Download citation
Download citation
link to html
K5Na[Ce2(SO4)6] contains two CeIII ions, cross-linked via two oxy­gen and four sulfate bridges, a unique configuration for cerium sulfates. Each cerium is (8 + 2)-coordinated by O atoms of four sulfate groups by bidentate linkages.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803023183/mg6026sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803023183/mg6026Isup2.hkl
Contains datablock I

Key indicators

  • Single-crystal X-ray study
  • T = 173 K
  • Mean [sigma](S-O) = 0.002 Å
  • R factor = 0.020
  • wR factor = 0.051
  • Data-to-parameter ratio = 21.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT731_ALERT_1_B Bond Calc 3.86040(10), Rep 3.8603(6) ...... 6.00 su-Rat NA1 -K2 1.555 1.554
Alert level C PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low ....... 0.99 PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 2 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Siemens, 1995); cell refinement: SAINT (Siemens, 1995); data reduction: SAINT (Siemens, 1995) and SADABS (Sheldrick, 2002); program(s) used to solve structure: SHELXTL (Bruker, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: DIAMOND (Brandenburg, 2000); software used to prepare material for publication: SHELXTL.

pentapotassium sodium hexasulfatodicerate(III) top
Crystal data top
K5Na[Ce2(SO4)6]F(000) = 1020
Mr = 1075.09Dx = 3.286 Mg m3
Monoclinic, C2/mMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yCell parameters from 7272 reflections
a = 9.2117 (2) Åθ = 2.5–32.9°
b = 16.3725 (4) ŵ = 5.81 mm1
c = 7.7207 (2) ÅT = 173 K
β = 111.059 (1)°Plate, yellow
V = 1086.65 (5) Å30.30 × 0.10 × 0.05 mm
Z = 2
Data collection top
Siemens SMART 1K CCD area-detector
diffractometer
1998 independent reflections
Radiation source: fine-focus sealed tube1852 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.032
ω scansθmax = 32.9°, θmin = 2.5°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2002)
h = 1413
Tmin = 0.269, Tmax = 0.745k = 2424
9019 measured reflectionsl = 1111
Refinement top
Refinement on F20 restraints
Least-squares matrix: fullPrimary atom site location: heavy-atom method
R[F2 > 2σ(F2)] = 0.020Secondary atom site location: difference Fourier map
wR(F2) = 0.051 w = 1/[σ2(Fo2) + (0.0262P)2 + 2.4852P]
where P = (Fo2 + 2Fc2)/3
S = 1.06(Δ/σ)max = 0.003
1998 reflectionsΔρmax = 1.28 e Å3
95 parametersΔρmin = 1.87 e Å3
Special details top

Experimental. Data were collected at low temperature using a Siemens SMART CCD diffractometer equiped with a LT-2 device. A full sphere of reciprocal space was scanned by 0.3° steps in ω with a crystal–to–detector distance of 3.97 cm, 20 s per frame. Preliminary orientation matrix was obtained from the first 100 frames using SMART (Siemens, 1995). The collected frames were integrated using the preliminary orientation matrix which was updated every 100 frames. Final cell parameters were obtained by refinement on the position of 7272 reflections with I>10σ(I) after integration of all the frames data using SAINT (Siemens, 1995).

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ce10.50000.356299 (10)0.50000.00625 (5)
S10.59615 (8)0.50000.80690 (10)0.00636 (12)
S20.12449 (6)0.33454 (3)0.31516 (7)0.00739 (10)
O10.7305 (3)0.50000.9799 (3)0.0097 (4)
O20.49980 (18)0.42535 (10)0.7920 (2)0.0091 (3)
O30.0339 (2)0.25857 (10)0.3055 (2)0.0136 (3)
O40.6430 (3)0.50000.6407 (3)0.0108 (4)
O50.24202 (19)0.31954 (10)0.2271 (2)0.0106 (3)
O60.2146 (2)0.35751 (11)0.5105 (2)0.0137 (3)
O70.01700 (19)0.39974 (10)0.2218 (2)0.0111 (3)
K10.72215 (6)0.34357 (3)0.11773 (7)0.01226 (9)
K20.00000.50000.50000.0432 (5)
Na10.00000.50000.00000.0085 (3)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ce10.00649 (8)0.00635 (8)0.00592 (8)0.0000.00224 (5)0.000
S10.0060 (3)0.0060 (3)0.0067 (3)0.0000.0018 (2)0.000
S20.0070 (2)0.0067 (2)0.0085 (2)0.00001 (16)0.00274 (17)0.00162 (17)
O10.0071 (9)0.0096 (10)0.0093 (10)0.0000.0010 (8)0.000
O20.0098 (7)0.0073 (6)0.0115 (7)0.0033 (5)0.0052 (6)0.0016 (6)
O30.0116 (7)0.0091 (7)0.0201 (8)0.0027 (6)0.0057 (6)0.0030 (6)
O40.0115 (10)0.0123 (10)0.0108 (10)0.0000.0065 (8)0.000
O50.0092 (7)0.0114 (7)0.0128 (7)0.0004 (6)0.0059 (6)0.0012 (6)
O60.0122 (8)0.0196 (9)0.0081 (7)0.0011 (6)0.0022 (6)0.0000 (6)
O70.0097 (7)0.0101 (7)0.0130 (7)0.0020 (6)0.0035 (6)0.0035 (6)
K10.0122 (2)0.0130 (2)0.0123 (2)0.00213 (16)0.00534 (17)0.00281 (16)
K20.1001 (15)0.0135 (5)0.0316 (7)0.0000.0426 (9)0.000
Na10.0096 (8)0.0092 (8)0.0091 (8)0.0000.0061 (6)0.000
Geometric parameters (Å, º) top
Ce1—O3i2.4953 (17)O6—K1iii2.7251 (17)
Ce1—O3ii2.4953 (17)O6—K23.0400 (18)
Ce1—O2iii2.5225 (16)O7—Na12.3363 (16)
Ce1—O22.5225 (16)O7—K1viii2.7018 (17)
Ce1—O52.6172 (17)O7—K22.7523 (17)
Ce1—O5iii2.6172 (17)K1—O7xii2.7018 (17)
Ce1—O6iii2.6594 (18)K1—O6iii2.7252 (17)
Ce1—O62.6594 (18)K1—O2iii2.7355 (16)
Ce1—O4iv2.7244 (12)K1—O1xiii2.7849 (10)
Ce1—O42.7244 (12)K1—O5i2.7872 (17)
Ce1—S1iv3.2289 (5)K1—O5xi2.8259 (17)
Ce1—S13.2289 (5)K1—O2xiii2.9344 (17)
S1—O11.459 (2)K1—O3xii3.0484 (18)
S1—O2v1.4904 (16)K1—O3i3.1165 (19)
S1—O21.4904 (16)K1—S1xiii3.4152 (7)
S1—O41.494 (2)K1—S2xii3.4672 (7)
S1—Ce1iv3.2289 (5)K1—S2i3.5529 (7)
S1—K1vi3.4152 (7)K2—O7xiv2.7523 (17)
S1—K1vii3.4153 (7)K2—O7v2.7523 (17)
S2—O71.4583 (17)K2—O7xv2.7523 (17)
S2—O31.4849 (17)K2—O6v3.0401 (18)
S2—O61.4853 (18)K2—O6xiv3.0401 (18)
S2—O51.4909 (17)K2—O6xv3.0401 (18)
S2—K23.4447 (5)K2—S2xiv3.4446 (5)
S2—K1viii3.4672 (7)K2—S2v3.4446 (5)
S2—K1ix3.5528 (7)K2—S2xv3.4447 (5)
O1—Na1x2.431 (2)Na1—O7v2.3363 (16)
O1—K1vi2.7849 (10)Na1—O7xvi2.3363 (16)
O1—K1vii2.7849 (10)Na1—O7xvii2.3364 (16)
O2—K1iii2.7355 (16)Na1—O1iv2.431 (2)
O2—K1vii2.9344 (17)Na1—O1xviii2.431 (2)
O3—Ce1ii2.4953 (17)Na1—K2xiii3.8603 (6)
O3—K1viii3.0483 (18)Na1—K1xix3.9507 (5)
O3—K1ix3.1165 (19)Na1—K1xx3.9507 (5)
O4—Ce1iv2.7244 (12)Na1—K1viii3.9507 (5)
O5—K1ix2.7872 (17)Na1—K1xi3.9507 (5)
O5—K1xi2.8259 (17)
O3i—Ce1—O3ii82.18 (8)O5i—K1—O2xiii130.28 (5)
O3i—Ce1—O2iii76.08 (6)O5xi—K1—O2xiii62.47 (5)
O3ii—Ce1—O2iii156.36 (6)O7xii—K1—O3xii48.66 (5)
O3i—Ce1—O2156.36 (6)O6iii—K1—O3xii74.28 (5)
O3ii—Ce1—O276.08 (6)O2iii—K1—O3xii139.90 (5)
O2iii—Ce1—O2126.75 (7)O1xiii—K1—O3xii116.80 (6)
O3i—Ce1—O567.42 (5)O5i—K1—O3xii58.02 (5)
O3ii—Ce1—O592.14 (5)O5xi—K1—O3xii88.60 (5)
O2iii—Ce1—O571.08 (5)O2xiii—K1—O3xii149.77 (5)
O2—Ce1—O5122.03 (5)O7xii—K1—O3i135.42 (5)
O3i—Ce1—O5iii92.14 (5)O6iii—K1—O3i59.95 (5)
O3ii—Ce1—O5iii67.42 (5)O2iii—K1—O3i63.40 (5)
O2iii—Ce1—O5iii122.03 (5)O1xiii—K1—O3i140.14 (6)
O2—Ce1—O5iii71.08 (5)O5i—K1—O3i48.07 (5)
O5—Ce1—O5iii153.41 (7)O5xi—K1—O3i129.53 (5)
O3i—Ce1—O6iii69.41 (5)O2xiii—K1—O3i108.04 (5)
O3ii—Ce1—O6iii111.27 (6)O3xii—K1—O3i96.91 (4)
O2iii—Ce1—O6iii69.58 (5)O7xii—K1—S1xiii90.30 (4)
O2—Ce1—O6iii110.01 (5)O6iii—K1—S1xiii124.56 (4)
O5—Ce1—O6iii126.78 (5)O2iii—K1—S1xiii73.48 (4)
O5iii—Ce1—O6iii53.46 (5)O1xiii—K1—S1xiii24.64 (4)
O3i—Ce1—O6111.27 (6)O5i—K1—S1xiii154.19 (4)
O3ii—Ce1—O669.41 (5)O5xi—K1—S1xiii64.38 (4)
O2iii—Ce1—O6110.01 (5)O2xiii—K1—S1xiii25.75 (3)
O2—Ce1—O669.58 (5)O3xii—K1—S1xiii134.49 (4)
O5—Ce1—O653.46 (5)O3i—K1—S1xiii128.60 (4)
O5iii—Ce1—O6126.78 (5)O7xii—K1—S2xii23.40 (4)
O6iii—Ce1—O6179.15 (8)O6iii—K1—S2xii75.54 (4)
O3i—Ce1—O4iv123.92 (6)O2iii—K1—S2xii133.44 (4)
O3ii—Ce1—O4iv138.05 (6)O1xiii—K1—S2xii92.02 (5)
O2iii—Ce1—O4iv54.00 (6)O5i—K1—S2xii83.25 (4)
O2—Ce1—O4iv79.27 (6)O5xi—K1—S2xii86.56 (4)
O5—Ce1—O4iv73.05 (6)O2xiii—K1—S2xii134.66 (4)
O5iii—Ce1—O4iv133.52 (6)O3xii—K1—S2xii25.31 (3)
O6iii—Ce1—O4iv108.85 (6)O3i—K1—S2xii117.27 (4)
O6—Ce1—O4iv70.37 (6)S1xiii—K1—S2xii112.37 (2)
O3i—Ce1—O4138.05 (6)O7xii—K1—S2i122.29 (4)
O3ii—Ce1—O4123.92 (6)O6iii—K1—S2i66.93 (4)
O2iii—Ce1—O479.27 (6)O2iii—K1—S2i87.98 (4)
O2—Ce1—O454.00 (6)O1xiii—K1—S2i164.75 (5)
O5—Ce1—O4133.52 (6)O5i—K1—S2i23.46 (3)
O5iii—Ce1—O473.05 (6)O5xi—K1—S2i115.04 (4)
O6iii—Ce1—O470.37 (6)O2xiii—K1—S2i122.40 (3)
O6—Ce1—O4108.85 (6)O3xii—K1—S2i76.21 (3)
O4iv—Ce1—O460.56 (9)O3i—K1—S2i24.63 (3)
O3i—Ce1—S1iv99.68 (4)S1xiii—K1—S2i147.40 (2)
O3ii—Ce1—S1iv158.46 (4)S2xii—K1—S2i99.896 (16)
O2iii—Ce1—S1iv26.58 (4)O7—K2—O7xiv180.0
O2—Ce1—S1iv103.96 (4)O7—K2—O7v73.23 (7)
O5—Ce1—S1iv69.30 (4)O7xiv—K2—O7v106.77 (7)
O5iii—Ce1—S1iv133.51 (4)O7—K2—O7xv106.77 (7)
O6iii—Ce1—S1iv89.18 (4)O7xiv—K2—O7xv73.23 (7)
O6—Ce1—S1iv90.20 (4)O7v—K2—O7xv180.0
O4iv—Ce1—S1iv27.42 (5)O7—K2—O649.03 (5)
O4—Ce1—S1iv68.23 (5)O7xiv—K2—O6130.97 (5)
O3i—Ce1—S1158.46 (4)O7v—K2—O6105.06 (5)
O3ii—Ce1—S199.68 (4)O7xv—K2—O674.94 (5)
O2iii—Ce1—S1103.96 (4)O7—K2—O6v105.06 (5)
O2—Ce1—S126.59 (4)O7xiv—K2—O6v74.94 (5)
O5—Ce1—S1133.51 (4)O7v—K2—O6v49.03 (5)
O5iii—Ce1—S169.30 (4)O7xv—K2—O6v130.97 (5)
O6iii—Ce1—S190.20 (4)O6—K2—O6v100.25 (7)
O6—Ce1—S189.18 (4)O7—K2—O6xiv130.97 (5)
O4iv—Ce1—S168.23 (5)O7xiv—K2—O6xiv49.03 (5)
O4—Ce1—S127.42 (5)O7v—K2—O6xiv74.94 (5)
S1iv—Ce1—S186.455 (19)O7xv—K2—O6xiv105.06 (5)
O1—S1—O2v110.88 (8)O6—K2—O6xiv180.00 (7)
O1—S1—O2110.88 (8)O6v—K2—O6xiv79.76 (7)
O2v—S1—O2110.18 (13)O7—K2—O6xv74.94 (5)
O1—S1—O4112.00 (14)O7xiv—K2—O6xv105.06 (5)
O2v—S1—O4106.35 (8)O7v—K2—O6xv130.97 (5)
O2—S1—O4106.35 (8)O7xv—K2—O6xv49.03 (5)
O1—S1—Ce1iv126.21 (4)O6—K2—O6xv79.75 (7)
O2v—S1—Ce1iv49.24 (6)O6v—K2—O6xv180.0
O2—S1—Ce1iv122.83 (7)O6xiv—K2—O6xv100.25 (7)
O4—S1—Ce1iv57.13 (5)O7—K2—S2xiv155.94 (3)
O1—S1—Ce1126.21 (4)O7xiv—K2—S2xiv24.06 (3)
O2v—S1—Ce1122.83 (7)O7v—K2—S2xiv88.57 (4)
O2—S1—Ce149.24 (6)O7xv—K2—S2xiv91.43 (4)
O4—S1—Ce157.13 (5)O6—K2—S2xiv154.49 (3)
Ce1iv—S1—Ce193.545 (19)O6v—K2—S2xiv72.27 (3)
O1—S1—K1vi52.72 (3)O6xiv—K2—S2xiv25.51 (3)
O2v—S1—K1vi58.80 (7)O6xv—K2—S2xiv107.73 (3)
O2—S1—K1vi135.38 (7)O7—K2—S2v91.43 (4)
O4—S1—K1vi118.26 (5)O7xiv—K2—S2v88.57 (4)
Ce1iv—S1—K1vi84.469 (9)O7v—K2—S2v24.06 (3)
Ce1—S1—K1vi175.14 (2)O7xv—K2—S2v155.94 (3)
O1—S1—K1vii52.72 (3)O6—K2—S2v107.73 (3)
O2v—S1—K1vii135.38 (7)O6v—K2—S2v25.51 (3)
O2—S1—K1vii58.80 (7)O6xiv—K2—S2v72.27 (3)
O4—S1—K1vii118.26 (5)O6xv—K2—S2v154.49 (3)
Ce1iv—S1—K1vii175.14 (2)S2xiv—K2—S2v76.300 (17)
Ce1—S1—K1vii84.468 (9)O7—K2—S2xv88.57 (4)
K1vi—S1—K1vii97.16 (2)O7xiv—K2—S2xv91.43 (4)
O7—S2—O3108.59 (10)O7v—K2—S2xv155.94 (3)
O7—S2—O6110.44 (10)O7xv—K2—S2xv24.06 (3)
O3—S2—O6111.23 (10)O6—K2—S2xv72.27 (3)
O7—S2—O5111.75 (10)O6v—K2—S2xv154.49 (3)
O3—S2—O5109.04 (10)O6xiv—K2—S2xv107.73 (3)
O6—S2—O5105.80 (10)O6xv—K2—S2xv25.51 (3)
O7—S2—Ce1124.25 (7)S2xiv—K2—S2xv103.700 (17)
O3—S2—Ce1127.14 (7)S2v—K2—S2xv180.0
O6—S2—Ce153.74 (7)O7—K2—S224.06 (3)
O5—S2—Ce152.13 (7)O7xiv—K2—S2155.94 (3)
O7—S2—K250.30 (7)O7v—K2—S291.43 (4)
O3—S2—K2114.51 (7)O7xv—K2—S288.57 (4)
O6—S2—K261.83 (7)O6—K2—S225.51 (3)
O5—S2—K2136.28 (7)O6v—K2—S2107.73 (3)
Ce1—S2—K2101.068 (14)O6xiv—K2—S2154.49 (3)
O7—S2—K1viii47.37 (7)O6xv—K2—S272.27 (3)
O3—S2—K1viii61.37 (7)S2xiv—K2—S2180.000 (11)
O6—S2—K1viii123.69 (7)S2v—K2—S2103.700 (17)
O5—S2—K1viii130.03 (7)S2xv—K2—S276.300 (17)
Ce1—S2—K1viii171.27 (2)O7—Na1—O7v89.27 (8)
K2—S2—K1viii71.711 (13)O7—Na1—O7xvi180.0
O7—S2—K1ix128.34 (7)O7v—Na1—O7xvi90.72 (8)
O3—S2—K1ix61.00 (7)O7—Na1—O7xvii90.72 (8)
O6—S2—K1ix120.55 (7)O7v—Na1—O7xvii180.0
O5—S2—K1ix48.09 (7)O7xvi—Na1—O7xvii89.28 (8)
Ce1—S2—K1ix83.386 (14)O7—Na1—O1iv98.93 (5)
K2—S2—K1ix175.236 (18)O7v—Na1—O1iv98.94 (5)
K1viii—S2—K1ix103.996 (18)O7xvi—Na1—O1iv81.06 (5)
S1—O1—Na1x124.70 (13)O7xvii—Na1—O1iv81.06 (5)
S1—O1—K1vi102.65 (6)O7—Na1—O1xviii81.06 (5)
Na1x—O1—K1vi98.25 (5)O7v—Na1—O1xviii81.06 (5)
S1—O1—K1vii102.65 (6)O7xvi—Na1—O1xviii98.94 (5)
Na1x—O1—K1vii98.25 (5)O7xvii—Na1—O1xviii98.94 (5)
K1vi—O1—K1vii133.74 (9)O1iv—Na1—O1xviii180.00 (11)
S1—O2—Ce1104.18 (8)O7—Na1—K2xiii135.14 (4)
S1—O2—K1iii149.38 (9)O7v—Na1—K2xiii135.14 (4)
Ce1—O2—K1iii104.42 (5)O7xvi—Na1—K2xiii44.86 (4)
S1—O2—K1vii95.46 (8)O7xvii—Na1—K2xiii44.86 (4)
Ce1—O2—K1vii109.70 (6)O1iv—Na1—K2xiii72.35 (5)
K1iii—O2—K1vii85.05 (5)O1xviii—Na1—K2xiii107.65 (5)
S2—O3—Ce1ii142.25 (11)O7—Na1—K244.86 (4)
S2—O3—K1viii93.32 (8)O7v—Na1—K244.86 (4)
Ce1ii—O3—K1viii109.28 (6)O7xvi—Na1—K2135.14 (4)
S2—O3—K1ix94.37 (8)O7xvii—Na1—K2135.14 (4)
Ce1ii—O3—K1ix94.95 (5)O1iv—Na1—K2107.65 (5)
K1viii—O3—K1ix127.62 (6)O1xviii—Na1—K272.35 (5)
S1—O4—Ce1iv95.44 (7)K2xiii—Na1—K2180.0
S1—O4—Ce195.44 (7)O7—Na1—K1xix138.22 (4)
Ce1iv—O4—Ce1119.44 (9)O7v—Na1—K1xix80.49 (4)
S2—O5—Ce1101.15 (8)O7xvi—Na1—K1xix41.78 (4)
S2—O5—K1ix108.46 (8)O7xvii—Na1—K1xix99.51 (4)
Ce1—O5—K1ix113.95 (6)O1iv—Na1—K1xix44.24 (2)
S2—O5—K1xi139.14 (9)O1xviii—Na1—K1xix135.76 (2)
Ce1—O5—K1xi110.29 (6)K2xiii—Na1—K1xix62.427 (7)
K1ix—O5—K1xi82.24 (5)K2—Na1—K1xix117.573 (7)
S2—O6—Ce199.49 (8)O7—Na1—K1xx99.51 (4)
S2—O6—K1iii151.45 (10)O7v—Na1—K1xx41.78 (4)
Ce1—O6—K1iii101.07 (6)O7xvi—Na1—K1xx80.49 (4)
S2—O6—K292.65 (8)O7xvii—Na1—K1xx138.22 (4)
Ce1—O6—K2130.19 (7)O1iv—Na1—K1xx135.76 (2)
K1iii—O6—K289.04 (5)O1xviii—Na1—K1xx44.24 (2)
S2—O7—Na1137.00 (10)K2xiii—Na1—K1xx117.573 (7)
S2—O7—K1viii109.23 (9)K2—Na1—K1xx62.427 (7)
Na1—O7—K1viii103.05 (6)K1xix—Na1—K1xx99.180 (15)
S2—O7—K2105.64 (8)O7—Na1—K1viii41.78 (4)
Na1—O7—K298.36 (6)O7v—Na1—K1viii99.51 (4)
K1viii—O7—K295.85 (5)O7xvi—Na1—K1viii138.22 (4)
O7xii—K1—O6iii81.18 (5)O7xvii—Na1—K1viii80.49 (4)
O7xii—K1—O2iii121.42 (5)O1iv—Na1—K1viii135.76 (2)
O6iii—K1—O2iii65.62 (5)O1xviii—Na1—K1viii44.24 (2)
O7xii—K1—O1xiii68.76 (6)K2xiii—Na1—K1viii117.573 (8)
O6iii—K1—O1xiii107.49 (6)K2—Na1—K1viii62.427 (7)
O2iii—K1—O1xiii76.88 (6)K1xix—Na1—K1viii180.0
O7xii—K1—O5i106.65 (5)K1xx—Na1—K1viii80.821 (15)
O6iii—K1—O5i78.18 (5)O7—Na1—K1xi80.49 (4)
O2iii—K1—O5i111.43 (5)O7v—Na1—K1xi138.22 (4)
O1xiii—K1—O5i171.55 (6)O7xvi—Na1—K1xi99.51 (4)
O7xii—K1—O5xi83.24 (5)O7xvii—Na1—K1xi41.78 (4)
O6iii—K1—O5xi161.96 (5)O1iv—Na1—K1xi44.24 (2)
O2iii—K1—O5xi131.25 (5)O1xviii—Na1—K1xi135.76 (2)
O1xiii—K1—O5xi74.90 (6)K2xiii—Na1—K1xi62.427 (7)
O5i—K1—O5xi97.76 (5)K2—Na1—K1xi117.573 (7)
O7xii—K1—O2xiii114.65 (5)K1xix—Na1—K1xi80.821 (15)
O6iii—K1—O2xiii133.13 (5)K1xx—Na1—K1xi180.0
O2iii—K1—O2xiii68.88 (6)K1viii—Na1—K1xi99.179 (15)
O1xiii—K1—O2xiii50.18 (5)
Symmetry codes: (i) x+1/2, y+1/2, z; (ii) x+1/2, y+1/2, z+1; (iii) x+1, y, z+1; (iv) x+1, y+1, z+1; (v) x, y+1, z; (vi) x, y+1, z+1; (vii) x, y, z+1; (viii) x1, y, z; (ix) x1/2, y+1/2, z; (x) x+1, y, z+1; (xi) x+1, y, z; (xii) x+1, y, z; (xiii) x, y, z1; (xiv) x, y+1, z+1; (xv) x, y, z+1; (xvi) x, y+1, z; (xvii) x, y, z; (xviii) x1, y, z1; (xix) x+1, y+1, z; (xx) x1, y+1, z.
 

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds