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Acta Cryst. (2012). E68, m1448-m1449    [ doi:10.1107/S1600536812044698 ]

Trichlorido(5,5'-dimethyl-2,2'-bipyridine-[kappa]2N,N')(dimethylformamide-[kappa]O)indium(III) hemihydrate

S. A. Shirvan, S. Haydari Dezfuli, F. Khazali, M. Aghajeri and A. Borsalani

Abstract top

The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent InIII complex molecules with similar structures and one lattice water molecule. In each complex molecule, the InIII atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O-H...Cl hydrogen bonds. Further weak C-H...Cl and C-H...O hydrogen bonds result in the formation of a three-dimensional structure.

Comment top

Recently, we reported the synthes and crystal structure of [Cd(5,5'-dmbpy)(µ-Br)2]n, (Shirvan & Haydari Dezfuli, 2012) [where 5,5'-dmbpy is 5,5'-dimethyl-2,2'-bipyridine]. 5,5'-Dimethyl-2,2'-bipyridine is a good bidentate ligand, and numerous complexes with 5,5'-dmbipy have been prepared, such as that of zinc (Khalighi et al., 2008), indium (Kalateh et al., 2008), iron (Amani et al., 2007), platin (Amani et al., 2009), copper (Albada et al., 2004) and mercury (Tadayon Pour et al., 2008; Alizadeh et al., 2010). Here, we report the synthesis and structure of the title compound.

The asymmetric unit of the title compound, (Fig. 1), contains two crystallographically independent [In(C12H12N2)Cl3(C3H7NO)] molecules and one water solvent molecule. The InIII atom is six-coordinated in a distorted octahedral configuration by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three Cl atoms. The In—Cl, In—O and In—N bond lengths and angles are collected in Table 1.

In the crystal structure, intermolecular O—H···Cl and C—H···O and C—H···Cl hydrogen bonds link the molecules (Fig. 2 & Table 2).

Related literature top

For related structures, see: Albada et al. (2004); Alizadeh et al. (2010); Amani et al. (2007, 2009); Kalateh et al. (2008); Khalighi et al. (2008); Shirvan & Haydari Dezfuli (2012); Tadayon Pour et al. (2008).

Experimental top

For the preparation of the title compound, a solution of 5,5'-dimethyl-2,2'-bipyridine (0.30 g, 1.65 mmol) in methanol (10 ml) was added to a solution of InCl3.4H2O (0.48 g, 1.65 mmol) in methanol (10 ml) and the resulting colorless solution was stirred for 20 min at 323 K. The suitable crystals for X-ray diffraction experiment were obtained by methanol diffusion to a colorless solution in dimethylformamide. Suitable crystals were isolated after one week (yield; 0.58 g, 72.1%).

Refinement top

Water H atoms were located in a difference Fourier map and refined with O—H distance of 0.84 (2) Å, Uiso(H) = 0.1 Å2. Other H atoms were positioned geometrically with C—H = 0.93 Å for aromatics H and 0.96 Å for methyl H atoms constrained to ride on their parent atoms, Uiso(H) = 1.2Ueq(C).

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
[Figure 2] Fig. 2. Unit-cell packing diagram for title molecule. Hydrogen bonds are shown as dashed lines.
Trichlorido(5,5'-dimethyl-2,2'-bipyridine- κ2N,N')(dimethylformamide-κO)indium(III) hemihydrate top
Crystal data top
[InCl3(C12H12N2)(C3H7NO)]·0.5H2OZ = 4
Mr = 487.51F(000) = 972
Triclinic, P1Dx = 1.680 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 11.3021 (5) ÅCell parameters from 15402 reflections
b = 11.4445 (5) Åθ = 2.4–26.0°
c = 15.0860 (6) ŵ = 1.65 mm−1
α = 91.089 (4)°T = 173 K
β = 96.024 (3)°Block, colorless
γ = 96.448 (4)°0.32 × 0.30 × 0.25 mm
V = 1927.34 (14) Å3
Data collection top
Bruker APEXII CCD area-detector
diffractometer		7524 independent reflections
Radiation source: fine-focus sealed tube6051 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.036
ω scansθmax = 26.0°, θmin = 2.4°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		h = −13→13
Tmin = 0.601, Tmax = 0.688k = −14→14
15402 measured reflectionsl = −18→18
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.067H atoms treated by a mixture of independent and constrained refinement
S = 1.03 w = 1/[σ2(Fo2) + (0.0309P)2 + 0.5815P]
where P = (Fo2 + 2Fc2)/3
7524 reflections(Δ/σ)max = 0.001
437 parametersΔρmax = 0.57 e Å−3
3 restraintsΔρmin = −0.54 e Å−3
Crystal data top
[InCl3(C12H12N2)(C3H7NO)]·0.5H2Oγ = 96.448 (4)°
Mr = 487.51V = 1927.34 (14) Å3
Triclinic, P1Z = 4
a = 11.3021 (5) ÅMo Kα radiation
b = 11.4445 (5) ŵ = 1.65 mm−1
c = 15.0860 (6) ÅT = 173 K
α = 91.089 (4)°0.32 × 0.30 × 0.25 mm
β = 96.024 (3)°
Data collection top
Bruker APEXII CCD area-detector
diffractometer		7524 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		6051 reflections with I > 2σ(I)
Tmin = 0.601, Tmax = 0.688Rint = 0.036
15402 measured reflectionsθmax = 26.0°
Refinement top
R[F2 > 2σ(F2)] = 0.034H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.067Δρmax = 0.57 e Å−3
S = 1.03Δρmin = −0.54 e Å−3
7524 reflectionsAbsolute structure: ?
437 parametersFlack parameter: ?
3 restraintsRogers parameter: ?
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.5123 (3)1.0246 (3)0.2042 (2)0.0251 (7)
H10.54501.08900.17460.030*
C20.3899 (3)1.0132 (3)0.2121 (2)0.0255 (7)
C30.3115 (3)1.1025 (4)0.1753 (3)0.0341 (9)
H3C0.26521.12700.22060.041*
H3B0.25871.06820.12530.041*
H3A0.36061.16940.15640.041*
C40.3441 (3)0.9152 (3)0.2551 (2)0.0277 (8)
H40.26250.90310.26080.033*
C50.4183 (3)0.8350 (3)0.2899 (2)0.0249 (7)
H50.38750.76970.31940.030*
C60.5403 (3)0.8539 (3)0.2797 (2)0.0222 (7)
C70.6250 (3)0.7694 (3)0.3113 (2)0.0206 (7)
C80.5969 (3)0.6830 (3)0.3715 (2)0.0261 (7)
H80.52270.67600.39350.031*
C90.6800 (3)0.6076 (3)0.3984 (2)0.0293 (8)
H90.66260.55100.44000.035*
C100.7899 (3)0.6162 (3)0.3633 (2)0.0272 (8)
C110.8797 (4)0.5334 (4)0.3906 (3)0.0377 (9)
H11C0.88450.52430.45390.045*
H11B0.95670.56450.37440.045*
H11A0.85540.45830.36090.045*
C120.8112 (3)0.7047 (3)0.3039 (2)0.0252 (7)
H120.88390.71170.27970.030*
C130.8628 (3)1.0800 (3)0.4086 (2)0.0269 (8)
H130.90231.13860.37700.032*
C140.9446 (4)1.1909 (4)0.5437 (3)0.0495 (12)
H14C1.00741.16570.58420.059*
H14B0.89241.23130.57660.059*
H14A0.97881.24300.50170.059*
C150.8199 (4)0.9974 (4)0.5493 (3)0.0422 (10)
H15A0.79730.92660.51340.051*
H15B0.75011.02370.57060.051*
H15C0.87560.98190.59900.051*
C160.4078 (3)0.2947 (3)0.3691 (2)0.0267 (7)
H160.34320.27360.40120.032*
C170.5101 (3)0.2392 (3)0.3877 (2)0.0272 (8)
C180.5177 (4)0.1442 (3)0.4548 (3)0.0359 (9)
H18A0.45720.07990.43720.043*
H18B0.50540.17510.51230.043*
H18C0.59530.11700.45770.043*
C190.6052 (3)0.2748 (3)0.3395 (2)0.0314 (8)
H190.67630.24100.34980.038*
C200.5954 (3)0.3597 (3)0.2764 (2)0.0312 (8)
H200.65940.38320.24420.037*
C210.4897 (3)0.4096 (3)0.2615 (2)0.0232 (7)
C220.4726 (3)0.5031 (3)0.1956 (2)0.0236 (7)
C230.5582 (3)0.5398 (3)0.1397 (2)0.0317 (8)
H230.62990.50670.14270.038*
C240.5356 (4)0.6265 (4)0.0791 (2)0.0341 (9)
H240.59250.65170.04110.041*
C250.4292 (3)0.6756 (3)0.0749 (2)0.0301 (8)
C260.4010 (4)0.7694 (4)0.0104 (3)0.0460 (11)
H26C0.47090.82500.00840.055*
H26B0.33710.80910.02930.055*
H26A0.37710.7341−0.04790.055*
C270.3478 (3)0.6325 (3)0.1325 (2)0.0287 (8)
H270.27440.66250.12950.034*
C280.1038 (3)0.2848 (4)0.1282 (2)0.0322 (8)
H280.07200.23560.17030.039*
C290.1028 (5)0.3466 (5)−0.0221 (3)0.0639 (15)
H29C0.14060.3045−0.06480.077*
H29B0.15910.40900.00580.077*
H29A0.03520.3791−0.05180.077*
C30−0.0240 (5)0.1663 (6)0.0160 (3)0.0706 (18)
H30A−0.04550.12300.06690.085*
H30B0.01050.1162−0.02350.085*
H30C−0.09410.1933−0.01460.085*
N10.5854 (2)0.9478 (2)0.23712 (18)0.0219 (6)
N20.7329 (2)0.7812 (2)0.27921 (17)0.0209 (6)
N30.8759 (3)1.0879 (3)0.49582 (19)0.0290 (7)
N40.3964 (2)0.3764 (2)0.30794 (18)0.0229 (6)
N50.3691 (3)0.5500 (3)0.19222 (18)0.0234 (6)
N60.0629 (3)0.2669 (3)0.0452 (2)0.0378 (8)
O10.7993 (2)0.9967 (2)0.36637 (15)0.0309 (6)
O20.1854 (2)0.3663 (2)0.15434 (17)0.0375 (6)
O30.1661 (4)0.5577 (4)−0.1491 (4)0.0903 (15)
Cl10.72933 (9)0.90119 (10)0.06210 (6)0.0395 (2)
Cl20.99623 (8)0.93947 (9)0.22712 (6)0.0333 (2)
Cl30.79761 (8)1.17277 (8)0.19951 (6)0.0313 (2)
Cl40.29650 (8)0.59312 (8)0.41650 (6)0.03024 (19)
Cl50.08798 (9)0.60500 (10)0.22539 (7)0.0435 (3)
Cl60.10673 (8)0.31911 (9)0.35452 (6)0.0355 (2)
In10.78415 (2)0.95952 (2)0.217222 (15)0.02104 (7)
In20.22743 (2)0.46926 (2)0.280738 (15)0.02290 (7)
H3D0.099 (2)0.521 (3)−0.168 (3)0.100*
H3E0.155 (3)0.6286 (12)−0.156 (3)0.100*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0259 (18)0.0258 (18)0.0228 (16)0.0032 (14)−0.0012 (14)0.0023 (14)
C20.0253 (18)0.0315 (19)0.0194 (16)0.0047 (15)−0.0001 (13)−0.0012 (14)
C30.029 (2)0.040 (2)0.034 (2)0.0100 (17)0.0012 (16)0.0072 (17)
C40.0188 (17)0.037 (2)0.0276 (17)0.0032 (15)0.0036 (14)−0.0021 (15)
C50.0258 (18)0.0259 (18)0.0227 (16)−0.0021 (14)0.0062 (14)0.0030 (14)
C60.0249 (18)0.0227 (17)0.0184 (15)−0.0008 (14)0.0042 (13)−0.0016 (13)
C70.0214 (17)0.0207 (17)0.0189 (15)−0.0019 (13)0.0034 (13)−0.0014 (13)
C80.0228 (18)0.0287 (19)0.0278 (17)0.0010 (14)0.0087 (14)0.0035 (14)
C90.034 (2)0.0283 (19)0.0262 (18)0.0044 (16)0.0052 (15)0.0079 (15)
C100.0265 (19)0.0279 (19)0.0275 (17)0.0052 (15)0.0022 (14)0.0025 (14)
C110.034 (2)0.039 (2)0.043 (2)0.0098 (18)0.0055 (18)0.0156 (18)
C120.0220 (18)0.0290 (19)0.0244 (17)0.0020 (14)0.0032 (13)−0.0009 (14)
C130.0236 (18)0.033 (2)0.0238 (17)0.0024 (15)0.0026 (14)0.0021 (15)
C140.059 (3)0.049 (3)0.034 (2)−0.010 (2)−0.003 (2)−0.006 (2)
C150.043 (2)0.059 (3)0.0232 (18)−0.006 (2)0.0073 (17)0.0034 (18)
C160.0285 (19)0.0246 (18)0.0280 (18)0.0033 (14)0.0071 (14)0.0036 (14)
C170.031 (2)0.0233 (18)0.0261 (17)0.0031 (15)−0.0029 (15)−0.0003 (14)
C180.040 (2)0.032 (2)0.037 (2)0.0107 (17)0.0023 (17)0.0090 (17)
C190.031 (2)0.030 (2)0.035 (2)0.0141 (16)0.0039 (16)0.0006 (16)
C200.0260 (19)0.033 (2)0.036 (2)0.0077 (16)0.0073 (16)0.0028 (16)
C210.0237 (18)0.0223 (17)0.0227 (16)0.0005 (14)0.0006 (13)0.0013 (13)
C220.0244 (18)0.0243 (18)0.0217 (16)0.0018 (14)0.0015 (13)−0.0005 (13)
C230.0263 (19)0.036 (2)0.0326 (19)−0.0013 (16)0.0095 (15)0.0031 (16)
C240.033 (2)0.042 (2)0.0265 (18)−0.0049 (17)0.0088 (15)0.0060 (16)
C250.032 (2)0.033 (2)0.0243 (18)−0.0030 (16)0.0014 (15)0.0070 (15)
C260.038 (2)0.058 (3)0.042 (2)0.003 (2)0.0017 (19)0.026 (2)
C270.0258 (19)0.032 (2)0.0281 (18)0.0048 (15)−0.0012 (15)0.0067 (15)
C280.0259 (19)0.041 (2)0.0300 (19)0.0034 (17)0.0055 (15)−0.0032 (16)
C290.080 (4)0.075 (4)0.035 (2)0.016 (3)−0.006 (2)0.007 (2)
C300.045 (3)0.107 (5)0.053 (3)−0.023 (3)0.013 (2)−0.039 (3)
N10.0232 (15)0.0209 (14)0.0210 (13)0.0001 (11)0.0022 (11)0.0026 (11)
N20.0216 (14)0.0211 (14)0.0197 (13)−0.0001 (11)0.0034 (11)0.0011 (11)
N30.0267 (16)0.0348 (17)0.0238 (15)−0.0005 (13)−0.0006 (12)−0.0027 (13)
N40.0211 (15)0.0235 (15)0.0236 (14)0.0012 (12)0.0010 (11)0.0041 (11)
N50.0220 (15)0.0279 (15)0.0197 (13)0.0001 (12)0.0015 (11)0.0029 (12)
N60.0271 (17)0.055 (2)0.0313 (17)0.0066 (15)0.0014 (13)−0.0081 (16)
O10.0349 (15)0.0336 (14)0.0220 (12)−0.0056 (11)0.0037 (10)−0.0001 (11)
O20.0383 (16)0.0420 (16)0.0289 (13)−0.0062 (13)0.0002 (12)−0.0016 (12)
O30.066 (3)0.056 (2)0.153 (4)0.007 (2)0.023 (3)0.036 (3)
Cl10.0392 (5)0.0567 (6)0.0198 (4)−0.0049 (5)0.0021 (4)−0.0024 (4)
Cl20.0199 (4)0.0461 (6)0.0344 (5)0.0039 (4)0.0040 (3)0.0086 (4)
Cl30.0316 (5)0.0272 (5)0.0364 (5)0.0020 (4)0.0097 (4)0.0079 (4)
Cl40.0338 (5)0.0286 (5)0.0276 (4)−0.0034 (4)0.0071 (4)0.0028 (3)
Cl50.0327 (5)0.0588 (7)0.0450 (5)0.0229 (5)0.0101 (4)0.0232 (5)
Cl60.0294 (5)0.0353 (5)0.0409 (5)−0.0057 (4)0.0085 (4)0.0084 (4)
In10.01898 (13)0.02579 (14)0.01822 (11)0.00006 (10)0.00357 (9)0.00353 (9)
In20.01887 (13)0.02634 (14)0.02381 (13)0.00307 (10)0.00239 (9)0.00571 (10)
Geometric parameters (Å, º) top
C1—N11.340 (4)C18—H18C0.9600
C1—C21.393 (5)C19—C201.378 (5)
C1—H10.9300C19—H190.9300
C2—C41.383 (5)C20—C211.381 (5)
C2—C31.504 (5)C20—H200.9300
C3—H3C0.9600C21—N41.349 (4)
C3—H3B0.9600C21—C221.490 (5)
C3—H3A0.9600C22—N51.337 (4)
C4—C51.386 (5)C22—C231.385 (5)
C4—H40.9300C23—C241.389 (6)
C5—C61.396 (5)C23—H230.9300
C5—H50.9300C24—C251.380 (6)
C6—N11.342 (4)C24—H240.9300
C6—C71.487 (5)C25—C271.387 (5)
C7—N21.352 (4)C25—C261.501 (5)
C7—C81.388 (5)C26—H26C0.9600
C8—C91.381 (5)C26—H26B0.9600
C8—H80.9300C26—H26A0.9600
C9—C101.395 (5)C27—N51.341 (4)
C9—H90.9300C27—H270.9300
C10—C121.384 (5)C28—O21.262 (4)
C10—C111.496 (5)C28—N61.293 (5)
C11—H11C0.9600C28—H280.9300
C11—H11B0.9600C29—N61.452 (6)
C11—H11A0.9600C29—H29C0.9600
C12—N21.343 (4)C29—H29B0.9600
C12—H120.9300C29—H29A0.9600
C13—O11.248 (4)C30—N61.456 (6)
C13—N31.309 (4)C30—H30A0.9600
C13—H130.9300C30—H30B0.9600
C14—N31.469 (5)C30—H30C0.9600
C14—H14C0.9600O3—H3D0.844 (10)
C14—H14B0.9600O3—H3E0.841 (10)
C14—H14A0.9600In1—Cl12.4185 (9)
C15—N31.454 (5)In1—Cl22.4227 (9)
C15—H15A0.9600In1—Cl32.4496 (9)
C15—H15B0.9600In1—O12.267 (2)
C15—H15C0.9600In1—N12.287 (3)
C16—N41.333 (4)In1—N22.301 (3)
C16—C171.387 (5)In2—Cl42.4737 (9)
C16—H160.9300In2—Cl52.4327 (10)
C17—C191.388 (5)In2—Cl62.4326 (9)
C17—C181.502 (5)In2—O22.202 (3)
C18—H18A0.9600In2—N42.292 (3)
C18—H18B0.9600In2—N52.316 (3)
N1—C1—C2123.4 (3)C24—C23—H23120.4
N1—C1—H1118.3C25—C24—C23120.2 (3)
C2—C1—H1118.3C25—C24—H24119.9
C4—C2—C1116.6 (3)C23—C24—H24119.9
C4—C2—C3121.7 (3)C24—C25—C27116.7 (3)
C1—C2—C3121.6 (3)C24—C25—C26122.0 (3)
C2—C3—H3C109.5C27—C25—C26121.3 (4)
C2—C3—H3B109.5C25—C26—H26C109.5
H3C—C3—H3B109.5C25—C26—H26B109.5
C2—C3—H3A109.5H26C—C26—H26B109.5
H3C—C3—H3A109.5C25—C26—H26A109.5
H3B—C3—H3A109.5H26C—C26—H26A109.5
C2—C4—C5120.8 (3)H26B—C26—H26A109.5
C2—C4—H4119.6N5—C27—C25123.7 (3)
C5—C4—H4119.6N5—C27—H27118.2
C4—C5—C6118.8 (3)C25—C27—H27118.2
C4—C5—H5120.6O2—C28—N6122.5 (4)
C6—C5—H5120.6O2—C28—H28118.7
N1—C6—C5120.9 (3)N6—C28—H28118.7
N1—C6—C7116.8 (3)N6—C29—H29C109.5
C5—C6—C7122.2 (3)N6—C29—H29B109.5
N2—C7—C8120.9 (3)H29C—C29—H29B109.5
N2—C7—C6116.7 (3)N6—C29—H29A109.5
C8—C7—C6122.4 (3)H29C—C29—H29A109.5
C9—C8—C7119.5 (3)H29B—C29—H29A109.5
C9—C8—H8120.3N6—C30—H30A109.5
C7—C8—H8120.3N6—C30—H30B109.5
C8—C9—C10120.1 (3)H30A—C30—H30B109.5
C8—C9—H9119.9N6—C30—H30C109.5
C10—C9—H9119.9H30A—C30—H30C109.5
C12—C10—C9116.8 (3)H30B—C30—H30C109.5
C12—C10—C11122.6 (3)C1—N1—C6119.4 (3)
C9—C10—C11120.6 (3)C1—N1—In1123.7 (2)
C10—C11—H11C109.5C6—N1—In1116.7 (2)
C10—C11—H11B109.5C12—N2—C7118.8 (3)
H11C—C11—H11B109.5C12—N2—In1124.1 (2)
C10—C11—H11A109.5C7—N2—In1115.0 (2)
H11C—C11—H11A109.5C13—N3—C15121.6 (3)
H11B—C11—H11A109.5C13—N3—C14121.2 (3)
N2—C12—C10123.8 (3)C15—N3—C14117.2 (3)
N2—C12—H12118.1C16—N4—C21119.0 (3)
C10—C12—H12118.1C16—N4—In2123.1 (2)
O1—C13—N3122.3 (3)C21—N4—In2117.8 (2)
O1—C13—H13118.8C22—N5—C27119.1 (3)
N3—C13—H13118.8C22—N5—In2117.4 (2)
N3—C14—H14C109.5C27—N5—In2123.2 (2)
N3—C14—H14B109.5C28—N6—C29120.8 (4)
H14C—C14—H14B109.5C28—N6—C30121.4 (4)
N3—C14—H14A109.5C29—N6—C30117.8 (4)
H14C—C14—H14A109.5C13—O1—In1126.5 (2)
H14B—C14—H14A109.5C28—O2—In2132.3 (3)
N3—C15—H15A109.5H3D—O3—H3E103.2 (16)
N3—C15—H15B109.5O1—In1—N180.31 (9)
H15A—C15—H15B109.5O1—In1—N274.40 (9)
N3—C15—H15C109.5N1—In1—N272.49 (10)
H15A—C15—H15C109.5O1—In1—Cl1168.73 (7)
H15B—C15—H15C109.5N1—In1—Cl189.31 (7)
N4—C16—C17124.0 (3)N2—In1—Cl198.40 (7)
N4—C16—H16118.0O1—In1—Cl290.23 (7)
C17—C16—H16118.0N1—In1—Cl2165.72 (7)
C16—C17—C19116.1 (3)N2—In1—Cl294.75 (7)
C16—C17—C18122.3 (3)Cl1—In1—Cl299.11 (3)
C19—C17—C18121.5 (3)O1—In1—Cl387.14 (7)
C17—C18—H18A109.5N1—In1—Cl392.18 (7)
C17—C18—H18B109.5N2—In1—Cl3157.55 (7)
H18A—C18—H18B109.5Cl1—In1—Cl397.68 (4)
C17—C18—H18C109.5Cl2—In1—Cl398.06 (3)
H18A—C18—H18C109.5O2—In2—N488.49 (10)
H18B—C18—H18C109.5O2—In2—N576.22 (10)
C20—C19—C17120.7 (3)N4—In2—N571.49 (10)
C20—C19—H19119.6O2—In2—Cl689.75 (7)
C17—C19—H19119.6N4—In2—Cl692.52 (7)
C19—C20—C21119.3 (4)N5—In2—Cl6158.71 (8)
C19—C20—H20120.4O2—In2—Cl589.31 (8)
C21—C20—H20120.4N4—In2—Cl5162.54 (7)
N4—C21—C20120.9 (3)N5—In2—Cl591.17 (8)
N4—C21—C22116.6 (3)Cl6—In2—Cl5104.79 (4)
C20—C21—C22122.6 (3)O2—In2—Cl4173.50 (8)
N5—C22—C23121.1 (3)N4—In2—Cl487.98 (7)
N5—C22—C21116.6 (3)N5—In2—Cl497.47 (7)
C23—C22—C21122.3 (3)Cl6—In2—Cl495.86 (3)
C22—C23—C24119.2 (4)Cl5—In2—Cl492.42 (4)
C22—C23—H23120.4
N1—C1—C2—C4−1.2 (5)C23—C22—N5—In2174.8 (3)
N1—C1—C2—C3179.1 (3)C21—C22—N5—In2−4.7 (4)
C1—C2—C4—C51.4 (5)C25—C27—N5—C22−2.1 (5)
C3—C2—C4—C5−178.9 (3)C25—C27—N5—In2−175.4 (3)
C2—C4—C5—C6−0.8 (5)O2—C28—N6—C29−4.9 (6)
C4—C5—C6—N1−0.1 (5)O2—C28—N6—C30174.8 (4)
C4—C5—C6—C7−177.1 (3)N3—C13—O1—In1−172.6 (3)
N1—C6—C7—N2−12.9 (4)N6—C28—O2—In2151.2 (3)
C5—C6—C7—N2164.3 (3)C13—O1—In1—N1−130.2 (3)
N1—C6—C7—C8166.3 (3)C13—O1—In1—N2155.4 (3)
C5—C6—C7—C8−16.5 (5)C13—O1—In1—Cl1−153.3 (3)
N2—C7—C8—C9−0.5 (5)C13—O1—In1—Cl260.6 (3)
C6—C7—C8—C9−179.7 (3)C13—O1—In1—Cl3−37.5 (3)
C7—C8—C9—C10−1.8 (5)C1—N1—In1—O1113.0 (3)
C8—C9—C10—C122.0 (5)C6—N1—In1—O1−71.1 (2)
C8—C9—C10—C11−178.8 (3)C1—N1—In1—N2−170.4 (3)
C9—C10—C12—N20.2 (5)C6—N1—In1—N25.5 (2)
C11—C10—C12—N2−179.1 (3)C1—N1—In1—Cl1−71.4 (2)
N4—C16—C17—C191.2 (5)C6—N1—In1—Cl1104.5 (2)
N4—C16—C17—C18−177.6 (3)C1—N1—In1—Cl2162.2 (2)
C16—C17—C19—C20−0.7 (5)C6—N1—In1—Cl2−22.0 (5)
C18—C17—C19—C20178.2 (3)C1—N1—In1—Cl326.3 (2)
C17—C19—C20—C210.1 (6)C6—N1—In1—Cl3−157.8 (2)
C19—C20—C21—N40.1 (5)C12—N2—In1—O1−91.2 (3)
C19—C20—C21—C22179.1 (3)C7—N2—In1—O172.3 (2)
N4—C21—C22—N53.7 (4)C12—N2—In1—N1−175.7 (3)
C20—C21—C22—N5−175.3 (3)C7—N2—In1—N1−12.3 (2)
N4—C21—C22—C23−175.8 (3)C12—N2—In1—Cl197.7 (2)
C20—C21—C22—C235.2 (5)C7—N2—In1—Cl1−98.9 (2)
N5—C22—C23—C24−0.2 (5)C12—N2—In1—Cl2−2.2 (2)
C21—C22—C23—C24179.3 (3)C7—N2—In1—Cl2161.2 (2)
C22—C23—C24—C250.1 (6)C12—N2—In1—Cl3−126.9 (2)
C23—C24—C25—C27−1.0 (5)C7—N2—In1—Cl336.5 (3)
C23—C24—C25—C26−179.9 (4)C28—O2—In2—N4111.2 (4)
C24—C25—C27—N52.1 (5)C28—O2—In2—N5−177.5 (4)
C26—C25—C27—N5−179.1 (4)C28—O2—In2—Cl618.7 (4)
C2—C1—N1—C60.4 (5)C28—O2—In2—Cl5−86.1 (4)
C2—C1—N1—In1176.1 (2)C28—O2—In2—Cl4168.4 (5)
C5—C6—N1—C10.3 (5)C16—N4—In2—O2−107.4 (3)
C7—C6—N1—C1177.5 (3)C21—N4—In2—O274.9 (2)
C5—C6—N1—In1−175.7 (2)C16—N4—In2—N5176.6 (3)
C7—C6—N1—In11.4 (3)C21—N4—In2—N5−1.0 (2)
C10—C12—N2—C7−2.5 (5)C16—N4—In2—Cl6−17.7 (3)
C10—C12—N2—In1160.4 (3)C21—N4—In2—Cl6164.6 (2)
C8—C7—N2—C122.6 (5)C16—N4—In2—Cl5169.7 (2)
C6—C7—N2—C12−178.2 (3)C21—N4—In2—Cl5−8.0 (4)
C8—C7—N2—In1−161.8 (2)C16—N4—In2—Cl478.1 (3)
C6—C7—N2—In117.5 (3)C21—N4—In2—Cl4−99.6 (2)
O1—C13—N3—C152.1 (6)C22—N5—In2—O2−89.9 (2)
O1—C13—N3—C14−175.8 (4)C27—N5—In2—O283.5 (3)
C17—C16—N4—C21−1.1 (5)C22—N5—In2—N43.1 (2)
C17—C16—N4—In2−178.7 (3)C27—N5—In2—N4176.5 (3)
C20—C21—N4—C160.4 (5)C22—N5—In2—Cl6−39.9 (4)
C22—C21—N4—C16−178.7 (3)C27—N5—In2—Cl6133.5 (2)
C20—C21—N4—In2178.1 (3)C22—N5—In2—Cl5−178.9 (2)
C22—C21—N4—In2−0.9 (4)C27—N5—In2—Cl5−5.5 (3)
C23—C22—N5—C271.1 (5)C22—N5—In2—Cl488.5 (2)
C21—C22—N5—C27−178.4 (3)C27—N5—In2—Cl4−98.1 (3)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O3—H3D···Cl5i0.84 (3)2.49 (3)3.326 (5)174 (3)
O3—H3E···Cl3ii0.84 (2)2.40 (2)3.183 (5)156 (3)
C5—H5···Cl40.932.693.620 (3)175
C8—H8···Cl40.932.693.574 (4)160
C9—H9···Cl4iii0.932.783.657 (3)158
C16—H16···Cl60.932.803.430 (4)126
C20—H20···O3iv0.932.603.526 (6)178
C23—H23···O3iv0.932.493.416 (6)173
C27—H27···Cl50.932.713.370 (4)129
Symmetry codes: (i) −x, −y+1, −z; (ii) −x+1, −y+2, −z; (iii) −x+1, −y+1, −z+1; (iv) −x+1, −y+1, −z.
Selected bond lengths (Å) top
In1—Cl12.4185 (9)In2—Cl42.4737 (9)
In1—Cl22.4227 (9)In2—Cl52.4327 (10)
In1—Cl32.4496 (9)In2—Cl62.4326 (9)
In1—O12.267 (2)In2—O22.202 (3)
In1—N12.287 (3)In2—N42.292 (3)
In1—N22.301 (3)In2—N52.316 (3)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O3—H3D···Cl5i0.84 (3)2.49 (3)3.326 (5)174 (3)
O3—H3E···Cl3ii0.842 (17)2.396 (19)3.183 (5)156 (3)
C5—H5···Cl40.932.693.620 (3)175
C8—H8···Cl40.932.693.574 (4)160
C9—H9···Cl4iii0.932.783.657 (3)158
C20—H20···O3iv0.932.603.526 (6)178
C23—H23···O3iv0.932.493.416 (6)173
Symmetry codes: (i) −x, −y+1, −z; (ii) −x+1, −y+2, −z; (iii) −x+1, −y+1, −z+1; (iv) −x+1, −y+1, −z.
Acknowledgements top

We are grateful to the Islamic Azad University, Omidieh Branch, for financial support.

references
References top

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