Electronic influence of β-diketonato-type ligands on the coordination of 1,5-cyclooctadiene to palladium(II) as defined by `Venus fly trap' geometric parameters

Hill, T.N.; Roodt, A.; Steyl, G.

doi:10.1107/S2052519212046738

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 7
Illustration of expanded fractions of the unit cell for (V) showing the intramolecular bonding indicated by a dashed line bond and the multiple disordered CF₃ moiety indicated by red, blue and black bonds, respectively. Only relevant H atoms have been included for clarity. Symmetry operators: (a) (i) $[x, {1\over 2}-y, {1\over 2}+z]$ ; (ii) -x, -y, 1-z; (iii) $[-x, {1\over 2}+y, {1\over 2}-z]$ ; (iv) x, 1+y, z. (b) (i) $[-x, {1\over 2}+y, {1\over 2}-z]$ ; (ii) -1+x, y, z; (iii) -x, -y, 1-z; (iv) -x, 1-y, 1-z.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 69| Part 1| December 2013| Pages 36-42

doi:10.1107/S2052519212046738

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