Tetra­kis(tri-p-tolyl­phosphine-κP)silver(I) hexa­fluoro­phosphate

The title compound, [Ag(P(p-tol)₃}₄]PF₆ or [Ag(C₂₁H₂₁P)₄]PF₆, crystallizes with parts of two independent formula units in the asymmetric unit. The Ag—P distances range between 2.5665 (13) and 2.6142 (7) Å, and the P—Ag—P angles between 109.310 (18) and 109.632 (18)°, indicating a distorted tetra­hedral geometry. Both Ag atoms and both PF₆⁻ anions lie on threefold rotation axes.

Key indicators

• Single-crystal X-ray study
• T = 101 K
• Mean [sigma](Wave) = 0.000 Å
• R factor = 0.038
• wR factor = 0.102
• Data-to-parameter ratio = 21.3

checkCIF/PLATON results

No syntax errors found



Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           28.35
           From the CIF: _reflns_number_total              12538
           Count of symmetry unique reflns         6684
           Completeness (_total/calc)            187.58%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      5854
           Fraction of Friedel pairs measured     0.876
           Are heavy atom types Z>Si present        yes

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   0 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker, 2004); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

Tetrakis(tri-p-tolylphosphine-κP)silver(I) hexafluorophosphate

Crystal data

[Ag(C21H21P)4]PF6	Dx = 1.299 Mg m^−3
Mr = 1470.23	Mo Kα radiation, λ = 0.71073 Å
Cubic, P213	Cell parameters from 8586 reflections
Hall symbol: P 2ac 2ab 3	θ = 2.3–25.7°
a = 24.6842 (4) Å	µ = 0.43 mm^−1
V = 15040.3 (4) Å^3	T = 101 K
Z = 8	Cuboid, colourless
F(000) = 6112	0.40 × 0.37 × 0.36 mm

Data collection

Bruker X8 APEX0II 4K KappaCCD diffractometer	12538 independent reflections
Radiation source: sealed tube	10906 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.064
Detector resolution: 512 pixels mm^-1	θmax = 28.4°, θmin = 1.2°
ω and φ scans	h = −32→32
Absorption correction: multi-scan (SADABS; Bruker, 2004)	k = −32→32
Tmin = 0.846, Tmax = 0.860	l = −32→32
122435 measured reflections

Refinement

Refinement on F^2	H-atom parameters constrained
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + (0.0501P)^2 + 9.1168P] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.038	(Δ/σ)max = 0.003
wR(F^2) = 0.102	Δρmax = 1.58 e Å^−3
S = 1.09	Δρmin = −0.55 e Å^−3
12538 reflections	Absolute structure: Flack (1983), 5852 Friedel pairs
588 parameters	Absolute structure parameter: −0.024 (17)
0 restraints

Special details

Experimental. The intensity data was collected on a Bruker X8 ApexII 4 K Kappa CCD diffractometer using an exposure time of 15 s/frame. A total of 809 frames were collected with a frame width of 0.5° covering up to θ = 25.65° with 100% completeness accomplished.

IR ν_PF6: 839.67 cm^-1; ³¹P NMR (121.495 MHz, 298 K, CD₂Cl₂): δ 4.80 p.p.m.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.732149 (8)	0.732149 (8)	0.732149 (8)	0.01623 (8)
Ag2	0.255160 (8)	0.755160 (8)	0.744840 (8)	0.01793 (8)
P01	1.00470 (6)	0.50470 (6)	0.99530 (6)	0.0481 (5)
P02	0.48752 (6)	0.51248 (6)	1.01248 (6)	0.0416 (4)
P11	0.79225 (3)	0.79225 (3)	0.79225 (3)	0.0199 (3)
P12	0.63752 (3)	0.77517 (3)	0.72403 (3)	0.01849 (15)
P23	0.19513 (3)	0.69513 (3)	0.80487 (3)	0.0230 (3)
P24	0.34121 (3)	0.78461 (3)	0.79910 (3)	0.01731 (14)
F11A	1.0014 (7)	0.5327 (5)	0.9360 (4)	0.134 (4)	0.5
F11B	0.9719 (7)	0.5089 (5)	0.9448 (4)	0.134 (4)	0.5
F12	0.95130 (19)	0.5287 (3)	1.0141 (2)	0.147 (2)
F21	0.46885 (13)	0.48476 (16)	0.95873 (12)	0.0778 (10)
F22	0.43170 (16)	0.4946 (2)	1.03813 (18)	0.1103 (15)
C111	0.83210 (12)	0.75585 (13)	0.84283 (12)	0.0242 (6)
C112	0.83388 (14)	0.77050 (16)	0.89717 (14)	0.0346 (8)
H112	0.8141	0.8011	0.9095	0.042*
C113	0.86446 (16)	0.74040 (18)	0.93330 (15)	0.0462 (10)
H113	0.8645	0.7501	0.9705	0.055*
C114	0.89500 (16)	0.69643 (16)	0.91634 (16)	0.0400 (9)
C115	0.89311 (14)	0.68244 (13)	0.86203 (15)	0.0301 (7)
H115	0.9141	0.6527	0.8494	0.036*
C116	0.86119 (13)	0.71105 (13)	0.82580 (13)	0.0256 (7)
H116	0.8593	0.6998	0.789	0.031*
C117	0.9306 (2)	0.6650 (2)	0.95448 (19)	0.0590 (13)
H11A	0.9686	0.6743	0.9479	0.088*
H11B	0.9252	0.6261	0.9485	0.088*
H11C	0.921	0.674	0.9919	0.088*
C211	0.63916 (12)	0.84253 (12)	0.69368 (12)	0.0212 (6)
C212	0.60280 (13)	0.85967 (13)	0.65422 (13)	0.0261 (7)
H212	0.5743	0.8363	0.643	0.031*
C213	0.60785 (15)	0.91087 (14)	0.63106 (14)	0.0324 (7)
H213	0.5829	0.9219	0.6039	0.039*
C214	0.64855 (15)	0.94588 (13)	0.64691 (15)	0.0332 (8)
C215	0.68394 (14)	0.92876 (13)	0.68703 (14)	0.0306 (7)
H215	0.712	0.9524	0.6987	0.037*
C216	0.67936 (13)	0.87784 (13)	0.71053 (13)	0.0247 (6)
H216	0.7039	0.8672	0.7382	0.03*
C217	0.6540 (2)	1.00130 (15)	0.62221 (18)	0.0494 (11)
H21A	0.6471	1.0289	0.6499	0.074*
H21B	0.6276	1.0053	0.5927	0.074*
H21C	0.6907	1.0059	0.6079	0.074*
C221	0.59100 (11)	0.73933 (12)	0.67921 (12)	0.0195 (6)
C222	0.53804 (12)	0.72571 (12)	0.69226 (13)	0.0236 (6)
H222	0.5238	0.7347	0.7269	0.028*
C223	0.50605 (12)	0.69900 (13)	0.65465 (13)	0.0256 (7)
H223	0.4701	0.6892	0.6643	0.031*
C224	0.52499 (13)	0.68608 (13)	0.60307 (13)	0.0251 (6)
C225	0.57819 (13)	0.69914 (14)	0.59142 (14)	0.0281 (7)
H225	0.5927	0.69	0.5569	0.034*
C226	0.61085 (12)	0.72517 (13)	0.62887 (13)	0.0259 (7)
H226	0.6473	0.7334	0.6198	0.031*
C227	0.48939 (14)	0.65850 (16)	0.56239 (15)	0.0346 (8)
H22A	0.5108	0.6492	0.5303	0.052*
H22B	0.4598	0.6829	0.552	0.052*
H22C	0.4743	0.6254	0.5783	0.052*
C231	0.59986 (11)	0.78528 (12)	0.78650 (12)	0.0199 (6)
C232	0.59169 (12)	0.74153 (13)	0.82122 (13)	0.0275 (7)
H232	0.6045	0.7067	0.8112	0.033*
C233	0.56511 (13)	0.74825 (15)	0.87006 (13)	0.0320 (7)
H233	0.5599	0.7179	0.8932	0.038*
C234	0.54599 (13)	0.79866 (15)	0.88569 (13)	0.0291 (7)
C235	0.55378 (13)	0.84216 (14)	0.85117 (14)	0.0284 (7)
H235	0.5406	0.8769	0.8612	0.034*
C236	0.58050 (12)	0.83571 (13)	0.80229 (13)	0.0225 (6)
H236	0.5857	0.8661	0.7793	0.027*
C237	0.51783 (17)	0.80629 (18)	0.93925 (16)	0.0453 (10)
H23A	0.5305	0.7788	0.9649	0.068*
H23B	0.4786	0.8026	0.9342	0.068*
H23C	0.526	0.8424	0.9535	0.068*
C311	0.22806 (13)	0.66930 (12)	0.86549 (12)	0.0245 (6)
C312	0.28104 (13)	0.65113 (12)	0.86081 (13)	0.0247 (6)
H312	0.2986	0.6524	0.8266	0.03*
C313	0.30859 (14)	0.63113 (13)	0.90541 (14)	0.0275 (7)
H313	0.3449	0.619	0.9013	0.033*
C314	0.28422 (16)	0.62852 (16)	0.95586 (15)	0.0381 (9)
C315	0.23161 (18)	0.64773 (18)	0.96049 (15)	0.0480 (11)
H315	0.2143	0.647	0.9949	0.058*
C316	0.20348 (16)	0.66816 (17)	0.91586 (14)	0.0390 (9)
H316	0.1675	0.6812	0.9201	0.047*
C317	0.3142 (2)	0.6063 (2)	1.00342 (16)	0.0575 (13)
H31A	0.32	0.5674	0.9984	0.086*
H31B	0.293	0.6124	1.0364	0.086*
H31C	0.3493	0.6246	1.0067	0.086*
C411	0.32941 (12)	0.81954 (12)	0.86334 (12)	0.0205 (6)
C412	0.28900 (13)	0.80129 (14)	0.89755 (13)	0.0279 (7)
H412	0.2681	0.7706	0.8876	0.034*
C413	0.27875 (15)	0.82732 (15)	0.94607 (14)	0.0344 (8)
H413	0.2507	0.8143	0.969	0.041*
C414	0.30859 (16)	0.87188 (14)	0.96173 (14)	0.0332 (8)
C415	0.34967 (16)	0.88970 (14)	0.92806 (14)	0.0359 (8)
H415	0.3709	0.92	0.9384	0.043*
C416	0.36020 (14)	0.86383 (13)	0.87937 (13)	0.0273 (7)
H416	0.3887	0.8765	0.8568	0.033*
C417	0.2971 (2)	0.89997 (17)	1.01489 (16)	0.0511 (12)
H41A	0.2608	0.9161	1.0138	0.077*
H41B	0.324	0.9285	1.0209	0.077*
H41C	0.2989	0.8736	1.0445	0.077*
C421	0.38335 (11)	0.83292 (11)	0.76242 (12)	0.0185 (6)
C422	0.43952 (12)	0.83227 (12)	0.76076 (12)	0.0237 (6)
H422	0.459	0.8049	0.7796	0.028*
C423	0.46718 (13)	0.87121 (13)	0.73187 (14)	0.0297 (7)
H423	0.5056	0.8698	0.7305	0.036*
C424	0.44042 (13)	0.91236 (14)	0.70486 (14)	0.0289 (7)
C425	0.38436 (13)	0.91334 (13)	0.70683 (13)	0.0268 (7)
H425	0.365	0.9414	0.6889	0.032*
C426	0.35660 (12)	0.87401 (12)	0.73460 (13)	0.0235 (6)
H426	0.3181	0.8748	0.7349	0.028*
C427	0.47038 (17)	0.95621 (18)	0.6741 (2)	0.0533 (12)
H42A	0.5074	0.9592	0.6881	0.08*
H42B	0.4516	0.9909	0.6789	0.08*
H42C	0.4715	0.9469	0.6356	0.08*
C431	0.38786 (11)	0.73038 (12)	0.81748 (12)	0.0201 (6)
C432	0.40076 (14)	0.69199 (13)	0.77873 (14)	0.0303 (7)
H432	0.3859	0.6951	0.7434	0.036*
C433	0.43488 (15)	0.64917 (14)	0.79067 (16)	0.0356 (8)
H433	0.444	0.6239	0.7631	0.043*
C434	0.45585 (14)	0.64280 (14)	0.84225 (17)	0.0374 (9)
C435	0.44320 (14)	0.68078 (16)	0.88057 (15)	0.0361 (8)
H435	0.4578	0.6773	0.916	0.043*
C436	0.40941 (12)	0.72439 (14)	0.86881 (13)	0.0275 (7)
H436	0.4011	0.7501	0.8962	0.033*
C437	0.49226 (18)	0.59554 (18)	0.8555 (2)	0.0542 (12)
H43A	0.5291	0.6032	0.8427	0.081*
H43B	0.4786	0.5629	0.8376	0.081*
H43C	0.4928	0.5899	0.8948	0.081*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
F21	0.0662 (19)	0.117 (3)	0.0498 (17)	−0.0149 (18)	−0.0221 (15)	−0.0188 (17)
F22	0.081 (2)	0.154 (4)	0.095 (3)	−0.020 (3)	0.038 (2)	−0.005 (3)
P02	0.0416 (4)	0.0416 (4)	0.0416 (4)	−0.0023 (5)	−0.0023 (5)	0.0023 (5)
P11	0.0199 (3)	0.0199 (3)	0.0199 (3)	−0.0027 (3)	−0.0027 (3)	−0.0027 (3)
P12	0.0151 (3)	0.0177 (3)	0.0227 (4)	0.0015 (3)	0.0012 (3)	0.0009 (3)
P23	0.0230 (3)	0.0230 (3)	0.0230 (3)	−0.0045 (3)	0.0045 (3)	0.0045 (3)
P24	0.0169 (3)	0.0188 (4)	0.0162 (3)	0.0003 (3)	−0.0009 (3)	−0.0009 (3)
Ag1	0.01623 (8)	0.01623 (8)	0.01623 (8)	0.00046 (7)	0.00046 (7)	0.00046 (7)
Ag2	0.01793 (8)	0.01793 (8)	0.01793 (8)	−0.00111 (7)	0.00111 (7)	0.00111 (7)
P01	0.0481 (5)	0.0481 (5)	0.0481 (5)	0.0058 (5)	−0.0058 (5)	−0.0058 (5)
F11A	0.219 (13)	0.131 (10)	0.052 (4)	0.016 (7)	0.010 (5)	0.022 (4)
F11B	0.219 (13)	0.131 (10)	0.052 (4)	0.016 (7)	0.010 (5)	0.022 (4)
F12	0.095 (3)	0.234 (6)	0.112 (4)	0.062 (4)	0.034 (3)	−0.014 (4)
C111	0.0240 (14)	0.0269 (16)	0.0217 (14)	−0.0051 (12)	−0.0054 (11)	0.0004 (12)
C112	0.0311 (17)	0.043 (2)	0.0295 (17)	−0.0005 (15)	−0.0093 (14)	−0.0082 (16)
C113	0.046 (2)	0.066 (3)	0.0260 (18)	−0.003 (2)	−0.0143 (15)	−0.0053 (18)
C114	0.036 (2)	0.044 (2)	0.039 (2)	−0.0051 (17)	−0.0170 (16)	0.0051 (17)
C115	0.0266 (17)	0.0238 (16)	0.0400 (19)	−0.0061 (13)	−0.0112 (14)	0.0021 (14)
C116	0.0264 (16)	0.0239 (16)	0.0266 (16)	−0.0043 (13)	−0.0056 (13)	0.0026 (13)
C117	0.055 (3)	0.072 (3)	0.050 (3)	0.008 (2)	−0.026 (2)	0.015 (2)
C211	0.0234 (15)	0.0189 (14)	0.0213 (15)	0.0029 (11)	0.0028 (12)	0.0007 (11)
C212	0.0256 (16)	0.0273 (16)	0.0254 (16)	0.0040 (13)	−0.0001 (12)	0.0005 (13)
C213	0.0377 (19)	0.0284 (18)	0.0310 (18)	0.0086 (15)	−0.0006 (15)	0.0039 (14)
C214	0.046 (2)	0.0212 (16)	0.0326 (19)	0.0045 (14)	0.0097 (15)	0.0041 (13)
C215	0.0323 (18)	0.0222 (16)	0.0374 (19)	0.0001 (13)	0.0035 (14)	−0.0038 (14)
C216	0.0213 (15)	0.0255 (16)	0.0274 (16)	0.0030 (12)	0.0013 (12)	−0.0025 (13)
C217	0.076 (3)	0.0261 (19)	0.046 (3)	−0.0031 (19)	0.000 (2)	0.0104 (17)
C221	0.0164 (13)	0.0177 (14)	0.0243 (14)	0.0028 (11)	−0.0004 (10)	0.0013 (11)
C222	0.0216 (15)	0.0215 (15)	0.0276 (15)	0.0045 (12)	0.0038 (12)	−0.0033 (12)
C223	0.0164 (14)	0.0272 (17)	0.0332 (17)	−0.0029 (12)	0.0040 (12)	−0.0016 (13)
C224	0.0226 (15)	0.0214 (15)	0.0313 (17)	0.0009 (12)	−0.0031 (13)	−0.0011 (12)
C225	0.0245 (16)	0.0326 (18)	0.0273 (17)	0.0027 (13)	0.0045 (13)	−0.0051 (13)
C226	0.0184 (14)	0.0299 (17)	0.0294 (16)	−0.0007 (12)	0.0051 (12)	−0.0032 (13)
C227	0.0266 (17)	0.044 (2)	0.0333 (19)	−0.0043 (15)	−0.0013 (14)	−0.0113 (16)
C231	0.0133 (13)	0.0232 (14)	0.0232 (15)	0.0011 (11)	−0.0027 (11)	0.0010 (11)
C232	0.0259 (15)	0.0251 (17)	0.0315 (17)	0.0033 (13)	0.0057 (12)	0.0031 (13)
C233	0.0311 (17)	0.0342 (18)	0.0307 (17)	−0.0009 (15)	0.0034 (13)	0.0049 (15)
C234	0.0214 (15)	0.0398 (19)	0.0261 (17)	−0.0041 (14)	0.0049 (12)	−0.0070 (14)
C235	0.0222 (16)	0.0318 (18)	0.0313 (18)	−0.0014 (13)	0.0006 (13)	−0.0089 (14)
C236	0.0187 (14)	0.0235 (15)	0.0251 (15)	−0.0013 (12)	0.0005 (12)	−0.0029 (12)
C237	0.045 (2)	0.058 (3)	0.032 (2)	−0.0035 (19)	0.0132 (17)	−0.0088 (18)
C311	0.0257 (16)	0.0251 (15)	0.0226 (15)	−0.0050 (13)	0.0036 (13)	0.0029 (12)
C312	0.0271 (16)	0.0191 (15)	0.0277 (16)	−0.0054 (12)	0.0063 (13)	0.0009 (12)
C313	0.0283 (17)	0.0191 (15)	0.0351 (18)	−0.0025 (12)	−0.0013 (13)	−0.0028 (13)
C314	0.047 (2)	0.038 (2)	0.0297 (18)	0.0126 (16)	−0.0065 (16)	−0.0036 (15)
C315	0.053 (2)	0.068 (3)	0.0226 (17)	0.024 (2)	0.0080 (17)	0.0083 (17)
C316	0.0338 (19)	0.055 (2)	0.0278 (18)	0.0142 (17)	0.0103 (15)	0.0081 (16)
C317	0.067 (3)	0.076 (3)	0.029 (2)	0.030 (3)	−0.010 (2)	−0.004 (2)
C411	0.0231 (15)	0.0212 (14)	0.0173 (14)	0.0020 (11)	0.0005 (11)	−0.0019 (11)
C412	0.0292 (17)	0.0310 (17)	0.0237 (16)	−0.0057 (13)	0.0025 (13)	−0.0055 (13)
C413	0.035 (2)	0.041 (2)	0.0266 (17)	−0.0083 (16)	0.0111 (14)	−0.0047 (14)
C414	0.048 (2)	0.0289 (18)	0.0226 (17)	−0.0035 (15)	0.0069 (15)	−0.0067 (13)
C415	0.053 (2)	0.0285 (18)	0.0261 (17)	−0.0178 (16)	0.0029 (16)	−0.0063 (14)
C416	0.0351 (18)	0.0267 (16)	0.0200 (15)	−0.0086 (13)	0.0043 (13)	−0.0025 (12)
C417	0.076 (3)	0.045 (2)	0.033 (2)	−0.018 (2)	0.021 (2)	−0.0194 (18)
C421	0.0174 (13)	0.0198 (13)	0.0184 (14)	−0.0010 (10)	−0.0013 (11)	−0.0024 (11)
C422	0.0206 (14)	0.0261 (15)	0.0245 (16)	0.0028 (11)	−0.0021 (12)	0.0048 (12)
C423	0.0189 (15)	0.0346 (17)	0.0357 (18)	−0.0007 (12)	−0.0014 (13)	0.0082 (15)
C424	0.0260 (17)	0.0314 (18)	0.0293 (17)	−0.0031 (13)	0.0022 (13)	0.0064 (14)
C425	0.0262 (16)	0.0269 (16)	0.0274 (17)	0.0017 (13)	−0.0021 (13)	0.0059 (13)
C426	0.0188 (14)	0.0261 (15)	0.0254 (15)	0.0005 (11)	0.0009 (12)	0.0008 (13)
C427	0.033 (2)	0.053 (3)	0.074 (3)	−0.0062 (19)	0.004 (2)	0.035 (2)
C431	0.0183 (13)	0.0192 (14)	0.0230 (14)	−0.0003 (11)	−0.0003 (11)	0.0040 (12)
C432	0.0325 (18)	0.0261 (16)	0.0321 (18)	0.0064 (13)	−0.0042 (14)	−0.0004 (13)
C433	0.0327 (19)	0.0271 (18)	0.047 (2)	0.0071 (14)	−0.0020 (16)	−0.0050 (15)
C434	0.0265 (17)	0.0282 (18)	0.057 (2)	0.0028 (14)	−0.0011 (16)	0.0146 (17)
C435	0.0251 (18)	0.046 (2)	0.037 (2)	0.0039 (15)	−0.0083 (14)	0.0133 (16)
C436	0.0214 (15)	0.0353 (18)	0.0259 (16)	0.0005 (13)	−0.0052 (12)	0.0030 (14)
C437	0.040 (2)	0.043 (3)	0.079 (3)	0.0132 (19)	0.000 (2)	0.013 (2)

Geometric parameters (Å, º)

F21—P02	1.562 (3)	C226—H226	0.95
F22—P02	1.579 (4)	C227—H22A	0.98
P02—F21^i	1.562 (3)	C227—H22B	0.98
P02—F21^ii	1.562 (3)	C227—H22C	0.98
P02—F22^ii	1.579 (4)	C231—C236	1.389 (4)
P02—F22^i	1.579 (4)	C231—C232	1.393 (4)
P11—C111^iii	1.826 (3)	C232—C233	1.382 (4)
P11—C111	1.826 (3)	C232—H232	0.95
P11—C111^iv	1.826 (3)	C233—C234	1.386 (5)
P11—Ag1	2.5695 (13)	C233—H233	0.95
P12—C231	1.818 (3)	C234—C235	1.384 (5)
P12—C221	1.824 (3)	C234—C237	1.506 (5)
P12—C211	1.824 (3)	C235—C236	1.384 (4)
P12—Ag1	2.5737 (7)	C235—H235	0.95
P23—C311^v	1.818 (3)	C236—H236	0.95
P23—C311	1.818 (3)	C237—H23A	0.98
P23—C311^vi	1.818 (3)	C237—H23B	0.98
P23—Ag2	2.5665 (13)	C237—H23C	0.98
P24—C431	1.823 (3)	C311—C316	1.384 (4)
P24—C421	1.823 (3)	C311—C312	1.387 (5)
P24—C411	1.828 (3)	C312—C313	1.385 (5)
P24—Ag2	2.6142 (7)	C312—H312	0.95
Ag1—P12^iv	2.5737 (7)	C313—C314	1.385 (5)
Ag1—P12^iii	2.5737 (7)	C313—H313	0.95
Ag2—P24^v	2.6142 (7)	C314—C315	1.387 (6)
Ag2—P24^vi	2.6142 (7)	C314—C317	1.492 (5)
P01—F11B^vii	1.489 (13)	C315—C316	1.397 (5)
P01—F11B	1.489 (13)	C315—H315	0.95
P01—F11B^viii	1.489 (13)	C316—H316	0.95
P01—F12^vii	1.518 (4)	C317—H31A	0.98
P01—F12^viii	1.518 (4)	C317—H31B	0.98
P01—F12	1.518 (4)	C317—H31C	0.98
P01—F11A^vii	1.622 (10)	C411—C412	1.382 (4)
P01—F11A	1.622 (10)	C411—C416	1.389 (4)
P01—F11A^viii	1.622 (10)	C412—C413	1.383 (5)
F11B—F12^viii	1.603 (13)	C412—H412	0.95
F12—F11B^vii	1.603 (14)	C413—C414	1.379 (5)
C111—C116	1.384 (5)	C413—H413	0.95
C111—C112	1.390 (4)	C414—C415	1.383 (5)
C112—C113	1.385 (5)	C414—C417	1.511 (5)
C112—H112	0.95	C415—C416	1.386 (5)
C113—C114	1.386 (6)	C415—H415	0.95
C113—H113	0.95	C416—H416	0.95
C114—C115	1.385 (5)	C417—H41A	0.98
C114—C117	1.503 (5)	C417—H41B	0.98
C115—C116	1.386 (4)	C417—H41C	0.98
C115—H115	0.95	C421—C422	1.387 (4)
C116—H116	0.95	C421—C426	1.391 (4)
C117—H11A	0.98	C422—C423	1.378 (4)
C117—H11B	0.98	C422—H422	0.95
C117—H11C	0.98	C423—C424	1.383 (5)
C211—C216	1.385 (4)	C423—H423	0.95
C211—C212	1.390 (4)	C424—C425	1.385 (5)
C212—C213	1.393 (5)	C424—C427	1.514 (5)
C212—H212	0.95	C425—C426	1.372 (4)
C213—C214	1.382 (5)	C425—H425	0.95
C213—H213	0.95	C426—H426	0.95
C214—C215	1.387 (5)	C427—H42A	0.98
C214—C217	1.504 (5)	C427—H42B	0.98
C215—C216	1.389 (5)	C427—H42C	0.98
C215—H215	0.95	C431—C436	1.382 (4)
C216—H216	0.95	C431—C432	1.383 (4)
C217—H21A	0.98	C432—C433	1.383 (5)
C217—H21B	0.98	C432—H432	0.95
C217—H21C	0.98	C433—C434	1.383 (5)
C221—C226	1.380 (4)	C433—H433	0.95
C221—C222	1.388 (4)	C434—C435	1.368 (6)
C222—C223	1.386 (4)	C434—C437	1.509 (5)
C222—H222	0.95	C435—C436	1.393 (5)
C223—C224	1.393 (5)	C435—H435	0.95
C223—H223	0.95	C436—H436	0.95
C224—C225	1.383 (5)	C437—H43A	0.98
C224—C227	1.498 (5)	C437—H43B	0.98
C225—C226	1.385 (5)	C437—H43C	0.98
C225—H225	0.95
F21—P02—F21^i	90.4 (2)	C223—C222—H222	120.1
F21—P02—F21^ii	90.4 (2)	C221—C222—H222	120.1
F21^i—P02—F21^ii	90.4 (2)	C222—C223—C224	122.0 (3)
F21—P02—F22^ii	91.5 (2)	C222—C223—H223	119
F21^i—P02—F22^ii	177.3 (2)	C224—C223—H223	119
F21^ii—P02—F22^ii	87.7 (2)	C225—C224—C223	117.1 (3)
F21—P02—F22^i	177.3 (2)	C225—C224—C227	121.6 (3)
F21^i—P02—F22^i	87.7 (2)	C223—C224—C227	121.3 (3)
F21^ii—P02—F22^i	91.5 (2)	C224—C225—C226	121.5 (3)
F22^ii—P02—F22^i	90.3 (3)	C224—C225—H225	119.3
F21—P02—F22	87.7 (2)	C226—C225—H225	119.3
F21^i—P02—F22	91.5 (2)	C221—C226—C225	120.8 (3)
F21^ii—P02—F22	177.3 (2)	C221—C226—H226	119.6
F22^ii—P02—F22	90.3 (3)	C225—C226—H226	119.6
F22^i—P02—F22	90.3 (3)	C224—C227—H22A	109.5
C111^iii—P11—C111	103.48 (12)	C224—C227—H22B	109.5
C111^iii—P11—C111^iv	103.48 (12)	H22A—C227—H22B	109.5
C111—P11—C111^iv	103.48 (12)	C224—C227—H22C	109.5
C111^iii—P11—Ag1	114.95 (10)	H22A—C227—H22C	109.5
C111—P11—Ag1	114.95 (10)	H22B—C227—H22C	109.5
C111^iv—P11—Ag1	114.95 (10)	C236—C231—C232	118.2 (3)
C231—P12—C221	105.02 (13)	C236—C231—P12	122.5 (2)
C231—P12—C211	103.57 (14)	C232—C231—P12	119.3 (2)
C221—P12—C211	101.94 (14)	C233—C232—C231	120.8 (3)
C231—P12—Ag1	117.05 (9)	C233—C232—H232	119.6
C221—P12—Ag1	114.74 (9)	C231—C232—H232	119.6
C211—P12—Ag1	112.83 (10)	C232—C233—C234	120.8 (3)
C311^v—P23—C311	103.66 (12)	C232—C233—H233	119.6
C311^v—P23—C311^vi	103.66 (12)	C234—C233—H233	119.6
C311—P23—C311^vi	103.66 (12)	C235—C234—C233	118.6 (3)
C311^v—P23—Ag2	114.80 (10)	C235—C234—C237	120.5 (3)
C311—P23—Ag2	114.80 (10)	C233—C234—C237	120.9 (3)
C311^vi—P23—Ag2	114.80 (10)	C234—C235—C236	120.9 (3)
C431—P24—C421	104.09 (13)	C234—C235—H235	119.6
C431—P24—C411	103.36 (14)	C236—C235—H235	119.6
C421—P24—C411	102.30 (13)	C235—C236—C231	120.8 (3)
C431—P24—Ag2	115.88 (10)	C235—C236—H236	119.6
C421—P24—Ag2	113.02 (9)	C231—C236—H236	119.6
C411—P24—Ag2	116.49 (10)	C234—C237—H23A	109.5
P11—Ag1—P12^iv	109.311 (18)	C234—C237—H23B	109.5
P11—Ag1—P12	109.310 (18)	H23A—C237—H23B	109.5
P12^iv—Ag1—P12	109.631 (18)	C234—C237—H23C	109.5
P11—Ag1—P12^iii	109.310 (18)	H23A—C237—H23C	109.5
P12^iv—Ag1—P12^iii	109.631 (18)	H23B—C237—H23C	109.5
P12—Ag1—P12^iii	109.632 (18)	C316—C311—C312	118.8 (3)
P23—Ag2—P24^v	109.502 (18)	C316—C311—P23	123.4 (3)
P23—Ag2—P24	109.502 (18)	C312—C311—P23	117.8 (2)
P24^v—Ag2—P24	109.441 (18)	C313—C312—C311	120.8 (3)
P23—Ag2—P24^vi	109.502 (18)	C313—C312—H312	119.6
P24^v—Ag2—P24^vi	109.441 (18)	C311—C312—H312	119.6
P24—Ag2—P24^vi	109.441 (18)	C314—C313—C312	121.2 (3)
F11B^vii—P01—F11B	115.7 (3)	C314—C313—H313	119.4
F11B^vii—P01—F11B^viii	115.7 (3)	C312—C313—H313	119.4
F11B—P01—F11B^viii	115.7 (3)	C313—C314—C315	117.7 (3)
F11B^vii—P01—F12^vii	75.9 (6)	C313—C314—C317	120.6 (4)
F11B—P01—F12^vii	163.8 (5)	C315—C314—C317	121.7 (4)
F11B^viii—P01—F12^vii	64.4 (6)	C314—C315—C316	121.6 (4)
F11B^vii—P01—F12^viii	163.8 (5)	C314—C315—H315	119.2
F11B—P01—F12^viii	64.4 (6)	C316—C315—H315	119.2
F11B^viii—P01—F12^viii	75.9 (6)	C311—C316—C315	119.9 (3)
F12^vii—P01—F12^viii	101.2 (3)	C311—C316—H316	120.1
F11B^vii—P01—F12	64.4 (6)	C315—C316—H316	120.1
F11B—P01—F12	75.9 (6)	C314—C317—H31A	109.5
F11B^viii—P01—F12	163.8 (5)	C314—C317—H31B	109.5
F12^vii—P01—F12	101.2 (3)	H31A—C317—H31B	109.5
F12^viii—P01—F12	101.2 (3)	C314—C317—H31C	109.5
F11B^vii—P01—F11A^vii	35.6 (7)	H31A—C317—H31C	109.5
F11B—P01—F11A^vii	102.2 (9)	H31B—C317—H31C	109.5
F11B^viii—P01—F11A^vii	97.9 (9)	C412—C411—C416	118.5 (3)
F12^vii—P01—F11A^vii	93.7 (6)	C412—C411—P24	119.4 (2)
F12^viii—P01—F11A^vii	159.1 (6)	C416—C411—P24	122.1 (2)
F12—P01—F11A^vii	90.1 (5)	C411—C412—C413	120.6 (3)
F11B^vii—P01—F11A	97.9 (9)	C411—C412—H412	119.7
F11B—P01—F11A	35.6 (7)	C413—C412—H412	119.7
F11B^viii—P01—F11A	102.2 (9)	C414—C413—C412	121.1 (3)
F12^vii—P01—F11A	159.1 (6)	C414—C413—H413	119.5
F12^viii—P01—F11A	90.1 (5)	C412—C413—H413	119.5
F12—P01—F11A	93.7 (6)	C413—C414—C415	118.5 (3)
F11A^vii—P01—F11A	71.5 (9)	C413—C414—C417	120.6 (3)
F11B^vii—P01—F11A^viii	102.2 (9)	C415—C414—C417	120.9 (3)
F11B—P01—F11A^viii	97.9 (9)	C414—C415—C416	120.8 (3)
F11B^viii—P01—F11A^viii	35.6 (7)	C414—C415—H415	119.6
F12^vii—P01—F11A^viii	90.1 (6)	C416—C415—H415	119.6
F12^viii—P01—F11A^viii	93.7 (6)	C415—C416—C411	120.5 (3)
F12—P01—F11A^viii	159.1 (6)	C415—C416—H416	119.8
F11A^vii—P01—F11A^viii	71.5 (9)	C411—C416—H416	119.8
F11A—P01—F11A^viii	71.5 (9)	C414—C417—H41A	109.5
P01—F11B—F12^viii	58.7 (5)	C414—C417—H41B	109.5
P01—F12—F11B^vii	56.9 (5)	H41A—C417—H41B	109.5
C116—C111—C112	119.0 (3)	C414—C417—H41C	109.5
C116—C111—P11	117.7 (2)	H41A—C417—H41C	109.5
C112—C111—P11	123.3 (3)	H41B—C417—H41C	109.5
C113—C112—C111	120.0 (4)	C422—C421—C426	117.9 (3)
C113—C112—H112	120	C422—C421—P24	125.3 (2)
C111—C112—H112	120	C426—C421—P24	116.8 (2)
C112—C113—C114	121.5 (3)	C423—C422—C421	120.2 (3)
C112—C113—H113	119.3	C423—C422—H422	119.9
C114—C113—H113	119.3	C421—C422—H422	119.9
C115—C114—C113	118.0 (3)	C422—C423—C424	121.7 (3)
C115—C114—C117	119.8 (4)	C422—C423—H423	119.2
C113—C114—C117	122.2 (4)	C424—C423—H423	119.2
C114—C115—C116	121.1 (3)	C423—C424—C425	118.2 (3)
C114—C115—H115	119.4	C423—C424—C427	122.2 (3)
C116—C115—H115	119.4	C425—C424—C427	119.5 (3)
C111—C116—C115	120.4 (3)	C426—C425—C424	120.3 (3)
C111—C116—H116	119.8	C426—C425—H425	119.9
C115—C116—H116	119.8	C424—C425—H425	119.9
C114—C117—H11A	109.5	C425—C426—C421	121.7 (3)
C114—C117—H11B	109.5	C425—C426—H426	119.2
H11A—C117—H11B	109.5	C421—C426—H426	119.2
C114—C117—H11C	109.5	C424—C427—H42A	109.5
H11A—C117—H11C	109.5	C424—C427—H42B	109.5
H11B—C117—H11C	109.5	H42A—C427—H42B	109.5
C216—C211—C212	118.8 (3)	C424—C427—H42C	109.5
C216—C211—P12	117.8 (2)	H42A—C427—H42C	109.5
C212—C211—P12	123.4 (2)	H42B—C427—H42C	109.5
C211—C212—C213	120.4 (3)	C436—C431—C432	118.2 (3)
C211—C212—H212	119.8	C436—C431—P24	123.3 (2)
C213—C212—H212	119.8	C432—C431—P24	118.4 (2)
C214—C213—C212	121.1 (3)	C433—C432—C431	121.1 (3)
C214—C213—H213	119.5	C433—C432—H432	119.5
C212—C213—H213	119.5	C431—C432—H432	119.5
C213—C214—C215	118.0 (3)	C434—C433—C432	120.7 (4)
C213—C214—C217	121.2 (4)	C434—C433—H433	119.6
C215—C214—C217	120.7 (4)	C432—C433—H433	119.6
C214—C215—C216	121.5 (3)	C435—C434—C433	118.3 (3)
C214—C215—H215	119.2	C435—C434—C437	121.1 (4)
C216—C215—H215	119.2	C433—C434—C437	120.7 (4)
C211—C216—C215	120.2 (3)	C434—C435—C436	121.5 (3)
C211—C216—H216	119.9	C434—C435—H435	119.3
C215—C216—H216	119.9	C436—C435—H435	119.3
C214—C217—H21A	109.5	C431—C436—C435	120.3 (3)
C214—C217—H21B	109.5	C431—C436—H436	119.9
H21A—C217—H21B	109.5	C435—C436—H436	119.9
C214—C217—H21C	109.5	C434—C437—H43A	109.5
H21A—C217—H21C	109.5	C434—C437—H43B	109.5
H21B—C217—H21C	109.5	H43A—C437—H43B	109.5
C226—C221—C222	118.8 (3)	C434—C437—H43C	109.5
C226—C221—P12	116.4 (2)	H43A—C437—H43C	109.5
C222—C221—P12	124.7 (2)	H43B—C437—H43C	109.5
C223—C222—C221	119.8 (3)
C111^iii—P11—Ag1—P12^iv	−104.93 (11)	P12—C221—C222—C223	179.2 (2)
C111—P11—Ag1—P12^iv	15.07 (11)	C221—C222—C223—C224	−1.3 (5)
C111^iv—P11—Ag1—P12^iv	135.07 (11)	C222—C223—C224—C225	2.5 (5)
C111^iii—P11—Ag1—P12	15.07 (11)	C222—C223—C224—C227	−178.4 (3)
C111—P11—Ag1—P12	135.07 (11)	C223—C224—C225—C226	−1.6 (5)
C111^iv—P11—Ag1—P12	−104.93 (11)	C227—C224—C225—C226	179.3 (3)
C111^iii—P11—Ag1—P12^iii	135.07 (11)	C222—C221—C226—C225	1.7 (5)
C111—P11—Ag1—P12^iii	−104.93 (11)	P12—C221—C226—C225	−178.3 (3)
C111^iv—P11—Ag1—P12^iii	15.07 (11)	C224—C225—C226—C221	−0.5 (5)
C231—P12—Ag1—P11	−59.70 (11)	C221—P12—C231—C236	−107.8 (3)
C221—P12—Ag1—P11	176.54 (10)	C211—P12—C231—C236	−1.2 (3)
C211—P12—Ag1—P11	60.36 (11)	Ag1—P12—C231—C236	123.6 (2)
C231—P12—Ag1—P12^iv	60.10 (12)	C221—P12—C231—C232	74.8 (3)
C221—P12—Ag1—P12^iv	−63.65 (10)	C211—P12—C231—C232	−178.6 (2)
C211—P12—Ag1—P12^iv	−179.84 (11)	Ag1—P12—C231—C232	−53.8 (3)
C231—P12—Ag1—P12^iii	−179.50 (11)	C236—C231—C232—C233	−0.1 (5)
C221—P12—Ag1—P12^iii	56.74 (11)	P12—C231—C232—C233	177.4 (3)
C211—P12—Ag1—P12^iii	−59.44 (12)	C231—C232—C233—C234	−0.1 (5)
C311^v—P23—Ag2—P24^v	−14.78 (11)	C232—C233—C234—C235	0.4 (5)
C311—P23—Ag2—P24^v	−134.78 (11)	C232—C233—C234—C237	−179.0 (3)
C311^vi—P23—Ag2—P24^v	105.22 (11)	C233—C234—C235—C236	−0.6 (5)
C311^v—P23—Ag2—P24	105.22 (11)	C237—C234—C235—C236	178.8 (3)
C311—P23—Ag2—P24	−14.78 (11)	C234—C235—C236—C231	0.5 (5)
C311^vi—P23—Ag2—P24	−134.78 (11)	C232—C231—C236—C235	−0.1 (4)
C311^v—P23—Ag2—P24^vi	−134.78 (11)	P12—C231—C236—C235	−177.5 (2)
C311—P23—Ag2—P24^vi	105.22 (11)	C311^v—P23—C311—C316	10.8 (4)
C311^vi—P23—Ag2—P24^vi	−14.78 (11)	C311^vi—P23—C311—C316	−97.2 (3)
C431—P24—Ag2—P23	65.73 (10)	Ag2—P23—C311—C316	136.8 (3)
C421—P24—Ag2—P23	−174.26 (10)	C311^v—P23—C311—C312	−167.5 (2)
C411—P24—Ag2—P23	−56.20 (11)	C311^vi—P23—C311—C312	84.5 (3)
C431—P24—Ag2—P24^v	−174.24 (10)	Ag2—P23—C311—C312	−41.5 (3)
C421—P24—Ag2—P24^v	−54.23 (10)	C316—C311—C312—C313	1.3 (5)
C411—P24—Ag2—P24^v	63.84 (12)	P23—C311—C312—C313	179.8 (2)
C431—P24—Ag2—P24^vi	−54.31 (11)	C311—C312—C313—C314	0.1 (5)
C421—P24—Ag2—P24^vi	65.70 (10)	C312—C313—C314—C315	−1.4 (5)
C411—P24—Ag2—P24^vi	−176.24 (11)	C312—C313—C314—C317	179.3 (4)
F11B^vii—P01—F11B—F12^viii	−162.0 (6)	C313—C314—C315—C316	1.1 (6)
F11B^viii—P01—F11B—F12^viii	57.9 (10)	C317—C314—C315—C316	−179.6 (4)
F12^vii—P01—F11B—F12^viii	−29 (2)	C312—C311—C316—C315	−1.5 (6)
F12—P01—F11B—F12^viii	−110.0 (6)	P23—C311—C316—C315	−179.9 (3)
F11A^vii—P01—F11B—F12^viii	163.0 (6)	C314—C315—C316—C311	0.3 (7)
F11A—P01—F11B—F12^viii	132.2 (18)	C431—P24—C411—C412	−86.7 (3)
F11A^viii—P01—F11B—F12^viii	90.4 (6)	C421—P24—C411—C412	165.4 (3)
F11B—P01—F12—F11B^vii	−128.1 (9)	Ag2—P24—C411—C412	41.6 (3)
F11B^viii—P01—F12—F11B^vii	94.5 (18)	C431—P24—C411—C416	92.7 (3)
F12^vii—P01—F12—F11B^vii	68.3 (7)	C421—P24—C411—C416	−15.2 (3)
F12^viii—P01—F12—F11B^vii	172.1 (7)	Ag2—P24—C411—C416	−139.0 (2)
F11A^vii—P01—F12—F11B^vii	−25.6 (10)	C416—C411—C412—C413	1.4 (5)
F11A—P01—F12—F11B^vii	−97.0 (9)	P24—C411—C412—C413	−179.2 (3)
F11A^viii—P01—F12—F11B^vii	−53.2 (14)	C411—C412—C413—C414	−0.3 (6)
C111^iii—P11—C111—C116	174.5 (2)	C412—C413—C414—C415	−0.8 (6)
C111^iv—P11—C111—C116	−77.8 (3)	C412—C413—C414—C417	−179.9 (4)
Ag1—P11—C111—C116	48.4 (3)	C413—C414—C415—C416	0.8 (6)
C111^iii—P11—C111—C112	−4.5 (3)	C417—C414—C415—C416	179.9 (4)
C111^iv—P11—C111—C112	103.2 (2)	C414—C415—C416—C411	0.3 (6)
Ag1—P11—C111—C112	−130.7 (3)	C412—C411—C416—C415	−1.4 (5)
C116—C111—C112—C113	0.0 (5)	P24—C411—C416—C415	179.2 (3)
P11—C111—C112—C113	179.1 (3)	C431—P24—C421—C422	−12.5 (3)
C111—C112—C113—C114	1.9 (6)	C411—P24—C421—C422	94.8 (3)
C112—C113—C114—C115	−1.5 (6)	Ag2—P24—C421—C422	−139.1 (2)
C112—C113—C114—C117	176.9 (4)	C431—P24—C421—C426	168.4 (2)
C113—C114—C115—C116	−0.8 (5)	C411—P24—C421—C426	−84.2 (2)
C117—C114—C115—C116	−179.3 (4)	Ag2—P24—C421—C426	41.8 (2)
C112—C111—C116—C115	−2.3 (5)	C426—C421—C422—C423	−0.5 (5)
P11—C111—C116—C115	178.6 (3)	P24—C421—C422—C423	−179.6 (2)
C114—C115—C116—C111	2.7 (5)	C421—C422—C423—C424	1.4 (5)
C231—P12—C211—C216	84.4 (3)	C422—C423—C424—C425	−0.8 (5)
C221—P12—C211—C216	−166.7 (2)	C422—C423—C424—C427	178.4 (4)
Ag1—P12—C211—C216	−43.1 (3)	C423—C424—C425—C426	−0.5 (5)
C231—P12—C211—C212	−96.6 (3)	C427—C424—C425—C426	−179.8 (4)
C221—P12—C211—C212	12.3 (3)	C424—C425—C426—C421	1.4 (5)
Ag1—P12—C211—C212	135.9 (2)	C422—C421—C426—C425	−0.9 (5)
C216—C211—C212—C213	1.9 (5)	P24—C421—C426—C425	178.3 (3)
P12—C211—C212—C213	−177.2 (3)	C421—P24—C431—C436	102.2 (3)
C211—C212—C213—C214	−0.6 (5)	C411—P24—C431—C436	−4.3 (3)
C212—C213—C214—C215	−0.7 (5)	Ag2—P24—C431—C436	−133.0 (2)
C212—C213—C214—C217	−179.7 (3)	C421—P24—C431—C432	−80.4 (3)
C213—C214—C215—C216	0.6 (5)	C411—P24—C431—C432	173.0 (3)
C217—C214—C215—C216	179.6 (3)	Ag2—P24—C431—C432	44.4 (3)
C212—C211—C216—C215	−1.9 (5)	C436—C431—C432—C433	−0.9 (5)
P12—C211—C216—C215	177.2 (2)	P24—C431—C432—C433	−178.4 (3)
C214—C215—C216—C211	0.7 (5)	C431—C432—C433—C434	1.8 (6)
C231—P12—C221—C226	−178.1 (2)	C432—C433—C434—C435	−1.9 (6)
C211—P12—C221—C226	74.2 (3)	C432—C433—C434—C437	178.9 (4)
Ag1—P12—C221—C226	−48.1 (3)	C433—C434—C435—C436	1.1 (5)
C231—P12—C221—C222	2.0 (3)	C437—C434—C435—C436	−179.7 (4)
C211—P12—C221—C222	−105.8 (3)	C432—C431—C436—C435	0.1 (5)
Ag1—P12—C221—C222	131.9 (2)	P24—C431—C436—C435	177.5 (3)
C226—C221—C222—C223	−0.8 (5)	C434—C435—C436—C431	−0.3 (5)

Symmetry codes: (i) −y+1, z−1/2, −x+3/2; (ii) −z+3/2, −x+1, y+1/2; (iii) y, z, x; (iv) z, x, y; (v) −z+1, x+1/2, −y+3/2; (vi) y−1/2, −z+3/2, −x+1; (vii) y+1/2, −z+3/2, −x+2; (viii) −z+2, x−1/2, −y+3/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C213—H213···F21^ix	0.95	2.54	3.439 (4)	159

Symmetry code: (ix) −x+1, y+1/2, −z+3/2.