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Acta Cryst. (2009). E65, m1025    [ doi:10.1107/S1600536809029961 ]

cis-Dichloridobis(triphenylphosphine-[kappa]P)platinum(II) chloroform solvate

J. Miao, C. Hu, X. Feng, H. Chen and Y. Nie

Abstract top

In the title compound, [PtCl2(C18H15P)2]·CHCl3, each PtII centre adopts a nearly square-planar coordination geometry formed by two P atoms [Pt-P = 2.2481 (17) and 2.2658 (19) Å] and two Cl anions [Pt-Cl = 2.3244 (19) and 2.3548 (17) Å]. The Cl atoms of the chloroform solvent molecule are disordered over two orientations in a 0.778 (11):0.222 (11) ratio. The crystal packing is stabilized by weak intermolecular C-H...Cl hydrogen bonds, exhibiting voids with a volume of 215 Å3.

Comment top

cis- and trans-Dichloridobis (triphenylphosphine)platinum(II) are useful to prepare other platinum complexes. The structures of the cis-isomer, either in unsolvated form (Fun et al., 2006) or as an acetone (Anderson et al., 1982) or trichoroform solvate (Al-Fawaz et al., 2004) have been reported. During the course of our studies on platinaborane cluster compounds using the cis-isomer as a starting material, we unexpectedly obtained the yellowish crystals of the title compound (I).

As shown in Fig.1, the platinum centre is four-coordinated and adopts a nearly square planar geometry. The Pt—P bond lengths (2.2481 (17) and 2.2658 (19) Å) and Pt—Cl bond lengths (2.3244 (19) and 2.3548 (17) Å), as well as the bond angles around the Pt atom are similar to those in the above-mentioned structures.

Intermolecular C—H···Cl hydrogen bonding is observed between the chloroform and the chloride (Table 1). Moreover, similar C—H···Cl interaction between one of the phenyl groups and the chloride (Table 1) links the molecules into a one-dimensional chain structure.

Related literature top

For the preparation of cis-[PtCl2(PPh3)2], see: Bailar & Itatani (1965). For the structure of trans-[PtCl2(PPh3)2], see: Johansson & Otto (2000). For the structures of related cis-complexes, see: Anderson et al. (1982); Al-Fawaz et al. (2004); Fun et al. (2006).

Experimental top

A mixture of PtCl2(PPh3)2 (314 mg, 0.4 mmol) and (Et4N)2B10H10 (150 mg, 0.4 mmol) in HOCH2CH2OH (38 ml) was heated at 100°C (oil) under N2 atomosphere for 39 h. The resulting mixture was filtered to get a red filtrate, to which ca 400 ml of water was added. The lower layer formed was separated and treated with water. This process was repeated till the lower layer was colourless. The upper water phase combined was extracted with CH2Cl2. The yellow organic layer was dried to result in a reddish solid. Recrystalization in CHCl3/n-hexane(1:4, V: V) afforded a small amount of yellowish crystals of the title compound suitable for X-ray analysis.

Refinement top

All H-atoms were positioned geometrically and refined using a riding model with d(C—H) = 0.93 Å, Uiso=1.2Ueq (C) for aromatic, and d(C—H) = 0.98 Å, Uiso=1.5Ueq (C) for CHCl3. The highest residual peak [1.89 eÅ-3] and deepest hole [-1.27 eÅ-3] are situated 1.05 Å and 0.97 Å, respectively, at atom Pt1.

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. View of (I) with atom labels and 25% probability displacement ellipsoids. For the disordered chloroform molecule, only major part is shown for clarity.
cis-Dichloridobis(triphenylphosphine-κP)platinum(II) chloroform solvate top
Crystal data top
[PtCl2(C18H15P)2]·CHCl3F(000) = 1784
Mr = 909.90Dx = 1.550 Mg m−3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 10.3174 (9) ÅCell parameters from 8493 reflections
b = 24.436 (2) Åθ = 2.2–28.2°
c = 15.6298 (18) ŵ = 4.05 mm−1
β = 98.199 (1)°T = 298 K
V = 3900.3 (7) Å3Block, yellowish
Z = 40.38 × 0.35 × 0.18 mm
Data collection top
Bruker SMART CCD area-detector
diffractometer		6877 independent reflections
Radiation source: fine-focus sealed tube4984 reflections with I > 2σ(I)
graphiteRint = 0.071
φ and ω scansθmax = 25.0°, θmin = 1.6°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		h = −12→12
Tmin = 0.309, Tmax = 0.530k = −29→28
18772 measured reflectionsl = −14→18
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.048Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.119H-atom parameters constrained
S = 0.97 w = 1/[σ2(Fo2) + (0.0594P)2]
where P = (Fo2 + 2Fc2)/3
6877 reflections(Δ/σ)max = 0.001
434 parametersΔρmax = 1.89 e Å−3
0 restraintsΔρmin = −1.27 e Å−3
Crystal data top
[PtCl2(C18H15P)2]·CHCl3V = 3900.3 (7) Å3
Mr = 909.90Z = 4
Monoclinic, P21/cMo Kα radiation
a = 10.3174 (9) ŵ = 4.05 mm−1
b = 24.436 (2) ÅT = 298 K
c = 15.6298 (18) Å0.38 × 0.35 × 0.18 mm
β = 98.199 (1)°
Data collection top
Bruker SMART CCD area-detector
diffractometer		6877 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		4984 reflections with I > 2σ(I)
Tmin = 0.309, Tmax = 0.530Rint = 0.071
18772 measured reflectionsθmax = 25.0°
Refinement top
R[F2 > 2σ(F2)] = 0.048H-atom parameters constrained
wR(F2) = 0.119Δρmax = 1.89 e Å−3
S = 0.97Δρmin = −1.27 e Å−3
6877 reflectionsAbsolute structure: ?
434 parametersFlack parameter: ?
0 restraintsRogers parameter: ?
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pt10.59334 (2)0.349888 (10)0.548206 (18)0.03195 (11)
Cl10.45377 (18)0.39079 (8)0.43652 (13)0.0477 (5)
Cl20.41302 (18)0.29552 (8)0.57114 (13)0.0492 (5)
Cl30.2158 (6)0.3208 (3)0.2316 (4)0.142 (3)0.778 (11)
Cl40.1897 (12)0.3400 (5)0.0514 (7)0.165 (4)0.778 (11)
Cl50.4219 (6)0.3691 (2)0.1644 (6)0.141 (3)0.778 (11)
Cl3'0.355 (3)0.3779 (12)0.078 (2)0.197 (14)0.222 (11)
Cl4'0.348 (3)0.3554 (9)0.2339 (17)0.156 (12)0.222 (11)
Cl5'0.147 (4)0.3153 (17)0.081 (3)0.167 (13)0.222 (11)
P10.75776 (17)0.40376 (7)0.51837 (12)0.0316 (4)
P20.70533 (18)0.30561 (7)0.66301 (13)0.0359 (4)
C10.8924 (7)0.3665 (3)0.4836 (5)0.0416 (18)
C21.0068 (7)0.3918 (4)0.4670 (6)0.054 (2)
H21.01600.42950.47330.065*
C31.1060 (9)0.3615 (4)0.4413 (7)0.072 (3)
H31.18360.37860.43260.086*
C41.0925 (9)0.3063 (4)0.4282 (6)0.068 (3)
H41.16140.28610.41200.081*
C50.9789 (8)0.2810 (4)0.4387 (6)0.061 (2)
H50.96770.24390.42640.074*
C60.8797 (8)0.3107 (3)0.4677 (5)0.048 (2)
H60.80300.29300.47670.058*
C70.7173 (7)0.4505 (3)0.4270 (5)0.0400 (18)
C80.7002 (8)0.4296 (3)0.3447 (5)0.051 (2)
H80.71010.39220.33670.061*
C90.6684 (9)0.4631 (4)0.2731 (6)0.065 (3)
H90.65540.44860.21750.078*
C100.6564 (8)0.5200 (4)0.2873 (6)0.061 (2)
H100.63620.54330.24030.073*
C110.6737 (8)0.5407 (4)0.3678 (6)0.058 (2)
H110.66500.57820.37600.070*
C120.7044 (7)0.5067 (3)0.4382 (5)0.048 (2)
H120.71650.52140.49360.058*
C130.8127 (7)0.4487 (3)0.6099 (5)0.0394 (17)
C140.9418 (8)0.4603 (3)0.6409 (5)0.053 (2)
H141.00930.44370.61680.064*
C150.9694 (10)0.4972 (4)0.7088 (6)0.067 (3)
H151.05600.50440.73170.080*
C160.8705 (10)0.5230 (4)0.7418 (7)0.070 (3)
H160.89020.54870.78570.084*
C170.7427 (10)0.5116 (3)0.7111 (6)0.065 (3)
H170.67560.52880.73470.078*
C180.7138 (8)0.4744 (3)0.6452 (5)0.050 (2)
H180.62680.46660.62420.061*
C190.8622 (7)0.3305 (3)0.7180 (5)0.046 (2)
C200.9782 (8)0.3178 (3)0.6859 (6)0.054 (2)
H200.97550.29780.63510.065*
C211.0977 (9)0.3351 (4)0.7302 (7)0.066 (3)
H211.17530.32610.70970.079*
C221.1006 (10)0.3649 (4)0.8029 (8)0.074 (3)
H221.18080.37710.83120.088*
C230.9906 (10)0.3775 (4)0.8358 (7)0.072 (3)
H230.99620.39740.88700.086*
C240.8702 (9)0.3613 (3)0.7945 (6)0.056 (2)
H240.79450.37060.81700.067*
C250.7459 (7)0.2350 (3)0.6415 (5)0.0449 (19)
C260.6929 (8)0.2102 (3)0.5647 (6)0.053 (2)
H260.63540.22940.52420.063*
C270.7260 (10)0.1560 (4)0.5481 (7)0.072 (3)
H270.69050.13900.49690.086*
C280.8114 (10)0.1285 (4)0.6082 (8)0.075 (3)
H280.83590.09290.59650.090*
C290.8601 (10)0.1517 (4)0.6835 (8)0.073 (3)
H290.91490.13160.72430.088*
C300.8301 (8)0.2050 (3)0.7013 (6)0.057 (2)
H300.86620.22100.75330.069*
C310.6018 (7)0.3029 (3)0.7490 (5)0.0418 (18)
C320.5768 (7)0.2541 (3)0.7894 (5)0.053 (2)
H320.61470.22170.77390.064*
C330.4960 (8)0.2537 (4)0.8523 (5)0.059 (2)
H330.47810.22080.87820.071*
C340.4418 (8)0.3009 (4)0.8770 (6)0.062 (2)
H340.38720.30060.91950.074*
C350.4694 (9)0.3492 (4)0.8379 (6)0.058 (2)
H350.43500.38190.85550.069*
C360.5457 (8)0.3501 (3)0.7742 (6)0.054 (2)
H360.56030.38300.74730.065*
C370.2974 (13)0.3240 (6)0.1404 (9)0.106 (4)
H370.33470.28790.13160.127*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt10.02648 (17)0.03000 (17)0.03899 (18)−0.00180 (11)0.00341 (12)0.00317 (13)
Cl10.0357 (10)0.0525 (12)0.0525 (12)0.0011 (9)−0.0018 (9)0.0159 (10)
Cl20.0363 (11)0.0537 (12)0.0566 (12)−0.0171 (9)0.0036 (9)0.0119 (10)
Cl30.124 (5)0.164 (5)0.145 (5)0.039 (4)0.043 (4)0.027 (4)
Cl40.175 (10)0.188 (10)0.120 (6)0.021 (7)−0.017 (6)−0.015 (6)
Cl50.102 (4)0.108 (4)0.212 (10)−0.007 (3)0.013 (5)0.006 (4)
Cl3'0.20 (3)0.20 (3)0.20 (3)0.00 (2)0.04 (3)−0.01 (2)
Cl4'0.17 (3)0.149 (19)0.15 (2)0.022 (17)0.006 (18)−0.001 (15)
Cl5'0.15 (2)0.17 (3)0.18 (3)−0.004 (19)0.01 (2)0.00 (2)
P10.0273 (10)0.0259 (9)0.0416 (11)−0.0011 (7)0.0046 (8)0.0021 (8)
P20.0331 (11)0.0335 (10)0.0403 (11)−0.0019 (8)0.0019 (9)0.0046 (9)
C10.034 (4)0.039 (4)0.052 (5)−0.001 (3)0.007 (4)0.003 (4)
C20.041 (5)0.059 (5)0.065 (6)−0.003 (4)0.015 (4)0.000 (5)
C30.049 (6)0.088 (8)0.083 (7)−0.004 (5)0.025 (5)−0.008 (6)
C40.051 (6)0.080 (7)0.074 (7)0.020 (5)0.016 (5)−0.003 (6)
C50.058 (6)0.057 (6)0.069 (6)0.019 (5)0.011 (5)−0.006 (5)
C60.045 (5)0.048 (5)0.054 (5)0.004 (4)0.012 (4)0.004 (4)
C70.035 (4)0.037 (4)0.049 (5)0.000 (3)0.010 (4)0.009 (4)
C80.055 (5)0.047 (5)0.052 (5)0.002 (4)0.014 (4)0.009 (4)
C90.071 (7)0.069 (6)0.057 (6)0.002 (5)0.013 (5)0.014 (5)
C100.064 (6)0.057 (6)0.062 (6)0.012 (4)0.014 (5)0.027 (5)
C110.062 (6)0.047 (5)0.067 (6)0.008 (4)0.013 (5)0.013 (5)
C120.049 (5)0.040 (5)0.056 (5)0.002 (4)0.008 (4)0.005 (4)
C130.036 (4)0.033 (4)0.048 (5)−0.004 (3)0.003 (4)0.002 (4)
C140.046 (5)0.052 (5)0.061 (5)−0.006 (4)0.005 (4)−0.001 (5)
C150.061 (6)0.063 (6)0.073 (7)−0.016 (5)−0.004 (5)−0.007 (6)
C160.080 (8)0.056 (6)0.072 (7)−0.013 (5)0.000 (6)−0.013 (5)
C170.067 (7)0.056 (6)0.072 (6)0.002 (5)0.008 (5)−0.014 (5)
C180.044 (5)0.048 (5)0.059 (6)−0.003 (4)0.006 (4)−0.004 (4)
C190.041 (5)0.043 (4)0.053 (5)0.000 (4)−0.001 (4)0.011 (4)
C200.049 (6)0.054 (5)0.058 (6)0.000 (4)0.001 (4)0.007 (5)
C210.043 (6)0.069 (6)0.082 (7)0.001 (5)−0.001 (5)0.010 (6)
C220.057 (7)0.080 (7)0.079 (8)−0.007 (5)−0.009 (6)−0.003 (6)
C230.067 (7)0.072 (7)0.070 (7)−0.010 (5)−0.008 (6)−0.007 (6)
C240.052 (6)0.058 (5)0.055 (6)−0.002 (4)0.000 (4)−0.002 (5)
C250.042 (5)0.037 (4)0.055 (5)−0.001 (3)0.004 (4)0.004 (4)
C260.052 (5)0.043 (5)0.064 (6)−0.001 (4)0.009 (4)0.004 (5)
C270.075 (7)0.059 (6)0.079 (7)−0.002 (5)0.005 (6)−0.009 (5)
C280.075 (8)0.053 (6)0.096 (9)0.008 (5)0.010 (7)−0.001 (6)
C290.070 (7)0.059 (6)0.087 (8)0.010 (5)0.003 (6)0.012 (6)
C300.060 (6)0.046 (5)0.065 (6)0.003 (4)0.001 (5)0.007 (5)
C310.039 (4)0.044 (5)0.042 (5)−0.005 (3)0.006 (4)0.005 (4)
C320.057 (6)0.049 (5)0.054 (5)−0.001 (4)0.008 (4)0.011 (4)
C330.066 (6)0.060 (6)0.052 (5)−0.011 (5)0.010 (5)0.019 (5)
C340.054 (6)0.077 (7)0.056 (6)0.005 (5)0.013 (5)0.012 (5)
C350.052 (6)0.064 (6)0.058 (6)0.012 (4)0.010 (5)0.004 (5)
C360.055 (6)0.054 (5)0.055 (6)0.005 (4)0.010 (5)0.014 (4)
C370.102 (11)0.098 (9)0.115 (11)0.020 (8)0.009 (9)−0.023 (9)
Geometric parameters (Å, °) top
Pt1—P12.2481 (17)C15—C161.362 (12)
Pt1—P22.2658 (19)C15—H150.9300
Pt1—Cl12.3244 (19)C16—C171.367 (12)
Pt1—Cl22.3548 (17)C16—H160.9300
Cl3—C371.758 (14)C17—C181.373 (11)
Cl4—C371.697 (17)C17—H170.9300
Cl5—C371.693 (15)C18—H180.9300
Cl3'—C371.79 (3)C19—C201.397 (11)
Cl4'—C371.67 (3)C19—C241.404 (11)
Cl5'—C371.70 (5)C20—C211.390 (12)
P1—C11.809 (7)C20—H200.9300
P1—C131.828 (8)C21—C221.347 (14)
P1—C71.829 (7)C21—H210.9300
P2—C251.818 (7)C22—C231.347 (13)
P2—C191.825 (8)C22—H220.9300
P2—C311.833 (7)C23—C241.375 (12)
C1—C61.388 (10)C23—H230.9300
C1—C21.389 (10)C24—H240.9300
C2—C31.369 (11)C25—C261.387 (11)
C2—H20.9300C25—C301.390 (11)
C3—C41.368 (12)C26—C271.399 (11)
C3—H30.9300C26—H260.9300
C4—C51.356 (12)C27—C281.369 (14)
C4—H40.9300C27—H270.9300
C5—C61.383 (10)C28—C291.338 (14)
C5—H50.9300C28—H280.9300
C6—H60.9300C29—C301.377 (11)
C7—C81.372 (10)C29—H290.9300
C7—C121.394 (10)C30—H300.9300
C8—C91.386 (11)C31—C361.374 (10)
C8—H80.9300C31—C321.390 (10)
C9—C101.415 (12)C32—C331.376 (10)
C9—H90.9300C32—H320.9300
C10—C111.344 (12)C33—C341.362 (11)
C10—H100.9300C33—H330.9300
C11—C121.379 (10)C34—C351.378 (11)
C11—H110.9300C34—H340.9300
C12—H120.9300C35—C361.353 (12)
C13—C181.380 (10)C35—H350.9300
C13—C141.380 (10)C36—H360.9300
C14—C151.391 (11)C37—H370.9800
C14—H140.9300
P1—Pt1—P297.43 (7)C24—C19—P2121.3 (6)
P1—Pt1—Cl189.85 (7)C21—C20—C19119.9 (9)
P2—Pt1—Cl1172.47 (6)C21—C20—H20120.1
P1—Pt1—Cl2176.28 (7)C19—C20—H20120.1
P2—Pt1—Cl286.26 (7)C22—C21—C20119.7 (9)
Cl1—Pt1—Cl286.48 (7)C22—C21—H21120.2
C1—P1—C13111.8 (3)C20—C21—H21120.2
C1—P1—C7100.3 (3)C23—C22—C21121.9 (10)
C13—P1—C7104.3 (3)C23—C22—H22119.1
C1—P1—Pt1113.7 (2)C21—C22—H22119.1
C13—P1—Pt1110.4 (2)C22—C23—C24120.5 (10)
C7—P1—Pt1115.6 (2)C22—C23—H23119.7
C25—P2—C19101.0 (4)C24—C23—H23119.7
C25—P2—C31105.9 (3)C23—C24—C19119.6 (9)
C19—P2—C31103.7 (4)C23—C24—H24120.2
C25—P2—Pt1114.3 (3)C19—C24—H24120.2
C19—P2—Pt1122.1 (3)C26—C25—C30118.9 (7)
C31—P2—Pt1108.3 (3)C26—C25—P2120.2 (6)
C6—C1—C2117.7 (7)C30—C25—P2121.0 (6)
C6—C1—P1119.4 (5)C25—C26—C27119.8 (9)
C2—C1—P1122.8 (6)C25—C26—H26120.1
C3—C2—C1120.3 (8)C27—C26—H26120.1
C3—C2—H2119.9C28—C27—C26119.2 (10)
C1—C2—H2119.9C28—C27—H27120.4
C4—C3—C2120.8 (9)C26—C27—H27120.4
C4—C3—H3119.6C29—C28—C27121.3 (10)
C2—C3—H3119.6C29—C28—H28119.4
C5—C4—C3120.2 (8)C27—C28—H28119.4
C5—C4—H4119.9C28—C29—C30120.8 (10)
C3—C4—H4119.9C28—C29—H29119.6
C4—C5—C6119.5 (9)C30—C29—H29119.6
C4—C5—H5120.2C29—C30—C25120.0 (9)
C6—C5—H5120.2C29—C30—H30120.0
C5—C6—C1121.2 (8)C25—C30—H30120.0
C5—C6—H6119.4C36—C31—C32118.4 (7)
C1—C6—H6119.4C36—C31—P2119.6 (6)
C8—C7—C12118.8 (7)C32—C31—P2122.0 (6)
C8—C7—P1119.0 (6)C33—C32—C31120.1 (8)
C12—C7—P1122.2 (6)C33—C32—H32119.9
C7—C8—C9121.4 (8)C31—C32—H32119.9
C7—C8—H8119.3C34—C33—C32120.7 (8)
C9—C8—H8119.3C34—C33—H33119.6
C8—C9—C10118.0 (9)C32—C33—H33119.6
C8—C9—H9121.0C33—C34—C35118.8 (8)
C10—C9—H9121.0C33—C34—H34120.6
C11—C10—C9120.9 (8)C35—C34—H34120.6
C11—C10—H10119.5C36—C35—C34121.1 (8)
C9—C10—H10119.5C36—C35—H35119.4
C10—C11—C12120.2 (8)C34—C35—H35119.4
C10—C11—H11119.9C35—C36—C31120.8 (8)
C12—C11—H11119.9C35—C36—H36119.6
C11—C12—C7120.6 (8)C31—C36—H36119.6
C11—C12—H12119.7Cl4'—C37—Cl551.1 (10)
C7—C12—H12119.7Cl4'—C37—Cl4134.5 (11)
C18—C13—C14119.9 (7)Cl5—C37—Cl4114.9 (10)
C18—C13—P1114.9 (6)Cl4'—C37—Cl5'133 (2)
C14—C13—P1125.1 (6)Cl5—C37—Cl5'143.7 (16)
C13—C14—C15118.9 (8)Cl4—C37—Cl5'31.2 (11)
C13—C14—H14120.5Cl4'—C37—Cl355.8 (11)
C15—C14—H14120.5Cl5—C37—Cl3106.5 (8)
C16—C15—C14120.4 (9)Cl4—C37—Cl3110.0 (9)
C16—C15—H15119.8Cl5'—C37—Cl386.0 (16)
C14—C15—H15119.8Cl4'—C37—Cl3'92.8 (15)
C15—C16—C17120.7 (9)Cl5—C37—Cl3'48.8 (12)
C15—C16—H16119.7Cl4—C37—Cl3'67.4 (13)
C17—C16—H16119.7Cl5'—C37—Cl3'98.4 (17)
C16—C17—C18119.6 (9)Cl3—C37—Cl3'135.1 (12)
C16—C17—H17120.2Cl4'—C37—H37117.1
C18—C17—H17120.2Cl5—C37—H37108.4
C17—C18—C13120.5 (8)Cl4—C37—H37108.4
C17—C18—H18119.8Cl5'—C37—H3799.0
C13—C18—H18119.8Cl3—C37—H37108.4
C20—C19—C24118.4 (8)Cl3'—C37—H37114.8
C20—C19—P2120.3 (7)
P2—Pt1—P1—C165.2 (3)Pt1—P1—C13—C14137.5 (6)
Cl1—Pt1—P1—C1−116.7 (3)C18—C13—C14—C151.2 (12)
Cl2—Pt1—P1—C1−107.5 (11)P1—C13—C14—C15177.1 (6)
P2—Pt1—P1—C13−61.5 (3)C13—C14—C15—C16−2.4 (13)
Cl1—Pt1—P1—C13116.6 (3)C14—C15—C16—C172.4 (14)
Cl2—Pt1—P1—C13125.9 (10)C15—C16—C17—C18−1.2 (14)
P2—Pt1—P1—C7−179.5 (3)C16—C17—C18—C130.0 (13)
Cl1—Pt1—P1—C7−1.4 (3)C14—C13—C18—C170.0 (12)
Cl2—Pt1—P1—C77.8 (11)P1—C13—C18—C17−176.4 (6)
P1—Pt1—P2—C25−107.0 (3)C25—P2—C19—C2044.4 (7)
Cl1—Pt1—P2—C2587.8 (6)C31—P2—C19—C20153.9 (6)
Cl2—Pt1—P2—C2572.6 (3)Pt1—P2—C19—C20−83.8 (7)
P1—Pt1—P2—C1915.1 (3)C25—P2—C19—C24−133.6 (7)
Cl1—Pt1—P2—C19−150.1 (6)C31—P2—C19—C24−24.0 (7)
Cl2—Pt1—P2—C19−165.4 (3)Pt1—P2—C19—C2498.3 (7)
P1—Pt1—P2—C31135.3 (3)C24—C19—C20—C210.6 (12)
Cl1—Pt1—P2—C31−30.0 (6)P2—C19—C20—C21−177.4 (6)
Cl2—Pt1—P2—C31−45.2 (3)C19—C20—C21—C22−1.3 (13)
C13—P1—C1—C6133.7 (6)C20—C21—C22—C231.8 (16)
C7—P1—C1—C6−116.3 (7)C21—C22—C23—C24−1.6 (17)
Pt1—P1—C1—C67.8 (7)C22—C23—C24—C191.0 (14)
C13—P1—C1—C2−50.2 (8)C20—C19—C24—C23−0.5 (12)
C7—P1—C1—C259.9 (8)P2—C19—C24—C23177.5 (7)
Pt1—P1—C1—C2−176.1 (6)C19—P2—C25—C26−142.3 (6)
C6—C1—C2—C3−4.2 (13)C31—P2—C25—C26109.8 (7)
P1—C1—C2—C3179.6 (7)Pt1—P2—C25—C26−9.3 (7)
C1—C2—C3—C42.6 (15)C19—P2—C25—C3037.7 (7)
C2—C3—C4—C51.5 (16)C31—P2—C25—C30−70.2 (7)
C3—C4—C5—C6−3.8 (15)Pt1—P2—C25—C30170.7 (6)
C4—C5—C6—C12.2 (13)C30—C25—C26—C27−0.8 (12)
C2—C1—C6—C51.8 (12)P2—C25—C26—C27179.1 (6)
P1—C1—C6—C5178.2 (7)C25—C26—C27—C28−0.4 (14)
C1—P1—C7—C849.8 (7)C26—C27—C28—C292.3 (16)
C13—P1—C7—C8165.7 (6)C27—C28—C29—C30−2.8 (17)
Pt1—P1—C7—C8−72.9 (6)C28—C29—C30—C251.5 (15)
C1—P1—C7—C12−129.5 (6)C26—C25—C30—C290.3 (12)
C13—P1—C7—C12−13.7 (7)P2—C25—C30—C29−179.6 (7)
Pt1—P1—C7—C12107.8 (6)C25—P2—C31—C36−174.3 (7)
C12—C7—C8—C9−1.1 (12)C19—P2—C31—C3679.7 (7)
P1—C7—C8—C9179.5 (6)Pt1—P2—C31—C36−51.3 (7)
C7—C8—C9—C101.2 (13)C25—P2—C31—C325.0 (8)
C8—C9—C10—C11−0.8 (13)C19—P2—C31—C32−100.9 (7)
C9—C10—C11—C120.3 (13)Pt1—P2—C31—C32128.1 (6)
C10—C11—C12—C7−0.2 (12)C36—C31—C32—C330.9 (12)
C8—C7—C12—C110.6 (11)P2—C31—C32—C33−178.5 (6)
P1—C7—C12—C11180.0 (6)C31—C32—C33—C34−1.4 (13)
C1—P1—C13—C18−174.0 (6)C32—C33—C34—C350.0 (13)
C7—P1—C13—C1878.5 (6)C33—C34—C35—C361.9 (14)
Pt1—P1—C13—C18−46.3 (6)C34—C35—C36—C31−2.4 (14)
C1—P1—C13—C149.9 (8)C32—C31—C36—C351.0 (13)
C7—P1—C13—C14−97.7 (7)P2—C31—C36—C35−179.7 (7)
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
C3—H3···Cl1i0.932.803.670 (10)157
C37—H37···Cl2ii0.982.433.390 (15)165
Symmetry codes: (i) x+1, y, z; (ii) x, −y+1/2, z−1/2.
Table 1
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
C3—H3···Cl1i0.932.803.670 (10)157
C37—H37···Cl2ii0.982.433.390 (15)165
Symmetry codes: (i) x+1, y, z; (ii) x, −y+1/2, z−1/2.
Acknowledgements top

The authors thank the University of Jinan (grant No. B0605) and the Key Subject Research Foundation of Shandong Province (grant No. XTD 0704) for support of this study.

references
References top

Al-Fawaz, A., Aldridge, S., Coombs, D. L., Dickinson, A. A., Willock, D. J., Ooi, L., Light, M. E., Coles, S. J. & Hursthouse, M. B. (2004). Dalton Trans. pp. 4030–4037.

Anderson, G. K., Clark, H. C., Davies, J. A. & Ferguson, G. (1982). J. Crystallogr. Spectrosc. Res., 12, 449–458.

Bailar, J. C. Jr & Itatani, H. (1965). Inorg. Chem. 4, 1618–1620.

Bruker (2001). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

Fun, H.-K., Chantrapromma, S., Liu, Y.-C., Chen, Z.-F. & Liang, H. (2006). Acta Cryst. E62, m1252–m1254.

Johansson, M. H. & Otto, S. (2000). Acta Cryst. C56, e12–e15.

Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.