (50%) shows the (R)-1-cyanoethyl group produced by irradiation. The shaded circles represent the D atoms. The occupancy factors of the D and H atoms in the disordered 1-cyanoethyl group are the same as those of the non-H/D atoms.

Journal logoSTRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS
ISSN: 2052-5206
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