Poly[bis­(μ-penta­fluoro­benzene­thiol­ato)lead(II)]

Fleischer, H.; Heller, C.; Schollmeyer, D.

doi:10.1107/S1600536806018563

Poly[bis(μ-pentafluorobenzenethiolato)lead(II)]

H. Fleischer, C. Heller and D. Schollmeyer

The title compound, [Pb(SC₆F₅)₂]_n, exhibits a layered structure containing two differently hexacoordinated Pb^II atoms. One is situated on a centre of inversion and is coordinated by six S atoms, its valence lone pair of electrons being consequently stereochemically inactive. The other Pb atom is pyramidally coordinated by three S atoms and forms three contacts to adjacent F atoms, the stereochemically active lone pair pointing towards the F₃ plane.

Read article Similar articles

Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806018563/hb2053sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806018563/hb2053Isup2.hkl Contains datablock I

CCDC reference: 610788

checkCIF report

Key indicators

Single-crystal X-ray study
T = 298 K
Mean (C-C) = 0.015 Å
R factor = 0.051
wR factor = 0.149
Data-to-parameter ratio = 15.6

checkCIF/PLATON results

No syntax errors found



Alert level B
RINTA01_ALERT_3_B  The value of Rint is greater than 0.15
            Rint given   0.161
PLAT020_ALERT_3_B The value of Rint is greater than 0.10 .........       0.16
PLAT061_ALERT_3_B Tmax/Tmin Range Test RR' too Large .............       0.73

Alert level C
PLAT040_ALERT_1_C No H-atoms in this Carbon Containing Compound ..          ?
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.33 Ratio
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       1.11
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         15
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          1
            S1  -PB1 -S1  -C1   -173.00 18.00   3.666   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          6
            S1  -PB1 -S1  -PB2    73.00 14.00   3.666   1.555   1.555   2.655
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         45
            S2  -PB1 -S2  -C7     50.00  9.00   3.666   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         50
            S2  -PB1 -S2  -PB2   165.00  9.00   3.666   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         89
            S3  -PB1 -S3  -C13    10.00  0.00   3.666   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         94
            S3  -PB1 -S3  -PB2    15.00  0.00   3.666   1.555   1.555   1.555

Alert level G
ABSTM02_ALERT_3_G  When printed, the submitted absorption T values will be
            replaced by the scaled T values. Since the ratio of scaled T's
            is identical to the ratio of reported T values, the scaling
            does not imply a change to the absorption corrections used in
            the study.
            Ratio of Tmax expected/reported      1.106
            Tmax scaled      0.332 Tmin scaled      0.033
CHEMS02_ALERT_1_G  Please check that you have entered the correct
            _publ_requested_category classification of your compound;
            FI or CI or EI for inorganic; FM or CM or EM for metal-organic;
            FO or CO or EO for organic.
            From the CIF: _publ_requested_category   EM
            From the CIF: _chemical_formula_sum:C12 F10 Pb1 S2

   0 ALERT level A = In general: serious problem
   3 ALERT level B = Potentially serious problem
  12 ALERT level C = Check and explain
   2 ALERT level G = General alerts; check

   5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   7 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

Poly[bis(µ-pentafluorobenzenethiolato)lead(II)] top

Crystal data top

[Pb(C₆F₅S)₂]	F(000) = 1656
M_r = 605.43	D_x = 2.824 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 2ybc	Cell parameters from 8121 reflections
a = 14.7217 (5) Å	θ = 2.4–28°
b = 13.7581 (5) Å	µ = 12.25 mm⁻¹
c = 10.5960 (4) Å	T = 298 K
β = 95.647 (1)°	Plate, yellow
V = 2135.73 (13) Å³	0.28 × 0.24 × 0.09 mm
Z = 6

Data collection top

Bruker SMART CCD diffractometer	5306 independent reflections
Radiation source: sealed tube	3532 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.161
ω scans	θ_max = 28.3°, θ_min = 2.0°
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	h = −19→19
T_min = 0.03, T_max = 0.30	k = −18→18
32252 measured reflections	l = −14→14

Refinement top

Refinement on F²	0 restraints
Least-squares matrix: full	Primary atom site location: structure-invariant direct methods
R[F² > 2σ(F²)] = 0.051	Secondary atom site location: difference Fourier map
wR(F²) = 0.149	w = 1/[σ²(F_o²) + (0.076P)² + 4.1862P] where P = (F_o² + 2F_c²)/3
S = 1.01	(Δ/σ)_max < 0.001
5306 reflections	Δρ_max = 2.22 e Å⁻³
340 parameters	Δρ_min = −1.58 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pb1	0.5000	0.5000	0.5000	0.05137 (16)
Pb2	0.51081 (2)	0.33516 (3)	0.15769 (3)	0.05254 (14)
S1	0.5479 (2)	0.64837 (18)	0.3139 (3)	0.0591 (6)
C1	0.6662 (7)	0.6580 (6)	0.3398 (9)	0.050 (2)
C2	0.7211 (9)	0.6009 (8)	0.2709 (10)	0.063 (3)
C3	0.8152 (10)	0.6078 (10)	0.2843 (12)	0.075 (3)
C4	0.8573 (8)	0.6744 (10)	0.3658 (13)	0.074 (3)
C5	0.8056 (8)	0.7317 (8)	0.4379 (10)	0.060 (2)
C6	0.7127 (8)	0.7239 (7)	0.4252 (9)	0.054 (2)
F2	0.6822 (6)	0.5361 (5)	0.1889 (7)	0.084 (2)
F3	0.8639 (6)	0.5513 (7)	0.2147 (8)	0.103 (3)
F4	0.9481 (5)	0.6837 (7)	0.3774 (9)	0.108 (3)
F5	0.8453 (6)	0.7980 (6)	0.5190 (7)	0.089 (2)
F6	0.6630 (4)	0.7838 (4)	0.4935 (5)	0.0630 (14)
S2	0.37825 (17)	0.38874 (16)	0.3029 (2)	0.0480 (5)
C7	0.2967 (6)	0.4544 (6)	0.2072 (7)	0.0437 (18)
C8	0.3179 (7)	0.5166 (6)	0.1106 (9)	0.050 (2)
C9	0.2523 (8)	0.5694 (7)	0.0385 (8)	0.053 (2)
C10	0.1621 (8)	0.5592 (8)	0.0598 (10)	0.063 (3)
C11	0.1372 (7)	0.4989 (8)	0.1537 (10)	0.060 (2)
C12	0.2045 (7)	0.4465 (7)	0.2246 (9)	0.053 (2)
F8	0.4050 (4)	0.5277 (5)	0.0852 (6)	0.0655 (15)
F9	0.2756 (5)	0.6314 (5)	−0.0517 (6)	0.0736 (18)
F10	0.0978 (5)	0.6118 (6)	−0.0091 (7)	0.091 (2)
F11	0.0496 (5)	0.4888 (7)	0.1736 (9)	0.094 (2)
F12	0.1785 (4)	0.3855 (5)	0.3135 (6)	0.0665 (15)
S3	0.59071 (16)	0.32156 (18)	0.3998 (2)	0.0525 (5)
C13	0.7067 (6)	0.3294 (6)	0.3796 (8)	0.0439 (17)
C14	0.7485 (7)	0.2704 (7)	0.2951 (8)	0.049 (2)
C15	0.8393 (7)	0.2720 (8)	0.2827 (9)	0.057 (2)
C16	0.8951 (7)	0.3338 (8)	0.3560 (10)	0.061 (2)
C17	0.8580 (7)	0.3956 (8)	0.4399 (10)	0.057 (2)
C18	0.7655 (8)	0.3925 (7)	0.4496 (9)	0.056 (2)
F14	0.6950 (4)	0.2074 (4)	0.2208 (5)	0.0623 (14)
F15	0.8759 (5)	0.2129 (6)	0.2004 (6)	0.0796 (19)
F16	0.9836 (4)	0.3380 (6)	0.3450 (7)	0.088 (2)
F17	0.9098 (5)	0.4585 (6)	0.5100 (8)	0.086 (2)
F18	0.7298 (5)	0.4535 (5)	0.5323 (6)	0.0686 (16)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pb1	0.0585 (3)	0.0437 (3)	0.0515 (3)	−0.0045 (2)	0.0035 (2)	0.00125 (19)
Pb2	0.0508 (2)	0.0550 (2)	0.0527 (2)	−0.00188 (15)	0.00916 (15)	0.00094 (15)
S1	0.0603 (15)	0.0485 (13)	0.0678 (15)	−0.0065 (10)	0.0039 (12)	0.0085 (10)
C1	0.057 (5)	0.042 (4)	0.052 (5)	0.005 (4)	0.013 (4)	0.009 (4)
C2	0.083 (8)	0.052 (5)	0.053 (5)	0.013 (5)	0.010 (5)	0.011 (4)
C3	0.081 (9)	0.078 (8)	0.068 (7)	0.029 (7)	0.022 (6)	0.019 (6)
C4	0.056 (6)	0.085 (8)	0.081 (8)	0.016 (6)	0.012 (6)	0.033 (7)
C5	0.058 (6)	0.062 (6)	0.056 (5)	−0.011 (5)	−0.010 (5)	0.014 (5)
C6	0.069 (6)	0.044 (5)	0.048 (5)	0.004 (4)	0.005 (4)	0.006 (4)
F2	0.112 (6)	0.066 (4)	0.074 (4)	0.008 (4)	0.019 (4)	−0.012 (3)
F3	0.106 (6)	0.112 (6)	0.099 (5)	0.048 (5)	0.045 (5)	0.017 (5)
F4	0.053 (4)	0.146 (8)	0.127 (7)	0.013 (4)	0.013 (4)	0.042 (6)
F5	0.088 (5)	0.085 (5)	0.089 (5)	−0.017 (4)	−0.020 (4)	0.011 (4)
F6	0.077 (4)	0.056 (3)	0.055 (3)	0.010 (3)	0.006 (3)	−0.002 (3)
S2	0.0559 (13)	0.0452 (11)	0.0424 (10)	0.0048 (9)	0.0021 (9)	−0.0006 (8)
C7	0.051 (5)	0.042 (4)	0.037 (4)	0.005 (4)	−0.001 (3)	−0.003 (3)
C8	0.061 (6)	0.042 (4)	0.047 (4)	−0.007 (4)	0.005 (4)	−0.003 (3)
C9	0.072 (7)	0.043 (5)	0.043 (4)	0.002 (4)	0.000 (4)	0.005 (4)
C10	0.075 (7)	0.056 (6)	0.055 (5)	0.014 (5)	−0.011 (5)	−0.006 (4)
C11	0.039 (5)	0.074 (7)	0.065 (6)	−0.003 (5)	−0.007 (4)	−0.011 (5)
C12	0.051 (5)	0.055 (5)	0.052 (5)	0.001 (4)	0.000 (4)	−0.004 (4)
F8	0.068 (4)	0.065 (3)	0.064 (3)	−0.010 (3)	0.012 (3)	0.014 (3)
F9	0.110 (6)	0.054 (3)	0.055 (3)	0.003 (3)	0.001 (3)	0.013 (3)
F10	0.088 (5)	0.085 (5)	0.093 (5)	0.027 (4)	−0.026 (4)	0.008 (4)
F11	0.055 (4)	0.113 (6)	0.113 (6)	0.002 (4)	0.002 (4)	0.013 (5)
F12	0.058 (4)	0.074 (4)	0.068 (3)	−0.008 (3)	0.011 (3)	0.013 (3)
S3	0.0453 (12)	0.0562 (13)	0.0559 (12)	−0.0013 (10)	0.0050 (10)	0.0027 (10)
C13	0.044 (4)	0.040 (4)	0.048 (4)	0.001 (4)	0.001 (3)	0.008 (3)
C14	0.055 (5)	0.047 (5)	0.044 (4)	0.003 (4)	0.000 (4)	0.005 (4)
C15	0.059 (6)	0.060 (6)	0.054 (5)	0.010 (5)	0.012 (5)	0.007 (4)
C16	0.048 (5)	0.071 (7)	0.064 (6)	−0.003 (5)	0.010 (5)	0.009 (5)
C17	0.053 (6)	0.055 (5)	0.059 (5)	−0.008 (4)	−0.003 (4)	0.004 (4)
C18	0.075 (7)	0.047 (5)	0.046 (5)	0.004 (5)	0.001 (4)	−0.001 (4)
F14	0.077 (4)	0.052 (3)	0.056 (3)	0.000 (3)	0.003 (3)	−0.009 (2)
F15	0.076 (4)	0.090 (5)	0.077 (4)	0.020 (4)	0.023 (3)	−0.010 (4)
F16	0.046 (4)	0.114 (7)	0.104 (6)	0.001 (4)	0.017 (4)	0.009 (4)
F17	0.069 (4)	0.086 (5)	0.099 (5)	−0.023 (4)	−0.006 (4)	−0.014 (4)
F18	0.076 (4)	0.063 (4)	0.067 (3)	0.004 (3)	0.006 (3)	−0.019 (3)

Geometric parameters (Å, º) top

Pb1—S1	2.971 (2)	C7—C12	1.392 (13)
Pb1—S1ⁱ	2.971 (2)	C7—C8	1.393 (12)
Pb1—S2	3.030 (2)	C8—F8	1.345 (11)
Pb1—S2ⁱ	3.030 (2)	C8—C9	1.377 (14)
Pb1—S3ⁱ	3.036 (2)	C9—F9	1.351 (11)
Pb1—S3	3.036 (2)	C9—C10	1.376 (16)
Pb2—S2	2.704 (2)	C10—F10	1.347 (12)
Pb2—S3	2.721 (2)	C10—C11	1.372 (16)
Pb2—S1ⁱⁱ	2.737 (3)	C11—F11	1.335 (12)
S1—C1	1.742 (11)	C11—C12	1.385 (14)
S1—Pb2ⁱⁱⁱ	2.737 (3)	C12—F12	1.344 (11)
C1—C2	1.385 (14)	S3—C13	1.746 (9)
C1—C6	1.409 (14)	C13—C18	1.389 (13)
C2—F2	1.334 (13)	C13—C14	1.394 (13)
C2—C3	1.382 (18)	C14—C15	1.356 (14)
C3—F3	1.328 (14)	C14—F14	1.367 (11)
C3—C4	1.37 (2)	C15—F15	1.344 (12)
C4—F4	1.337 (14)	C15—C16	1.369 (16)
C4—C5	1.378 (17)	C16—F16	1.321 (12)
C5—F5	1.347 (13)	C16—C17	1.381 (15)
C5—C6	1.365 (15)	C17—F17	1.331 (12)
C6—F6	1.357 (11)	C17—C18	1.375 (15)
S2—C7	1.746 (9)	C18—F18	1.356 (11)

S1—Pb1—S1ⁱ	180.0	Pb2—S2—Pb1	96.83 (8)
S1—Pb1—S2	93.01 (7)	C12—C7—C8	116.0 (8)
S1ⁱ—Pb1—S2	86.99 (7)	C12—C7—S2	120.4 (7)
S1—Pb1—S2ⁱ	86.99 (7)	C8—C7—S2	123.6 (7)
S1ⁱ—Pb1—S2ⁱ	93.01 (7)	F8—C8—C9	117.4 (8)
S2—Pb1—S2ⁱ	180.0	F8—C8—C7	120.3 (9)
S1—Pb1—S3ⁱ	79.50 (7)	C9—C8—C7	122.4 (9)
S1ⁱ—Pb1—S3ⁱ	100.50 (7)	F9—C9—C10	119.8 (9)
S2—Pb1—S3ⁱ	113.51 (6)	F9—C9—C8	120.8 (10)
S2ⁱ—Pb1—S3ⁱ	66.49 (6)	C10—C9—C8	119.4 (9)
S1—Pb1—S3	100.50 (7)	F10—C10—C11	119.6 (11)
S1ⁱ—Pb1—S3	79.50 (7)	F10—C10—C9	119.6 (10)
S2—Pb1—S3	66.49 (6)	C11—C10—C9	120.7 (9)
S2ⁱ—Pb1—S3	113.51 (6)	F11—C11—C10	120.6 (10)
S3ⁱ—Pb1—S3	180.0	F11—C11—C12	120.6 (10)
S2—Pb2—S3	75.61 (7)	C10—C11—C12	118.8 (10)
S2—Pb2—S1ⁱⁱ	86.56 (8)	F12—C12—C11	117.9 (9)
S3—Pb2—S1ⁱⁱ	86.77 (8)	F12—C12—C7	119.4 (8)
C1—S1—Pb2ⁱⁱⁱ	103.5 (3)	C11—C12—C7	122.7 (9)
C1—S1—Pb1	104.3 (3)	C13—S3—Pb2	102.6 (3)
Pb2ⁱⁱⁱ—S1—Pb1	118.29 (10)	C13—S3—Pb1	117.6 (3)
C2—C1—C6	115.6 (10)	Pb2—S3—Pb1	96.31 (7)
C2—C1—S1	120.0 (8)	C18—C13—C14	114.6 (9)
C6—C1—S1	124.4 (7)	C18—C13—S3	122.6 (7)
F2—C2—C3	118.4 (11)	C14—C13—S3	122.8 (7)
F2—C2—C1	119.2 (11)	C15—C14—F14	118.1 (9)
C3—C2—C1	122.5 (11)	C15—C14—C13	123.6 (9)
F3—C3—C4	120.5 (13)	F14—C14—C13	118.3 (8)
F3—C3—C2	119.5 (14)	F15—C15—C14	121.0 (10)
C4—C3—C2	119.9 (11)	F15—C15—C16	119.2 (10)
F4—C4—C3	120.7 (13)	C14—C15—C16	119.8 (9)
F4—C4—C5	119.7 (13)	F16—C16—C15	121.3 (10)
C3—C4—C5	119.6 (11)	F16—C16—C17	119.1 (10)
F5—C5—C6	119.0 (11)	C15—C16—C17	119.6 (10)
F5—C5—C4	120.8 (11)	F17—C17—C18	119.7 (10)
C6—C5—C4	120.2 (11)	F17—C17—C16	121.2 (10)
F6—C6—C5	119.1 (9)	C18—C17—C16	119.1 (9)
F6—C6—C1	118.7 (9)	F18—C18—C17	118.6 (9)
C5—C6—C1	122.1 (10)	F18—C18—C13	118.1 (10)
C7—S2—Pb2	107.7 (3)	C17—C18—C13	123.3 (9)
C7—S2—Pb1	117.7 (3)

S1ⁱ—Pb1—S1—C1	−173 (18)	C7—C8—C9—F9	177.8 (8)
S2—Pb1—S1—C1	−132.1 (3)	F8—C8—C9—C10	179.0 (8)
S2ⁱ—Pb1—S1—C1	47.9 (3)	C7—C8—C9—C10	−1.6 (14)
S3ⁱ—Pb1—S1—C1	114.5 (3)	F9—C9—C10—F10	−0.5 (14)
S3—Pb1—S1—C1	−65.5 (3)	C8—C9—C10—F10	178.9 (9)
S1ⁱ—Pb1—S1—Pb2ⁱⁱⁱ	73 (14)	F9—C9—C10—C11	−177.8 (9)
S2—Pb1—S1—Pb2ⁱⁱⁱ	113.71 (10)	C8—C9—C10—C11	1.6 (15)
S2ⁱ—Pb1—S1—Pb2ⁱⁱⁱ	−66.29 (10)	F10—C10—C11—F11	3.1 (16)
S3ⁱ—Pb1—S1—Pb2ⁱⁱⁱ	0.35 (10)	C9—C10—C11—F11	−179.6 (10)
S3—Pb1—S1—Pb2ⁱⁱⁱ	−179.65 (10)	F10—C10—C11—C12	−179.1 (9)
Pb2ⁱⁱⁱ—S1—C1—C2	−143.9 (7)	C9—C10—C11—C12	−1.8 (16)
Pb1—S1—C1—C2	91.8 (7)	F11—C11—C12—F12	−0.1 (15)
Pb2ⁱⁱⁱ—S1—C1—C6	33.7 (8)	C10—C11—C12—F12	−177.9 (9)
Pb1—S1—C1—C6	−90.6 (7)	F11—C11—C12—C7	179.8 (9)
C6—C1—C2—F2	179.4 (8)	C10—C11—C12—C7	2.0 (15)
S1—C1—C2—F2	−2.7 (12)	C8—C7—C12—F12	178.0 (8)
C6—C1—C2—C3	−0.1 (14)	S2—C7—C12—F12	−1.9 (12)
S1—C1—C2—C3	177.7 (8)	C8—C7—C12—C11	−1.9 (13)
F2—C2—C3—F3	0.9 (15)	S2—C7—C12—C11	178.2 (8)
C1—C2—C3—F3	−179.6 (9)	S2—Pb2—S3—C13	−158.1 (3)
F2—C2—C3—C4	178.9 (10)	S1ⁱⁱ—Pb2—S3—C13	114.7 (3)
C1—C2—C3—C4	−1.5 (16)	S2—Pb2—S3—Pb1	−37.95 (6)
F3—C3—C4—F4	−0.1 (17)	S1ⁱⁱ—Pb2—S3—Pb1	−125.23 (8)
C2—C3—C4—F4	−178.2 (10)	S1—Pb1—S3—C13	54.4 (3)
F3—C3—C4—C5	−179.5 (10)	S1ⁱ—Pb1—S3—C13	−125.6 (3)
C2—C3—C4—C5	2.5 (17)	S2—Pb1—S3—C13	143.2 (3)
F4—C4—C5—F5	0.7 (15)	S2ⁱ—Pb1—S3—C13	−36.8 (3)
C3—C4—C5—F5	−180.0 (10)	S3ⁱ—Pb1—S3—C13	−102 (39)
F4—C4—C5—C6	178.9 (9)	S1—Pb1—S3—Pb2	−53.29 (8)
C3—C4—C5—C6	−1.8 (16)	S1ⁱ—Pb1—S3—Pb2	126.71 (8)
F5—C5—C6—F6	0.8 (13)	S2—Pb1—S3—Pb2	35.43 (6)
C4—C5—C6—F6	−177.4 (9)	S2ⁱ—Pb1—S3—Pb2	−144.57 (6)
F5—C5—C6—C1	178.3 (8)	S3ⁱ—Pb1—S3—Pb2	151 (39)
C4—C5—C6—C1	0.1 (15)	Pb2—S3—C13—C18	130.3 (7)
C2—C1—C6—F6	178.4 (8)	Pb1—S3—C13—C18	26.3 (8)
S1—C1—C6—F6	0.6 (12)	Pb2—S3—C13—C14	−51.9 (7)
C2—C1—C6—C5	0.8 (13)	Pb1—S3—C13—C14	−156.0 (6)
S1—C1—C6—C5	−176.9 (7)	C18—C13—C14—C15	1.4 (13)
S3—Pb2—S2—C7	160.1 (3)	S3—C13—C14—C15	−176.5 (7)
S1ⁱⁱ—Pb2—S2—C7	−112.4 (3)	C18—C13—C14—F14	−178.8 (8)
S3—Pb2—S2—Pb1	38.09 (7)	S3—C13—C14—F14	3.3 (11)
S1ⁱⁱ—Pb2—S2—Pb1	125.62 (7)	F14—C14—C15—F15	−0.4 (13)
S1—Pb1—S2—C7	−49.7 (3)	C13—C14—C15—F15	179.4 (8)
S1ⁱ—Pb1—S2—C7	130.3 (3)	F14—C14—C15—C16	−179.7 (9)
S2ⁱ—Pb1—S2—C7	50 (9)	C13—C14—C15—C16	0.2 (15)
S3ⁱ—Pb1—S2—C7	30.1 (4)	F15—C15—C16—F16	1.6 (15)
S3—Pb1—S2—C7	−149.9 (4)	C14—C15—C16—F16	−179.1 (9)
S1—Pb1—S2—Pb2	64.41 (8)	F15—C15—C16—C17	179.3 (9)
S1ⁱ—Pb1—S2—Pb2	−115.59 (8)	C14—C15—C16—C17	−1.4 (15)
S2ⁱ—Pb1—S2—Pb2	165 (9)	F16—C16—C17—F17	−0.5 (15)
S3ⁱ—Pb1—S2—Pb2	144.27 (6)	C15—C16—C17—F17	−178.1 (10)
S3—Pb1—S2—Pb2	−35.73 (6)	F16—C16—C17—C18	178.8 (9)
Pb2—S2—C7—C12	144.4 (7)	C15—C16—C17—C18	1.1 (15)
Pb1—S2—C7—C12	−107.6 (7)	F17—C17—C18—F18	−0.8 (14)
Pb2—S2—C7—C8	−35.5 (8)	C16—C17—C18—F18	179.9 (9)
Pb1—S2—C7—C8	72.5 (8)	F17—C17—C18—C13	179.8 (9)
C12—C7—C8—F8	−178.8 (8)	C16—C17—C18—C13	0.5 (15)
S2—C7—C8—F8	1.1 (12)	C14—C13—C18—F18	178.9 (8)
C12—C7—C8—C9	1.7 (13)	S3—C13—C18—F18	−3.2 (12)
S2—C7—C8—C9	−178.4 (7)	C14—C13—C18—C17	−1.7 (13)
F8—C8—C9—F9	−1.6 (13)	S3—C13—C18—C17	176.2 (8)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, y−1/2, −z+1/2; (iii) −x+1, y+1/2, −z+1/2.

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

Poly[bis­(μ-penta­fluoro­benzene­thiol­ato)lead(II)]

Supporting information

Key indicators

checkCIF/PLATON results

Poly[bis(μ-pentafluorobenzenethiolato)lead(II)]