(p-Toluene­sulfonato)tris­(triphenyl­arsine)silver(I)

In the title monomeric compound, [Ag(C₇H₇O₃S)(C₁₈H₁₅As)₃], the Ag atom is coordinated by three arsine ligands and one O atom, forming a distorted tetra­hedral configuration. The Ag-As bond distances are 2.5765 (9), 2.6025 (3) and 2.6071 (3) Å, and the Ag-O bond distance is 2.4070 (14) Å.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.024
• wR factor = 0.065
• Data-to-parameter ratio = 20.6

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       4.03 Ratio
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Ag     -   As1     ..      12.94 su
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Ag     -   As2     ..      20.77 su
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Ag     -   As3     ..      26.25 su

Alert level C
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.74 Ratio

   0 ALERT level A = In general: serious problem
   4 ALERT level B = Potentially serious problem
   1 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: SHELXTL (Bruker 2004).

(p-Toluenesulfonato)tris(triphenylarsine)silver(I)

Crystal data

[Ag(C7H7O3S)(C18H15As)3]	Z = 2
Mr = 1197.72	F(000) = 1208
Triclinic, P1	Dx = 1.545 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 13.1327 (8) Å	Cell parameters from 8130 reflections
b = 13.8625 (7) Å	θ = 2.9–28.3°
c = 14.3603 (8) Å	µ = 2.39 mm^−1
α = 87.473 (2)°	T = 100 K
β = 81.202 (2)°	Plate, colourless
γ = 85.870 (2)°	0.29 × 0.25 × 0.11 mm
V = 2575.4 (2) Å^3

Data collection

Bruker X8 APEXII 4K KappaCCD area-detector diffractometer	12804 independent reflections
Radiation source: fine-focus sealed tube	11099 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.028
Detector resolution: 0 pixels mm^-1	θmax = 28.3°, θmin = 1.5°
φ and ω scans	h = −17→17
Absorption correction: multi-scan (SADABS; Bruker, 2004)	k = −18→18
Tmin = 0.539, Tmax = 0.771	l = −19→19
38157 measured reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.024	w = 1/[σ^2(Fo^2) + (0.0316P)^2 + 0.5342P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.066	(Δ/σ)max = 0.002
S = 1.09	Δρmax = 0.48 e Å^−3
12804 reflections	Δρmin = −0.39 e Å^−3
623 parameters

Special details

Experimental. The intensity data were collected on a Bruker X8 Apex II 4 K Kappa CCD diffractometer using an exposure time of 10 s/frame. A total of 1407 frames were collected with a frame width of 0.5° covering up to θ = 28.31° with 99.8% completeness accomplished.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ag	0.249754 (11)	0.704263 (9)	0.209858 (10)	0.01332 (4)
As1	0.253726 (15)	0.526319 (13)	0.269888 (13)	0.01339 (5)
As2	0.199292 (16)	0.735434 (13)	0.041933 (13)	0.01400 (5)
As3	0.152252 (16)	0.823665 (13)	0.333139 (14)	0.01462 (5)
S	0.49951 (4)	0.74231 (3)	0.21563 (3)	0.01623 (10)
O1	0.42598 (11)	0.73519 (10)	0.14907 (10)	0.0190 (3)
O2	0.47585 (13)	0.68055 (10)	0.29922 (11)	0.0261 (3)
O3	0.60606 (11)	0.73258 (11)	0.17055 (12)	0.0274 (4)
C1	0.47906 (15)	0.86298 (13)	0.25489 (14)	0.0171 (4)
C2	0.40917 (16)	0.92799 (14)	0.21880 (15)	0.0198 (4)
H2	0.3729	0.9091	0.1709	0.024*
C3	0.39215 (17)	1.02072 (15)	0.25251 (18)	0.0275 (5)
H3	0.3441	1.0651	0.2273	0.033*
C4	0.44373 (19)	1.04965 (16)	0.3220 (2)	0.0344 (6)
C5	0.5148 (2)	0.98447 (18)	0.3567 (2)	0.0401 (7)
H5	0.5518	1.0039	0.4039	0.048*
C6	0.53299 (19)	0.89123 (16)	0.32365 (17)	0.0292 (5)
H6	0.582	0.8472	0.348	0.035*
C7	0.4229 (2)	1.15133 (18)	0.3581 (3)	0.0576 (9)
H7A	0.4759	1.1926	0.326	0.086*
H7B	0.4245	1.1498	0.4261	0.086*
H7C	0.3548	1.1773	0.3455	0.086*
C11	0.32397 (15)	0.43015 (13)	0.18465 (13)	0.0143 (4)
C12	0.28817 (16)	0.33852 (14)	0.18210 (14)	0.0197 (4)
H12	0.2284	0.3214	0.2239	0.024*
C13	0.33912 (17)	0.27182 (15)	0.11880 (15)	0.0228 (4)
H13	0.3138	0.2096	0.1169	0.027*
C14	0.42634 (17)	0.29591 (15)	0.05893 (14)	0.0227 (4)
H14	0.4607	0.2506	0.015	0.027*
C15	0.46401 (18)	0.38585 (16)	0.06258 (16)	0.0262 (5)
H15	0.5252	0.4017	0.0222	0.031*
C16	0.41284 (17)	0.45341 (15)	0.12503 (15)	0.0227 (4)
H16	0.4387	0.5154	0.1269	0.027*
C21	0.30916 (15)	0.48749 (13)	0.38456 (13)	0.0144 (4)
C22	0.27659 (18)	0.53910 (15)	0.46530 (15)	0.0242 (5)
H22	0.2266	0.5921	0.4643	0.029*
C23	0.31653 (19)	0.51382 (17)	0.54767 (16)	0.0291 (5)
H23	0.2931	0.5491	0.603	0.035*
C24	0.39027 (17)	0.43762 (15)	0.54992 (15)	0.0222 (4)
H24	0.4177	0.4204	0.6063	0.027*
C25	0.42333 (18)	0.38710 (15)	0.46905 (15)	0.0247 (5)
H25	0.4743	0.335	0.4697	0.03*
C26	0.38317 (18)	0.41143 (14)	0.38719 (15)	0.0226 (5)
H26	0.4065	0.3757	0.3321	0.027*
C31	0.11704 (15)	0.47616 (13)	0.29217 (14)	0.0153 (4)
C32	0.08555 (16)	0.41223 (14)	0.36715 (14)	0.0193 (4)
H32	0.1296	0.3949	0.4127	0.023*
C33	−0.01059 (18)	0.37410 (16)	0.37481 (17)	0.0272 (5)
H33	−0.032	0.3303	0.4256	0.033*
C34	−0.07527 (17)	0.39958 (16)	0.30890 (17)	0.0293 (5)
H34	−0.1402	0.3722	0.3138	0.035*
C35	−0.04543 (17)	0.46509 (16)	0.23572 (17)	0.0273 (5)
H35	−0.0904	0.4838	0.1913	0.033*
C36	0.05037 (17)	0.50307 (14)	0.22781 (15)	0.0209 (4)
H36	0.0707	0.5481	0.1778	0.025*
C41	0.26063 (16)	0.65443 (13)	−0.06187 (13)	0.0163 (4)
C42	0.26745 (17)	0.55476 (14)	−0.04558 (15)	0.0212 (4)
H42	0.2394	0.5278	0.014	0.025*
C43	0.31522 (18)	0.49455 (15)	−0.11633 (16)	0.0255 (5)
H43	0.3206	0.4265	−0.1047	0.031*
C44	0.35485 (19)	0.53295 (16)	−0.20335 (15)	0.0275 (5)
H44	0.3879	0.4915	−0.2515	0.033*
C45	0.34633 (19)	0.63216 (16)	−0.22052 (15)	0.0268 (5)
H45	0.3725	0.6586	−0.2809	0.032*
C46	0.29962 (18)	0.69308 (15)	−0.14970 (15)	0.0229 (5)
H46	0.2944	0.7611	−0.1615	0.028*
C51	0.22369 (16)	0.86270 (13)	−0.01603 (14)	0.0169 (4)
C52	0.32159 (17)	0.89563 (14)	−0.01807 (15)	0.0219 (4)
H52	0.3723	0.8573	0.01	0.026*
C53	0.34517 (18)	0.98436 (15)	−0.06104 (17)	0.0290 (5)
H53	0.4123	1.0064	−0.0628	0.035*
C54	0.2716 (2)	1.04103 (16)	−0.10135 (19)	0.0347 (6)
H54	0.2879	1.102	−0.1305	0.042*
C55	0.1741 (2)	1.00871 (17)	−0.0991 (2)	0.0385 (6)
H55	0.1235	1.0477	−0.1268	0.046*
C56	0.14955 (19)	0.91931 (15)	−0.05653 (17)	0.0291 (5)
H56	0.0825	0.8973	−0.0553	0.035*
C61	0.05311 (16)	0.72451 (13)	0.04043 (14)	0.0158 (4)
C62	−0.01491 (17)	0.74506 (14)	0.12257 (14)	0.0207 (4)
H62	0.011	0.7649	0.1764	0.025*
C63	−0.11984 (18)	0.73687 (15)	0.12643 (16)	0.0253 (5)
H63	−0.1656	0.7513	0.1827	0.03*
C64	−0.15818 (17)	0.70767 (15)	0.04864 (16)	0.0243 (5)
H64	−0.2303	0.7033	0.0507	0.029*
C65	−0.09040 (18)	0.68477 (16)	−0.03253 (16)	0.0266 (5)
H65	−0.1164	0.6629	−0.0855	0.032*
C66	0.01474 (17)	0.69346 (15)	−0.03710 (15)	0.0226 (4)
H66	0.0604	0.6782	−0.0932	0.027*
C71	0.19412 (16)	0.82757 (13)	0.45646 (14)	0.0164 (4)
C72	0.12585 (17)	0.85718 (15)	0.53557 (14)	0.0214 (4)
H72	0.0551	0.8723	0.5308	0.026*
C73	0.16050 (18)	0.86476 (15)	0.62135 (15)	0.0239 (5)
H73	0.1134	0.8842	0.6753	0.029*
C74	0.2633 (2)	0.84410 (16)	0.62812 (16)	0.0296 (5)
H74	0.2877	0.8507	0.6863	0.036*
C75	0.3311 (2)	0.8137 (2)	0.54977 (18)	0.0383 (6)
H75	0.402	0.7993	0.5546	0.046*
C76	0.29678 (18)	0.80402 (16)	0.46456 (16)	0.0263 (5)
H76	0.3435	0.7813	0.4117	0.032*
C81	0.00657 (16)	0.79982 (13)	0.36716 (13)	0.0166 (4)
C82	−0.02103 (17)	0.70452 (14)	0.37875 (14)	0.0205 (4)
H82	0.0313	0.6532	0.3722	0.025*
C83	−0.12318 (18)	0.68361 (15)	0.39954 (15)	0.0249 (5)
H83	−0.1407	0.6181	0.4068	0.03*
C84	−0.20044 (18)	0.75743 (17)	0.40989 (17)	0.0291 (5)
H84	−0.2708	0.743	0.4243	0.035*
C85	−0.17384 (18)	0.85301 (17)	0.39887 (19)	0.0339 (6)
H85	−0.2263	0.9041	0.4061	0.041*
C86	−0.07107 (17)	0.87412 (15)	0.37742 (17)	0.0265 (5)
H86	−0.0536	0.9396	0.3697	0.032*
C91	0.13918 (15)	0.96044 (13)	0.29733 (14)	0.0171 (4)
C92	0.12371 (16)	0.98448 (14)	0.20535 (15)	0.0208 (4)
H92	0.1241	0.9349	0.1617	0.025*
C93	0.10768 (17)	1.08086 (15)	0.17688 (16)	0.0245 (5)
H93	0.097	1.0971	0.114	0.029*
C94	0.10734 (17)	1.15300 (14)	0.24041 (17)	0.0251 (5)
H94	0.0946	1.2188	0.2215	0.03*
C95	0.12549 (17)	1.12977 (14)	0.33143 (16)	0.0231 (5)
H95	0.1269	1.1797	0.3744	0.028*
C96	0.14168 (16)	1.03356 (14)	0.36020 (15)	0.0202 (4)
H96	0.1544	1.0177	0.4226	0.024*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag	0.01364 (8)	0.01168 (7)	0.01428 (7)	−0.00001 (5)	−0.00133 (5)	−0.00038 (5)
As1	0.01429 (10)	0.01096 (9)	0.01488 (10)	−0.00051 (7)	−0.00261 (8)	0.00087 (7)
As2	0.01640 (11)	0.01292 (9)	0.01224 (9)	0.00088 (7)	−0.00181 (8)	0.00039 (7)
As3	0.01470 (10)	0.01252 (9)	0.01555 (10)	0.00016 (7)	0.00146 (8)	−0.00321 (7)
S	0.0129 (2)	0.0146 (2)	0.0205 (2)	0.00121 (18)	−0.00043 (19)	−0.00349 (18)
O1	0.0152 (7)	0.0222 (7)	0.0193 (7)	−0.0026 (6)	−0.0002 (6)	−0.0046 (6)
O2	0.0337 (9)	0.0180 (7)	0.0258 (8)	0.0003 (6)	−0.0041 (7)	0.0015 (6)
O3	0.0124 (8)	0.0294 (8)	0.0396 (9)	0.0010 (6)	0.0012 (7)	−0.0142 (7)
C1	0.0142 (10)	0.0140 (9)	0.0224 (10)	−0.0006 (7)	0.0007 (8)	−0.0033 (7)
C2	0.0143 (10)	0.0197 (10)	0.0256 (11)	−0.0013 (8)	−0.0031 (8)	−0.0010 (8)
C3	0.0188 (12)	0.0164 (10)	0.0468 (14)	0.0005 (8)	−0.0034 (10)	−0.0018 (9)
C4	0.0268 (13)	0.0216 (11)	0.0558 (17)	−0.0003 (9)	−0.0066 (12)	−0.0147 (11)
C5	0.0436 (16)	0.0302 (13)	0.0525 (17)	−0.0011 (11)	−0.0223 (13)	−0.0178 (12)
C6	0.0293 (13)	0.0222 (11)	0.0394 (14)	0.0041 (9)	−0.0167 (11)	−0.0075 (9)
C7	0.0481 (19)	0.0291 (14)	0.102 (3)	0.0068 (13)	−0.0264 (18)	−0.0345 (16)
C11	0.0141 (10)	0.0160 (9)	0.0127 (9)	0.0014 (7)	−0.0032 (7)	−0.0001 (7)
C12	0.0178 (11)	0.0228 (10)	0.0179 (10)	−0.0053 (8)	0.0019 (8)	−0.0029 (8)
C13	0.0239 (12)	0.0218 (10)	0.0228 (11)	−0.0022 (9)	−0.0018 (9)	−0.0073 (8)
C14	0.0218 (11)	0.0293 (11)	0.0152 (10)	0.0086 (9)	−0.0013 (8)	−0.0033 (8)
C15	0.0199 (12)	0.0288 (11)	0.0254 (11)	0.0026 (9)	0.0072 (9)	0.0046 (9)
C16	0.0179 (11)	0.0201 (10)	0.0286 (11)	−0.0005 (8)	−0.0001 (9)	0.0036 (8)
C21	0.0152 (10)	0.0129 (8)	0.0155 (9)	−0.0029 (7)	−0.0033 (8)	0.0008 (7)
C22	0.0231 (12)	0.0257 (11)	0.0241 (11)	0.0092 (9)	−0.0064 (9)	−0.0108 (9)
C23	0.0280 (13)	0.0381 (13)	0.0221 (11)	0.0077 (10)	−0.0075 (10)	−0.0131 (9)
C24	0.0257 (12)	0.0241 (10)	0.0187 (10)	−0.0031 (9)	−0.0088 (9)	−0.0013 (8)
C25	0.0311 (13)	0.0189 (10)	0.0251 (11)	0.0074 (9)	−0.0113 (10)	−0.0031 (8)
C26	0.0299 (13)	0.0188 (10)	0.0189 (10)	0.0061 (9)	−0.0061 (9)	−0.0042 (8)
C31	0.0134 (10)	0.0128 (8)	0.0187 (9)	0.0007 (7)	0.0017 (8)	−0.0051 (7)
C32	0.0183 (11)	0.0195 (10)	0.0192 (10)	−0.0008 (8)	−0.0008 (8)	0.0000 (8)
C33	0.0225 (12)	0.0256 (11)	0.0310 (12)	−0.0064 (9)	0.0067 (10)	−0.0019 (9)
C34	0.0133 (11)	0.0310 (12)	0.0429 (14)	−0.0035 (9)	0.0027 (10)	−0.0144 (10)
C35	0.0175 (11)	0.0350 (12)	0.0308 (12)	0.0054 (9)	−0.0082 (9)	−0.0127 (10)
C36	0.0219 (11)	0.0204 (10)	0.0210 (10)	0.0025 (8)	−0.0061 (9)	−0.0029 (8)
C41	0.0180 (10)	0.0163 (9)	0.0148 (9)	0.0013 (7)	−0.0038 (8)	−0.0012 (7)
C42	0.0230 (11)	0.0177 (10)	0.0221 (10)	−0.0005 (8)	−0.0013 (9)	0.0000 (8)
C43	0.0293 (13)	0.0159 (10)	0.0313 (12)	0.0019 (9)	−0.0050 (10)	−0.0042 (8)
C44	0.0306 (13)	0.0295 (11)	0.0224 (11)	0.0056 (10)	−0.0048 (10)	−0.0110 (9)
C45	0.0338 (14)	0.0292 (11)	0.0155 (10)	0.0034 (10)	0.0004 (9)	−0.0031 (8)
C46	0.0309 (13)	0.0180 (10)	0.0184 (10)	0.0036 (9)	−0.0016 (9)	0.0001 (8)
C51	0.0199 (11)	0.0135 (9)	0.0164 (9)	0.0001 (8)	0.0001 (8)	−0.0001 (7)
C52	0.0193 (11)	0.0202 (10)	0.0248 (11)	0.0028 (8)	−0.0012 (9)	0.0007 (8)
C53	0.0234 (12)	0.0229 (11)	0.0382 (13)	−0.0056 (9)	0.0041 (10)	0.0035 (9)
C54	0.0327 (14)	0.0214 (11)	0.0466 (15)	−0.0037 (10)	0.0018 (12)	0.0119 (10)
C55	0.0329 (15)	0.0230 (12)	0.0596 (18)	0.0008 (10)	−0.0143 (13)	0.0198 (11)
C56	0.0243 (12)	0.0200 (10)	0.0431 (14)	−0.0036 (9)	−0.0080 (11)	0.0097 (9)
C61	0.0169 (10)	0.0123 (8)	0.0180 (10)	−0.0016 (7)	−0.0024 (8)	0.0030 (7)
C62	0.0236 (12)	0.0210 (10)	0.0169 (10)	0.0026 (8)	−0.0030 (8)	−0.0004 (8)
C63	0.0226 (12)	0.0279 (11)	0.0218 (11)	0.0039 (9)	0.0038 (9)	0.0037 (8)
C64	0.0191 (11)	0.0230 (10)	0.0302 (12)	−0.0042 (9)	−0.0027 (9)	0.0061 (9)
C65	0.0244 (12)	0.0301 (11)	0.0271 (12)	−0.0063 (9)	−0.0065 (10)	−0.0031 (9)
C66	0.0223 (12)	0.0278 (11)	0.0174 (10)	−0.0033 (9)	−0.0010 (9)	−0.0012 (8)
C71	0.0198 (11)	0.0122 (8)	0.0168 (9)	−0.0017 (7)	−0.0008 (8)	−0.0013 (7)
C72	0.0186 (11)	0.0240 (10)	0.0205 (10)	−0.0016 (8)	0.0017 (8)	−0.0043 (8)
C73	0.0295 (13)	0.0223 (10)	0.0182 (10)	−0.0034 (9)	0.0031 (9)	−0.0014 (8)
C74	0.0377 (15)	0.0320 (12)	0.0200 (11)	0.0038 (10)	−0.0100 (10)	−0.0005 (9)
C75	0.0261 (14)	0.0561 (16)	0.0323 (14)	0.0146 (12)	−0.0095 (11)	−0.0070 (12)
C76	0.0212 (12)	0.0331 (12)	0.0223 (11)	0.0087 (9)	−0.0001 (9)	−0.0041 (9)
C81	0.0163 (10)	0.0185 (9)	0.0148 (9)	−0.0032 (8)	0.0002 (8)	−0.0042 (7)
C82	0.0247 (12)	0.0186 (10)	0.0177 (10)	−0.0023 (8)	−0.0011 (9)	−0.0009 (8)
C83	0.0305 (13)	0.0243 (11)	0.0204 (11)	−0.0118 (9)	−0.0007 (9)	0.0012 (8)
C84	0.0194 (12)	0.0357 (12)	0.0316 (13)	−0.0097 (10)	0.0015 (10)	0.0000 (10)
C85	0.0176 (12)	0.0307 (12)	0.0514 (16)	−0.0002 (10)	0.0019 (11)	−0.0051 (11)
C86	0.0208 (12)	0.0187 (10)	0.0382 (13)	−0.0022 (8)	0.0021 (10)	−0.0040 (9)
C91	0.0128 (10)	0.0140 (9)	0.0229 (10)	−0.0009 (7)	0.0031 (8)	−0.0019 (7)
C92	0.0191 (11)	0.0177 (9)	0.0251 (11)	−0.0013 (8)	−0.0009 (9)	−0.0029 (8)
C93	0.0210 (12)	0.0234 (10)	0.0297 (12)	−0.0030 (9)	−0.0064 (9)	0.0050 (9)
C94	0.0168 (11)	0.0148 (9)	0.0422 (14)	−0.0009 (8)	−0.0009 (10)	0.0038 (9)
C95	0.0194 (11)	0.0143 (9)	0.0341 (12)	−0.0023 (8)	0.0020 (9)	−0.0049 (8)
C96	0.0193 (11)	0.0176 (9)	0.0224 (10)	−0.0013 (8)	0.0024 (8)	−0.0043 (8)

Geometric parameters (Å, º)

Ag—O1	2.4070 (14)	C41—C42	1.390 (3)
Ag—As1	2.5765 (3)	C42—C43	1.388 (3)
Ag—As3	2.6025 (3)	C42—H42	0.95
Ag—As2	2.6071 (3)	C43—C44	1.378 (3)
As1—C11	1.9360 (18)	C43—H43	0.95
As1—C21	1.9400 (19)	C44—C45	1.386 (3)
As1—C31	1.9474 (19)	C44—H44	0.95
As2—C61	1.940 (2)	C45—C46	1.391 (3)
As2—C51	1.9437 (19)	C45—H45	0.95
As2—C41	1.9447 (19)	C46—H46	0.95
As3—C71	1.937 (2)	C51—C56	1.388 (3)
As3—C91	1.9450 (19)	C51—C52	1.391 (3)
As3—C81	1.949 (2)	C52—C53	1.385 (3)
S—O3	1.4487 (15)	C52—H52	0.95
S—O2	1.4506 (16)	C53—C54	1.382 (3)
S—O1	1.4698 (15)	C53—H53	0.95
S—C1	1.7777 (18)	C54—C55	1.381 (3)
C1—C2	1.381 (3)	C54—H54	0.95
C1—C6	1.385 (3)	C55—C56	1.394 (3)
C2—C3	1.385 (3)	C55—H55	0.95
C2—H2	0.95	C56—H56	0.95
C3—C4	1.377 (3)	C61—C66	1.387 (3)
C3—H3	0.95	C61—C62	1.393 (3)
C4—C5	1.385 (4)	C62—C63	1.383 (3)
C4—C7	1.515 (3)	C62—H62	0.95
C5—C6	1.388 (3)	C63—C64	1.381 (3)
C5—H5	0.95	C63—H63	0.95
C6—H6	0.95	C64—C65	1.388 (3)
C7—H7A	0.98	C64—H64	0.95
C7—H7B	0.98	C65—C66	1.386 (3)
C7—H7C	0.98	C65—H65	0.95
C11—C16	1.387 (3)	C66—H66	0.95
C11—C12	1.390 (3)	C71—C76	1.385 (3)
C12—C13	1.388 (3)	C71—C72	1.393 (3)
C12—H12	0.95	C72—C73	1.388 (3)
C13—C14	1.375 (3)	C72—H72	0.95
C13—H13	0.95	C73—C74	1.377 (3)
C14—C15	1.380 (3)	C73—H73	0.95
C14—H14	0.95	C74—C75	1.385 (3)
C15—C16	1.390 (3)	C74—H74	0.95
C15—H15	0.95	C75—C76	1.382 (3)
C16—H16	0.95	C75—H75	0.95
C21—C22	1.384 (3)	C76—H76	0.95
C21—C26	1.385 (3)	C81—C82	1.391 (3)
C22—C23	1.387 (3)	C81—C86	1.392 (3)
C22—H22	0.95	C82—C83	1.378 (3)
C23—C24	1.383 (3)	C82—H82	0.95
C23—H23	0.95	C83—C84	1.384 (3)
C24—C25	1.379 (3)	C83—H83	0.95
C24—H24	0.95	C84—C85	1.391 (3)
C25—C26	1.379 (3)	C84—H84	0.95
C25—H25	0.95	C85—C86	1.387 (3)
C26—H26	0.95	C85—H85	0.95
C31—C36	1.389 (3)	C86—H86	0.95
C31—C32	1.396 (3)	C91—C92	1.389 (3)
C32—C33	1.391 (3)	C91—C96	1.392 (3)
C32—H32	0.95	C92—C93	1.391 (3)
C33—C34	1.384 (3)	C92—H92	0.95
C33—H33	0.95	C93—C94	1.382 (3)
C34—C35	1.387 (3)	C93—H93	0.95
C34—H34	0.95	C94—C95	1.384 (3)
C35—C36	1.385 (3)	C94—H94	0.95
C35—H35	0.95	C95—C96	1.390 (3)
C36—H36	0.95	C95—H95	0.95
C41—C46	1.386 (3)	C96—H96	0.95
O1—Ag—As1	105.81 (3)	C46—C41—C42	119.66 (18)
O1—Ag—As3	116.50 (3)	C46—C41—As2	122.17 (14)
As1—Ag—As3	113.505 (9)	C42—C41—As2	118.15 (15)
O1—Ag—As2	90.17 (3)	C43—C42—C41	120.0 (2)
As1—Ag—As2	115.463 (8)	C43—C42—H42	120
As3—Ag—As2	113.207 (9)	C41—C42—H42	120
C11—As1—C21	100.80 (8)	C44—C43—C42	120.34 (19)
C11—As1—C31	99.07 (8)	C44—C43—H43	119.8
C21—As1—C31	102.96 (8)	C42—C43—H43	119.8
C11—As1—Ag	117.55 (6)	C43—C44—C45	119.81 (19)
C21—As1—Ag	120.85 (5)	C43—C44—H44	120.1
C31—As1—Ag	112.48 (6)	C45—C44—H44	120.1
C61—As2—C51	103.25 (8)	C44—C45—C46	120.2 (2)
C61—As2—C41	101.49 (8)	C44—C45—H45	119.9
C51—As2—C41	100.00 (8)	C46—C45—H45	119.9
C61—As2—Ag	112.46 (6)	C41—C46—C45	119.93 (19)
C51—As2—Ag	116.31 (6)	C41—C46—H46	120
C41—As2—Ag	120.84 (6)	C45—C46—H46	120
C71—As3—C91	101.81 (8)	C56—C51—C52	119.78 (19)
C71—As3—C81	101.10 (8)	C56—C51—As2	123.09 (16)
C91—As3—C81	99.42 (8)	C52—C51—As2	117.10 (15)
C71—As3—Ag	119.95 (6)	C53—C52—C51	120.1 (2)
C91—As3—Ag	118.52 (6)	C53—C52—H52	120
C81—As3—Ag	112.80 (5)	C51—C52—H52	120
O3—S—O2	114.59 (10)	C54—C53—C52	120.4 (2)
O3—S—O1	112.66 (9)	C54—C53—H53	119.8
O2—S—O1	112.10 (9)	C52—C53—H53	119.8
O3—S—C1	105.75 (9)	C55—C54—C53	119.7 (2)
O2—S—C1	105.79 (9)	C55—C54—H54	120.1
O1—S—C1	105.00 (9)	C53—C54—H54	120.1
S—O1—Ag	118.95 (8)	C54—C55—C56	120.5 (2)
C2—C1—C6	119.88 (18)	C54—C55—H55	119.8
C2—C1—S	120.87 (16)	C56—C55—H55	119.8
C6—C1—S	119.24 (16)	C51—C56—C55	119.6 (2)
C1—C2—C3	119.9 (2)	C51—C56—H56	120.2
C1—C2—H2	120.1	C55—C56—H56	120.2
C3—C2—H2	120.1	C66—C61—C62	119.23 (19)
C4—C3—C2	121.1 (2)	C66—C61—As2	122.81 (15)
C4—C3—H3	119.5	C62—C61—As2	117.90 (15)
C2—C3—H3	119.5	C63—C62—C61	120.6 (2)
C3—C4—C5	118.6 (2)	C63—C62—H62	119.7
C3—C4—C7	119.9 (2)	C61—C62—H62	119.7
C5—C4—C7	121.5 (2)	C64—C63—C62	120.1 (2)
C4—C5—C6	121.1 (2)	C64—C63—H63	119.9
C4—C5—H5	119.5	C62—C63—H63	119.9
C6—C5—H5	119.5	C63—C64—C65	119.4 (2)
C1—C6—C5	119.4 (2)	C63—C64—H64	120.3
C1—C6—H6	120.3	C65—C64—H64	120.3
C5—C6—H6	120.3	C66—C65—C64	120.7 (2)
C4—C7—H7A	109.5	C66—C65—H65	119.6
C4—C7—H7B	109.5	C64—C65—H65	119.6
H7A—C7—H7B	109.5	C65—C66—C61	119.8 (2)
C4—C7—H7C	109.5	C65—C66—H66	120.1
H7A—C7—H7C	109.5	C61—C66—H66	120.1
H7B—C7—H7C	109.5	C76—C71—C72	119.35 (19)
C16—C11—C12	119.27 (18)	C76—C71—As3	118.29 (15)
C16—C11—As1	118.90 (14)	C72—C71—As3	122.29 (16)
C12—C11—As1	121.83 (15)	C73—C72—C71	120.4 (2)
C13—C12—C11	120.43 (19)	C73—C72—H72	119.8
C13—C12—H12	119.8	C71—C72—H72	119.8
C11—C12—H12	119.8	C74—C73—C72	119.8 (2)
C14—C13—C12	119.95 (19)	C74—C73—H73	120.1
C14—C13—H13	120	C72—C73—H73	120.1
C12—C13—H13	120	C73—C74—C75	119.8 (2)
C13—C14—C15	120.05 (19)	C73—C74—H74	120.1
C13—C14—H14	120	C75—C74—H74	120.1
C15—C14—H14	120	C76—C75—C74	120.7 (2)
C14—C15—C16	120.3 (2)	C76—C75—H75	119.7
C14—C15—H15	119.8	C74—C75—H75	119.7
C16—C15—H15	119.8	C75—C76—C71	119.8 (2)
C11—C16—C15	119.92 (19)	C75—C76—H76	120.1
C11—C16—H16	120	C71—C76—H76	120.1
C15—C16—H16	120	C82—C81—C86	118.75 (19)
C22—C21—C26	118.90 (19)	C82—C81—As3	118.54 (15)
C22—C21—As1	119.26 (15)	C86—C81—As3	122.69 (15)
C26—C21—As1	121.80 (14)	C83—C82—C81	120.9 (2)
C21—C22—C23	120.31 (19)	C83—C82—H82	119.6
C21—C22—H22	119.8	C81—C82—H82	119.6
C23—C22—H22	119.8	C82—C83—C84	120.4 (2)
C24—C23—C22	120.51 (19)	C82—C83—H83	119.8
C24—C23—H23	119.7	C84—C83—H83	119.8
C22—C23—H23	119.7	C83—C84—C85	119.3 (2)
C25—C24—C23	119.0 (2)	C83—C84—H84	120.4
C25—C24—H24	120.5	C85—C84—H84	120.4
C23—C24—H24	120.5	C86—C85—C84	120.4 (2)
C24—C25—C26	120.7 (2)	C86—C85—H85	119.8
C24—C25—H25	119.6	C84—C85—H85	119.8
C26—C25—H25	119.6	C85—C86—C81	120.3 (2)
C25—C26—C21	120.57 (18)	C85—C86—H86	119.8
C25—C26—H26	119.7	C81—C86—H86	119.8
C21—C26—H26	119.7	C92—C91—C96	119.62 (18)
C36—C31—C32	119.36 (19)	C92—C91—As3	117.47 (14)
C36—C31—As1	117.68 (15)	C96—C91—As3	122.88 (16)
C32—C31—As1	122.91 (16)	C91—C92—C93	120.30 (19)
C33—C32—C31	119.7 (2)	C91—C92—H92	119.9
C33—C32—H32	120.2	C93—C92—H92	119.9
C31—C32—H32	120.2	C94—C93—C92	119.8 (2)
C34—C33—C32	120.4 (2)	C94—C93—H93	120.1
C34—C33—H33	119.8	C92—C93—H93	120.1
C32—C33—H33	119.8	C93—C94—C95	120.24 (19)
C33—C34—C35	120.1 (2)	C93—C94—H94	119.9
C33—C34—H34	120	C95—C94—H94	119.9
C35—C34—H34	120	C94—C95—C96	120.18 (19)
C36—C35—C34	119.6 (2)	C94—C95—H95	119.9
C36—C35—H35	120.2	C96—C95—H95	119.9
C34—C35—H35	120.2	C95—C96—C91	119.8 (2)
C35—C36—C31	120.8 (2)	C95—C96—H96	120.1
C35—C36—H36	119.6	C91—C96—H96	120.1
C31—C36—H36	119.6
O1—Ag—As1—C11	−51.09 (7)	C34—C35—C36—C31	0.2 (3)
As3—Ag—As1—C11	179.94 (6)	C32—C31—C36—C35	−1.9 (3)
As2—Ag—As1—C11	46.86 (7)	As1—C31—C36—C35	175.69 (15)
O1—Ag—As1—C21	72.82 (7)	C61—As2—C41—C46	101.76 (19)
As3—Ag—As1—C21	−56.15 (7)	C51—As2—C41—C46	−4.1 (2)
As2—Ag—As1—C21	170.77 (7)	Ag—As2—C41—C46	−133.11 (16)
O1—Ag—As1—C31	−165.18 (7)	C61—As2—C41—C42	−79.95 (17)
As3—Ag—As1—C31	65.85 (6)	C51—As2—C41—C42	174.18 (17)
As2—Ag—As1—C31	−67.23 (6)	Ag—As2—C41—C42	45.18 (19)
O1—Ag—As2—C61	−178.50 (7)	C46—C41—C42—C43	1.5 (3)
As1—Ag—As2—C61	73.85 (6)	As2—C41—C42—C43	−176.85 (17)
As3—Ag—As2—C61	−59.36 (6)	C41—C42—C43—C44	−0.9 (3)
O1—Ag—As2—C51	−59.74 (7)	C42—C43—C44—C45	−0.4 (4)
As1—Ag—As2—C51	−167.39 (7)	C43—C44—C45—C46	1.2 (4)
As3—Ag—As2—C51	59.40 (7)	C42—C41—C46—C45	−0.8 (3)
O1—Ag—As2—C41	61.64 (8)	As2—C41—C46—C45	177.50 (17)
As1—Ag—As2—C41	−46.01 (7)	C44—C45—C46—C41	−0.6 (4)
As3—Ag—As2—C41	−179.22 (7)	C61—As2—C51—C56	−6.9 (2)
O1—Ag—As3—C71	−67.23 (8)	C41—As2—C51—C56	97.51 (19)
As1—Ag—As3—C71	56.06 (7)	Ag—As2—C51—C56	−130.59 (17)
As2—Ag—As3—C71	−169.79 (7)	C61—As2—C51—C52	174.73 (15)
O1—Ag—As3—C91	58.36 (8)	C41—As2—C51—C52	−80.83 (16)
As1—Ag—As3—C91	−178.35 (7)	Ag—As2—C51—C52	51.07 (17)
As2—Ag—As3—C91	−44.20 (7)	C56—C51—C52—C53	−0.5 (3)
O1—Ag—As3—C81	173.87 (7)	As2—C51—C52—C53	177.91 (16)
As1—Ag—As3—C81	−62.85 (7)	C51—C52—C53—C54	0.6 (3)
As2—Ag—As3—C81	71.31 (7)	C52—C53—C54—C55	−0.3 (4)
O3—S—O1—Ag	163.03 (8)	C53—C54—C55—C56	0.0 (4)
O2—S—O1—Ag	32.01 (11)	C52—C51—C56—C55	0.1 (3)
C1—S—O1—Ag	−82.37 (10)	As2—C51—C56—C55	−178.16 (19)
As1—Ag—O1—S	−71.84 (8)	C54—C55—C56—C51	0.1 (4)
As3—Ag—O1—S	55.35 (9)	C51—As2—C61—C66	84.65 (17)
As2—Ag—O1—S	171.57 (8)	C41—As2—C61—C66	−18.64 (18)
O3—S—C1—C2	116.39 (18)	Ag—As2—C61—C66	−149.19 (15)
O2—S—C1—C2	−121.67 (18)	C51—As2—C61—C62	−98.11 (16)
O1—S—C1—C2	−2.95 (19)	C41—As2—C61—C62	158.60 (15)
O3—S—C1—C6	−64.6 (2)	Ag—As2—C61—C62	28.05 (16)
O2—S—C1—C6	57.3 (2)	C66—C61—C62—C63	−1.5 (3)
O1—S—C1—C6	176.03 (18)	As2—C61—C62—C63	−178.82 (15)
C6—C1—C2—C3	−1.0 (3)	C61—C62—C63—C64	0.3 (3)
S—C1—C2—C3	178.01 (17)	C62—C63—C64—C65	1.3 (3)
C1—C2—C3—C4	−0.2 (3)	C63—C64—C65—C66	−1.8 (3)
C2—C3—C4—C5	1.2 (4)	C64—C65—C66—C61	0.6 (3)
C2—C3—C4—C7	−179.5 (2)	C62—C61—C66—C65	1.0 (3)
C3—C4—C5—C6	−1.1 (4)	As2—C61—C66—C65	178.23 (16)
C7—C4—C5—C6	179.6 (3)	C91—As3—C71—C76	−103.77 (17)
C2—C1—C6—C5	1.0 (4)	C81—As3—C71—C76	154.02 (16)
S—C1—C6—C5	−178.0 (2)	Ag—As3—C71—C76	29.34 (18)
C4—C5—C6—C1	0.0 (4)	C91—As3—C71—C72	73.33 (17)
C21—As1—C11—C16	−96.85 (17)	C81—As3—C71—C72	−28.88 (17)
C31—As1—C11—C16	157.98 (17)	Ag—As3—C71—C72	−153.55 (14)
Ag—As1—C11—C16	36.65 (18)	C76—C71—C72—C73	1.2 (3)
C21—As1—C11—C12	82.71 (17)	As3—C71—C72—C73	−175.91 (15)
C31—As1—C11—C12	−22.46 (18)	C71—C72—C73—C74	0.8 (3)
Ag—As1—C11—C12	−143.78 (15)	C72—C73—C74—C75	−1.5 (3)
C16—C11—C12—C13	−1.8 (3)	C73—C74—C75—C76	0.2 (4)
As1—C11—C12—C13	178.69 (16)	C74—C75—C76—C71	1.8 (4)
C11—C12—C13—C14	0.8 (3)	C72—C71—C76—C75	−2.5 (3)
C12—C13—C14—C15	0.9 (3)	As3—C71—C76—C75	174.70 (19)
C13—C14—C15—C16	−1.6 (3)	C71—As3—C81—C82	−89.23 (16)
C12—C11—C16—C15	1.1 (3)	C91—As3—C81—C82	166.65 (16)
As1—C11—C16—C15	−179.37 (16)	Ag—As3—C81—C82	40.15 (17)
C14—C15—C16—C11	0.6 (3)	C71—As3—C81—C86	92.82 (18)
C11—As1—C21—C22	−179.41 (17)	C91—As3—C81—C86	−11.30 (19)
C31—As1—C21—C22	−77.37 (17)	Ag—As3—C81—C86	−137.80 (16)
Ag—As1—C21—C22	49.10 (18)	C86—C81—C82—C83	0.3 (3)
C11—As1—C21—C26	2.80 (18)	As3—C81—C82—C83	−177.71 (16)
C31—As1—C21—C26	104.84 (17)	C81—C82—C83—C84	−0.4 (3)
Ag—As1—C21—C26	−128.69 (15)	C82—C83—C84—C85	0.1 (3)
C26—C21—C22—C23	−1.0 (3)	C83—C84—C85—C86	0.2 (4)
As1—C21—C22—C23	−178.82 (18)	C84—C85—C86—C81	−0.3 (4)
C21—C22—C23—C24	0.8 (4)	C82—C81—C86—C85	0.0 (3)
C22—C23—C24—C25	−0.1 (4)	As3—C81—C86—C85	177.99 (19)
C23—C24—C25—C26	−0.5 (3)	C71—As3—C91—C92	171.16 (16)
C24—C25—C26—C21	0.3 (3)	C81—As3—C91—C92	−85.30 (17)
C22—C21—C26—C25	0.4 (3)	Ag—As3—C91—C92	37.21 (18)
As1—C21—C26—C25	178.19 (17)	C71—As3—C91—C96	−10.75 (19)
C11—As1—C31—C36	−85.13 (15)	C81—As3—C91—C96	92.79 (18)
C21—As1—C31—C36	171.49 (14)	Ag—As3—C91—C96	−144.71 (15)
Ag—As1—C31—C36	39.83 (15)	C96—C91—C92—C93	−2.0 (3)
C11—As1—C31—C32	92.35 (16)	As3—C91—C92—C93	176.20 (16)
C21—As1—C31—C32	−11.03 (17)	C91—C92—C93—C94	0.1 (3)
Ag—As1—C31—C32	−142.69 (14)	C92—C93—C94—C95	1.6 (3)
C36—C31—C32—C33	2.0 (3)	C93—C94—C95—C96	−1.6 (3)
As1—C31—C32—C33	−175.47 (15)	C94—C95—C96—C91	−0.3 (3)
C31—C32—C33—C34	−0.4 (3)	C92—C91—C96—C95	2.0 (3)
C32—C33—C34—C35	−1.4 (3)	As3—C91—C96—C95	−176.02 (16)
C33—C34—C35—C36	1.5 (3)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C24—H24···O2^i	0.95	2.43	3.302 (3)	153
C43—H43···O3^ii	0.95	2.51	3.330 (2)	145
C64—H64···O3^iii	0.95	2.56	3.318 (3)	137
C76—H76···O2	0.95	2.56	3.488 (3)	165

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, −y+1, −z; (iii) x−1, y, z.