Water molecules insert into N—H⋯Cl—M hydrogen bonds while M—Cl⋯X—C halogen bonds remain intact in dihydrates of halopyridinium hexachloroplatinates

Zordan, F.; Brammer, L.

doi:10.1107/S0108768104016064

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 4
(a) Structure of (2b) showing O—H⋯Cl(Pt) and N—H⋯O hydrogen bonds, and Pt—Cl⋯I—C halogen bonds that link the molecular components within one layer of the network. Rows of anions lie along the a axis, layers lie in the (011) plane. (b) View of (2b) approximately down the a axis showing three anion layers (horizontally) and the two types of cation/water hydrogen-bonding arrangement and dipole-assisted cation stacking between anion layers.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 60| Part 5| September 2004| Pages 512-519

doi:10.1107/S0108768104016064

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