The title compound, C
23H
25N
5O
4, was synthesized by the reaction of methyl (2-{[3-(3-pyridyl)-1,2,4-oxadiazol-5-yl]methoxy}phenyl)acetate and
N,
N-dimethylformamide dimethyl acetal. In the crystal structure, there are intramolecular C—H
O and C—H
N and intermolecular C—H
π interactions.
Supporting information
CCDC reference: 270288
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.004 Å
- R factor = 0.053
- wR factor = 0.182
- Data-to-parameter ratio = 14.7
checkCIF/PLATON results
No syntax errors found
Alert level A
PLAT052_ALERT_1_A (Proper) Absorption Correction Method Missing .. ?
Alert level C
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ?
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ?
PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ?
1 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
3 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
0 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: CAD-4 Software (Enraf–Nonius, 1989); cell refinement: CAD-4 Software; data reduction: XCAD4 (Harms & Wocadlo, 1995); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Siemens, 1996); software used to prepare material for publication: SHELXL97.
Methyl 3-dimethylamino-2-(2-{2-dimethylamino-1-[3-(3-pyridyl)-1,2,4-oxadiazol-
5-yl]vinyloxy}phenyl)acrylate
top
Crystal data top
C23H25N5O4 | F(000) = 920 |
Mr = 435.48 | Dx = 1.325 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
a = 8.6250 (17) Å | Cell parameters from 25 reflections |
b = 9.6390 (19) Å | θ = 10–13° |
c = 26.273 (5) Å | µ = 0.09 mm−1 |
β = 91.28 (3)° | T = 293 K |
V = 2183.7 (8) Å3 | Tablet, colourless |
Z = 4 | 0.40 × 0.30 × 0.20 mm |
Data collection top
Enraf–Nonius CAD-4 diffractometer | 2426 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.027 |
Graphite monochromator | θmax = 26.0°, θmin = 1.6° |
ω/2θ scans | h = 0→10 |
Absorption correction: ψ scan (North et al., 1968) | k = 0→11 |
Tmin = 0.964, Tmax = 0.982 | l = −31→31 |
4550 measured reflections | 3 standard reflections every 200 reflections |
4257 independent reflections | intensity decay: none |
Refinement top
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.053 | H-atom parameters constrained |
wR(F2) = 0.182 | w = 1/[σ2(Fo2) + (0.1P)2 + 1.2P] where P = (Fo2 + 2Fc2)/3 |
S = 0.93 | (Δ/σ)max = 0.013 |
4257 reflections | Δρmax = 0.29 e Å−3 |
290 parameters | Δρmin = −0.24 e Å−3 |
0 restraints | Extinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.0100 (17) |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
O1 | 0.4684 (3) | 0.6663 (2) | 0.32844 (8) | 0.0550 (6) | |
O2 | 0.2363 (2) | 0.4156 (2) | 0.39497 (7) | 0.0399 (5) | |
O3 | 0.2164 (3) | 0.0530 (3) | 0.46863 (9) | 0.0656 (7) | |
O4 | 0.0474 (3) | 0.2254 (2) | 0.48021 (8) | 0.0548 (6) | |
N1 | 0.2789 (4) | 0.3991 (3) | 0.13676 (11) | 0.0626 (8) | |
N2 | 0.4940 (3) | 0.6675 (3) | 0.27505 (10) | 0.0566 (8) | |
N3 | 0.3291 (3) | 0.4942 (3) | 0.29525 (9) | 0.0412 (6) | |
N4 | 0.3353 (3) | 0.6239 (3) | 0.47575 (10) | 0.0564 (8) | |
N5 | 0.1193 (3) | 0.0355 (3) | 0.31549 (10) | 0.0463 (6) | |
C1 | 0.3728 (5) | 0.4632 (4) | 0.10467 (14) | 0.0645 (10) | |
H1B | 0.3627 | 0.4415 | 0.0703 | 0.077* | |
C2 | 0.4831 (4) | 0.5588 (4) | 0.11896 (13) | 0.0632 (11) | |
H2B | 0.5471 | 0.5984 | 0.0949 | 0.076* | |
C3 | 0.4976 (3) | 0.5951 (4) | 0.16947 (12) | 0.0545 (9) | |
H3B | 0.5699 | 0.6611 | 0.1802 | 0.065* | |
C4 | 0.4017 (3) | 0.5307 (3) | 0.20415 (11) | 0.0418 (7) | |
C5 | 0.2969 (4) | 0.4334 (3) | 0.18571 (12) | 0.0506 (8) | |
H5A | 0.2346 | 0.3888 | 0.2091 | 0.061* | |
C6 | 0.4101 (3) | 0.5653 (3) | 0.25865 (11) | 0.0403 (7) | |
C7 | 0.3694 (3) | 0.5606 (3) | 0.33659 (11) | 0.0379 (7) | |
C8 | 0.3209 (3) | 0.5370 (3) | 0.38798 (11) | 0.0405 (7) | |
C9 | 0.0789 (3) | 0.4168 (3) | 0.38094 (10) | 0.0327 (6) | |
C10 | −0.0004 (3) | 0.5362 (3) | 0.36803 (11) | 0.0409 (7) | |
H10A | 0.0507 | 0.6211 | 0.3678 | 0.049* | |
C11 | −0.1573 (4) | 0.5289 (3) | 0.35529 (12) | 0.0463 (8) | |
H11A | −0.2120 | 0.6093 | 0.3472 | 0.056* | |
C12 | −0.2316 (3) | 0.4032 (4) | 0.35467 (12) | 0.0492 (8) | |
H12A | −0.3363 | 0.3979 | 0.3455 | 0.059* | |
C13 | −0.1506 (3) | 0.2847 (3) | 0.36764 (11) | 0.0450 (7) | |
H13A | −0.2023 | 0.2000 | 0.3673 | 0.054* | |
C14 | 0.0067 (3) | 0.2878 (3) | 0.38121 (10) | 0.0325 (6) | |
C15 | 0.0915 (3) | 0.1596 (3) | 0.39666 (10) | 0.0351 (6) | |
C16 | 0.1278 (3) | 0.1376 (3) | 0.45053 (11) | 0.0426 (7) | |
C17 | 0.0678 (5) | 0.2074 (4) | 0.53439 (12) | 0.0712 (11) | |
H17A | 0.0057 | 0.2743 | 0.5518 | 0.107* | |
H17B | 0.1750 | 0.2205 | 0.5438 | 0.107* | |
H17C | 0.0362 | 0.1155 | 0.5437 | 0.107* | |
C18 | 0.1293 (3) | 0.0519 (3) | 0.36618 (11) | 0.0396 (7) | |
H18A | 0.1695 | −0.0246 | 0.3836 | 0.048* | |
C19 | 0.0819 (4) | 0.1468 (4) | 0.27997 (12) | 0.0610 (10) | |
H19A | 0.0583 | 0.2296 | 0.2986 | 0.092* | |
H19B | −0.0063 | 0.1206 | 0.2592 | 0.092* | |
H19C | 0.1690 | 0.1636 | 0.2587 | 0.092* | |
C20 | 0.1558 (5) | −0.0969 (4) | 0.29305 (15) | 0.0715 (11) | |
H20A | 0.1789 | −0.1629 | 0.3195 | 0.107* | |
H20B | 0.2441 | −0.0871 | 0.2718 | 0.107* | |
H20C | 0.0686 | −0.1289 | 0.2729 | 0.107* | |
C21 | 0.3651 (3) | 0.6239 (3) | 0.42581 (12) | 0.0463 (8) | |
H21A | 0.4273 | 0.6970 | 0.4155 | 0.056* | |
C22 | 0.2453 (4) | 0.5195 (4) | 0.50128 (13) | 0.0634 (10) | |
H22A | 0.2120 | 0.4503 | 0.4771 | 0.095* | |
H22B | 0.1562 | 0.5620 | 0.5160 | 0.095* | |
H22C | 0.3078 | 0.4769 | 0.5276 | 0.095* | |
C23 | 0.3934 (5) | 0.7359 (4) | 0.50808 (15) | 0.0768 (12) | |
H23A | 0.4522 | 0.7995 | 0.4881 | 0.115* | |
H23B | 0.4586 | 0.6982 | 0.5347 | 0.115* | |
H23C | 0.3077 | 0.7839 | 0.5228 | 0.115* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
O1 | 0.0573 (14) | 0.0649 (15) | 0.0429 (13) | −0.0270 (12) | 0.0058 (10) | −0.0025 (11) |
O2 | 0.0312 (10) | 0.0443 (11) | 0.0441 (12) | −0.0071 (9) | −0.0014 (8) | 0.0041 (9) |
O3 | 0.0693 (16) | 0.0789 (17) | 0.0483 (14) | 0.0198 (14) | −0.0032 (12) | 0.0132 (12) |
O4 | 0.0703 (15) | 0.0612 (14) | 0.0331 (11) | 0.0083 (12) | 0.0029 (10) | −0.0002 (10) |
N1 | 0.087 (2) | 0.0543 (17) | 0.0461 (17) | 0.0141 (16) | −0.0069 (16) | −0.0050 (14) |
N2 | 0.0589 (17) | 0.0697 (19) | 0.0416 (15) | −0.0230 (15) | 0.0080 (13) | 0.0020 (13) |
N3 | 0.0387 (13) | 0.0455 (14) | 0.0394 (14) | −0.0060 (11) | 0.0038 (11) | −0.0005 (11) |
N4 | 0.0669 (19) | 0.0631 (18) | 0.0394 (15) | −0.0196 (15) | 0.0065 (13) | −0.0091 (13) |
N5 | 0.0534 (16) | 0.0421 (14) | 0.0437 (15) | 0.0012 (12) | 0.0043 (12) | −0.0062 (11) |
C1 | 0.073 (3) | 0.078 (3) | 0.042 (2) | 0.032 (2) | −0.0007 (18) | −0.0042 (18) |
C2 | 0.0421 (19) | 0.103 (3) | 0.045 (2) | 0.025 (2) | 0.0125 (15) | 0.020 (2) |
C3 | 0.0311 (16) | 0.081 (2) | 0.052 (2) | 0.0084 (16) | 0.0039 (14) | 0.0108 (18) |
C4 | 0.0336 (15) | 0.0523 (18) | 0.0394 (16) | 0.0122 (14) | 0.0020 (12) | 0.0055 (13) |
C5 | 0.062 (2) | 0.0449 (18) | 0.0449 (19) | 0.0061 (16) | 0.0016 (15) | 0.0012 (14) |
C6 | 0.0320 (15) | 0.0460 (17) | 0.0429 (17) | 0.0009 (13) | 0.0012 (12) | 0.0038 (14) |
C7 | 0.0304 (14) | 0.0426 (16) | 0.0409 (16) | −0.0065 (12) | 0.0022 (12) | 0.0004 (13) |
C8 | 0.0331 (15) | 0.0431 (16) | 0.0453 (17) | −0.0083 (13) | 0.0038 (13) | −0.0003 (13) |
C9 | 0.0292 (14) | 0.0395 (15) | 0.0296 (14) | −0.0030 (12) | 0.0027 (11) | −0.0017 (12) |
C10 | 0.0456 (17) | 0.0354 (16) | 0.0418 (17) | −0.0004 (13) | 0.0039 (13) | 0.0024 (12) |
C11 | 0.0426 (17) | 0.0503 (19) | 0.0460 (18) | 0.0117 (15) | 0.0014 (14) | 0.0046 (14) |
C12 | 0.0319 (16) | 0.062 (2) | 0.053 (2) | 0.0015 (15) | −0.0035 (14) | 0.0003 (16) |
C13 | 0.0346 (16) | 0.0493 (18) | 0.0510 (19) | −0.0068 (14) | −0.0005 (13) | −0.0007 (15) |
C14 | 0.0310 (14) | 0.0377 (15) | 0.0291 (14) | −0.0005 (12) | 0.0040 (11) | −0.0012 (11) |
C15 | 0.0333 (15) | 0.0346 (15) | 0.0374 (15) | −0.0051 (12) | 0.0032 (11) | 0.0030 (12) |
C16 | 0.0427 (17) | 0.0434 (17) | 0.0418 (17) | −0.0006 (14) | 0.0020 (13) | 0.0024 (14) |
C17 | 0.097 (3) | 0.085 (3) | 0.0323 (18) | 0.006 (2) | 0.0059 (18) | 0.0048 (18) |
C18 | 0.0372 (16) | 0.0368 (16) | 0.0450 (17) | −0.0029 (13) | 0.0019 (13) | 0.0046 (13) |
C19 | 0.077 (2) | 0.068 (2) | 0.0378 (18) | 0.011 (2) | 0.0044 (16) | −0.0016 (16) |
C20 | 0.087 (3) | 0.058 (2) | 0.070 (3) | 0.004 (2) | 0.004 (2) | −0.0255 (19) |
C21 | 0.0427 (17) | 0.0515 (19) | 0.0447 (18) | −0.0125 (14) | 0.0049 (13) | −0.0036 (14) |
C22 | 0.073 (2) | 0.077 (2) | 0.0406 (18) | −0.015 (2) | 0.0105 (17) | 0.0023 (17) |
C23 | 0.094 (3) | 0.079 (3) | 0.058 (2) | −0.027 (2) | 0.006 (2) | −0.022 (2) |
Geometric parameters (Å, º) top
O1—C7 | 1.350 (3) | C9—C14 | 1.391 (4) |
O1—N2 | 1.425 (3) | C10—C11 | 1.388 (4) |
O2—C9 | 1.399 (3) | C10—H10A | 0.9300 |
O2—C8 | 1.394 (3) | C11—C12 | 1.370 (4) |
O3—C16 | 1.208 (4) | C11—H11A | 0.9300 |
O4—C16 | 1.352 (4) | C12—C13 | 1.378 (4) |
O4—C17 | 1.441 (4) | C12—H12A | 0.9300 |
N1—C5 | 1.334 (4) | C13—C14 | 1.395 (4) |
N1—C1 | 1.333 (5) | C13—H13A | 0.9300 |
N2—C6 | 1.291 (4) | C14—C15 | 1.487 (4) |
N3—C7 | 1.301 (4) | C15—C18 | 1.355 (4) |
N3—C6 | 1.383 (4) | C15—C16 | 1.458 (4) |
N4—C21 | 1.342 (4) | C17—H17A | 0.9600 |
N4—C22 | 1.445 (4) | C17—H17B | 0.9600 |
N4—C23 | 1.456 (4) | C17—H17C | 0.9600 |
N5—C18 | 1.342 (4) | C18—H18A | 0.9300 |
N5—C20 | 1.444 (4) | C19—H19A | 0.9600 |
N5—C19 | 1.453 (4) | C19—H19B | 0.9600 |
C1—C2 | 1.371 (5) | C19—H19C | 0.9600 |
C1—H1B | 0.9300 | C20—H20A | 0.9600 |
C2—C3 | 1.375 (5) | C20—H20B | 0.9600 |
C2—H2B | 0.9300 | C20—H20C | 0.9600 |
C3—C4 | 1.391 (4) | C21—H21A | 0.9300 |
C3—H3B | 0.9300 | C22—H22A | 0.9600 |
C4—C5 | 1.383 (4) | C22—H22B | 0.9600 |
C4—C6 | 1.470 (4) | C22—H22C | 0.9600 |
C5—H5A | 0.9300 | C23—H23A | 0.9600 |
C7—C8 | 1.440 (4) | C23—H23B | 0.9600 |
C8—C21 | 1.348 (4) | C23—H23C | 0.9600 |
C9—C10 | 1.378 (4) | | |
| | | |
C7—O1—N2 | 105.9 (2) | C12—C13—C14 | 122.0 (3) |
C9—O2—C8 | 117.8 (2) | C12—C13—H13A | 119.0 |
C16—O4—C17 | 116.2 (3) | C14—C13—H13A | 119.0 |
C5—N1—C1 | 115.8 (3) | C9—C14—C13 | 116.8 (3) |
C6—N2—O1 | 103.0 (2) | C9—C14—C15 | 121.8 (2) |
C7—N3—C6 | 102.0 (2) | C13—C14—C15 | 121.4 (2) |
C21—N4—C22 | 124.7 (3) | C18—C15—C16 | 114.4 (3) |
C21—N4—C23 | 120.0 (3) | C18—C15—C14 | 126.8 (3) |
C22—N4—C23 | 115.3 (3) | C16—C15—C14 | 118.6 (2) |
C18—N5—C20 | 120.0 (3) | O3—C16—O4 | 121.6 (3) |
C18—N5—C19 | 124.0 (3) | O3—C16—C15 | 126.9 (3) |
C20—N5—C19 | 116.0 (3) | O4—C16—C15 | 111.5 (3) |
N1—C1—C2 | 124.4 (3) | O4—C17—H17A | 109.5 |
N1—C1—H1B | 117.8 | O4—C17—H17B | 109.5 |
C2—C1—H1B | 117.8 | H17A—C17—H17B | 109.5 |
C1—C2—C3 | 118.9 (3) | O4—C17—H17C | 109.5 |
C1—C2—H2B | 120.6 | H17A—C17—H17C | 109.5 |
C3—C2—H2B | 120.6 | H17B—C17—H17C | 109.5 |
C2—C3—C4 | 118.4 (3) | N5—C18—C15 | 131.7 (3) |
C2—C3—H3B | 120.8 | N5—C18—H18A | 114.1 |
C4—C3—H3B | 120.8 | C15—C18—H18A | 114.1 |
C5—C4—C3 | 117.8 (3) | N5—C19—H19A | 109.5 |
C5—C4—C6 | 120.8 (3) | N5—C19—H19B | 109.5 |
C3—C4—C6 | 121.3 (3) | H19A—C19—H19B | 109.5 |
N1—C5—C4 | 124.6 (3) | N5—C19—H19C | 109.5 |
N1—C5—H5A | 117.7 | H19A—C19—H19C | 109.5 |
C4—C5—H5A | 117.7 | H19B—C19—H19C | 109.5 |
N2—C6—N3 | 115.7 (3) | N5—C20—H20A | 109.5 |
N2—C6—C4 | 120.9 (3) | N5—C20—H20B | 109.5 |
N3—C6—C4 | 123.4 (3) | H20A—C20—H20B | 109.5 |
N3—C7—O1 | 113.4 (2) | N5—C20—H20C | 109.5 |
N3—C7—C8 | 128.8 (3) | H20A—C20—H20C | 109.5 |
O1—C7—C8 | 117.8 (2) | H20B—C20—H20C | 109.5 |
C21—C8—O2 | 124.4 (3) | N4—C21—C8 | 131.6 (3) |
C21—C8—C7 | 120.7 (3) | N4—C21—H21A | 114.2 |
O2—C8—C7 | 114.8 (2) | C8—C21—H21A | 114.2 |
C10—C9—C14 | 121.9 (2) | N4—C22—H22A | 109.5 |
C10—C9—O2 | 123.1 (2) | N4—C22—H22B | 109.5 |
C14—C9—O2 | 115.0 (2) | H22A—C22—H22B | 109.5 |
C9—C10—C11 | 119.5 (3) | N4—C22—H22C | 109.5 |
C9—C10—H10A | 120.2 | H22A—C22—H22C | 109.5 |
C11—C10—H10A | 120.2 | H22B—C22—H22C | 109.5 |
C12—C11—C10 | 120.1 (3) | N4—C23—H23A | 109.5 |
C12—C11—H11A | 120.0 | N4—C23—H23B | 109.5 |
C10—C11—H11A | 120.0 | H23A—C23—H23B | 109.5 |
C11—C12—C13 | 119.7 (3) | N4—C23—H23C | 109.5 |
C11—C12—H12A | 120.2 | H23A—C23—H23C | 109.5 |
C13—C12—H12A | 120.2 | H23B—C23—H23C | 109.5 |
| | | |
C7—O1—N2—C6 | −0.2 (3) | C14—C9—C10—C11 | 0.6 (4) |
C5—N1—C1—C2 | 0.2 (5) | O2—C9—C10—C11 | −179.0 (2) |
N1—C1—C2—C3 | −1.6 (5) | C9—C10—C11—C12 | −1.2 (5) |
C1—C2—C3—C4 | 1.4 (5) | C10—C11—C12—C13 | 1.2 (5) |
C2—C3—C4—C5 | 0.1 (4) | C11—C12—C13—C14 | −0.5 (5) |
C2—C3—C4—C6 | −179.5 (3) | C10—C9—C14—C13 | 0.1 (4) |
C1—N1—C5—C4 | 1.4 (5) | O2—C9—C14—C13 | 179.7 (2) |
C3—C4—C5—N1 | −1.6 (5) | C10—C9—C14—C15 | −178.1 (3) |
C6—C4—C5—N1 | 178.0 (3) | O2—C9—C14—C15 | 1.5 (4) |
O1—N2—C6—N3 | 0.2 (3) | C12—C13—C14—C9 | −0.2 (4) |
O1—N2—C6—C4 | 179.2 (2) | C12—C13—C14—C15 | 178.1 (3) |
C7—N3—C6—N2 | −0.1 (3) | C9—C14—C15—C18 | −111.8 (3) |
C7—N3—C6—C4 | −179.1 (3) | C13—C14—C15—C18 | 70.0 (4) |
C5—C4—C6—N2 | −171.5 (3) | C9—C14—C15—C16 | 74.2 (3) |
C3—C4—C6—N2 | 8.1 (4) | C13—C14—C15—C16 | −104.0 (3) |
C5—C4—C6—N3 | 7.4 (4) | C17—O4—C16—O3 | −3.0 (4) |
C3—C4—C6—N3 | −173.0 (3) | C17—O4—C16—C15 | 176.6 (3) |
C6—N3—C7—O1 | −0.1 (3) | C18—C15—C16—O3 | 18.4 (4) |
C6—N3—C7—C8 | 178.9 (3) | C14—C15—C16—O3 | −166.8 (3) |
N2—O1—C7—N3 | 0.2 (3) | C18—C15—C16—O4 | −161.1 (2) |
N2—O1—C7—C8 | −178.9 (3) | C14—C15—C16—O4 | 13.7 (4) |
C9—O2—C8—C21 | 104.4 (3) | C20—N5—C18—C15 | −174.5 (3) |
C9—O2—C8—C7 | −79.7 (3) | C19—N5—C18—C15 | 9.4 (5) |
N3—C7—C8—C21 | −174.5 (3) | C16—C15—C18—N5 | −177.3 (3) |
O1—C7—C8—C21 | 4.4 (4) | C14—C15—C18—N5 | 8.5 (5) |
N3—C7—C8—O2 | 9.5 (4) | C22—N4—C21—C8 | 1.8 (6) |
O1—C7—C8—O2 | −171.6 (2) | C23—N4—C21—C8 | −177.3 (4) |
C8—O2—C9—C10 | −10.1 (4) | O2—C8—C21—N4 | −4.5 (6) |
C8—O2—C9—C14 | 170.3 (2) | C7—C8—C21—N4 | 179.9 (3) |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
C5—H5A···N3 | 0.93 | 2.60 | 2.944 (4) | 103 |
C18—H18A···O3 | 0.93 | 2.38 | 2.778 (4) | 105 |
C21—H21A···O1 | 0.93 | 2.34 | 2.758 (3) | 107 |
C22—H22A···O2 | 0.96 | 2.20 | 2.967 (4) | 136 |
C22—H22A···O4 | 0.96 | 2.59 | 3.349 (5) | 136 |
C13—H13A···Cg1i | 0.93 | 2.58 | 3.488 (2) | 164 |
Symmetry code: (i) −x, y−1/2, −z+1/2. |