Acta Cryst. (2006). E62, m2869-m2871  [ doi:10.1107/S1600536806039997 ]

(Acetylacetonato-²O,O')(dimethylformamide-O)[2-phenoxyethanal (2-oxidobenzylidene)hydrazonato-³O,N,O']cobalt(III)

X.-H. Chen and S.-X. Liu

Online 13 October 2006

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean (C-C) = 0.005 Å
• R factor = 0.044
• wR factor = 0.124
• Data-to-parameter ratio = 17.8

checkCIF/PLATON results

No syntax errors found



Alert level A
DIFF020_ALERT_1_A  _diffrn_standards_interval_count and
            _diffrn_standards_interval_time are missing. Number of measurements
            between standards or time (min) between standards.

Alert level B
PLAT201_ALERT_2_B Isotropic non-H Atoms in Main Residue(s) .......          1      
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.74 Ratio
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.72 Ratio
PLAT222_ALERT_3_B Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       4.39 Ratio
PLAT222_ALERT_3_B Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       4.38 Ratio
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for         N3     
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for         N6     

Alert level C
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT230_ALERT_2_C Hirshfeld Test Diff for    O2     -   C8      ..       5.44 su   
PLAT230_ALERT_2_C Hirshfeld Test Diff for    O8     -   C31     ..       6.62 su   
PLAT230_ALERT_2_C Hirshfeld Test Diff for    O10    -   C39     ..       5.49 su   
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C10     
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          3     
            O2  -CO1 -O1  -C1    -77.00  2.00   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          7     
            O1  -CO1 -O2  -C8     67.00  2.00   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         13     
            O5  -CO1 -O4  -C16   172.40  0.80   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         20     
            O4  -CO1 -O5  -C19   158.60  0.80   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         21     
            N1  -CO1 -O6  -C21   116.40  0.80   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         28     
            O8  -CO2 -O7  -C24   -53.00  3.00   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         32     
            O7  -CO2 -O8  -C31    45.00  3.00   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         38     
            O11 -CO2 -O10 -C39   154.70  1.10   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         45     
            O10 -CO2 -O11 -C42   148.70  1.10   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         46     
            N4  -CO2 -O12 -C44   131.40  0.80   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         54     
            O6  -CO1 -N1  -C7    168.00  0.70   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         59     
            O6  -CO1 -N1  -N2    -16.20  0.90   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         66     
            O12 -CO2 -N4  -C30   154.90  0.70   1.555   1.555   1.555   1.555  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         71     
            O12 -CO2 -N4  -N5    -26.90  0.90   1.555   1.555   1.555   1.555  

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K    
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K    

   1 ALERT level A = In general: serious problem
   7 ALERT level B = Potentially serious problem
  19 ALERT level C = Check and explain
   2 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   9 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
  14 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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