Bis[1,2-bis­(diphenyl­phosphino)ethane-κ2P,P′]silver(I) bis­(chloro­difluoro­acetato-κO)(cyclo­hexyl)diphenyl­stannate(IV)

Teo, Y.Y.; Lo, K.M.; Ng, S.W.

doi:10.1107/S1600536807016662

Bis[1,2-bis(diphenylphosphino)ethane-κ²P,P′]silver(I) bis(chlorodifluoroacetato-κO)(cyclohexyl)diphenylstannate(IV)

In the title salt, [Ag(Ph₂CH₂CH₂Ph₂)₂]⁺[c-HexPh₂Sn(ClF₂CCO₂)₂]⁻ or [Ag(C₂₆H₂₄P₂)₂][Sn(C₆H₅)₂(C₆H₁₁)(C₂ClF₂O₂)₂], the Ag^I atom shows a tetrahedral coordination, while the Sn^IV atom is in a trans-trigonal–bipyramidal coordination.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807016662/ci2314sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536807016662/ci2314Isup2.hkl Contains datablock I

CCDC reference: 647143

checkCIF report

Key indicators

Single-crystal X-ray study
T = 173 K
Mean (C-C) = 0.008 Å
Disorder in main residue
R factor = 0.049
wR factor = 0.168
Data-to-parameter ratio = 12.6

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT220_ALERT_2_A Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       4.93 Ratio
PLAT241_ALERT_2_A Check High      Ueq as Compared to Neighbors for        Cl2
PLAT241_ALERT_2_A Check High      Ueq as Compared to Neighbors for         F3
PLAT241_ALERT_2_A Check High      Ueq as Compared to Neighbors for         F4
PLAT308_ALERT_2_A Single Bonded Metal Atom (Unusual !) ...........        Ag1
PLAT432_ALERT_2_A Short Inter X...Y Contact  O2     ..  C45     ..       2.53 Ang.
PLAT432_ALERT_2_A Short Inter X...Y Contact  C5'    ..  C27     ..       2.83 Ang.
PLAT432_ALERT_2_A Short Inter X...Y Contact  C47    ..  C74'    ..       2.73 Ang.

Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    O     Ueq(max)/Ueq(min) ...       3.68 Ratio
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C35
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        Cl1
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for         F1
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for         F2
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        O1'
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        O2'
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for       Cl2'
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C20
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for       C22'
PLAT301_ALERT_3_B Main Residue  Disorder .........................      47.00 Perc.
PLAT410_ALERT_2_B Short Intra H...H Contact  H24'   ..  H35B    ..       1.87 Ang.
PLAT432_ALERT_2_B Short Inter X...Y Contact  Cl1'   ..  C39'    ..       3.06 Ang.
PLAT432_ALERT_2_B Short Inter X...Y Contact  C5'    ..  C64     ..       3.01 Ang.

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000)         100 Deg.
PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 =          3
PLAT215_ALERT_3_C Disordered C55     has ADP max/min Ratio .......       3.20
PLAT215_ALERT_3_C Disordered C55'    has ADP max/min Ratio .......       3.30
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.49 Ratio
PLAT220_ALERT_2_C Large Non-Solvent   Cl     Ueq(max)/Ueq(min) ...       2.54 Ratio
PLAT220_ALERT_2_C Large Non-Solvent    F     Ueq(max)/Ueq(min) ...       2.54 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C39
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for       C51'
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for       Cl1'
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        F1'
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        F2'
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C21
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        F3'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        F4'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         O1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C20'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C21'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C22
PLAT313_ALERT_2_C Oxygen with three covalent bonds (rare) ........         O4
PLAT313_ALERT_2_C Oxygen with three covalent bonds (rare) ........        O4'
PLAT410_ALERT_2_C Short Intra H...H Contact  H62A   ..  H64     ..       1.94 Ang.
PLAT432_ALERT_2_C Short Inter X...Y Contact  O2     ..  C46     ..       2.93 Ang.
PLAT432_ALERT_2_C Short Inter X...Y Contact  O2'    ..  C61     ..       2.94 Ang.
PLAT432_ALERT_2_C Short Inter X...Y Contact  C5'    ..  C26     ..       3.12 Ang.
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      36.00 A   3 
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          3
              H

Alert level G
FORMU01_ALERT_1_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and _chemical_formula_moiety. This is
            usually due to the moiety formula being in the wrong format.
            Atom count from _chemical_formula_sum:   C74 H69 Ag1 Cl2 F4 O4 P4 Sn
            Atom count from _chemical_formula_moiety:C107 H48 Ag1 F4 O4 P4 Sn1

   8 ALERT level A = In general: serious problem
  14 ALERT level B = Potentially serious problem
  30 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  43 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: APEX2 (Bruker, 2004); cell refinement: SAINT (Bruker, 2004); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2007).

Bis[1,2-bis(diphenylphosphino)ethane-κ²P,P']silver(I) bis(chlorodifluoroacetato-κO)(cyclohexyl)diphenylstannate(IV) top

Crystal data top

[Ag(C₂₆H₂₄P₂)₂][Sn(C₆H₅)₂(C₆H₁₁)(C₂ClF₂O₂)₂]	Z = 2
M_r = 1519.63	F(000) = 1544
Triclinic, P1	D_x = 1.452 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 11.7453 (2) Å	Cell parameters from 6891 reflections
b = 14.7704 (2) Å	θ = 2.4–31.8°
c = 21.1302 (3) Å	µ = 0.87 mm⁻¹
α = 97.582 (1)°	T = 173 K
β = 94.641 (1)°	Block, colourless
γ = 105.550 (1)°	0.49 × 0.32 × 0.16 mm
V = 3474.62 (9) Å³

Data collection top

Bruker APEXII area-detector diffractometer	15831 independent reflections
Radiation source: medium-focus sealed tube	12918 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.028
φ and ω scans	θ_max = 27.5°, θ_min = 1.0°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −15→15
T_min = 0.735, T_max = 0.874	k = −19→19
54063 measured reflections	l = −27→27

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.049	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.168	H-atom parameters constrained
S = 1.30	w = 1/[σ²(F_o²) + (0.0845P)² + 3.9457P] where P = (F_o² + 2F_c²)/3
15831 reflections	(Δ/σ)_max = 0.001
1252 parameters	Δρ_max = 2.61 e Å⁻³
1021 restraints	Δρ_min = −1.35 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Sn1	0.3267 (2)	0.59216 (18)	0.32429 (11)	0.0212 (3)	0.50
Cl1	0.0997 (5)	0.6435 (5)	0.1041 (2)	0.1227 (17)	0.50
Cl2	0.3641 (7)	0.3912 (4)	0.5195 (3)	0.1347 (19)	0.50
F1	0.3208 (9)	0.7336 (8)	0.0968 (5)	0.1227 (17)	0.50
F2	0.2868 (10)	0.5924 (7)	0.1070 (5)	0.1227 (17)	0.50
F3	0.2002 (11)	0.4661 (11)	0.5251 (6)	0.1347 (19)	0.50
F4	0.3817 (12)	0.5544 (7)	0.5354 (6)	0.1347 (19)	0.50
O1	0.3210 (5)	0.6452 (4)	0.2283 (3)	0.0295 (14)	0.50
O2	0.2339 (9)	0.7636 (6)	0.2241 (4)	0.078 (3)	0.50
O3	0.3200 (17)	0.5560 (9)	0.4207 (5)	0.028 (3)	0.50
O4	0.2743 (11)	0.3977 (9)	0.3921 (6)	0.042 (3)	0.50
C1	0.4186 (4)	0.7304 (3)	0.3792 (2)	0.0217 (16)	0.50
C2	0.5028 (5)	0.7330 (3)	0.4301 (2)	0.0273 (15)	0.50
H2	0.5165	0.6756	0.4399	0.033*	0.50
C3	0.5671 (4)	0.8197 (3)	0.4666 (2)	0.0278 (16)	0.50
H3	0.6247	0.8215	0.5014	0.033*	0.50
C4	0.5472 (5)	0.9038 (3)	0.4523 (2)	0.0280 (16)	0.50
H4	0.5911	0.9630	0.4773	0.034*	0.50
C5	0.4629 (5)	0.9012 (3)	0.4014 (3)	0.028 (2)	0.50
H5	0.4493	0.9586	0.3916	0.034*	0.50
C6	0.3987 (5)	0.8145 (3)	0.3649 (2)	0.0262 (15)	0.50
H6	0.3411	0.8127	0.3301	0.031*	0.50
C7	0.1348 (8)	0.5250 (16)	0.3047 (7)	0.025 (3)	0.50
C8	0.0643 (12)	0.5119 (17)	0.3543 (5)	0.038 (6)	0.50
H8	0.0987	0.5350	0.3977	0.046*	0.50
C9	−0.0566 (12)	0.4652 (14)	0.3405 (5)	0.050 (4)	0.50
H9	−0.1048	0.4562	0.3744	0.060*	0.50
C10	−0.1069 (7)	0.4315 (10)	0.2770 (5)	0.036 (3)	0.50
H10	−0.1895	0.3995	0.2676	0.044*	0.50
C11	−0.0364 (8)	0.4445 (9)	0.2274 (4)	0.037 (3)	0.50
H11	−0.0707	0.4215	0.1841	0.045*	0.50
C12	0.0845 (8)	0.4913 (12)	0.2412 (6)	0.038 (3)	0.50
H12	0.1328	0.5003	0.2073	0.046*	0.50
C13	0.4290 (12)	0.5027 (12)	0.2852 (9)	0.028 (5)	0.50
H13	0.4453	0.4632	0.3179	0.033*	0.50
C14	0.3640 (12)	0.4362 (11)	0.2236 (8)	0.033 (4)	0.50
H14A	0.2895	0.3932	0.2334	0.040*	0.50
H14B	0.3422	0.4746	0.1920	0.040*	0.50
C15	0.4401 (13)	0.3769 (11)	0.1939 (9)	0.058 (5)	0.50
H15A	0.4044	0.3487	0.1492	0.069*	0.50
H15B	0.4385	0.3239	0.2183	0.069*	0.50
C16	0.5693 (13)	0.4329 (12)	0.1931 (8)	0.062 (5)	0.50
H16A	0.6169	0.3870	0.1874	0.074*	0.50
H16B	0.5735	0.4654	0.1549	0.074*	0.50
C17	0.6279 (11)	0.5068 (11)	0.2517 (7)	0.056 (4)	0.50
H17A	0.7031	0.5486	0.2416	0.067*	0.50
H17B	0.6476	0.4744	0.2874	0.067*	0.50
C18	0.5466 (13)	0.5674 (9)	0.2728 (8)	0.043 (4)	0.50
H18A	0.5849	0.6125	0.3125	0.051*	0.50
H18B	0.5326	0.6048	0.2389	0.051*	0.50
C19	0.2694 (5)	0.6960 (5)	0.2005 (4)	0.040 (2)	0.50
C20	0.2499 (7)	0.6690 (6)	0.1274 (4)	0.051 (3)	0.50
C21	0.2977 (8)	0.4727 (9)	0.4304 (6)	0.059 (6)	0.50
C22	0.3034 (11)	0.4748 (7)	0.5018 (5)	0.058 (4)	0.50
Sn1'	0.3038 (2)	0.5812 (2)	0.31102 (11)	0.0292 (4)	0.50
Cl1'	0.2833 (6)	0.5241 (4)	0.0652 (3)	0.1173 (14)	0.50
Cl2'	0.3929 (2)	0.5095 (2)	0.55380 (13)	0.0527 (5)	0.50
F1'	0.1086 (10)	0.5710 (8)	0.0934 (6)	0.1173 (14)	0.50
F2'	0.2367 (12)	0.6816 (7)	0.0637 (6)	0.1173 (14)	0.50
F3'	0.1830 (6)	0.4559 (7)	0.5093 (3)	0.0527 (5)	0.50
F4'	0.2678 (6)	0.3484 (5)	0.5017 (3)	0.0527 (5)	0.50
O1'	0.2710 (12)	0.6059 (8)	0.2095 (4)	0.083 (3)	0.50
O2'	0.3684 (10)	0.7266 (7)	0.1707 (6)	0.103 (4)	0.50
O3'	0.3313 (17)	0.5416 (8)	0.4116 (5)	0.030 (3)	0.50
O4'	0.3060 (9)	0.3869 (8)	0.3860 (6)	0.030 (2)	0.50
C1'	0.3646 (5)	0.7312 (3)	0.3484 (3)	0.0313 (17)	0.50
C2'	0.4628 (5)	0.7677 (4)	0.3950 (3)	0.037 (2)	0.50
H2'	0.5021	0.7261	0.4120	0.044*	0.50
C3'	0.5036 (5)	0.8652 (4)	0.4167 (3)	0.040 (2)	0.50
H3'	0.5707	0.8901	0.4486	0.048*	0.50
C4'	0.4462 (6)	0.9261 (3)	0.3919 (3)	0.039 (3)	0.50
H4'	0.4740	0.9927	0.4068	0.047*	0.50
C5'	0.3480 (6)	0.8896 (4)	0.3454 (3)	0.040 (2)	0.50
H5'	0.3087	0.9312	0.3284	0.048*	0.50
C6'	0.3072 (4)	0.7921 (4)	0.3236 (3)	0.0349 (18)	0.50
H6'	0.2401	0.7672	0.2918	0.042*	0.50
C7'	0.1182 (8)	0.5196 (18)	0.3038 (8)	0.039 (5)	0.50
C8'	0.0626 (12)	0.5157 (19)	0.3594 (6)	0.043 (6)	0.50
H8'	0.1077	0.5425	0.4001	0.052*	0.50
C9'	−0.0591 (12)	0.4725 (15)	0.3553 (5)	0.049 (4)	0.50
H9'	−0.0971	0.4698	0.3933	0.058*	0.50
C10'	−0.1251 (8)	0.4333 (10)	0.2957 (6)	0.052 (4)	0.50
H10'	−0.2082	0.4038	0.2930	0.062*	0.50
C11'	−0.0694 (10)	0.4372 (9)	0.2401 (5)	0.043 (3)	0.50
H11'	−0.1146	0.4103	0.1994	0.051*	0.50
C12'	0.0522 (10)	0.4803 (12)	0.2441 (6)	0.039 (3)	0.50
H12'	0.0902	0.4830	0.2061	0.047*	0.50
C13'	0.4352 (14)	0.5122 (11)	0.2808 (10)	0.033 (6)	0.50
H13'	0.4696	0.4930	0.3200	0.039*	0.50
C14'	0.3675 (12)	0.4201 (10)	0.2359 (8)	0.032 (4)	0.50
H14C	0.3219	0.4354	0.1994	0.038*	0.50
H14D	0.3102	0.3794	0.2595	0.038*	0.50
C15'	0.4528 (14)	0.3653 (8)	0.2102 (8)	0.046 (4)	0.50
H15C	0.4073	0.3064	0.1809	0.056*	0.50
H15D	0.4963	0.3471	0.2464	0.056*	0.50
C16'	0.5425 (13)	0.4302 (10)	0.1735 (7)	0.052 (4)	0.50
H16C	0.5927	0.3944	0.1520	0.062*	0.50
H16D	0.4999	0.4553	0.1407	0.062*	0.50
C17'	0.6189 (10)	0.5118 (9)	0.2255 (6)	0.038 (3)	0.50
H17C	0.6541	0.4854	0.2605	0.046*	0.50
H17D	0.6845	0.5526	0.2067	0.046*	0.50
C18'	0.5389 (14)	0.5703 (9)	0.2522 (7)	0.041 (4)	0.50
H18C	0.5872	0.6229	0.2858	0.049*	0.50
H18D	0.5081	0.5990	0.2172	0.049*	0.50
C19'	0.2908 (7)	0.6481 (6)	0.1643 (4)	0.068 (3)	0.50
C20'	0.2253 (10)	0.6095 (7)	0.0986 (4)	0.074 (4)	0.50
C21'	0.3107 (7)	0.4593 (7)	0.4248 (4)	0.0154 (19)	0.50
C22'	0.2883 (10)	0.4406 (7)	0.4935 (4)	0.030 (2)	0.50
Ag1	0.83481 (2)	1.043954 (19)	0.233263 (13)	0.02338 (9)
P1	0.95430 (10)	1.13312 (9)	0.33567 (5)	0.0351 (3)
P2	1.01377 (8)	1.11636 (8)	0.18360 (5)	0.0254 (2)
P3	0.74021 (11)	0.87088 (7)	0.22093 (6)	0.0346 (3)
P4	0.62866 (9)	1.05532 (7)	0.20820 (5)	0.0277 (2)
C23	1.0438 (5)	1.0535 (4)	0.3782 (2)	0.0232 (18)	0.50
C24	1.0833 (5)	1.0735 (4)	0.4437 (2)	0.0336 (18)	0.50
H24	1.0687	1.1260	0.4696	0.040*	0.50
C25	1.1441 (6)	1.0169 (4)	0.4713 (2)	0.042 (2)	0.50
H25	1.1711	1.0306	0.5161	0.051*	0.50
C26	1.1654 (5)	0.9402 (4)	0.4334 (3)	0.038 (2)	0.50
H26	1.2070	0.9015	0.4523	0.046*	0.50
C27	1.1259 (5)	0.9201 (3)	0.3680 (3)	0.0364 (19)	0.50
H27	1.1405	0.8677	0.3421	0.044*	0.50
C28	1.0651 (5)	0.9768 (4)	0.34035 (19)	0.0280 (16)	0.50
H28	1.0381	0.9630	0.2956	0.034*	0.50
C29	0.9044 (6)	1.1842 (6)	0.4057 (3)	0.024 (2)	0.50
C30	0.8012 (6)	1.1321 (4)	0.4266 (3)	0.0315 (19)	0.50
H30	0.7642	1.0681	0.4068	0.038*	0.50
C31	0.7521 (6)	1.1735 (5)	0.4764 (3)	0.041 (2)	0.50
H31	0.6815	1.1379	0.4906	0.049*	0.50
C32	0.8062 (7)	1.2672 (5)	0.5053 (3)	0.042 (3)	0.50
H32	0.7726	1.2955	0.5393	0.051*	0.50
C33	0.9094 (8)	1.3193 (4)	0.4844 (5)	0.051 (4)	0.50
H33	0.9464	1.3833	0.5042	0.061*	0.50
C34	0.9585 (7)	1.2778 (6)	0.4346 (5)	0.040 (3)	0.50
H34	1.0291	1.3134	0.4204	0.048*	0.50
C23'	1.0558 (4)	1.0982 (4)	0.3781 (2)	0.0219 (17)	0.50
C24'	1.1553 (4)	1.1608 (3)	0.4159 (3)	0.0284 (16)	0.50
H24'	1.1704	1.2274	0.4168	0.034*	0.50
C25'	1.2326 (4)	1.1257 (3)	0.4524 (3)	0.0333 (18)	0.50
H25'	1.3007	1.1685	0.4782	0.040*	0.50
C26'	1.2105 (5)	1.0282 (4)	0.4512 (3)	0.0343 (18)	0.50
H26'	1.2633	1.0043	0.4761	0.041*	0.50
C27'	1.1109 (5)	0.9657 (3)	0.4134 (3)	0.038 (2)	0.50
H27'	1.0958	0.8990	0.4125	0.046*	0.50
C28'	1.0336 (4)	1.0007 (3)	0.3769 (3)	0.0287 (17)	0.50
H28'	0.9656	0.9579	0.3511	0.034*	0.50
C29'	0.8794 (6)	1.1990 (6)	0.3937 (4)	0.024 (2)	0.50
C30'	0.7662 (6)	1.1517 (5)	0.4062 (3)	0.039 (2)	0.50
H30'	0.7256	1.0908	0.3823	0.046*	0.50
C31'	0.7123 (6)	1.1936 (6)	0.4535 (3)	0.045 (2)	0.50
H31'	0.6349	1.1613	0.4620	0.053*	0.50
C32'	0.7717 (8)	1.2827 (6)	0.4884 (4)	0.047 (3)	0.50
H32'	0.7349	1.3113	0.5208	0.057*	0.50
C33'	0.8849 (8)	1.3299 (5)	0.4760 (5)	0.055 (4)	0.50
H33'	0.9255	1.3909	0.4999	0.067*	0.50
C34'	0.9388 (6)	1.2881 (6)	0.4287 (5)	0.047 (4)	0.50
H34'	1.0162	1.3204	0.4202	0.056*	0.50
C35	1.0601 (6)	1.2298 (4)	0.3057 (3)	0.071 (2)
H35A	1.0174	1.2732	0.2896	0.085*
H35B	1.1216	1.2670	0.3413	0.085*
C36	1.1200 (4)	1.1889 (4)	0.2513 (2)	0.0450 (12)
H36A	1.1674	1.1495	0.2687	0.054*
H36B	1.1755	1.2421	0.2356	0.054*
C37	1.0094 (5)	1.1699 (4)	0.1123 (2)	0.0283 (16)	0.50
C38	1.0335 (7)	1.2683 (4)	0.1183 (2)	0.049 (3)	0.50
H38	1.0564	1.3065	0.1596	0.059*	0.50
C39	1.0241 (8)	1.3107 (3)	0.0639 (3)	0.059 (3)	0.50
H39	1.0405	1.3779	0.0680	0.071*	0.50
C40	0.9905 (7)	1.2547 (4)	0.0035 (3)	0.049 (2)	0.50
H40	0.9841	1.2837	−0.0336	0.059*	0.50
C41	0.9665 (6)	1.1564 (4)	−0.00245 (19)	0.039 (2)	0.50
H41	0.9436	1.1181	−0.0437	0.047*	0.50
C42	0.9759 (5)	1.1140 (3)	0.0519 (3)	0.0292 (16)	0.50
H42	0.9595	1.0467	0.0479	0.035*	0.50
C43	1.1035 (4)	1.0292 (4)	0.1636 (3)	0.0289 (18)	0.50
C44	1.0775 (4)	0.9427 (4)	0.1863 (3)	0.0339 (18)	0.50
H44	1.0118	0.9254	0.2100	0.041*	0.50
C45	1.1477 (5)	0.8816 (4)	0.1744 (3)	0.042 (2)	0.50
H45	1.1300	0.8225	0.1900	0.050*	0.50
C46	1.2439 (5)	0.9069 (4)	0.1398 (3)	0.043 (2)	0.50
H46	1.2919	0.8651	0.1316	0.051*	0.50
C47	1.2699 (4)	0.9934 (4)	0.1170 (3)	0.044 (2)	0.50
H47	1.3356	1.0107	0.0933	0.053*	0.50
C48	1.1997 (5)	1.0545 (4)	0.1289 (3)	0.0349 (18)	0.50
H48	1.2174	1.1136	0.1134	0.042*	0.50
C37'	1.0022 (4)	1.2159 (3)	0.1379 (2)	0.0222 (14)	0.50
C38'	1.1006 (3)	1.2865 (4)	0.1274 (3)	0.0276 (17)	0.50
H38'	1.1780	1.2888	0.1460	0.033*	0.50
C39'	1.0860 (4)	1.3538 (4)	0.0896 (3)	0.0363 (19)	0.50
H39'	1.1533	1.4021	0.0824	0.044*	0.50
C40'	0.9729 (5)	1.3505 (4)	0.0625 (3)	0.039 (2)	0.50
H40'	0.9629	1.3965	0.0367	0.047*	0.50
C41'	0.8744 (4)	1.2799 (4)	0.0730 (3)	0.0379 (19)	0.50
H41'	0.7971	1.2776	0.0544	0.046*	0.50
C42'	0.8890 (4)	1.2126 (3)	0.1108 (3)	0.0279 (16)	0.50
H42'	0.8217	1.1643	0.1180	0.033*	0.50
C43'	1.0957 (5)	1.0515 (4)	0.1367 (2)	0.0229 (15)	0.50
C44'	1.1335 (6)	0.9829 (4)	0.1647 (2)	0.039 (2)	0.50
H44'	1.1261	0.9785	0.2087	0.047*	0.50
C45'	1.1822 (6)	0.9206 (4)	0.1282 (3)	0.043 (2)	0.50
H45'	1.2081	0.8737	0.1474	0.052*	0.50
C46'	1.1931 (6)	0.9270 (4)	0.0638 (3)	0.0378 (19)	0.50
H46'	1.2263	0.8844	0.0389	0.045*	0.50
C47'	1.1552 (6)	0.9956 (5)	0.0359 (2)	0.048 (2)	0.50
H47'	1.1626	1.0000	−0.0081	0.058*	0.50
C48'	1.1065 (6)	1.0579 (4)	0.0723 (3)	0.039 (2)	0.50
H48'	1.0807	1.1048	0.0532	0.047*	0.50
C49	0.7244 (9)	0.7974 (7)	0.1445 (3)	0.030 (3)	0.50
C50	0.6254 (8)	0.7197 (8)	0.1234 (5)	0.042 (3)	0.50
H50	0.5629	0.7049	0.1494	0.051*	0.50
C51	0.6180 (8)	0.6638 (6)	0.0640 (5)	0.055 (5)	0.50
H51	0.5503	0.6107	0.0496	0.066*	0.50
C52	0.7095 (9)	0.6854 (6)	0.0259 (4)	0.056 (4)	0.50
H52	0.7044	0.6472	−0.0147	0.067*	0.50
C53	0.8085 (8)	0.7631 (6)	0.0470 (3)	0.059 (3)	0.50
H53	0.8710	0.7779	0.0210	0.070*	0.50
C54	0.8159 (7)	0.8190 (5)	0.1064 (3)	0.047 (2)	0.50
H54	0.8836	0.8721	0.1208	0.056*	0.50
C55	0.8058 (10)	0.8057 (8)	0.2796 (4)	0.026 (3)	0.50
C56	0.8742 (13)	0.7484 (11)	0.2559 (4)	0.036 (4)	0.50
H56	0.8861	0.7424	0.2117	0.043*	0.50
C57	0.9253 (13)	0.6998 (10)	0.2967 (6)	0.041 (3)	0.50
H57	0.9721	0.6606	0.2805	0.049*	0.50
C58	0.9080 (10)	0.7085 (9)	0.3613 (6)	0.040 (3)	0.50
H58	0.9429	0.6753	0.3892	0.048*	0.50
C59	0.8396 (8)	0.7658 (9)	0.3850 (4)	0.041 (3)	0.50
H59	0.8277	0.7718	0.4291	0.049*	0.50
C60	0.7885 (7)	0.8144 (7)	0.3441 (5)	0.033 (3)	0.50
H60	0.7417	0.8536	0.3603	0.040*	0.50
C49'	0.7158 (9)	0.8031 (7)	0.1369 (3)	0.045 (5)	0.50
C50'	0.6530 (11)	0.7071 (7)	0.1252 (5)	0.050 (4)	0.50
H50'	0.6232	0.6761	0.1596	0.059*	0.50
C51'	0.6339 (11)	0.6564 (5)	0.0631 (6)	0.076 (8)	0.50
H51'	0.5910	0.5908	0.0551	0.091*	0.50
C52'	0.6775 (9)	0.7017 (7)	0.0128 (4)	0.067 (5)	0.50
H52'	0.6644	0.6671	−0.0296	0.080*	0.50
C53'	0.7402 (7)	0.7977 (7)	0.0246 (3)	0.055 (3)	0.50
H53'	0.7700	0.8287	−0.0098	0.067*	0.50
C54'	0.7594 (6)	0.8484 (5)	0.0866 (3)	0.039 (2)	0.50
H54'	0.8023	0.9140	0.0946	0.047*	0.50
C55'	0.7755 (10)	0.7936 (8)	0.2709 (4)	0.027 (3)	0.50
C56'	0.8548 (13)	0.7418 (12)	0.2551 (5)	0.042 (5)	0.50
H56'	0.8751	0.7345	0.2125	0.050*	0.50
C57'	0.9044 (13)	0.7005 (12)	0.3016 (7)	0.050 (4)	0.50
H57'	0.9586	0.6651	0.2907	0.060*	0.50
C58'	0.8747 (10)	0.7110 (10)	0.3639 (6)	0.043 (3)	0.50
H58'	0.9086	0.6828	0.3957	0.051*	0.50
C59'	0.7953 (7)	0.7629 (8)	0.3798 (4)	0.036 (3)	0.50
H59'	0.7750	0.7701	0.4224	0.044*	0.50
C60'	0.7457 (7)	0.8041 (6)	0.3333 (5)	0.028 (2)	0.50
H60'	0.6915	0.8395	0.3441	0.034*	0.50
C61	0.5866 (5)	0.8688 (3)	0.2363 (3)	0.0544 (15)
H61A	0.5347	0.8024	0.2269	0.065*
H61B	0.5863	0.8933	0.2822	0.065*
C62	0.5384 (4)	0.9294 (3)	0.1945 (3)	0.0520 (14)
H62A	0.4560	0.9265	0.2030	0.062*
H62B	0.5354	0.9024	0.1487	0.062*
C63	0.5484 (7)	1.1143 (5)	0.2659 (4)	0.026 (3)	0.50
C64	0.4438 (7)	1.0673 (4)	0.2882 (4)	0.032 (2)	0.50
H64	0.4076	1.0015	0.2728	0.039*	0.50
C65	0.3922 (6)	1.1165 (6)	0.3328 (4)	0.043 (3)	0.50
H65	0.3208	1.0844	0.3479	0.051*	0.50
C66	0.4451 (8)	1.2128 (5)	0.3552 (4)	0.042 (3)	0.50
H66	0.4099	1.2464	0.3856	0.051*	0.50
C67	0.5497 (8)	1.2598 (4)	0.3329 (4)	0.056 (3)	0.50
H67	0.5859	1.3256	0.3483	0.067*	0.50
C68	0.6013 (7)	1.2106 (5)	0.2883 (4)	0.048 (3)	0.50
H68	0.6727	1.2427	0.2732	0.058*	0.50
C69	0.5863 (6)	1.0847 (4)	0.13523 (18)	0.025 (2)	0.50
C70	0.5839 (5)	1.0271 (3)	0.0773 (2)	0.0261 (15)	0.50
H70	0.6022	0.9682	0.0771	0.031*	0.50
C71	0.5547 (5)	1.0556 (4)	0.01946 (18)	0.0313 (17)	0.50
H71	0.5530	1.0162	−0.0202	0.038*	0.50
C72	0.5279 (6)	1.1418 (4)	0.0196 (2)	0.0341 (19)	0.50
H72	0.5079	1.1613	−0.0199	0.041*	0.50
C73	0.5303 (6)	1.1994 (3)	0.0776 (3)	0.0344 (19)	0.50
H73	0.5120	1.2583	0.0777	0.041*	0.50
C74	0.5595 (6)	1.1709 (4)	0.1354 (2)	0.0275 (16)	0.50
H74	0.5612	1.2103	0.1750	0.033*	0.50
C63'	0.5761 (6)	1.1219 (4)	0.2714 (3)	0.023 (2)	0.50
C64'	0.4560 (6)	1.1006 (4)	0.2793 (3)	0.030 (2)	0.50
H64'	0.4011	1.0458	0.2542	0.036*	0.50
C65'	0.4161 (4)	1.1594 (5)	0.3238 (3)	0.036 (2)	0.50
H65'	0.3340	1.1448	0.3292	0.044*	0.50
C66'	0.4965 (6)	1.2395 (5)	0.3605 (3)	0.033 (2)	0.50
H66'	0.4693	1.2797	0.3909	0.040*	0.50
C67'	0.6166 (5)	1.2608 (4)	0.3526 (3)	0.042 (2)	0.50
H67'	0.6715	1.3156	0.3777	0.050*	0.50
C68'	0.6565 (5)	1.2020 (5)	0.3081 (3)	0.0307 (18)	0.50
H68'	0.7386	1.2166	0.3027	0.037*	0.50
C69'	0.5882 (5)	1.1143 (5)	0.1357 (2)	0.026 (2)	0.50
C70'	0.6761 (4)	1.1382 (5)	0.0957 (3)	0.041 (2)	0.50
H70'	0.7504	1.1256	0.1046	0.049*	0.50
C71'	0.6552 (5)	1.1806 (5)	0.0426 (3)	0.049 (2)	0.50
H71'	0.7153	1.1969	0.0152	0.059*	0.50
C72'	0.5465 (6)	1.1990 (5)	0.0296 (3)	0.042 (2)	0.50
H72'	0.5322	1.2280	−0.0067	0.050*	0.50
C73'	0.4585 (4)	1.1751 (5)	0.0696 (3)	0.038 (2)	0.50
H73'	0.3842	1.1878	0.0607	0.045*	0.50
C74'	0.4794 (4)	1.1328 (5)	0.1227 (2)	0.0283 (16)	0.50
H74'	0.4193	1.1165	0.1501	0.034*	0.50

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.0258 (7)	0.0161 (6)	0.0219 (7)	0.0065 (5)	0.0011 (4)	0.0035 (5)
Cl1	0.144 (4)	0.132 (4)	0.066 (2)	0.003 (3)	−0.032 (2)	0.024 (2)
Cl2	0.210 (5)	0.105 (3)	0.103 (3)	0.059 (3)	0.010 (3)	0.045 (3)
F1	0.144 (4)	0.132 (4)	0.066 (2)	0.003 (3)	−0.032 (2)	0.024 (2)
F2	0.144 (4)	0.132 (4)	0.066 (2)	0.003 (3)	−0.032 (2)	0.024 (2)
F3	0.210 (5)	0.105 (3)	0.103 (3)	0.059 (3)	0.010 (3)	0.045 (3)
F4	0.210 (5)	0.105 (3)	0.103 (3)	0.059 (3)	0.010 (3)	0.045 (3)
O1	0.020 (3)	0.031 (3)	0.036 (3)	0.000 (2)	−0.004 (2)	0.016 (3)
O2	0.121 (7)	0.084 (6)	0.050 (4)	0.076 (5)	−0.017 (4)	0.000 (4)
O3	0.040 (5)	0.021 (4)	0.021 (4)	0.009 (4)	0.009 (3)	−0.011 (3)
O4	0.051 (6)	0.036 (5)	0.036 (5)	0.006 (4)	0.011 (4)	0.003 (4)
C1	0.024 (4)	0.023 (4)	0.021 (4)	0.010 (3)	0.005 (3)	0.006 (3)
C2	0.031 (4)	0.022 (3)	0.029 (4)	0.007 (3)	0.002 (3)	0.007 (3)
C3	0.027 (3)	0.031 (4)	0.023 (3)	0.006 (3)	0.000 (3)	0.003 (3)
C4	0.030 (4)	0.022 (3)	0.027 (4)	0.002 (3)	0.009 (3)	−0.004 (3)
C5	0.038 (5)	0.019 (4)	0.028 (4)	0.007 (4)	0.003 (3)	0.003 (3)
C6	0.033 (4)	0.024 (4)	0.023 (3)	0.012 (3)	0.001 (3)	0.001 (3)
C7	0.034 (5)	0.022 (6)	0.026 (6)	0.014 (4)	0.013 (4)	0.009 (5)
C8	0.047 (9)	0.030 (8)	0.036 (7)	0.009 (6)	0.014 (6)	−0.002 (5)
C9	0.053 (7)	0.046 (7)	0.048 (6)	0.004 (5)	0.031 (6)	0.000 (5)
C10	0.030 (5)	0.027 (5)	0.052 (6)	0.007 (4)	0.019 (5)	0.000 (5)
C11	0.028 (5)	0.047 (6)	0.043 (5)	0.012 (5)	0.023 (4)	0.014 (5)
C12	0.031 (5)	0.045 (6)	0.045 (6)	0.016 (5)	0.012 (5)	0.013 (5)
C13	0.026 (7)	0.020 (6)	0.038 (7)	0.009 (4)	0.002 (5)	0.006 (5)
C14	0.031 (5)	0.031 (6)	0.035 (6)	0.007 (4)	0.002 (4)	0.001 (5)
C15	0.056 (7)	0.053 (8)	0.069 (9)	0.031 (6)	0.008 (6)	−0.005 (6)
C16	0.047 (7)	0.058 (7)	0.083 (9)	0.022 (6)	0.020 (7)	−0.004 (6)
C17	0.037 (6)	0.056 (7)	0.076 (8)	0.015 (5)	0.018 (6)	0.008 (6)
C18	0.035 (5)	0.035 (6)	0.056 (8)	0.013 (4)	0.004 (5)	−0.003 (5)
C19	0.051 (5)	0.046 (5)	0.031 (4)	0.019 (4)	0.008 (4)	0.022 (4)
C20	0.082 (6)	0.031 (4)	0.031 (4)	0.006 (4)	−0.023 (4)	0.013 (4)
C21	0.058 (8)	0.051 (8)	0.059 (9)	0.006 (6)	0.003 (6)	0.000 (6)
C22	0.087 (8)	0.031 (7)	0.045 (6)	0.008 (6)	0.010 (6)	−0.012 (5)
Sn1'	0.0342 (10)	0.0237 (6)	0.0313 (10)	0.0082 (6)	0.0127 (6)	0.0043 (6)
Cl1'	0.160 (4)	0.089 (3)	0.104 (3)	0.036 (3)	0.015 (3)	0.017 (2)
Cl2'	0.0505 (12)	0.0691 (15)	0.0388 (11)	0.0200 (11)	0.0045 (9)	0.0039 (10)
F1'	0.160 (4)	0.089 (3)	0.104 (3)	0.036 (3)	0.015 (3)	0.017 (2)
F2'	0.160 (4)	0.089 (3)	0.104 (3)	0.036 (3)	0.015 (3)	0.017 (2)
F3'	0.0505 (12)	0.0691 (15)	0.0388 (11)	0.0200 (11)	0.0045 (9)	0.0039 (10)
F4'	0.0505 (12)	0.0691 (15)	0.0388 (11)	0.0200 (11)	0.0045 (9)	0.0039 (10)
O1'	0.126 (8)	0.079 (6)	0.057 (5)	0.035 (6)	0.030 (6)	0.027 (5)
O2'	0.092 (7)	0.093 (7)	0.110 (7)	0.004 (5)	0.015 (6)	0.014 (6)
O3'	0.037 (5)	0.022 (5)	0.029 (5)	0.013 (4)	0.004 (4)	−0.015 (3)
O4'	0.034 (5)	0.020 (3)	0.033 (4)	0.005 (3)	0.013 (3)	−0.003 (3)
C1'	0.036 (4)	0.025 (4)	0.038 (4)	0.012 (3)	0.015 (4)	0.010 (3)
C2'	0.039 (5)	0.030 (5)	0.042 (5)	0.010 (4)	0.007 (4)	0.006 (4)
C3'	0.038 (5)	0.036 (5)	0.043 (5)	0.006 (4)	0.004 (4)	0.005 (4)
C4'	0.050 (5)	0.029 (5)	0.044 (5)	0.015 (4)	0.014 (4)	0.006 (4)
C5'	0.046 (5)	0.031 (4)	0.047 (5)	0.014 (4)	0.016 (4)	0.012 (4)
C6'	0.036 (4)	0.034 (4)	0.037 (4)	0.010 (3)	0.012 (3)	0.009 (3)
C7'	0.042 (6)	0.031 (7)	0.053 (9)	0.022 (5)	0.007 (6)	0.009 (6)
C8'	0.040 (9)	0.046 (10)	0.046 (8)	0.015 (7)	0.017 (7)	0.003 (7)
C9'	0.048 (7)	0.045 (7)	0.057 (6)	0.019 (5)	0.017 (5)	0.005 (6)
C10'	0.049 (6)	0.037 (6)	0.073 (8)	0.014 (5)	0.003 (6)	0.019 (6)
C11'	0.050 (7)	0.036 (5)	0.037 (6)	0.002 (5)	0.003 (5)	0.012 (5)
C12'	0.053 (7)	0.038 (6)	0.030 (5)	0.016 (6)	0.005 (5)	0.013 (4)
C13'	0.035 (8)	0.020 (7)	0.042 (8)	0.006 (5)	0.008 (6)	0.000 (5)
C14'	0.035 (5)	0.023 (5)	0.036 (7)	0.006 (4)	0.007 (4)	0.007 (5)
C15'	0.058 (7)	0.024 (5)	0.054 (7)	0.007 (5)	0.024 (5)	−0.004 (5)
C16'	0.043 (7)	0.049 (6)	0.062 (7)	0.018 (5)	0.017 (6)	−0.009 (5)
C17'	0.023 (4)	0.042 (5)	0.052 (6)	0.010 (4)	0.011 (4)	0.007 (5)
C18'	0.038 (6)	0.033 (5)	0.046 (7)	−0.003 (4)	0.016 (5)	0.008 (5)
C19'	0.095 (8)	0.032 (5)	0.063 (7)	0.003 (5)	−0.012 (6)	0.001 (5)
C20'	0.080 (8)	0.094 (8)	0.048 (6)	0.029 (7)	0.001 (6)	0.005 (6)
C21'	0.017 (4)	0.018 (4)	0.007 (3)	0.002 (3)	−0.003 (3)	−0.003 (3)
C22'	0.050 (5)	0.020 (5)	0.020 (4)	0.015 (4)	0.001 (3)	−0.004 (4)
Ag1	0.02703 (15)	0.02058 (15)	0.02196 (15)	0.00455 (11)	0.00564 (10)	0.00431 (10)
P1	0.0313 (5)	0.0403 (6)	0.0224 (5)	−0.0052 (4)	0.0106 (4)	−0.0082 (4)
P2	0.0221 (4)	0.0356 (5)	0.0187 (4)	0.0066 (4)	0.0049 (3)	0.0069 (4)
P3	0.0498 (7)	0.0188 (5)	0.0351 (6)	0.0045 (4)	0.0264 (5)	0.0021 (4)
P4	0.0267 (5)	0.0267 (5)	0.0247 (5)	0.0014 (4)	0.0074 (4)	−0.0027 (4)
C23	0.015 (3)	0.026 (5)	0.024 (4)	−0.003 (4)	0.003 (3)	0.005 (4)
C24	0.035 (4)	0.038 (4)	0.028 (4)	0.015 (3)	−0.007 (3)	0.003 (3)
C25	0.047 (5)	0.050 (5)	0.034 (4)	0.021 (4)	−0.011 (4)	0.014 (4)
C26	0.030 (4)	0.039 (4)	0.046 (5)	0.012 (4)	−0.009 (4)	0.015 (4)
C27	0.029 (4)	0.032 (4)	0.048 (5)	0.012 (3)	0.001 (3)	0.002 (4)
C28	0.028 (4)	0.027 (4)	0.028 (4)	0.009 (3)	0.000 (3)	0.001 (3)
C29	0.032 (4)	0.029 (4)	0.017 (4)	0.014 (4)	0.003 (3)	0.008 (3)
C30	0.040 (5)	0.029 (4)	0.028 (4)	0.013 (3)	0.014 (4)	0.004 (3)
C31	0.049 (5)	0.046 (5)	0.036 (5)	0.023 (4)	0.020 (4)	0.014 (4)
C32	0.056 (6)	0.051 (5)	0.034 (5)	0.032 (5)	0.018 (4)	0.013 (4)
C33	0.067 (7)	0.041 (6)	0.046 (6)	0.024 (5)	0.009 (5)	−0.005 (5)
C34	0.044 (5)	0.039 (6)	0.037 (6)	0.012 (5)	0.014 (4)	−0.001 (4)
C23'	0.021 (3)	0.027 (4)	0.017 (3)	0.003 (3)	0.008 (3)	0.001 (3)
C24'	0.029 (4)	0.029 (4)	0.026 (4)	0.009 (3)	−0.002 (3)	0.002 (3)
C25'	0.031 (4)	0.035 (4)	0.033 (4)	0.012 (3)	−0.003 (3)	0.002 (3)
C26'	0.033 (4)	0.038 (4)	0.037 (4)	0.016 (4)	0.005 (3)	0.011 (3)
C27'	0.039 (4)	0.027 (4)	0.048 (5)	0.009 (3)	−0.004 (4)	0.011 (4)
C28'	0.029 (4)	0.019 (4)	0.035 (4)	0.000 (3)	0.002 (3)	0.006 (4)
C29'	0.029 (4)	0.034 (5)	0.015 (4)	0.017 (4)	0.003 (3)	0.008 (3)
C30'	0.042 (5)	0.048 (5)	0.028 (4)	0.013 (4)	0.008 (4)	0.011 (4)
C31'	0.048 (5)	0.061 (6)	0.036 (5)	0.026 (5)	0.021 (4)	0.016 (4)
C32'	0.063 (6)	0.056 (6)	0.037 (5)	0.038 (5)	0.016 (5)	0.008 (4)
C33'	0.059 (6)	0.053 (7)	0.055 (7)	0.025 (6)	0.016 (5)	−0.018 (5)
C34'	0.043 (6)	0.039 (6)	0.056 (7)	0.017 (5)	0.007 (5)	−0.011 (5)
C35	0.078 (4)	0.051 (3)	0.051 (3)	−0.032 (3)	0.038 (3)	−0.024 (2)
C36	0.038 (2)	0.051 (3)	0.028 (2)	−0.015 (2)	0.0110 (18)	−0.0055 (19)
C37	0.023 (3)	0.035 (4)	0.026 (4)	0.004 (3)	0.004 (3)	0.011 (3)
C38	0.065 (6)	0.038 (5)	0.036 (5)	0.004 (5)	0.002 (5)	0.006 (4)
C39	0.074 (7)	0.050 (6)	0.055 (6)	0.011 (5)	0.013 (5)	0.021 (5)
C40	0.053 (5)	0.063 (6)	0.038 (5)	0.015 (4)	0.012 (4)	0.027 (4)
C41	0.030 (4)	0.062 (5)	0.022 (4)	0.007 (4)	0.009 (3)	0.007 (4)
C42	0.026 (3)	0.034 (4)	0.025 (4)	0.003 (3)	0.000 (3)	0.008 (3)
C43	0.024 (4)	0.042 (5)	0.019 (4)	0.005 (3)	0.002 (3)	0.008 (4)
C44	0.030 (4)	0.041 (4)	0.032 (4)	0.009 (3)	0.006 (3)	0.010 (3)
C45	0.041 (4)	0.047 (5)	0.036 (4)	0.012 (4)	−0.002 (4)	0.006 (4)
C46	0.028 (4)	0.055 (5)	0.043 (5)	0.018 (4)	−0.005 (4)	−0.008 (4)
C47	0.029 (4)	0.058 (5)	0.044 (5)	0.012 (4)	0.004 (4)	0.000 (4)
C48	0.024 (4)	0.045 (5)	0.032 (4)	0.004 (3)	0.004 (3)	0.007 (3)
C37'	0.030 (4)	0.020 (3)	0.017 (3)	0.010 (3)	0.007 (3)	0.000 (3)
C38'	0.028 (4)	0.029 (4)	0.025 (4)	0.005 (3)	0.008 (3)	0.005 (3)
C39'	0.043 (5)	0.032 (4)	0.033 (4)	0.007 (4)	0.009 (4)	0.007 (3)
C40'	0.057 (5)	0.039 (5)	0.027 (4)	0.019 (4)	0.008 (4)	0.009 (3)
C41'	0.044 (4)	0.039 (4)	0.033 (4)	0.017 (4)	−0.005 (4)	0.005 (3)
C42'	0.033 (4)	0.026 (4)	0.024 (3)	0.008 (3)	0.002 (3)	0.002 (3)
C43'	0.021 (3)	0.023 (4)	0.024 (4)	0.005 (3)	0.005 (3)	0.000 (3)
C44'	0.050 (5)	0.044 (5)	0.032 (4)	0.023 (4)	0.013 (4)	0.009 (4)
C45'	0.047 (5)	0.043 (5)	0.048 (5)	0.027 (4)	0.013 (4)	0.005 (4)
C46'	0.036 (4)	0.038 (4)	0.039 (4)	0.014 (3)	0.010 (3)	−0.004 (4)
C47'	0.068 (6)	0.052 (5)	0.033 (4)	0.031 (5)	0.014 (4)	0.000 (4)
C48'	0.053 (5)	0.041 (4)	0.031 (4)	0.025 (4)	0.010 (4)	0.005 (3)
C49	0.038 (6)	0.028 (6)	0.024 (5)	0.009 (5)	0.014 (4)	0.002 (4)
C50	0.046 (6)	0.047 (6)	0.037 (5)	0.020 (5)	0.006 (4)	0.001 (4)
C51	0.075 (8)	0.042 (7)	0.045 (8)	0.020 (6)	−0.001 (6)	−0.011 (5)
C52	0.068 (7)	0.054 (6)	0.044 (6)	0.024 (6)	0.013 (5)	−0.014 (5)
C53	0.081 (7)	0.049 (5)	0.046 (5)	0.013 (5)	0.036 (5)	0.003 (4)
C54	0.070 (6)	0.033 (4)	0.034 (4)	0.005 (4)	0.025 (4)	0.003 (4)
C55	0.031 (6)	0.010 (4)	0.028 (5)	−0.010 (4)	0.009 (4)	−0.004 (4)
C56	0.042 (6)	0.027 (6)	0.035 (7)	0.005 (5)	0.014 (5)	−0.003 (5)
C57	0.050 (6)	0.034 (6)	0.036 (6)	0.011 (5)	0.004 (5)	0.000 (5)
C58	0.039 (6)	0.034 (5)	0.049 (6)	0.010 (4)	0.018 (5)	0.009 (4)
C59	0.046 (7)	0.050 (6)	0.036 (5)	0.017 (6)	0.026 (5)	0.022 (4)
C60	0.035 (6)	0.035 (5)	0.030 (5)	0.006 (4)	0.015 (4)	0.004 (4)
C49'	0.055 (8)	0.039 (8)	0.042 (7)	0.017 (6)	0.015 (6)	−0.001 (6)
C50'	0.062 (7)	0.033 (5)	0.049 (7)	0.010 (5)	0.000 (5)	0.001 (5)
C51'	0.085 (10)	0.069 (10)	0.064 (11)	0.017 (8)	−0.003 (8)	−0.011 (7)
C52'	0.073 (7)	0.078 (8)	0.057 (7)	0.046 (6)	0.009 (6)	−0.018 (6)
C53'	0.046 (5)	0.096 (7)	0.028 (4)	0.025 (5)	0.011 (4)	0.008 (5)
C54'	0.030 (4)	0.061 (5)	0.027 (4)	0.012 (4)	0.009 (3)	0.008 (4)
C55'	0.027 (6)	0.014 (5)	0.026 (4)	−0.013 (4)	0.006 (4)	−0.005 (4)
C56'	0.049 (7)	0.037 (7)	0.036 (7)	0.004 (5)	0.016 (5)	0.003 (6)
C57'	0.051 (7)	0.047 (7)	0.054 (8)	0.013 (5)	0.020 (6)	0.004 (6)
C58'	0.045 (7)	0.047 (6)	0.039 (5)	0.008 (5)	0.020 (5)	0.016 (5)
C59'	0.031 (5)	0.038 (5)	0.037 (5)	0.001 (4)	0.007 (4)	0.010 (4)
C60'	0.026 (5)	0.018 (4)	0.032 (5)	−0.006 (4)	0.003 (4)	0.004 (3)
C61	0.059 (3)	0.023 (2)	0.078 (4)	0.000 (2)	0.049 (3)	−0.001 (2)
C62	0.027 (2)	0.030 (2)	0.088 (4)	−0.0007 (18)	0.020 (2)	−0.017 (2)
C63	0.036 (5)	0.025 (5)	0.019 (4)	0.012 (3)	0.002 (4)	0.002 (4)
C64	0.028 (4)	0.037 (5)	0.034 (5)	0.015 (4)	0.002 (3)	0.003 (4)
C65	0.040 (5)	0.058 (6)	0.038 (5)	0.026 (5)	0.010 (4)	0.009 (5)
C66	0.055 (7)	0.047 (6)	0.036 (5)	0.029 (5)	0.013 (5)	0.009 (5)
C67	0.090 (8)	0.038 (5)	0.046 (6)	0.027 (5)	0.021 (6)	0.004 (4)
C68	0.064 (6)	0.039 (5)	0.042 (5)	0.009 (5)	0.025 (5)	0.008 (4)
C69	0.018 (4)	0.028 (5)	0.026 (4)	0.006 (3)	0.002 (3)	−0.001 (3)
C70	0.027 (3)	0.032 (4)	0.021 (3)	0.013 (3)	0.004 (3)	0.000 (3)
C71	0.032 (4)	0.044 (4)	0.019 (3)	0.014 (3)	0.006 (3)	0.001 (3)
C72	0.041 (4)	0.039 (5)	0.020 (4)	0.008 (4)	0.002 (3)	0.006 (3)
C73	0.046 (5)	0.033 (4)	0.034 (4)	0.025 (4)	0.007 (4)	0.009 (3)
C74	0.035 (4)	0.027 (4)	0.025 (4)	0.017 (3)	0.006 (3)	0.000 (3)
C63'	0.026 (4)	0.028 (5)	0.020 (5)	0.013 (3)	0.004 (3)	0.007 (4)
C64'	0.030 (5)	0.030 (5)	0.031 (4)	0.013 (4)	0.006 (3)	−0.002 (4)
C65'	0.026 (4)	0.045 (6)	0.042 (5)	0.017 (4)	0.010 (4)	0.001 (5)
C66'	0.034 (5)	0.037 (5)	0.028 (4)	0.014 (4)	0.008 (4)	−0.002 (4)
C67'	0.043 (5)	0.042 (5)	0.035 (5)	0.015 (4)	0.000 (4)	−0.008 (4)
C68'	0.033 (4)	0.033 (4)	0.026 (4)	0.014 (3)	−0.001 (3)	−0.002 (3)
C69'	0.024 (4)	0.034 (5)	0.017 (4)	0.005 (3)	−0.001 (3)	0.001 (3)
C70'	0.032 (4)	0.056 (5)	0.039 (4)	0.014 (4)	0.008 (3)	0.022 (4)
C71'	0.047 (5)	0.068 (6)	0.036 (5)	0.011 (4)	0.014 (4)	0.025 (4)
C72'	0.049 (5)	0.043 (5)	0.035 (5)	0.014 (4)	−0.003 (4)	0.016 (4)
C73'	0.042 (5)	0.038 (5)	0.037 (4)	0.022 (4)	−0.005 (4)	0.002 (4)
C74'	0.027 (4)	0.033 (4)	0.028 (4)	0.016 (3)	0.004 (3)	0.003 (3)

Geometric parameters (Å, º) top

Sn1—C13	2.144 (10)	C24'—H24'	0.95
Sn1—C1	2.161 (4)	C25'—C26'	1.39
Sn1—O3	2.176 (9)	C25'—H25'	0.95
Sn1—C7	2.186 (8)	C26'—C27'	1.39
Sn1—O1	2.270 (6)	C26'—H26'	0.95
Cl1—C20	1.718 (8)	C27'—C28'	1.39
Cl2—C22	1.650 (9)	C27'—H27'	0.95
F1—C20	1.359 (8)	C28'—H28'	0.95
F2—C20	1.348 (9)	C29'—C30'	1.39
F3—C22	1.326 (9)	C29'—C34'	1.39
F4—C22	1.352 (9)	C30'—C31'	1.39
O1—C19	1.257 (7)	C30'—H30'	0.95
O2—C19	1.243 (8)	C31'—C32'	1.39
O3—C21	1.235 (9)	C31'—H31'	0.95
O4—C21	1.233 (9)	C32'—C33'	1.39
C1—C2	1.39	C32'—H32'	0.95
C1—C6	1.39	C33'—C34'	1.39
C2—C3	1.39	C33'—H33'	0.95
C2—H2	0.95	C34'—H34'	0.95
C3—C4	1.39	C35—C36	1.534 (7)
C3—H3	0.95	C35—H35A	0.99
C4—C5	1.39	C35—H35B	0.99
C4—H4	0.95	C36—H36A	0.99
C5—C6	1.39	C36—H36B	0.99
C5—H5	0.95	C37—C38	1.39
C6—H6	0.95	C37—C42	1.39
C7—C8	1.39	C38—C39	1.39
C7—C12	1.39	C38—H38	0.95
C8—C9	1.39	C39—C40	1.39
C8—H8	0.95	C39—H39	0.95
C9—C10	1.39	C40—C41	1.39
C9—H9	0.95	C40—H40	0.95
C10—C11	1.39	C41—C42	1.39
C10—H10	0.95	C41—H41	0.95
C11—C12	1.39	C42—H42	0.95
C11—H11	0.95	C43—C44	1.39
C12—H12	0.95	C43—C48	1.39
C13—C18	1.519 (10)	C44—C45	1.39
C13—C14	1.530 (9)	C44—H44	0.95
C13—H13	1.00	C45—C46	1.39
C14—C15	1.526 (9)	C45—H45	0.95
C14—H14A	0.99	C46—C47	1.39
C14—H14B	0.99	C46—H46	0.95
C15—C16	1.524 (9)	C47—C48	1.39
C15—H15A	0.99	C47—H47	0.95
C15—H15B	0.99	C48—H48	0.95
C16—C17	1.517 (9)	C37'—C38'	1.39
C16—H16A	0.99	C37'—C42'	1.39
C16—H16B	0.99	C38'—C39'	1.39
C17—C18	1.528 (9)	C38'—H38'	0.95
C17—H17A	0.99	C39'—C40'	1.39
C17—H17B	0.99	C39'—H39'	0.95
C18—H18A	0.99	C40'—C41'	1.39
C18—H18B	0.99	C40'—H40'	0.95
C19—C20	1.525 (8)	C41'—C42'	1.39
C21—C22	1.501 (9)	C41'—H41'	0.95
Sn1'—C7'	2.109 (9)	C42'—H42'	0.95
Sn1'—C13'	2.159 (11)	C43'—C44'	1.39
Sn1'—C1'	2.155 (5)	C43'—C48'	1.39
Sn1'—O1'	2.243 (9)	C44'—C45'	1.39
Sn1'—O3'	2.298 (10)	C44'—H44'	0.95
Cl1'—C20'	1.690 (9)	C45'—C46'	1.39
Cl2'—C22'	1.705 (10)	C45'—H45'	0.95
F1'—C20'	1.324 (9)	C46'—C47'	1.39
F2'—C20'	1.357 (9)	C46'—H46'	0.95
F3'—C22'	1.375 (12)	C47'—C48'	1.39
F4'—C22'	1.355 (12)	C47'—H47'	0.95
O1'—C19'	1.214 (8)	C48'—H48'	0.95
O2'—C19'	1.251 (8)	C49—C50	1.39
O3'—C21'	1.249 (8)	C49—C54	1.39
O4'—C21'	1.244 (8)	C50—C51	1.39
C1'—C2'	1.39	C50—H50	0.95
C1'—C6'	1.39	C51—C52	1.39
C2'—C3'	1.39	C51—H51	0.95
C2'—H2'	0.95	C52—C53	1.39
C3'—C4'	1.39	C52—H52	0.95
C3'—H3'	0.95	C53—C54	1.39
C4'—C5'	1.39	C53—H53	0.95
C4'—H4'	0.95	C54—H54	0.95
C5'—C6'	1.39	C55—C56	1.39
C5'—H5'	0.95	C55—C60	1.39
C6'—H6'	0.95	C56—C57	1.39
C7'—C8'	1.39	C56—H56	0.95
C7'—C12'	1.39	C57—C58	1.39
C8'—C9'	1.39	C57—H57	0.95
C8'—H8'	0.95	C58—C59	1.39
C9'—C10'	1.39	C58—H58	0.95
C9'—H9'	0.95	C59—C60	1.39
C10'—C11'	1.39	C59—H59	0.95
C10'—H10'	0.95	C60—H60	0.95
C11'—C12'	1.39	C49'—C50'	1.39
C11'—H11'	0.95	C49'—C54'	1.39
C12'—H12'	0.95	C50'—C51'	1.39
C13'—C18'	1.509 (9)	C50'—H50'	0.95
C13'—C14'	1.529 (9)	C51'—C52'	1.39
C13'—H13'	1.00	C51'—H51'	0.95
C14'—C15'	1.537 (9)	C52'—C53'	1.39
C14'—H14C	0.99	C52'—H52'	0.95
C14'—H14D	0.99	C53'—C54'	1.39
C15'—C16'	1.555 (9)	C53'—H53'	0.95
C15'—H15C	0.99	C54'—H54'	0.95
C15'—H15D	0.99	C55'—C56'	1.39
C16'—C17'	1.542 (9)	C55'—C60'	1.39
C16'—H16C	0.99	C56'—C57'	1.39
C16'—H16D	0.99	C56'—H56'	0.95
C17'—C18'	1.530 (9)	C57'—C58'	1.39
C17'—H17C	0.99	C57'—H57'	0.95
C17'—H17D	0.99	C58'—C59'	1.39
C18'—H18C	0.99	C58'—H58'	0.95
C18'—H18D	0.99	C59'—C60'	1.39
C19'—C20'	1.491 (9)	C59'—H59'	0.95
C21'—C22'	1.542 (8)	C60'—H60'	0.95
Ag1—P3	2.4682 (10)	C61—C62	1.517 (9)
Ag1—P2	2.4721 (10)	C61—H61A	0.99
Ag1—P1	2.4803 (11)	C61—H61B	0.99
Ag1—P4	2.4910 (11)	C62—H62A	0.99
P1—C23'	1.664 (4)	C62—H62B	0.99
P1—C29	1.785 (5)	C63—C64	1.39
P1—C35	1.844 (5)	C63—C68	1.39
P1—C29'	1.882 (6)	C64—C65	1.39
P1—C23	2.021 (4)	C64—H64	0.95
P2—C37	1.795 (4)	C65—C66	1.39
P2—C43'	1.795 (4)	C65—H65	0.95
P2—C36	1.828 (4)	C66—C67	1.39
P2—C37'	1.890 (4)	C66—H66	0.95
P2—C43	1.898 (4)	C67—C68	1.39
P3—C55'	1.759 (9)	C67—H67	0.95
P3—C49	1.789 (6)	C68—H68	0.95
P3—C61	1.852 (5)	C69—C70	1.39
P3—C49'	1.879 (7)	C69—C74	1.39
P3—C55	1.901 (7)	C70—C71	1.39
P4—C69	1.727 (4)	C70—H70	0.95
P4—C63'	1.801 (5)	C71—C72	1.39
P4—C62	1.849 (5)	C71—H71	0.95
P4—C63	1.867 (5)	C72—C73	1.39
P4—C69'	1.946 (4)	C72—H72	0.95
C23—C24	1.39	C73—C74	1.39
C23—C28	1.39	C73—H73	0.95
C24—C25	1.39	C74—H74	0.95
C24—H24	0.95	C63'—C64'	1.39
C25—C26	1.39	C63'—C68'	1.39
C25—H25	0.95	C64'—C65'	1.39
C26—C27	1.39	C64'—H64'	0.95
C26—H26	0.95	C65'—C66'	1.39
C27—C28	1.39	C65'—H65'	0.95
C27—H27	0.95	C66'—C67'	1.39
C28—H28	0.95	C66'—H66'	0.95
C29—C30	1.39	C67'—C68'	1.39
C29—C34	1.39	C67'—H67'	0.95
C30—C31	1.39	C68'—H68'	0.95
C30—H30	0.95	C69'—C70'	1.39
C31—C32	1.39	C69'—C74'	1.39
C31—H31	0.95	C70'—C71'	1.39
C32—C33	1.39	C70'—H70'	0.95
C32—H32	0.95	C71'—C72'	1.39
C33—C34	1.39	C71'—H71'	0.95
C33—H33	0.95	C72'—C73'	1.39
C34—H34	0.95	C72'—H72'	0.95
C23'—C24'	1.39	C73'—C74'	1.39
C23'—C28'	1.39	C73'—H73'	0.95
C24'—C25'	1.39	C74'—H74'	0.95

C13—Sn1—C1	119.1 (5)	C31—C32—H32	120.0
C13—Sn1—O3	100.3 (7)	C32—C33—C34	120.0
C1—Sn1—O3	80.9 (4)	C32—C33—H33	120.0
C13—Sn1—C7	112.9 (7)	C34—C33—H33	120.0
C1—Sn1—C7	128.0 (6)	C33—C34—C29	120.0
O3—Sn1—C7	88.5 (7)	C33—C34—H34	120.0
C13—Sn1—O1	87.5 (6)	C29—C34—H34	120.0
C1—Sn1—O1	94.8 (2)	C24'—C23'—C28'	120.0
O3—Sn1—O1	172.1 (5)	C24'—C23'—P1	123.7 (3)
C7—Sn1—O1	89.1 (5)	C28'—C23'—P1	116.2 (3)
C19—O1—Sn1	138.0 (5)	C25'—C24'—C23'	120.0
C21—O3—Sn1	121.9 (9)	C25'—C24'—H24'	120.0
C2—C1—C6	120.0	C23'—C24'—H24'	120.0
C2—C1—Sn1	116.9 (3)	C24'—C25'—C26'	120.0
C6—C1—Sn1	123.1 (3)	C24'—C25'—H25'	120.0
C3—C2—C1	120.0	C26'—C25'—H25'	120.0
C3—C2—H2	120.0	C25'—C26'—C27'	120.0
C1—C2—H2	120.0	C25'—C26'—H26'	120.0
C4—C3—C2	120.0	C27'—C26'—H26'	120.0
C4—C3—H3	120.0	C28'—C27'—C26'	120.0
C2—C3—H3	120.0	C28'—C27'—H27'	120.0
C3—C4—C5	120.0	C26'—C27'—H27'	120.0
C3—C4—H4	120.0	C27'—C28'—C23'	120.0
C5—C4—H4	120.0	C27'—C28'—H28'	120.0
C4—C5—C6	120.0	C23'—C28'—H28'	120.0
C4—C5—H5	120.0	C30'—C29'—C34'	120.0
C6—C5—H5	120.0	C30'—C29'—P1	117.9 (5)
C5—C6—C1	120.0	C34'—C29'—P1	121.7 (5)
C5—C6—H6	120.0	C29'—C30'—C31'	120.0
C1—C6—H6	120.0	C29'—C30'—H30'	120.0
C8—C7—C12	120.0	C31'—C30'—H30'	120.0
C8—C7—Sn1	121.3 (7)	C32'—C31'—C30'	120.0
C12—C7—Sn1	118.6 (7)	C32'—C31'—H31'	120.0
C7—C8—C9	120.0	C30'—C31'—H31'	120.0
C7—C8—H8	120.0	C33'—C32'—C31'	120.0
C9—C8—H8	120.0	C33'—C32'—H32'	120.0
C8—C9—C10	120.0	C31'—C32'—H32'	120.0
C8—C9—H9	120.0	C34'—C33'—C32'	120.0
C10—C9—H9	120.0	C34'—C33'—H33'	120.0
C9—C10—C11	120.0	C32'—C33'—H33'	120.0
C9—C10—H10	120.0	C33'—C34'—C29'	120.0
C11—C10—H10	120.0	C33'—C34'—H34'	120.0
C12—C11—C10	120.0	C29'—C34'—H34'	120.0
C12—C11—H11	120.0	C36—C35—P1	110.5 (4)
C10—C11—H11	120.0	C36—C35—H35A	109.6
C11—C12—C7	120.0	P1—C35—H35A	109.6
C11—C12—H12	120.0	C36—C35—H35B	109.6
C7—C12—H12	120.0	P1—C35—H35B	109.6
C18—C13—C14	111.1 (11)	H35A—C35—H35B	108.1
C18—C13—Sn1	107.3 (10)	C35—C36—P2	113.1 (4)
C14—C13—Sn1	112.3 (10)	C35—C36—H36A	109.0
C18—C13—H13	108.7	P2—C36—H36A	109.0
C14—C13—H13	108.7	C35—C36—H36B	109.0
Sn1—C13—H13	108.7	P2—C36—H36B	109.0
C15—C14—C13	111.9 (9)	H36A—C36—H36B	107.8
C15—C14—H14A	109.2	C38—C37—C42	120.0
C13—C14—H14A	109.2	C38—C37—P2	119.2 (3)
C15—C14—H14B	109.2	C42—C37—P2	120.7 (3)
C13—C14—H14B	109.2	C37—C38—C39	120.0
H14A—C14—H14B	107.9	C37—C38—H38	120.0
C14—C15—C16	114.0 (10)	C39—C38—H38	120.0
C14—C15—H15A	108.7	C40—C39—C38	120.0
C16—C15—H15A	108.7	C40—C39—H39	120.0
C14—C15—H15B	108.7	C38—C39—H39	120.0
C16—C15—H15B	108.7	C41—C40—C39	120.0
H15A—C15—H15B	107.6	C41—C40—H40	120.0
C17—C16—C15	116.9 (10)	C39—C40—H40	120.0
C17—C16—H16A	108.1	C40—C41—C42	120.0
C15—C16—H16A	108.1	C40—C41—H41	120.0
C17—C16—H16B	108.1	C42—C41—H41	120.0
C15—C16—H16B	108.1	C41—C42—C37	120.0
H16A—C16—H16B	107.3	C41—C42—H42	120.0
C16—C17—C18	111.5 (10)	C37—C42—H42	120.0
C16—C17—H17A	109.3	C44—C43—C48	120.0
C18—C17—H17A	109.3	C44—C43—P2	120.4 (3)
C16—C17—H17B	109.3	C48—C43—P2	119.5 (3)
C18—C17—H17B	109.3	C43—C44—C45	120.0
H17A—C17—H17B	108.0	C43—C44—H44	120.0
C13—C18—C17	109.1 (9)	C45—C44—H44	120.0
C13—C18—H18A	109.9	C46—C45—C44	120.0
C17—C18—H18A	109.9	C46—C45—H45	120.0
C13—C18—H18B	109.9	C44—C45—H45	120.0
C17—C18—H18B	109.9	C47—C46—C45	120.0
H18A—C18—H18B	108.3	C47—C46—H46	120.0
O2—C19—O1	129.3 (8)	C45—C46—H46	120.0
O2—C19—C20	117.3 (7)	C46—C47—C48	120.0
O1—C19—C20	113.5 (7)	C46—C47—H47	120.0
F2—C20—F1	99.1 (9)	C48—C47—H47	120.0
F2—C20—C19	112.5 (7)	C47—C48—C43	120.0
F1—C20—C19	113.6 (7)	C47—C48—H48	120.0
F2—C20—Cl1	109.1 (7)	C43—C48—H48	120.0
F1—C20—Cl1	115.4 (7)	C38'—C37'—C42'	120.0
C19—C20—Cl1	107.1 (5)	C38'—C37'—P2	123.2 (3)
O4—C21—O3	130.3 (13)	C42'—C37'—P2	116.7 (3)
O4—C21—C22	122.4 (11)	C39'—C38'—C37'	120.0
O3—C21—C22	107.3 (9)	C39'—C38'—H38'	120.0
F3—C22—F4	107.3 (10)	C37'—C38'—H38'	120.0
F3—C22—C21	115.0 (9)	C38'—C39'—C40'	120.0
F4—C22—C21	112.9 (10)	C38'—C39'—H39'	120.0
F3—C22—Cl2	111.5 (9)	C40'—C39'—H39'	120.0
F4—C22—Cl2	101.9 (8)	C39'—C40'—C41'	120.0
C21—C22—Cl2	107.5 (7)	C39'—C40'—H40'	120.0
C7'—Sn1'—C13'	127.1 (8)	C41'—C40'—H40'	120.0
C7'—Sn1'—C1'	115.3 (7)	C42'—C41'—C40'	120.0
C13'—Sn1'—C1'	117.5 (5)	C42'—C41'—H41'	120.0
C7'—Sn1'—O1'	86.1 (6)	C40'—C41'—H41'	120.0
C13'—Sn1'—O1'	88.3 (7)	C41'—C42'—C37'	120.0
C1'—Sn1'—O1'	93.1 (4)	C41'—C42'—H42'	120.0
C7'—Sn1'—O3'	91.6 (7)	C37'—C42'—H42'	120.0
C13'—Sn1'—O3'	89.4 (7)	C44'—C43'—C48'	120.0
C1'—Sn1'—O3'	92.0 (4)	C44'—C43'—P2	116.7 (3)
O1'—Sn1'—O3'	174.9 (4)	C48'—C43'—P2	122.6 (3)
C19'—O1'—Sn1'	154.9 (10)	C45'—C44'—C43'	120.0
C21'—O3'—Sn1'	126.1 (8)	C45'—C44'—H44'	120.0
C2'—C1'—C6'	120.0	C43'—C44'—H44'	120.0
C2'—C1'—Sn1'	120.8 (3)	C44'—C45'—C46'	120.0
C6'—C1'—Sn1'	119.1 (3)	C44'—C45'—H45'	120.0
C3'—C2'—C1'	120.0	C46'—C45'—H45'	120.0
C3'—C2'—H2'	120.0	C45'—C46'—C47'	120.0
C1'—C2'—H2'	120.0	C45'—C46'—H46'	120.0
C2'—C3'—C4'	120.0	C47'—C46'—H46'	120.0
C2'—C3'—H3'	120.0	C48'—C47'—C46'	120.0
C4'—C3'—H3'	120.0	C48'—C47'—H47'	120.0
C3'—C4'—C5'	120.0	C46'—C47'—H47'	120.0
C3'—C4'—H4'	120.0	C47'—C48'—C43'	120.0
C5'—C4'—H4'	120.0	C47'—C48'—H48'	120.0
C6'—C5'—C4'	120.0	C43'—C48'—H48'	120.0
C6'—C5'—H5'	120.0	C50—C49—C54	120.0
C4'—C5'—H5'	120.0	C50—C49—P3	122.1 (5)
C5'—C6'—C1'	120.0	C54—C49—P3	117.9 (5)
C5'—C6'—H6'	120.0	C51—C50—C49	120.0
C1'—C6'—H6'	120.0	C51—C50—H50	120.0
C8'—C7'—C12'	120.0	C49—C50—H50	120.0
C8'—C7'—Sn1'	119.5 (8)	C50—C51—C52	120.0
C12'—C7'—Sn1'	120.5 (8)	C50—C51—H51	120.0
C9'—C8'—C7'	120.0	C52—C51—H51	120.0
C9'—C8'—H8'	120.0	C53—C52—C51	120.0
C7'—C8'—H8'	120.0	C53—C52—H52	120.0
C10'—C9'—C8'	120.0	C51—C52—H52	120.0
C10'—C9'—H9'	120.0	C52—C53—C54	120.0
C8'—C9'—H9'	120.0	C52—C53—H53	120.0
C9'—C10'—C11'	120.0	C54—C53—H53	120.0
C9'—C10'—H10'	120.0	C53—C54—C49	120.0
C11'—C10'—H10'	120.0	C53—C54—H54	120.0
C12'—C11'—C10'	120.0	C49—C54—H54	120.0
C12'—C11'—H11'	120.0	C56—C55—C60	120.0
C10'—C11'—H11'	120.0	C56—C55—P3	117.5 (6)
C11'—C12'—C7'	120.0	C60—C55—P3	122.5 (6)
C11'—C12'—H12'	120.0	C55—C56—C57	120.0
C7'—C12'—H12'	120.0	C55—C56—H56	120.0
C18'—C13'—C14'	112.5 (10)	C57—C56—H56	120.0
C18'—C13'—Sn1'	117.4 (11)	C58—C57—C56	120.0
C14'—C13'—Sn1'	106.6 (10)	C58—C57—H57	120.0
C18'—C13'—H13'	106.5	C56—C57—H57	120.0
C14'—C13'—H13'	106.5	C57—C58—C59	120.0
Sn1'—C13'—H13'	106.5	C57—C58—H58	120.0
C13'—C14'—C15'	111.3 (9)	C59—C58—H58	120.0
C13'—C14'—H14C	109.4	C60—C59—C58	120.0
C15'—C14'—H14C	109.4	C60—C59—H59	120.0
C13'—C14'—H14D	109.4	C58—C59—H59	120.0
C15'—C14'—H14D	109.4	C59—C60—C55	120.0
H14C—C14'—H14D	108.0	C59—C60—H60	120.0
C14'—C15'—C16'	108.7 (10)	C55—C60—H60	120.0
C14'—C15'—H15C	109.9	C50'—C49'—C54'	120.0
C16'—C15'—H15C	109.9	C50'—C49'—P3	119.5 (5)
C14'—C15'—H15D	109.9	C54'—C49'—P3	120.5 (5)
C16'—C15'—H15D	109.9	C49'—C50'—C51'	120.0
H15C—C15'—H15D	108.3	C49'—C50'—H50'	120.0
C17'—C16'—C15'	105.1 (9)	C51'—C50'—H50'	120.0
C17'—C16'—H16C	110.7	C50'—C51'—C52'	120.0
C15'—C16'—H16C	110.7	C50'—C51'—H51'	120.0
C17'—C16'—H16D	110.7	C52'—C51'—H51'	120.0
C15'—C16'—H16D	110.7	C51'—C52'—C53'	120.0
H16C—C16'—H16D	108.8	C51'—C52'—H52'	120.0
C18'—C17'—C16'	108.3 (9)	C53'—C52'—H52'	120.0
C18'—C17'—H17C	110.0	C54'—C53'—C52'	120.0
C16'—C17'—H17C	110.0	C54'—C53'—H53'	120.0
C18'—C17'—H17D	110.0	C52'—C53'—H53'	120.0
C16'—C17'—H17D	110.0	C53'—C54'—C49'	120.0
H17C—C17'—H17D	108.4	C53'—C54'—H54'	120.0
C13'—C18'—C17'	113.1 (9)	C49'—C54'—H54'	120.0
C13'—C18'—H18C	109.0	C56'—C55'—C60'	120.0
C17'—C18'—H18C	109.0	C56'—C55'—P3	121.1 (7)
C13'—C18'—H18D	109.0	C60'—C55'—P3	117.0 (7)
C17'—C18'—H18D	109.0	C57'—C56'—C55'	120.0
H18C—C18'—H18D	107.8	C57'—C56'—H56'	120.0
O1'—C19'—O2'	121.1 (10)	C55'—C56'—H56'	120.0
O1'—C19'—C20'	122.2 (9)	C58'—C57'—C56'	120.0
O2'—C19'—C20'	116.7 (9)	C58'—C57'—H57'	120.0
F1'—C20'—F2'	103.4 (9)	C56'—C57'—H57'	120.0
F1'—C20'—C19'	118.2 (9)	C57'—C58'—C59'	120.0
F2'—C20'—C19'	109.0 (9)	C57'—C58'—H58'	120.0
F1'—C20'—Cl1'	106.6 (8)	C59'—C58'—H58'	120.0
F2'—C20'—Cl1'	111.9 (8)	C60'—C59'—C58'	120.0
C19'—C20'—Cl1'	107.7 (6)	C60'—C59'—H59'	120.0
O4'—C21'—O3'	124.9 (10)	C58'—C59'—H59'	120.0
O4'—C21'—C22'	114.5 (9)	C59'—C60'—C55'	120.0
O3'—C21'—C22'	120.6 (9)	C59'—C60'—H60'	120.0
F3'—C22'—F4'	99.6 (8)	C55'—C60'—H60'	120.0
F3'—C22'—C21'	112.0 (7)	C62—C61—P3	110.3 (3)
F4'—C22'—C21'	114.9 (8)	C62—C61—H61A	109.6
F3'—C22'—Cl2'	104.6 (6)	P3—C61—H61A	109.6
F4'—C22'—Cl2'	108.5 (6)	C62—C61—H61B	109.6
C21'—C22'—Cl2'	115.7 (7)	P3—C61—H61B	109.6
P3—Ag1—P2	123.91 (4)	H61A—C61—H61B	108.1
P3—Ag1—P1	120.82 (4)	C61—C62—P4	113.3 (4)
P2—Ag1—P1	84.65 (3)	C61—C62—H62A	108.9
P3—Ag1—P4	85.16 (4)	P4—C62—H62A	108.9
P2—Ag1—P4	127.78 (4)	C61—C62—H62B	108.9
P1—Ag1—P4	119.08 (4)	P4—C62—H62B	108.9
C23'—P1—C35	96.5 (3)	H62A—C62—H62B	107.7
C29—P1—C35	107.9 (3)	C64—C63—C68	120.0
C23'—P1—C29'	108.0 (3)	C64—C63—P4	124.0 (4)
C35—P1—C29'	103.1 (3)	C68—C63—P4	116.0 (4)
C29—P1—C23	98.2 (3)	C63—C64—C65	120.0
C35—P1—C23	109.7 (3)	C63—C64—H64	120.0
C23'—P1—Ag1	125.38 (19)	C65—C64—H64	120.0
C29—P1—Ag1	128.5 (3)	C66—C65—C64	120.0
C35—P1—Ag1	100.5 (2)	C66—C65—H65	120.0
C29'—P1—Ag1	117.7 (3)	C64—C65—H65	120.0
C23—P1—Ag1	111.49 (16)	C65—C66—C67	120.0
C37—P2—C36	115.2 (2)	C65—C66—H66	120.0
C43'—P2—C36	105.7 (3)	C67—C66—H66	120.0
C43'—P2—C37'	104.8 (3)	C66—C67—C68	120.0
C37—P2—C43	102.9 (3)	C66—C67—H67	120.0
C36—P2—C43	95.2 (3)	C68—C67—H67	120.0
C37'—P2—C43	125.8 (2)	C67—C68—C63	120.0
C37—P2—Ag1	123.7 (2)	C67—C68—H68	120.0
C43'—P2—Ag1	125.2 (2)	C63—C68—H68	120.0
C36—P2—Ag1	104.28 (14)	C70—C69—C74	120.0
C37'—P2—Ag1	115.35 (16)	C70—C69—P4	121.9 (3)
C43—P2—Ag1	111.87 (17)	C74—C69—P4	118.1 (3)
C55'—P3—C49	99.2 (5)	C71—C70—C69	120.0
C55'—P3—C61	102.8 (4)	C71—C70—H70	120.0
C49—P3—C61	105.3 (4)	C69—C70—H70	120.0
C55'—P3—C49'	105.3 (5)	C72—C71—C70	120.0
C61—P3—C49'	102.1 (4)	C72—C71—C71ⁱ	119.9 (6)
C49—P3—C55	104.1 (5)	C70—C71—C71ⁱ	98.5 (6)
C61—P3—C55	110.1 (4)	C72—C71—H71	120.0
C49'—P3—C55	110.4 (5)	C70—C71—H71	120.0
C55'—P3—Ag1	125.9 (4)	C71ⁱ—C71—H71	49.7
C49—P3—Ag1	120.2 (3)	C71—C72—C73	120.0
C61—P3—Ag1	100.77 (15)	C71—C72—H72	120.0
C49'—P3—Ag1	116.2 (3)	C73—C72—H72	120.0
C55—P3—Ag1	115.7 (4)	C74—C73—C72	120.0
C69—P4—C63'	109.2 (3)	C74—C73—H73	120.0
C69—P4—C62	98.3 (3)	C72—C73—H73	120.0
C63'—P4—C62	109.8 (3)	C73—C74—C69	120.0
C69—P4—C63	103.8 (3)	C73—C74—H74	120.0
C62—P4—C63	103.1 (3)	C69—C74—H74	120.0
C63'—P4—C69'	99.9 (3)	C64'—C63'—C68'	120.0
C62—P4—C69'	108.6 (3)	C64'—C63'—P4	121.2 (4)
C63—P4—C69'	95.7 (3)	C68'—C63'—P4	118.4 (4)
C69—P4—Ag1	119.8 (2)	C65'—C64'—C63'	120.0
C63'—P4—Ag1	115.0 (2)	C65'—C64'—H64'	120.0
C62—P4—Ag1	102.82 (17)	C63'—C64'—H64'	120.0
C63—P4—Ag1	124.4 (3)	C64'—C65'—C66'	120.0
C69'—P4—Ag1	120.63 (17)	C64'—C65'—H65'	120.0
C24—C23—C28	120.0	C66'—C65'—H65'	120.0
C24—C23—P1	121.6 (3)	C65'—C66'—C67'	120.0
C28—C23—P1	118.4 (3)	C65'—C66'—H66'	120.0
C25—C24—C23	120.0	C67'—C66'—H66'	120.0
C25—C24—H24	120.0	C66'—C67'—C68'	120.0
C23—C24—H24	120.0	C66'—C67'—H67'	120.0
C24—C25—C26	120.0	C68'—C67'—H67'	120.0
C24—C25—H25	120.0	C67'—C68'—C63'	120.0
C26—C25—H25	120.0	C67'—C68'—H68'	120.0
C27—C26—C25	120.0	C63'—C68'—H68'	120.0
C27—C26—H26	120.0	C70'—C69'—C74'	120.0
C25—C26—H26	120.0	C70'—C69'—P4	115.9 (3)
C28—C27—C26	120.0	C74'—C69'—P4	124.1 (3)
C28—C27—H27	120.0	C69'—C70'—C71'	120.0
C26—C27—H27	120.0	C69'—C70'—H70'	120.0
C27—C28—C23	120.0	C71'—C70'—H70'	120.0
C27—C28—H28	120.0	C72'—C71'—C70'	120.0
C23—C28—H28	120.0	C72'—C71'—H71'	120.0
C30—C29—C34	120.0	C70'—C71'—H71'	120.0
C30—C29—P1	118.4 (4)	C71'—C72'—C73'	120.0
C34—C29—P1	121.2 (4)	C71'—C72'—H72'	120.0
C29—C30—C31	120.0	C73'—C72'—H72'	120.0
C29—C30—H30	120.0	C74'—C73'—C72'	120.0
C31—C30—H30	120.0	C74'—C73'—H73'	120.0
C30—C31—C32	120.0	C72'—C73'—H73'	120.0
C30—C31—H31	120.0	C73'—C74'—C69'	120.0
C32—C31—H31	120.0	C73'—C74'—H74'	120.0
C33—C32—C31	120.0	C69'—C74'—H74'	120.0
C33—C32—H32	120.0

C13—Sn1—O1—C19	171.4 (8)	C35—P1—C29'—C30'	155.4 (5)
C1—Sn1—O1—C19	−69.6 (7)	C23—P1—C29'—C30'	−86.3 (5)
C7—Sn1—O1—C19	58.4 (9)	Ag1—P1—C29'—C30'	45.8 (5)
C13—Sn1—O3—C21	−45.1 (12)	C23'—P1—C29'—C34'	70.0 (5)
C1—Sn1—O3—C21	−163.2 (12)	C29—P1—C29'—C34'	79.2 (17)
C7—Sn1—O3—C21	67.9 (12)	C35—P1—C29'—C34'	−31.4 (6)
C13—Sn1—C1—C2	−53.1 (7)	C23—P1—C29'—C34'	87.0 (5)
O3—Sn1—C1—C2	43.7 (6)	Ag1—P1—C29'—C34'	−140.9 (4)
C7—Sn1—C1—C2	124.5 (7)	C34'—C29'—C30'—C31'	0.0
O1—Sn1—C1—C2	−142.9 (3)	P1—C29'—C30'—C31'	173.4 (6)
C13—Sn1—C1—C6	125.5 (7)	C29'—C30'—C31'—C32'	0.0
O3—Sn1—C1—C6	−137.7 (6)	C30'—C31'—C32'—C33'	0.0
C7—Sn1—C1—C6	−56.9 (7)	C31'—C32'—C33'—C34'	0.0
O1—Sn1—C1—C6	35.7 (4)	C32'—C33'—C34'—C29'	0.0
C6—C1—C2—C3	0.0	C30'—C29'—C34'—C33'	0.0
Sn1—C1—C2—C3	178.6 (4)	P1—C29'—C34'—C33'	−173.1 (6)
C1—C2—C3—C4	0.0	C23'—P1—C35—C36	76.3 (5)
C2—C3—C4—C5	0.0	C29—P1—C35—C36	171.9 (5)
C3—C4—C5—C6	0.0	C29'—P1—C35—C36	−173.5 (5)
C4—C5—C6—C1	0.0	C23—P1—C35—C36	66.0 (5)
C2—C1—C6—C5	0.0	Ag1—P1—C35—C36	−51.6 (5)
Sn1—C1—C6—C5	−178.5 (4)	P1—C35—C36—P2	57.9 (6)
C13—Sn1—C7—C8	121.7 (10)	C37—P2—C36—C35	107.2 (5)
C1—Sn1—C7—C8	−56.0 (11)	C43'—P2—C36—C35	−165.3 (5)
O3—Sn1—C7—C8	21.1 (9)	C37'—P2—C36—C35	87.0 (5)
O1—Sn1—C7—C8	−151.4 (9)	C43—P2—C36—C35	−145.8 (5)
C13—Sn1—C7—C12	−55.5 (14)	Ag1—P2—C36—C35	−31.6 (5)
C1—Sn1—C7—C12	126.8 (9)	C43'—P2—C37—C38	−134.7 (4)
O3—Sn1—C7—C12	−156.0 (12)	C36—P2—C37—C38	−31.4 (4)
O1—Sn1—C7—C12	31.5 (11)	C37'—P2—C37—C38	19.6 (5)
C12—C7—C8—C9	0.0	C43—P2—C37—C38	−133.6 (4)
Sn1—C7—C8—C9	−177.1 (15)	Ag1—P2—C37—C38	98.6 (3)
C7—C8—C9—C10	0.0	C43'—P2—C37—C42	48.9 (4)
C8—C9—C10—C11	0.0	C36—P2—C37—C42	152.2 (4)
C9—C10—C11—C12	0.0	C37'—P2—C37—C42	−156.8 (7)
C10—C11—C12—C7	0.0	C43—P2—C37—C42	50.0 (4)
C8—C7—C12—C11	0.0	Ag1—P2—C37—C42	−77.8 (4)
Sn1—C7—C12—C11	177.2 (14)	C42—C37—C38—C39	0.0
C1—Sn1—C13—C18	−28.8 (14)	P2—C37—C38—C39	−176.4 (4)
O3—Sn1—C13—C18	−114.0 (12)	C37—C38—C39—C40	0.0
C7—Sn1—C13—C18	153.3 (11)	C38—C39—C40—C41	0.0
O1—Sn1—C13—C18	65.3 (11)	C39—C40—C41—C42	0.0
C1—Sn1—C13—C14	−151.1 (9)	C40—C41—C42—C37	0.0
O3—Sn1—C13—C14	123.7 (12)	C38—C37—C42—C41	0.0
C7—Sn1—C13—C14	31.0 (14)	P2—C37—C42—C41	176.3 (5)
O1—Sn1—C13—C14	−57.0 (12)	C37—P2—C43—C44	−145.5 (3)
C18—C13—C14—C15	56.6 (18)	C43'—P2—C43—C44	−142.7 (9)
Sn1—C13—C14—C15	176.7 (12)	C36—P2—C43—C44	97.1 (3)
C13—C14—C15—C16	−43 (2)	C37'—P2—C43—C44	−159.7 (3)
C14—C15—C16—C17	39 (2)	Ag1—P2—C43—C44	−10.6 (4)
C15—C16—C17—C18	−45 (2)	C37—P2—C43—C48	38.0 (4)
C14—C13—C18—C17	−63.0 (16)	C43'—P2—C43—C48	40.8 (7)
Sn1—C13—C18—C17	174.0 (11)	C36—P2—C43—C48	−79.4 (3)
C16—C17—C18—C13	56.2 (17)	C37'—P2—C43—C48	23.8 (4)
Sn1—O1—C19—O2	29.6 (7)	Ag1—P2—C43—C48	172.9 (3)
Sn1—O1—C19—C20	−150.9 (6)	C48—C43—C44—C45	0.0
O2—C19—C20—F2	−177.3 (8)	P2—C43—C44—C45	−176.5 (4)
O1—C19—C20—F2	3.1 (8)	C43—C44—C45—C46	0.0
O2—C19—C20—F1	71.2 (9)	C44—C45—C46—C47	0.0
O1—C19—C20—F1	−108.5 (9)	C45—C46—C47—C48	0.0
O2—C19—C20—Cl1	−57.4 (6)	C46—C47—C48—C43	0.0
O1—C19—C20—Cl1	122.9 (6)	C44—C43—C48—C47	0.0
Sn1—O3—C21—O4	−1.4 (12)	P2—C43—C48—C47	176.5 (4)
Sn1—O3—C21—C22	178.7 (12)	C37—P2—C37'—C38'	−88.9 (6)
O4—C21—C22—F3	−86.9 (11)	C43'—P2—C37'—C38'	−62.6 (4)
O3—C21—C22—F3	93.0 (11)	C36—P2—C37'—C38'	45.9 (3)
O4—C21—C22—F4	149.5 (10)	C43—P2—C37'—C38'	−56.2 (4)
O3—C21—C22—F4	−30.6 (10)	Ag1—P2—C37'—C38'	155.7 (3)
O4—C21—C22—Cl2	37.9 (10)	C37—P2—C37'—C42'	86.8 (6)
O3—C21—C22—Cl2	−142.1 (9)	C43'—P2—C37'—C42'	113.1 (3)
C7'—Sn1'—O1'—C19'	149.1 (19)	C36—P2—C37'—C42'	−138.4 (3)
C13'—Sn1'—O1'—C19'	−83.5 (18)	C43—P2—C37'—C42'	119.6 (3)
C1'—Sn1'—O1'—C19'	34.0 (17)	Ag1—P2—C37'—C42'	−28.6 (3)
C7'—Sn1'—O3'—C21'	64.3 (13)	C42'—C37'—C38'—C39'	0.0
C13'—Sn1'—O3'—C21'	−62.8 (12)	P2—C37'—C38'—C39'	175.6 (4)
C1'—Sn1'—O3'—C21'	179.7 (11)	C37'—C38'—C39'—C40'	0.0
C7'—Sn1'—C1'—C2'	134.7 (6)	C38'—C39'—C40'—C41'	0.0
C13'—Sn1'—C1'—C2'	−48.4 (8)	C39'—C40'—C41'—C42'	0.0
O1'—Sn1'—C1'—C2'	−138.1 (4)	C40'—C41'—C42'—C37'	0.0
O3'—Sn1'—C1'—C2'	42.0 (6)	C38'—C37'—C42'—C41'	0.0
C7'—Sn1'—C1'—C6'	−47.8 (7)	P2—C37'—C42'—C41'	−175.9 (4)
C13'—Sn1'—C1'—C6'	129.2 (7)	C37—P2—C43'—C44'	−178.5 (4)
O1'—Sn1'—C1'—C6'	39.4 (5)	C36—P2—C43'—C44'	67.6 (4)
O3'—Sn1'—C1'—C6'	−140.5 (6)	C37'—P2—C43'—C44'	170.1 (3)
C6'—C1'—C2'—C3'	0.0	C43—P2—C43'—C44'	4.3 (6)
Sn1'—C1'—C2'—C3'	177.5 (4)	Ag1—P2—C43'—C44'	−53.2 (4)
C1'—C2'—C3'—C4'	0.0	C37—P2—C43'—C48'	−8.0 (4)
C2'—C3'—C4'—C5'	0.0	C36—P2—C43'—C48'	−121.8 (4)
C3'—C4'—C5'—C6'	0.0	C37'—P2—C43'—C48'	−19.4 (4)
C4'—C5'—C6'—C1'	0.0	C43—P2—C43'—C48'	174.8 (9)
C2'—C1'—C6'—C5'	0.0	Ag1—P2—C43'—C48'	117.3 (3)
Sn1'—C1'—C6'—C5'	−177.5 (4)	C48'—C43'—C44'—C45'	0.0
C13'—Sn1'—C7'—C8'	118.4 (11)	P2—C43'—C44'—C45'	170.8 (4)
C1'—Sn1'—C7'—C8'	−65.0 (10)	C43'—C44'—C45'—C46'	0.0
O1'—Sn1'—C7'—C8'	−156.6 (9)	C44'—C45'—C46'—C47'	0.0
O3'—Sn1'—C7'—C8'	28.0 (9)	C45'—C46'—C47'—C48'	0.0
C13'—Sn1'—C7'—C12'	−59.5 (17)	C46'—C47'—C48'—C43'	0.0
C1'—Sn1'—C7'—C12'	117.1 (11)	C44'—C43'—C48'—C47'	0.0
O1'—Sn1'—C7'—C12'	25.5 (13)	P2—C43'—C48'—C47'	−170.2 (4)
O3'—Sn1'—C7'—C12'	−150.0 (13)	C55'—P3—C49—C50	74.7 (7)
C12'—C7'—C8'—C9'	0.0	C61—P3—C49—C50	−31.4 (6)
Sn1'—C7'—C8'—C9'	−177.9 (17)	C49'—P3—C49—C50	−92 (5)
C7'—C8'—C9'—C10'	0.0	C55—P3—C49—C50	84.5 (6)
C8'—C9'—C10'—C11'	0.0	Ag1—P3—C49—C50	−143.9 (4)
C9'—C10'—C11'—C12'	0.0	C55'—P3—C49—C54	−104.3 (7)
C10'—C11'—C12'—C7'	0.0	C61—P3—C49—C54	149.6 (5)
C8'—C7'—C12'—C11'	0.0	C49'—P3—C49—C54	89 (5)
Sn1'—C7'—C12'—C11'	177.9 (17)	C55—P3—C49—C54	−94.5 (7)
C7'—Sn1'—C13'—C18'	143.3 (12)	Ag1—P3—C49—C54	37.1 (7)
C1'—Sn1'—C13'—C18'	−33.2 (16)	C54—C49—C50—C51	0.0
O1'—Sn1'—C13'—C18'	59.5 (13)	P3—C49—C50—C51	−179.0 (8)
O3'—Sn1'—C13'—C18'	−125.1 (14)	C49—C50—C51—C52	0.0
C7'—Sn1'—C13'—C14'	16.1 (16)	C50—C51—C52—C53	0.0
C1'—Sn1'—C13'—C14'	−160.5 (9)	C51—C52—C53—C54	0.0
O1'—Sn1'—C13'—C14'	−67.8 (11)	C52—C53—C54—C49	0.0
O3'—Sn1'—C13'—C14'	107.7 (12)	C50—C49—C54—C53	0.0
C18'—C13'—C14'—C15'	49.0 (19)	P3—C49—C54—C53	179.0 (8)
Sn1'—C13'—C14'—C15'	179.0 (11)	C55'—P3—C55—C56	91 (4)
C13'—C14'—C15'—C16'	−58.9 (16)	C49—P3—C55—C56	27.5 (6)
C14'—C15'—C16'—C17'	67.0 (14)	C61—P3—C55—C56	139.9 (5)
C15'—C16'—C17'—C18'	−66.0 (13)	C49'—P3—C55—C56	27.9 (6)
C14'—C13'—C18'—C17'	−49.1 (19)	Ag1—P3—C55—C56	−106.7 (5)
Sn1'—C13'—C18'—C17'	−173.5 (11)	C55'—P3—C55—C60	−89 (4)
C16'—C17'—C18'—C13'	58.6 (16)	C49—P3—C55—C60	−153.1 (7)
Sn1'—O1'—C19'—O2'	−6.5 (17)	C61—P3—C55—C60	−40.7 (8)
Sn1'—O1'—C19'—C20'	173.1 (16)	C49'—P3—C55—C60	−152.7 (7)
O1'—C19'—C20'—F1'	43.3 (10)	Ag1—P3—C55—C60	72.7 (8)
O2'—C19'—C20'—F1'	−137.1 (10)	C60—C55—C56—C57	0.0
O1'—C19'—C20'—F2'	160.8 (9)	P3—C55—C56—C57	179.4 (7)
O2'—C19'—C20'—F2'	−19.6 (9)	C55—C56—C57—C58	0.0
O1'—C19'—C20'—Cl1'	−77.6 (8)	C56—C57—C58—C59	0.0
O2'—C19'—C20'—Cl1'	102.0 (8)	C57—C58—C59—C60	0.0
Sn1'—O3'—C21'—O4'	22.4 (11)	C58—C59—C60—C55	0.0
Sn1'—O3'—C21'—C22'	−157.5 (11)	C56—C55—C60—C59	0.0
O4'—C21'—C22'—F3'	−112.1 (9)	P3—C55—C60—C59	−179.3 (8)
O3'—C21'—C22'—F3'	67.8 (10)	C55'—P3—C49'—C50'	41.6 (6)
O4'—C21'—C22'—F4'	0.5 (10)	C49—P3—C49'—C50'	55 (5)
O3'—C21'—C22'—F4'	−179.6 (10)	C61—P3—C49'—C50'	−65.4 (5)
O4'—C21'—C22'—Cl2'	128.2 (8)	C55—P3—C49'—C50'	51.6 (6)
O3'—C21'—C22'—Cl2'	−51.9 (8)	Ag1—P3—C49'—C50'	−174.0 (4)
P3—Ag1—P1—C23'	45.1 (2)	C55'—P3—C49'—C54'	−138.7 (7)
P2—Ag1—P1—C23'	−81.6 (2)	C49—P3—C49'—C54'	−125 (5)
P4—Ag1—P1—C23'	147.7 (2)	C61—P3—C49'—C54'	114.2 (6)
P3—Ag1—P1—C29	−85.9 (3)	C55—P3—C49'—C54'	−128.7 (7)
P2—Ag1—P1—C29	147.5 (3)	Ag1—P3—C49'—C54'	5.6 (8)
P4—Ag1—P1—C29	16.8 (3)	C54'—C49'—C50'—C51'	0.0
P3—Ag1—P1—C35	150.9 (3)	P3—C49'—C50'—C51'	179.6 (8)
P2—Ag1—P1—C35	24.3 (3)	C49'—C50'—C51'—C52'	0.0
P4—Ag1—P1—C35	−106.4 (3)	C50'—C51'—C52'—C53'	0.0
P3—Ag1—P1—C29'	−98.1 (3)	C51'—C52'—C53'—C54'	0.0
P2—Ag1—P1—C29'	135.3 (3)	C52'—C53'—C54'—C49'	0.0
P4—Ag1—P1—C29'	4.6 (3)	C50'—C49'—C54'—C53'	0.0
P3—Ag1—P1—C23	34.70 (19)	P3—C49'—C54'—C53'	−179.6 (8)
P2—Ag1—P1—C23	−91.93 (19)	C49—P3—C55'—C56'	42.8 (6)
P4—Ag1—P1—C23	137.38 (18)	C61—P3—C55'—C56'	150.9 (5)
P3—Ag1—P2—C37	101.7 (2)	C49'—P3—C55'—C56'	44.3 (6)
P1—Ag1—P2—C37	−134.5 (2)	C55—P3—C55'—C56'	−75 (4)
P4—Ag1—P2—C37	−11.4 (2)	Ag1—P3—C55'—C56'	−95.5 (6)
P3—Ag1—P2—C43'	−2.5 (2)	C49—P3—C55'—C60'	−153.0 (6)
P1—Ag1—P2—C43'	121.3 (2)	C61—P3—C55'—C60'	−44.9 (7)
P4—Ag1—P2—C43'	−115.6 (2)	C49'—P3—C55'—C60'	−151.5 (6)
P3—Ag1—P2—C36	−124.0 (2)	C55—P3—C55'—C60'	89 (4)
P1—Ag1—P2—C36	−0.1 (2)	Ag1—P3—C55'—C60'	68.7 (8)
P4—Ag1—P2—C36	122.9 (2)	C60'—C55'—C56'—C57'	0.0
P3—Ag1—P2—C37'	130.27 (19)	P3—C55'—C56'—C57'	163.7 (8)
P1—Ag1—P2—C37'	−105.87 (19)	C55'—C56'—C57'—C58'	0.0
P4—Ag1—P2—C37'	17.17 (19)	C56'—C57'—C58'—C59'	0.0
P3—Ag1—P2—C43	−22.2 (2)	C57'—C58'—C59'—C60'	0.0
P1—Ag1—P2—C43	101.6 (2)	C58'—C59'—C60'—C55'	0.0
P4—Ag1—P2—C43	−135.3 (2)	C56'—C55'—C60'—C59'	0.0
P2—Ag1—P3—C55'	89.3 (5)	P3—C55'—C60'—C59'	−164.4 (7)
P1—Ag1—P3—C55'	−16.4 (5)	C55'—P3—C61—C62	−177.6 (5)
P4—Ag1—P3—C55'	−137.6 (5)	C49—P3—C61—C62	−74.3 (5)
P2—Ag1—P3—C49	−41.2 (4)	C49'—P3—C61—C62	−68.7 (5)
P1—Ag1—P3—C49	−146.9 (4)	C55—P3—C61—C62	174.0 (5)
P4—Ag1—P3—C49	91.9 (4)	Ag1—P3—C61—C62	51.4 (4)
P2—Ag1—P3—C61	−156.1 (2)	P3—C61—C62—P4	−59.4 (4)
P1—Ag1—P3—C61	98.2 (2)	C69—P4—C62—C61	157.2 (4)
P4—Ag1—P3—C61	−23.0 (2)	C63'—P4—C62—C61	−88.9 (4)
P2—Ag1—P3—C49'	−46.8 (4)	C63—P4—C62—C61	−96.4 (4)
P1—Ag1—P3—C49'	−152.5 (4)	C69'—P4—C62—C61	162.8 (4)
P4—Ag1—P3—C49'	86.4 (4)	Ag1—P4—C62—C61	33.9 (4)
P2—Ag1—P3—C55	85.2 (4)	C69—P4—C63—C64	100.3 (5)
P1—Ag1—P3—C55	−20.5 (4)	C63'—P4—C63—C64	−135 (3)
P4—Ag1—P3—C55	−141.7 (4)	C62—P4—C63—C64	−1.9 (6)
P3—Ag1—P4—C69	−109.0 (2)	C69'—P4—C63—C64	108.8 (5)
P2—Ag1—P4—C69	21.0 (2)	Ag1—P4—C63—C64	−117.7 (5)
P1—Ag1—P4—C69	128.2 (2)	C69—P4—C63—C68	−81.6 (5)
P3—Ag1—P4—C63'	117.8 (3)	C63'—P4—C63—C68	43 (2)
P2—Ag1—P4—C63'	−112.2 (3)	C62—P4—C63—C68	176.2 (4)
P1—Ag1—P4—C63'	−5.0 (3)	C69'—P4—C63—C68	−73.2 (5)
P3—Ag1—P4—C62	−1.4 (2)	Ag1—P4—C63—C68	60.4 (5)
P2—Ag1—P4—C62	128.6 (2)	C68—C63—C64—C65	0.0
P1—Ag1—P4—C62	−124.2 (2)	P4—C63—C64—C65	178.0 (7)
P3—Ag1—P4—C63	114.5 (3)	C63—C64—C65—C66	0.0
P2—Ag1—P4—C63	−115.5 (3)	C64—C65—C66—C67	0.0
P1—Ag1—P4—C63	−8.3 (3)	C65—C66—C67—C68	0.0
P3—Ag1—P4—C69'	−122.4 (3)	C66—C67—C68—C63	0.0
P2—Ag1—P4—C69'	7.6 (3)	C64—C63—C68—C67	0.0
P1—Ag1—P4—C69'	114.8 (3)	P4—C63—C68—C67	−178.1 (6)
C23'—P1—C23—C24	52.7 (9)	C63'—P4—C69—C70	−161.5 (4)
C29—P1—C23—C24	−21.0 (4)	C62—P4—C69—C70	−47.1 (4)
C35—P1—C23—C24	91.4 (4)	C63—P4—C69—C70	−152.9 (4)
C29'—P1—C23—C24	−23.0 (4)	C69'—P4—C69—C70	160.3 (16)
Ag1—P1—C23—C24	−158.1 (3)	Ag1—P4—C69—C70	63.0 (4)
C23'—P1—C23—C28	−127.5 (10)	C63'—P4—C69—C74	21.6 (4)
C29—P1—C23—C28	158.7 (4)	C62—P4—C69—C74	135.9 (3)
C35—P1—C23—C28	−88.8 (3)	C63—P4—C69—C74	30.1 (4)
C29'—P1—C23—C28	156.7 (4)	C69'—P4—C69—C74	−16.7 (13)
Ag1—P1—C23—C28	21.6 (3)	Ag1—P4—C69—C74	−114.0 (3)
C28—C23—C24—C25	0.0	C74—C69—C70—C71	0.0
P1—C23—C24—C25	179.7 (4)	P4—C69—C70—C71	−176.9 (5)
C23—C24—C25—C26	0.0	C69—C70—C71—C72	0.0
C24—C25—C26—C27	0.0	C69—C70—C71—C71ⁱ	−132.0 (6)
C25—C26—C27—C28	0.0	C70—C71—C72—C73	0.0
C26—C27—C28—C23	0.0	C71ⁱ—C71—C72—C73	122.0 (7)
C24—C23—C28—C27	0.0	C71—C72—C73—C74	0.0
P1—C23—C28—C27	−179.7 (4)	C72—C73—C74—C69	0.0
C23'—P1—C29—C30	−99.8 (5)	C70—C69—C74—C73	0.0
C35—P1—C29—C30	162.3 (5)	P4—C69—C74—C73	177.1 (5)
C29'—P1—C29—C30	88.9 (17)	C69—P4—C63'—C64'	72.0 (5)
C23—P1—C29—C30	−83.8 (5)	C62—P4—C63'—C64'	−34.7 (5)
Ag1—P1—C29—C30	42.1 (6)	C63—P4—C63'—C64'	14 (2)
C23'—P1—C29—C34	87.7 (5)	C69'—P4—C63'—C64'	79.3 (4)
C35—P1—C29—C34	−10.3 (6)	Ag1—P4—C63'—C64'	−150.0 (3)
C29'—P1—C29—C34	−83.6 (17)	C69—P4—C63'—C68'	−101.1 (5)
C23—P1—C29—C34	103.6 (5)	C62—P4—C63'—C68'	152.2 (4)
Ag1—P1—C29—C34	−130.4 (4)	C63—P4—C63'—C68'	−159 (3)
C34—C29—C30—C31	0.0	C69'—P4—C63'—C68'	−93.8 (4)
P1—C29—C30—C31	−172.6 (6)	Ag1—P4—C63'—C68'	36.9 (5)
C29—C30—C31—C32	0.0	C68'—C63'—C64'—C65'	0.0
C30—C31—C32—C33	0.0	P4—C63'—C64'—C65'	−173.0 (6)
C31—C32—C33—C34	0.0	C63'—C64'—C65'—C66'	0.0
C32—C33—C34—C29	0.0	C64'—C65'—C66'—C67'	0.0
C30—C29—C34—C33	0.0	C65'—C66'—C67'—C68'	0.0
P1—C29—C34—C33	172.4 (6)	C66'—C67'—C68'—C63'	0.0
C29—P1—C23'—C24'	−66.6 (4)	C64'—C63'—C68'—C67'	0.0
C35—P1—C23'—C24'	41.8 (4)	P4—C63'—C68'—C67'	173.2 (6)
C29'—P1—C23'—C24'	−64.3 (4)	C69—P4—C69'—C70'	−82.0 (14)
C23—P1—C23'—C24'	−174.5 (11)	C63'—P4—C69'—C70'	134.4 (4)
Ag1—P1—C23'—C24'	149.7 (3)	C62—P4—C69'—C70'	−110.7 (3)
C29—P1—C23'—C28'	110.3 (4)	C63—P4—C69'—C70'	143.4 (4)
C35—P1—C23'—C28'	−141.3 (3)	Ag1—P4—C69'—C70'	7.4 (4)
C29'—P1—C23'—C28'	112.6 (4)	C69—P4—C69'—C74'	97.9 (15)
C23—P1—C23'—C28'	2.4 (8)	C63'—P4—C69'—C74'	−45.7 (5)
Ag1—P1—C23'—C28'	−33.4 (4)	C62—P4—C69'—C74'	69.2 (4)
C28'—C23'—C24'—C25'	0.0	C63—P4—C69'—C74'	−36.7 (5)
P1—C23'—C24'—C25'	176.8 (4)	Ag1—P4—C69'—C74'	−172.7 (3)
C23'—C24'—C25'—C26'	0.0	C74'—C69'—C70'—C71'	0.0
C24'—C25'—C26'—C27'	0.0	P4—C69'—C70'—C71'	179.9 (5)
C25'—C26'—C27'—C28'	0.0	C69'—C70'—C71'—C72'	0.0
C26'—C27'—C28'—C23'	0.0	C70'—C71'—C72'—C73'	0.0
C24'—C23'—C28'—C27'	0.0	C71'—C72'—C73'—C74'	0.0
P1—C23'—C28'—C27'	−177.0 (4)	C72'—C73'—C74'—C69'	0.0
C23'—P1—C29'—C30'	−103.2 (5)	C70'—C69'—C74'—C73'	0.0
C29—P1—C29'—C30'	−94.1 (17)	P4—C69'—C74'—C73'	−179.9 (5)

Symmetry code: (i) −x+1, −y+2, −z.

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Bis[1,2-bis­(diphenyl­phosphino)ethane-κ2P,P′]silver(I) bis­(chloro­difluoro­acetato-κO)(cyclo­hexyl)diphenyl­stannate(IV)

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Bis[1,2-bis(diphenylphosphino)ethane-κ²P,P′]silver(I) bis(chlorodifluoroacetato-κO)(cyclohexyl)diphenylstannate(IV)