Effects of the [OC6F5] moiety upon structural geometry: crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(NtBu)(CH2R)2 with pentafluorophenol

Cole, J.M.; Chan, M.C.W.; Gibson, V.C.; Howard, J.A.K.

doi:10.1107/S0108768111029259

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

IUCr IT WDC

home archive editors for authors for readers submit subscribe open access

view article

Figure 1
A summary of the chemical formation of Cp*Ta(N^tBu)(CH₂R)₂ and its subsequent reactivity with pentafluorophenol: (a) 2 RCH₂MgCl, Et₂O; (b) 2 C₆F₅OH, toluene; (c) 2 C₆F₅OH, toluene, 333 K for 10 d.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 67| Part 5| August 2011| Pages 416-424

doi:10.1107/S0108768111029259

Follow Acta Cryst. B

Search term		doi		Advanced search
Author		volume	page