Bond-length distributions for ions bonded to oxygen: results for the non-metals and discussion of lone-pair stereoactivity and the polymerization of PO4

Gagné, O.C.; Hawthorne, F.C.

doi:10.1107/S2052520617017541

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 11
Polymerization of a PO₄ group as a function of the number of bridging oxygen atoms (O_br): (a) O_br = 0 (monomer), (b) O_br = 1 (dimer), (c) O_br = 2 (trimer), (d) O_br = 3, (e) O_br = 4. The valence-sum rule cannot be satisfied for the central P⁵⁺ ion in (e), and this unit does not exist.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 74| Part 1| February 2018| Pages 79-96

https://doi.org/10.1107/S2052520617017541

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