Acta Cryst. (2003). E59, m207-m209  [ doi:10.1107/S1600536803006597 ]

Hexacarbonyldicobalt addition across the CC bond of the alkynethiolate ligand in the cluster [Ru₃(₃,²-CCSiMe₃)(-SCCSiMe₃)(CO)₉]

E. Delgado, M. I. Alcalde, B. Donnadieu, E. Hernandez and J. Sanchez-Nieves

Online 31 March 2003

Key indicators

• Single-crystal X-ray study
• T = 180 K
• Mean (C-C) = 0.005 Å
• R factor = 0.032
• wR factor = 0.094
• Data-to-parameter ratio = 15.8

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level A:



DIFF_020  Alert A _diffrn_standards_interval_count and                          
          _diffrn_standards_interval_time are missing. Number of measurements   
          between standards or time (min) between standards.                    

DIFF_022  Alert A _diffrn_standards_decay_% is missing                          
          Percentage decrease in standards intensity.                           


 Alert Level B:



PLAT_601  Alert B Structure Contains Solvent Accessible VOIDS of     142.00 A   3


 Alert Level C:



REFLT_03                                                                        
         From the CIF: _diffrn_reflns_theta_max           26.23                 
         From the CIF: _reflns_number_total               6954                  
         TEST2: Reflns within _diffrn_reflns_theta_max                          
         Count of symmetry unique reflns         7687                           
         Completeness (_total/calc)             90.46%                          
          Alert C: < 95% complete                                               

PLAT_320  Alert C Check Hybridisation of  C(2)   in Main Residue          ?


 2 Alert Level A = Potentially serious problem

 1 Alert Level B = Potential problem

 2 Alert Level C = Please check

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