metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

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ISSN: 2056-9890

Bis[O,O′-bis­­(4-tert-butyl­phen­yl) di­thio­phosphato-κ2S,S′]bis­­(pyridine-κN)lead(II)

aInstitute of Functionalized Materials, Sichuan University of Science and Engineering, Zigong 643000, People's Republic of China, and bCollege of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering, Zigong 643000, People's Republic of China
*Correspondence e-mail: zxlsuse@sina.com

(Received 11 August 2013; accepted 26 August 2013; online 31 August 2013)

In the title compound, [Pb(C20H26O2PS2)2(C5H5N)2], the PbII ion is coordinated by two S,S′-bidentate anions and two pyridine mol­ecules. The PbN2S4 coordination geometry approximates to a penta­gonal bipyramid with one equatorial site vacant. The N atoms occupy the axial sites. One of the pyridine mol­ecules is disordered over two sets of sites in a 0.907 (7):0.093 (7) ratio and one of the tert-butyl groups is disordered over two sets of sites in a 0.534 (6):0.466 (6) ratio. An intra­molecular C—H⋯O inter­action occurs in one of the ligands. In the crystal, pairs of short Pb⋯S contacts [3.4018 (11) Å] generate a centrosymmetric dimeric assembly with the distant S atom lying in the region of the vacant coordination site of the metal atom. No directional packing inter­actions occur.

Related literature

For the preparation of the ligand, see: Li & Xie (1997[Li, J.-S. & Xie, B. (1997). Acta Chim. Sin. 55, 892-896.]). For van der Waals radii, see: Bondi (1964[Bondi, A. (1964). J. Phys. Chem. 68, 441-451.]).

[Scheme 1]

Experimental

Crystal data
  • [Pb(C20H26O2PS2)2(C5H5N)2]

  • Mr = 1152.39

  • Triclinic, [P \overline 1]

  • a = 12.4260 (3) Å

  • b = 12.9136 (3) Å

  • c = 17.9749 (4) Å

  • α = 89.7528 (18)°

  • β = 79.4467 (19)°

  • γ = 71.298 (2)°

  • V = 2681.22 (10) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 3.40 mm−1

  • T = 150 K

  • 0.25 × 0.20 × 0.20 mm

Data collection
  • Bruker APEXII diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2008[Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.483, Tmax = 0.549

  • 22556 measured reflections

  • 10953 independent reflections

  • 9252 reflections with I > 2σ(I)

  • Rint = 0.031

Refinement
  • R[F2 > 2σ(F2)] = 0.033

  • wR(F2) = 0.068

  • S = 1.02

  • 10953 reflections

  • 663 parameters

  • 572 restraints

  • H-atom parameters constrained

  • Δρmax = 0.80 e Å−3

  • Δρmin = −0.69 e Å−3

Table 1
Selected bond lengths (Å)

Pb1—N1 2.711 (3)
Pb1—N2 2.732 (18)
Pb1—S3 2.8090 (9)
Pb1—S1 2.9009 (9)
Pb1—S4 3.0577 (9)
Pb1—S2 3.0742 (9)

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
C12—H12⋯O1 0.95 2.45 3.083 (5) 124

Data collection: APEX2 (Bruker, 2008[Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2008[Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

The crystal structure of the title compound is presented herein. The asymmetric unit contains Pb(II)cation, two C20H26O2PS2 ligand anions, two pyridine molecule. The local coordination environment around Pb(II) centers is depicted in Fig. 1.

The Pb(II) ion is coordinated by four S atoms of two bis(4-tert-butylphenyl) dithiophosphate anion ligands with Pb···S distances from 2.8089 (9) to 3.0742 (9)\%A, and two N atoms of two pyridine molecules. The PbN2S4 coordination geometry approximates to a pentagonal bipyramid with one equatorial site vacant. The N atoms occupy the axial sites.

In the crystal, short Pb···S contacts [3.4018 (11) Å] generate a dimeric assembly. The Bondi (1964) contact distance for Pb and S is 3.80Å. No directional contacts could be identified in the packing.

Related literature top

For the preparation of the ligand, see: Li & Xie (1997). For van der Waals radii, see: Bondi (1964).

Experimental top

bis(4-tert-Butylphenyl) dithiophosphate (L) was synthesized according to the procedure described by Li and Xie (1997). The compound PbL2 was prepared by treatment of Pb(NO3)2 (0.33 g, 1.0 mmol) with L (0.94 g, 2.0 mmol) in methanol (40 ml). After refluxing for 3 h, the resulting mixture was cooled to room temperature, the precipitate was filtered off, washed with methanol, and the product PbL2 was obtained as a colorless solid. The product was treated with pyridine (0.51 g, 6.5 mmol) in refluxing acetone and methanol (v/v = 1:1) solution for 5 h. the solution was cooled to room temperature, the precipitate was filtered off, and the adduct [PbL2(Py)2] was obtained as a colorless solid. The filtrate was slowly evaporated at room temperature for several days until colorless blocks of the title adduct appeared.

Computing details top

Data collection: APEX2 (Bruker, 2008); cell refinement: SAINT (Bruker, 2008); data reduction: SAINT (Bruker, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The crystal structure with displacement ellipsoids shown at the 30% level.
Bis[O,O'-bis(4-tert-butylphenyl) dithiophosphato-κ2S,S']bis(pyridine-κN)lead(II) top
Crystal data top
[Pb(C20H26O2PS2)2(C5H5N)2]Z = 2
Mr = 1152.39F(000) = 1168
Triclinic, P1Dx = 1.427 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 12.4260 (3) ÅCell parameters from 10707 reflections
b = 12.9136 (3) Åθ = 2.9–29.2°
c = 17.9749 (4) ŵ = 3.40 mm1
α = 89.7528 (18)°T = 150 K
β = 79.4467 (19)°Block, colorless
γ = 71.298 (2)°0.25 × 0.20 × 0.20 mm
V = 2681.22 (10) Å3
Data collection top
Bruker APEXII
diffractometer
10953 independent reflections
Radiation source: fine-focus sealed tube9252 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.031
ω scansθmax = 26.4°, θmin = 2.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2008)
h = 1515
Tmin = 0.483, Tmax = 0.549k = 1613
22556 measured reflectionsl = 2222
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.033Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.068H-atom parameters constrained
S = 1.02 w = 1/[σ2(Fo2) + (0.025P)2 + 0.850P]
where P = (Fo2 + 2Fc2)/3
10953 reflections(Δ/σ)max = 0.002
663 parametersΔρmax = 0.80 e Å3
572 restraintsΔρmin = 0.69 e Å3
Crystal data top
[Pb(C20H26O2PS2)2(C5H5N)2]γ = 71.298 (2)°
Mr = 1152.39V = 2681.22 (10) Å3
Triclinic, P1Z = 2
a = 12.4260 (3) ÅMo Kα radiation
b = 12.9136 (3) ŵ = 3.40 mm1
c = 17.9749 (4) ÅT = 150 K
α = 89.7528 (18)°0.25 × 0.20 × 0.20 mm
β = 79.4467 (19)°
Data collection top
Bruker APEXII
diffractometer
10953 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2008)
9252 reflections with I > 2σ(I)
Tmin = 0.483, Tmax = 0.549Rint = 0.031
22556 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.033572 restraints
wR(F2) = 0.068H-atom parameters constrained
S = 1.02Δρmax = 0.80 e Å3
10953 reflectionsΔρmin = 0.69 e Å3
663 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pb10.612885 (11)0.604091 (11)0.396926 (7)0.03145 (5)
P10.62254 (8)0.66393 (7)0.58583 (5)0.0271 (2)
P20.70541 (8)0.61341 (7)0.20625 (5)0.0282 (2)
S10.72725 (8)0.69068 (7)0.49614 (5)0.0335 (2)
S20.51198 (9)0.59419 (8)0.56523 (5)0.0404 (2)
S30.74784 (8)0.68922 (8)0.28674 (5)0.0341 (2)
S40.57837 (8)0.55505 (8)0.23833 (5)0.0371 (2)
O10.6962 (2)0.60457 (18)0.64789 (13)0.0333 (6)
O20.55836 (19)0.78039 (17)0.63186 (12)0.0315 (6)
O30.81414 (19)0.51538 (18)0.16392 (13)0.0333 (6)
O40.6861 (2)0.69140 (18)0.13647 (12)0.0324 (6)
N10.7945 (3)0.4160 (2)0.38507 (17)0.0363 (7)
C10.7648 (3)0.4943 (3)0.64080 (18)0.0288 (8)
C20.7151 (3)0.4137 (3)0.6512 (3)0.0522 (12)
H20.63330.43160.65880.063*
C30.7845 (4)0.3060 (3)0.6505 (3)0.0567 (12)
H30.74900.25060.65670.068*
C40.9035 (3)0.2758 (3)0.6412 (2)0.0354 (9)
C50.9505 (3)0.3594 (3)0.6319 (2)0.0469 (11)
H51.03200.34230.62610.056*
C60.8818 (3)0.4681 (3)0.6309 (2)0.0436 (10)
H60.91660.52390.62340.052*
C70.9755 (3)0.1559 (3)0.6426 (2)0.0474 (10)
C80.9290 (7)0.1076 (4)0.7139 (3)0.099 (3)0.907 (7)
H8A0.97720.03120.71530.148*0.907 (7)
H8B0.84920.11090.71350.148*0.907 (7)
H8C0.93060.14960.75870.148*0.907 (7)
C91.1030 (5)0.1402 (4)0.6397 (5)0.089 (2)0.907 (7)
H9A1.14540.06230.64200.133*0.907 (7)
H9B1.11100.18130.68290.133*0.907 (7)
H9C1.13460.16710.59240.133*0.907 (7)
C100.9666 (6)0.0917 (4)0.5746 (3)0.0732 (19)0.907 (7)
H10A1.01310.01460.57560.110*0.907 (7)
H10B0.99560.12170.52780.110*0.907 (7)
H10C0.88560.09760.57640.110*0.907 (7)
C8A1.014 (6)0.151 (4)0.719 (2)0.089 (10)0.093 (7)
H8D1.04850.07460.72990.133*0.093 (7)
H8E0.94740.18740.75860.133*0.093 (7)
H8F1.07200.18870.71620.133*0.093 (7)
C9A1.089 (3)0.135 (5)0.587 (3)0.083 (11)0.093 (7)
H9D1.07380.14720.53540.125*0.093 (7)
H9E1.13850.05880.58900.125*0.093 (7)
H9F1.12890.18460.60010.125*0.093 (7)
C10A0.898 (4)0.086 (3)0.644 (4)0.095 (11)0.093 (7)
H10D0.82380.12950.63110.142*0.093 (7)
H10E0.88330.05920.69500.142*0.093 (7)
H10F0.93540.02310.60730.142*0.093 (7)
C110.4633 (3)0.7995 (3)0.69197 (18)0.0268 (7)
C120.4578 (3)0.7252 (3)0.7470 (2)0.0372 (9)
H120.51720.65630.74370.045*
C130.3648 (3)0.7526 (3)0.8070 (2)0.0370 (9)
H130.36100.70130.84460.044*
C140.2771 (3)0.8520 (3)0.81404 (19)0.0316 (8)
C150.2841 (3)0.9232 (3)0.75728 (19)0.0321 (8)
H150.22410.99160.76010.038*
C160.3763 (3)0.8975 (3)0.69617 (19)0.0304 (8)
H160.37890.94770.65760.037*
C170.1796 (3)0.8792 (3)0.8847 (2)0.0424 (10)
C180.2339 (4)0.8845 (4)0.9543 (2)0.0606 (13)
H18C0.26950.94240.94920.091*
H18A0.29320.81400.95770.091*
H18B0.17380.90041.00020.091*
C190.1218 (4)0.7908 (4)0.8933 (3)0.0632 (13)
H19C0.06150.80820.93920.095*
H19B0.17980.71980.89720.095*
H19A0.08690.78770.84900.095*
C200.0872 (4)0.9891 (4)0.8809 (3)0.0696 (15)
H20C0.12231.04730.87760.104*
H20B0.02671.00320.92660.104*
H20A0.05300.98750.83610.104*
C210.8799 (3)0.4028 (3)0.4228 (2)0.0448 (10)
H210.87590.46070.45680.054*
C220.9744 (4)0.3083 (3)0.4147 (2)0.0492 (11)
H221.03440.30140.44230.059*
C230.9798 (4)0.2249 (3)0.3660 (2)0.0502 (11)
H231.04390.15910.35880.060*
C240.8910 (4)0.2380 (3)0.3278 (2)0.0530 (11)
H240.89250.18100.29400.064*
C250.7997 (4)0.3342 (3)0.3387 (2)0.0444 (10)
H250.73830.34240.31220.053*
N20.4568 (16)0.8110 (13)0.4130 (4)0.051 (3)0.534 (6)
C260.4243 (9)0.8513 (7)0.3507 (5)0.047 (3)0.534 (6)
H260.45170.80290.30660.056*0.534 (6)
C270.3548 (7)0.9559 (6)0.3418 (5)0.0426 (19)0.534 (6)
H270.32620.97650.29650.051*0.534 (6)
C280.3301 (8)1.0278 (7)0.4026 (4)0.045 (2)0.534 (6)
H280.28181.10130.40120.054*0.534 (6)
C290.3750 (8)0.9935 (6)0.4654 (5)0.061 (2)0.534 (6)
H290.35881.04200.50870.073*0.534 (6)
C300.4437 (9)0.8876 (6)0.4643 (5)0.067 (3)0.534 (6)
H300.48570.86750.50410.081*0.534 (6)
N2A0.460 (2)0.7957 (17)0.4024 (6)0.054 (3)0.466 (6)
C26A0.4523 (12)0.8674 (9)0.3542 (6)0.061 (3)0.466 (6)
H26A0.49360.84520.30390.073*0.466 (6)
C27A0.3878 (9)0.9755 (8)0.3700 (6)0.057 (3)0.466 (6)
H27A0.39321.02640.33240.069*0.466 (6)
C28A0.3161 (10)1.0120 (8)0.4382 (6)0.057 (3)0.466 (6)
H28A0.27241.08730.44900.068*0.466 (6)
C29A0.3097 (10)0.9362 (7)0.4902 (5)0.070 (3)0.466 (6)
H29A0.25880.95770.53790.084*0.466 (6)
C30A0.3765 (9)0.8293 (7)0.4737 (5)0.064 (3)0.466 (6)
H30A0.36870.77600.50900.077*0.466 (6)
C310.9261 (3)0.5243 (3)0.14579 (19)0.0291 (8)
C321.0056 (3)0.4731 (3)0.1880 (2)0.0440 (10)
H320.98460.43450.23040.053*
C331.1175 (3)0.4770 (3)0.1691 (2)0.0425 (10)
H331.17260.44110.19910.051*
C341.1505 (3)0.5319 (3)0.10792 (19)0.0307 (8)
C351.0673 (3)0.5826 (4)0.0672 (2)0.0530 (12)
H351.08770.62140.02480.064*
C360.9545 (3)0.5803 (4)0.0848 (2)0.0509 (11)
H360.89890.61650.05530.061*
C371.2725 (3)0.5398 (3)0.0861 (2)0.0392 (9)
C381.3553 (3)0.4724 (4)0.1342 (2)0.0578 (12)
H38B1.32630.49850.18750.087*
H38C1.43190.48000.11740.087*
H38A1.36120.39520.12860.087*
C391.3226 (4)0.4988 (5)0.0037 (2)0.0761 (16)
H39C1.40220.50000.00950.114*
H39B1.27550.54620.02920.114*
H39A1.32220.42370.00330.114*
C401.2644 (4)0.6592 (4)0.0955 (4)0.0893 (19)
H40C1.34010.66700.07570.134*
H40B1.24070.68330.14940.134*
H40A1.20710.70420.06760.134*
C410.5936 (3)0.7898 (3)0.14164 (18)0.0314 (8)
C420.4882 (3)0.7893 (3)0.1280 (2)0.0445 (10)
H420.47600.72190.11910.053*
C430.4006 (3)0.8869 (3)0.1275 (2)0.0473 (10)
H430.32830.88530.11810.057*
C440.4144 (3)0.9882 (3)0.1401 (2)0.0377 (9)
C450.5218 (3)0.9850 (3)0.1545 (2)0.0376 (9)
H450.53461.05200.16400.045*
C460.6104 (3)0.8876 (3)0.1554 (2)0.0367 (9)
H460.68260.88830.16540.044*
C470.3209 (3)1.0973 (3)0.1363 (2)0.0459 (10)
C480.2985 (4)1.1711 (4)0.2073 (3)0.0787 (16)
H48C0.37041.18390.21280.118*
H48A0.27151.13570.25190.118*
H48B0.23941.24130.20290.118*
C490.2050 (4)1.0846 (4)0.1314 (4)0.090 (2)
H49C0.14571.15690.13630.135*
H49A0.18381.04030.17240.135*
H49B0.21081.04820.08240.135*
C500.3605 (5)1.1537 (4)0.0675 (3)0.093 (2)
H50C0.43391.16440.07140.139*
H50B0.30181.22490.06500.139*
H50A0.37141.10810.02150.139*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pb10.02567 (8)0.03976 (9)0.02520 (7)0.00793 (6)0.00047 (5)0.00004 (5)
P10.0258 (5)0.0289 (5)0.0254 (4)0.0084 (4)0.0026 (4)0.0029 (4)
P20.0242 (5)0.0363 (5)0.0259 (4)0.0153 (4)0.0009 (4)0.0022 (4)
S10.0294 (5)0.0375 (5)0.0311 (5)0.0134 (4)0.0050 (4)0.0050 (4)
S20.0445 (6)0.0620 (6)0.0262 (5)0.0345 (5)0.0036 (4)0.0003 (4)
S30.0318 (5)0.0459 (5)0.0292 (5)0.0206 (5)0.0029 (4)0.0043 (4)
S40.0322 (5)0.0540 (6)0.0345 (5)0.0282 (5)0.0039 (4)0.0012 (4)
O10.0335 (14)0.0305 (13)0.0288 (13)0.0003 (12)0.0067 (11)0.0083 (10)
O20.0290 (13)0.0284 (13)0.0311 (13)0.0064 (11)0.0042 (11)0.0027 (10)
O30.0240 (13)0.0360 (14)0.0377 (14)0.0115 (11)0.0035 (11)0.0056 (11)
O40.0307 (14)0.0380 (14)0.0283 (13)0.0133 (12)0.0011 (11)0.0017 (10)
N10.0330 (17)0.0361 (17)0.0383 (17)0.0093 (15)0.0062 (15)0.0019 (14)
C10.0293 (19)0.0299 (19)0.0233 (17)0.0065 (17)0.0008 (15)0.0004 (14)
C20.025 (2)0.047 (3)0.080 (3)0.012 (2)0.000 (2)0.020 (2)
C30.047 (3)0.045 (3)0.089 (4)0.027 (2)0.020 (3)0.027 (2)
C40.038 (2)0.0295 (19)0.041 (2)0.0122 (18)0.0110 (18)0.0043 (16)
C50.028 (2)0.035 (2)0.078 (3)0.0089 (19)0.015 (2)0.000 (2)
C60.036 (2)0.028 (2)0.074 (3)0.0164 (19)0.018 (2)0.0041 (19)
C70.053 (3)0.031 (2)0.061 (3)0.013 (2)0.019 (2)0.0058 (19)
C80.141 (6)0.045 (3)0.081 (4)0.001 (4)0.003 (4)0.032 (3)
C90.071 (4)0.035 (3)0.163 (7)0.002 (3)0.058 (4)0.014 (4)
C100.106 (5)0.033 (3)0.080 (4)0.008 (3)0.042 (4)0.006 (3)
C8A0.095 (17)0.039 (15)0.106 (16)0.015 (15)0.023 (16)0.022 (15)
C9A0.089 (16)0.036 (15)0.102 (17)0.014 (15)0.023 (16)0.012 (16)
C10A0.106 (16)0.039 (15)0.110 (17)0.019 (15)0.027 (16)0.021 (15)
C110.0235 (18)0.0301 (19)0.0246 (17)0.0075 (16)0.0010 (15)0.0035 (14)
C120.031 (2)0.032 (2)0.038 (2)0.0011 (17)0.0005 (17)0.0014 (16)
C130.037 (2)0.041 (2)0.0293 (19)0.0083 (19)0.0040 (17)0.0083 (16)
C140.0256 (19)0.043 (2)0.0248 (18)0.0087 (18)0.0054 (15)0.0029 (15)
C150.0249 (19)0.0334 (19)0.0313 (19)0.0001 (16)0.0065 (16)0.0016 (15)
C160.0293 (19)0.0303 (19)0.0291 (18)0.0068 (17)0.0042 (16)0.0004 (15)
C170.029 (2)0.058 (3)0.031 (2)0.005 (2)0.0021 (17)0.0012 (18)
C180.052 (3)0.097 (4)0.026 (2)0.021 (3)0.004 (2)0.011 (2)
C190.046 (3)0.092 (4)0.051 (3)0.031 (3)0.006 (2)0.009 (2)
C200.043 (3)0.078 (3)0.055 (3)0.010 (3)0.019 (2)0.001 (2)
C210.042 (2)0.041 (2)0.050 (2)0.009 (2)0.016 (2)0.0088 (19)
C220.045 (3)0.041 (2)0.065 (3)0.011 (2)0.024 (2)0.002 (2)
C230.050 (3)0.030 (2)0.062 (3)0.000 (2)0.013 (2)0.0028 (19)
C240.062 (3)0.042 (2)0.058 (3)0.015 (2)0.021 (2)0.011 (2)
C250.044 (2)0.046 (2)0.046 (2)0.013 (2)0.016 (2)0.0020 (19)
N20.053 (4)0.045 (5)0.027 (4)0.023 (4)0.009 (4)0.020 (3)
C260.049 (5)0.034 (4)0.045 (4)0.010 (4)0.011 (4)0.000 (3)
C270.056 (4)0.035 (4)0.037 (4)0.014 (3)0.010 (3)0.005 (3)
C280.046 (4)0.040 (4)0.040 (4)0.008 (3)0.002 (4)0.001 (4)
C290.073 (5)0.042 (4)0.045 (4)0.017 (4)0.020 (4)0.012 (3)
C300.074 (5)0.050 (4)0.046 (4)0.025 (4)0.015 (4)0.010 (3)
N2A0.051 (5)0.058 (6)0.029 (4)0.016 (5)0.002 (4)0.016 (4)
C26A0.059 (6)0.042 (5)0.057 (5)0.001 (5)0.021 (4)0.010 (4)
C27A0.058 (5)0.042 (5)0.059 (5)0.006 (4)0.003 (4)0.005 (4)
C28A0.054 (5)0.042 (4)0.060 (5)0.007 (4)0.015 (5)0.022 (4)
C29A0.063 (5)0.071 (5)0.045 (4)0.020 (4)0.006 (4)0.013 (4)
C30A0.055 (5)0.057 (5)0.046 (4)0.017 (4)0.012 (4)0.011 (4)
C310.0230 (18)0.0324 (19)0.0295 (18)0.0109 (16)0.0047 (15)0.0047 (15)
C320.033 (2)0.045 (2)0.046 (2)0.0060 (19)0.0025 (19)0.0185 (18)
C330.029 (2)0.052 (2)0.040 (2)0.0059 (19)0.0043 (18)0.0130 (18)
C340.0274 (19)0.036 (2)0.0288 (18)0.0108 (17)0.0059 (16)0.0031 (15)
C350.035 (2)0.082 (3)0.045 (2)0.025 (2)0.004 (2)0.028 (2)
C360.032 (2)0.087 (3)0.040 (2)0.023 (2)0.0131 (19)0.025 (2)
C370.034 (2)0.053 (2)0.037 (2)0.021 (2)0.0105 (18)0.0033 (18)
C380.028 (2)0.095 (4)0.050 (3)0.019 (2)0.009 (2)0.003 (2)
C390.036 (3)0.154 (5)0.039 (3)0.037 (3)0.002 (2)0.004 (3)
C400.062 (3)0.074 (4)0.152 (6)0.042 (3)0.036 (4)0.015 (4)
C410.034 (2)0.039 (2)0.0222 (17)0.0138 (18)0.0037 (16)0.0013 (15)
C420.044 (2)0.038 (2)0.057 (3)0.016 (2)0.019 (2)0.0053 (19)
C430.038 (2)0.053 (3)0.060 (3)0.021 (2)0.018 (2)0.003 (2)
C440.039 (2)0.046 (2)0.033 (2)0.019 (2)0.0084 (18)0.0008 (17)
C450.040 (2)0.036 (2)0.042 (2)0.019 (2)0.0095 (18)0.0020 (17)
C460.033 (2)0.046 (2)0.039 (2)0.0221 (19)0.0090 (17)0.0037 (17)
C470.039 (2)0.049 (2)0.052 (3)0.013 (2)0.018 (2)0.001 (2)
C480.071 (4)0.062 (3)0.084 (4)0.011 (3)0.024 (3)0.020 (3)
C490.048 (3)0.063 (3)0.163 (6)0.009 (3)0.046 (4)0.009 (4)
C500.096 (4)0.070 (4)0.083 (4)0.002 (3)0.002 (4)0.033 (3)
Geometric parameters (Å, º) top
Pb1—N2A2.58 (2)C20—H20A0.9800
Pb1—N12.711 (3)C21—C221.382 (5)
Pb1—N22.732 (18)C21—H210.9500
Pb1—S32.8090 (9)C22—C231.369 (5)
Pb1—S12.9009 (9)C22—H220.9500
Pb1—S43.0577 (9)C23—C241.369 (6)
Pb1—S23.0742 (9)C23—H230.9500
P1—O21.607 (2)C24—C251.373 (5)
P1—O11.608 (3)C24—H240.9500
P1—S21.9540 (13)C25—H250.9500
P1—S11.9816 (12)N2—C301.305 (11)
P2—O31.594 (2)N2—C261.309 (12)
P2—O41.609 (2)C26—C271.377 (6)
P2—S41.9541 (12)C26—H260.9500
P2—S31.9880 (12)C27—C281.362 (6)
O1—C11.397 (4)C27—H270.9500
O2—C111.404 (4)C28—C291.360 (7)
O3—C311.411 (4)C28—H280.9500
O4—C411.403 (4)C29—C301.359 (6)
N1—C251.326 (4)C29—H290.9500
N1—C211.328 (5)C30—H300.9500
C1—C61.361 (5)N2A—C26A1.26 (2)
C1—C21.368 (5)N2A—C30A1.463 (19)
C2—C31.380 (5)C26A—C27A1.369 (7)
C2—H20.9500C26A—H26A0.9500
C3—C41.382 (5)C27A—C28A1.361 (7)
C3—H30.9500C27A—H27A0.9500
C4—C51.379 (5)C28A—C29A1.362 (7)
C4—C71.522 (5)C28A—H28A0.9500
C5—C61.391 (5)C29A—C30A1.364 (7)
C5—H50.9500C29A—H29A0.9500
C6—H60.9500C30A—H30A0.9500
C7—C101.520 (5)C31—C321.356 (5)
C7—C10A1.521 (9)C31—C361.366 (5)
C7—C81.522 (5)C32—C331.387 (5)
C7—C9A1.522 (9)C32—H320.9500
C7—C91.522 (5)C33—C341.377 (5)
C7—C8A1.524 (9)C33—H330.9500
C8—H8A0.9800C34—C351.368 (5)
C8—H8B0.9800C34—C371.531 (5)
C8—H8C0.9800C35—C361.389 (5)
C9—H9A0.9800C35—H350.9500
C9—H9B0.9800C36—H360.9500
C9—H9C0.9800C37—C381.518 (5)
C10—H10A0.9800C37—C401.520 (6)
C10—H10B0.9800C37—C391.524 (5)
C10—H10C0.9800C38—H38B0.9800
C8A—H8D0.9800C38—H38C0.9800
C8A—H8E0.9800C38—H38A0.9800
C8A—H8F0.9800C39—H39C0.9800
C9A—H9D0.9800C39—H39B0.9800
C9A—H9E0.9800C39—H39A0.9800
C9A—H9F0.9800C40—H40C0.9800
C10A—H10D0.9800C40—H40B0.9800
C10A—H10E0.9800C40—H40A0.9800
C10A—H10F0.9800C41—C461.376 (5)
C11—C161.368 (4)C41—C421.377 (5)
C11—C121.384 (5)C42—C431.377 (5)
C12—C131.381 (5)C42—H420.9500
C12—H120.9500C43—C441.398 (5)
C13—C141.381 (5)C43—H430.9500
C13—H130.9500C44—C451.393 (5)
C14—C151.380 (5)C44—C471.522 (5)
C14—C171.540 (5)C45—C461.383 (5)
C15—C161.389 (4)C45—H450.9500
C15—H150.9500C46—H460.9500
C16—H160.9500C47—C501.517 (6)
C17—C201.523 (5)C47—C491.519 (6)
C17—C191.525 (6)C47—C481.525 (6)
C17—C181.537 (5)C48—H48C0.9800
C18—H18C0.9800C48—H48A0.9800
C18—H18A0.9800C48—H48B0.9800
C18—H18B0.9800C49—H49C0.9800
C19—H19C0.9800C49—H49A0.9800
C19—H19B0.9800C49—H49B0.9800
C19—H19A0.9800C50—H50C0.9800
C20—H20C0.9800C50—H50B0.9800
C20—H20B0.9800C50—H50A0.9800
N2A—Pb1—N1172.4 (4)H19C—C19—H19A109.5
N2A—Pb1—N24.7 (5)H19B—C19—H19A109.5
N1—Pb1—N2170.1 (3)C17—C20—H20C109.5
N2A—Pb1—S384.4 (3)C17—C20—H20B109.5
N1—Pb1—S388.79 (6)H20C—C20—H20B109.5
N2—Pb1—S385.2 (3)C17—C20—H20A109.5
N2A—Pb1—S189.1 (4)H20C—C20—H20A109.5
N1—Pb1—S186.54 (7)H20B—C20—H20A109.5
N2—Pb1—S184.7 (3)N1—C21—C22122.7 (4)
S3—Pb1—S181.43 (2)N1—C21—H21118.7
N2A—Pb1—S490.2 (3)C22—C21—H21118.7
N1—Pb1—S490.53 (7)C23—C22—C21118.5 (4)
N2—Pb1—S494.81 (19)C23—C22—H22120.7
S3—Pb1—S469.48 (2)C21—C22—H22120.7
S1—Pb1—S4150.83 (2)C22—C23—C24118.8 (4)
N2A—Pb1—S287.1 (3)C22—C23—H23120.6
N1—Pb1—S296.97 (7)C24—C23—H23120.6
N2—Pb1—S284.10 (16)C23—C24—C25119.4 (4)
S3—Pb1—S2148.29 (3)C23—C24—H24120.3
S1—Pb1—S267.91 (2)C25—C24—H24120.3
S4—Pb1—S2141.17 (2)N1—C25—C24122.2 (4)
O2—P1—O197.61 (12)N1—C25—H25118.9
O2—P1—S2111.63 (10)C24—C25—H25118.9
O1—P1—S2113.50 (10)C30—N2—C26112.2 (14)
O2—P1—S1106.22 (9)C30—N2—Pb1127.0 (10)
O1—P1—S1109.96 (10)C26—N2—Pb1115.6 (8)
S2—P1—S1116.15 (6)N2—C26—C27127.3 (11)
O3—P2—O498.63 (12)N2—C26—H26116.3
O3—P2—S4107.59 (10)C27—C26—H26116.3
O4—P2—S4112.64 (10)C28—C27—C26115.1 (9)
O3—P2—S3111.16 (10)C28—C27—H27122.4
O4—P2—S3109.05 (10)C26—C27—H27122.4
S4—P2—S3116.34 (5)C29—C28—C27119.5 (8)
P1—S1—Pb190.15 (4)C29—C28—H28120.2
P1—S2—Pb185.72 (4)C27—C28—H28120.2
P2—S3—Pb189.40 (4)C30—C29—C28117.7 (8)
P2—S4—Pb183.07 (4)C30—C29—H29121.1
C1—O1—P1123.7 (2)C28—C29—H29121.1
C11—O2—P1123.5 (2)N2—C30—C29125.5 (10)
C31—O3—P2122.0 (2)N2—C30—H30117.2
C41—O4—P2122.82 (19)C29—C30—H30117.2
C25—N1—C21118.3 (3)C26A—N2A—C30A115.2 (18)
C25—N1—Pb1118.9 (3)C26A—N2A—Pb1129.0 (13)
C21—N1—Pb1122.7 (2)C30A—N2A—Pb1115.6 (10)
C6—C1—C2119.9 (3)N2A—C26A—C27A124.0 (13)
C6—C1—O1119.2 (3)N2A—C26A—H26A118.0
C2—C1—O1120.6 (3)C27A—C26A—H26A118.0
C1—C2—C3119.5 (4)C28A—C27A—C26A121.8 (10)
C1—C2—H2120.2C28A—C27A—H27A119.1
C3—C2—H2120.2C26A—C27A—H27A119.1
C2—C3—C4122.5 (4)C27A—C28A—C29A117.2 (9)
C2—C3—H3118.7C27A—C28A—H28A121.4
C4—C3—H3118.7C29A—C28A—H28A121.4
C5—C4—C3116.3 (3)C28A—C29A—C30A119.9 (9)
C5—C4—C7123.5 (3)C28A—C29A—H29A120.1
C3—C4—C7120.2 (3)C30A—C29A—H29A120.1
C4—C5—C6121.8 (4)C29A—C30A—N2A120.9 (12)
C4—C5—H5119.1C29A—C30A—H30A119.6
C6—C5—H5119.1N2A—C30A—H30A119.6
C1—C6—C5119.9 (3)C32—C31—C36120.9 (3)
C1—C6—H6120.0C32—C31—O3119.0 (3)
C5—C6—H6120.0C36—C31—O3120.1 (3)
C10—C7—C10A55 (3)C31—C32—C33119.9 (3)
C10—C7—C8107.9 (4)C31—C32—H32120.1
C10A—C7—C856 (3)C33—C32—H32120.1
C10—C7—C9A74 (3)C34—C33—C32121.4 (4)
C10A—C7—C9A124 (4)C34—C33—H33119.3
C8—C7—C9A138 (2)C32—C33—H33119.3
C10—C7—C4109.6 (3)C35—C34—C33116.7 (3)
C10A—C7—C4109.1 (19)C35—C34—C37120.4 (3)
C8—C7—C4109.9 (3)C33—C34—C37122.9 (3)
C9A—C7—C4108 (2)C34—C35—C36123.3 (4)
C10—C7—C9107.8 (4)C34—C35—H35118.4
C10A—C7—C9138.4 (19)C36—C35—H35118.4
C8—C7—C9109.1 (5)C31—C36—C35117.9 (4)
C9A—C7—C938 (3)C31—C36—H36121.1
C4—C7—C9112.4 (3)C35—C36—H36121.1
C10—C7—C8A147 (2)C38—C37—C40108.8 (4)
C10A—C7—C8A109 (4)C38—C37—C39107.7 (4)
C8—C7—C8A53 (3)C40—C37—C39109.4 (4)
C9A—C7—C8A102 (4)C38—C37—C34113.1 (3)
C4—C7—C8A102.9 (19)C40—C37—C34108.5 (3)
C9—C7—C8A64 (3)C39—C37—C34109.4 (3)
C7—C8—H8A109.5C37—C38—H38B109.5
C7—C8—H8B109.5C37—C38—H38C109.5
C7—C8—H8C109.5H38B—C38—H38C109.5
C7—C9—H9A109.5C37—C38—H38A109.5
C7—C9—H9B109.5H38B—C38—H38A109.5
C7—C9—H9C109.5H38C—C38—H38A109.5
C7—C10—H10A109.5C37—C39—H39C109.5
C7—C10—H10B109.5C37—C39—H39B109.5
C7—C10—H10C109.5H39C—C39—H39B109.5
C7—C8A—H8D109.5C37—C39—H39A109.5
C7—C8A—H8E109.5H39C—C39—H39A109.5
H8D—C8A—H8E109.5H39B—C39—H39A109.5
C7—C8A—H8F109.5C37—C40—H40C109.5
H8D—C8A—H8F109.5C37—C40—H40B109.5
H8E—C8A—H8F109.5H40C—C40—H40B109.5
C7—C9A—H9D109.5C37—C40—H40A109.5
C7—C9A—H9E109.5H40C—C40—H40A109.5
H9D—C9A—H9E109.5H40B—C40—H40A109.5
C7—C9A—H9F109.5C46—C41—C42119.9 (4)
H9D—C9A—H9F109.5C46—C41—O4119.8 (3)
H9E—C9A—H9F109.5C42—C41—O4120.2 (3)
C7—C10A—H10D109.5C41—C42—C43119.8 (4)
C7—C10A—H10E109.5C41—C42—H42120.1
H10D—C10A—H10E109.5C43—C42—H42120.1
C7—C10A—H10F109.5C42—C43—C44122.3 (4)
H10D—C10A—H10F109.5C42—C43—H43118.8
H10E—C10A—H10F109.5C44—C43—H43118.8
C16—C11—C12120.2 (3)C45—C44—C43116.1 (4)
C16—C11—O2117.3 (3)C45—C44—C47120.5 (3)
C12—C11—O2122.4 (3)C43—C44—C47123.4 (3)
C13—C12—C11119.0 (3)C46—C45—C44122.3 (3)
C13—C12—H12120.5C46—C45—H45118.9
C11—C12—H12120.5C44—C45—H45118.9
C14—C13—C12122.2 (3)C41—C46—C45119.7 (3)
C14—C13—H13118.9C41—C46—H46120.1
C12—C13—H13118.9C45—C46—H46120.1
C15—C14—C13117.2 (3)C50—C47—C49109.3 (4)
C15—C14—C17123.6 (3)C50—C47—C44108.7 (3)
C13—C14—C17119.2 (3)C49—C47—C44112.7 (4)
C14—C15—C16121.8 (3)C50—C47—C48109.2 (4)
C14—C15—H15119.1C49—C47—C48105.7 (4)
C16—C15—H15119.1C44—C47—C48111.2 (3)
C11—C16—C15119.5 (3)C47—C48—H48C109.5
C11—C16—H16120.3C47—C48—H48A109.5
C15—C16—H16120.3H48C—C48—H48A109.5
C20—C17—C19108.4 (4)C47—C48—H48B109.5
C20—C17—C18108.6 (4)H48C—C48—H48B109.5
C19—C17—C18109.5 (3)H48A—C48—H48B109.5
C20—C17—C14112.0 (3)C47—C49—H49C109.5
C19—C17—C14110.5 (3)C47—C49—H49A109.5
C18—C17—C14107.8 (3)H49C—C49—H49A109.5
C17—C18—H18C109.5C47—C49—H49B109.5
C17—C18—H18A109.5H49C—C49—H49B109.5
H18C—C18—H18A109.5H49A—C49—H49B109.5
C17—C18—H18B109.5C47—C50—H50C109.5
H18C—C18—H18B109.5C47—C50—H50B109.5
H18A—C18—H18B109.5H50C—C50—H50B109.5
C17—C19—H19C109.5C47—C50—H50A109.5
C17—C19—H19B109.5H50C—C50—H50A109.5
H19C—C19—H19B109.5H50B—C50—H50A109.5
C17—C19—H19A109.5
O2—P1—S1—Pb1122.28 (10)C12—C11—C16—C151.9 (5)
O1—P1—S1—Pb1133.11 (9)O2—C11—C16—C15175.9 (3)
S2—P1—S1—Pb12.50 (6)C14—C15—C16—C110.4 (5)
N2A—Pb1—S1—P185.7 (3)C15—C14—C17—C205.0 (5)
N1—Pb1—S1—P1100.50 (7)C13—C14—C17—C20176.8 (4)
N2—Pb1—S1—P184.2 (2)C15—C14—C17—C19125.9 (4)
S3—Pb1—S1—P1170.20 (4)C13—C14—C17—C1955.9 (5)
S4—Pb1—S1—P1174.61 (5)C15—C14—C17—C18114.4 (4)
S2—Pb1—S1—P11.54 (4)C13—C14—C17—C1863.8 (5)
O2—P1—S2—Pb1119.60 (10)C25—N1—C21—C221.1 (6)
O1—P1—S2—Pb1131.28 (9)Pb1—N1—C21—C22177.7 (3)
S1—P1—S2—Pb12.37 (6)N1—C21—C22—C230.3 (6)
N2A—Pb1—S2—P188.7 (4)C21—C22—C23—C240.5 (6)
N1—Pb1—S2—P184.95 (8)C22—C23—C24—C250.5 (7)
N2—Pb1—S2—P185.1 (3)C21—N1—C25—C241.2 (6)
S3—Pb1—S2—P114.11 (8)Pb1—N1—C25—C24177.7 (3)
S1—Pb1—S2—P11.57 (4)C23—C24—C25—N10.4 (7)
S4—Pb1—S2—P1175.44 (4)N2A—Pb1—N2—C30177 (9)
O3—P2—S3—Pb1110.71 (10)N1—Pb1—N2—C3044.2 (16)
O4—P2—S3—Pb1141.59 (9)S3—Pb1—N2—C3097.5 (10)
S4—P2—S3—Pb112.87 (6)S1—Pb1—N2—C3015.7 (10)
N2A—Pb1—S3—P2100.2 (4)S4—Pb1—N2—C30166.4 (10)
N1—Pb1—S3—P283.19 (8)S2—Pb1—N2—C3052.6 (10)
N2—Pb1—S3—P2104.8 (3)N2A—Pb1—N2—C2625 (7)
S1—Pb1—S3—P2169.87 (5)N1—Pb1—N2—C26108.0 (12)
S4—Pb1—S3—P27.83 (4)S3—Pb1—N2—C2654.7 (11)
S2—Pb1—S3—P2175.46 (5)S1—Pb1—N2—C26136.5 (11)
O3—P2—S4—Pb1113.52 (11)S4—Pb1—N2—C2614.2 (12)
O4—P2—S4—Pb1138.86 (10)S2—Pb1—N2—C26155.2 (12)
S3—P2—S4—Pb111.90 (6)C30—N2—C26—C2718 (2)
N2A—Pb1—S4—P292.0 (4)Pb1—N2—C26—C27174.1 (9)
N1—Pb1—S4—P280.48 (7)N2—C26—C27—C288.8 (18)
N2—Pb1—S4—P291.1 (3)C26—C27—C28—C290.9 (14)
S3—Pb1—S4—P28.03 (4)C27—C28—C29—C300.2 (15)
S1—Pb1—S4—P23.37 (8)C26—N2—C30—C2918.7 (19)
S2—Pb1—S4—P2177.68 (4)Pb1—N2—C30—C29171.6 (9)
O2—P1—O1—C1175.0 (2)C28—C29—C30—N211.0 (17)
S2—P1—O1—C157.4 (3)N1—Pb1—N2A—C26A46 (4)
S1—P1—O1—C174.6 (3)N2—Pb1—N2A—C26A119 (9)
O1—P1—O2—C1177.6 (3)S3—Pb1—N2A—C26A19.6 (17)
S2—P1—O2—C1141.4 (3)S1—Pb1—N2A—C26A101.1 (17)
S1—P1—O2—C11169.0 (2)S4—Pb1—N2A—C26A49.7 (17)
O4—P2—O3—C3174.6 (3)S2—Pb1—N2A—C26A169.0 (17)
S4—P2—O3—C31168.2 (2)N1—Pb1—N2A—C30A128.3 (17)
S3—P2—O3—C3139.8 (3)N2—Pb1—N2A—C30A55 (7)
O3—P2—O4—C41176.0 (2)S3—Pb1—N2A—C30A154.8 (13)
S4—P2—O4—C4162.8 (3)S1—Pb1—N2A—C30A73.3 (13)
S3—P2—O4—C4167.9 (3)S4—Pb1—N2A—C30A135.9 (13)
N2A—Pb1—N1—C25121 (2)S2—Pb1—N2A—C30A5.4 (12)
N2—Pb1—N1—C25147.7 (9)C30A—N2A—C26A—C27A12 (3)
S3—Pb1—N1—C2594.6 (3)Pb1—N2A—C26A—C27A162.0 (12)
S1—Pb1—N1—C25176.1 (3)N2A—C26A—C27A—C28A7 (3)
S4—Pb1—N1—C2525.1 (3)C26A—C27A—C28A—C29A1 (2)
S2—Pb1—N1—C25116.7 (3)C27A—C28A—C29A—C30A2.1 (19)
N2A—Pb1—N1—C2158 (2)C28A—C29A—C30A—N2A3 (2)
N2—Pb1—N1—C2131.1 (10)C26A—N2A—C30A—C29A11 (2)
S3—Pb1—N1—C2184.2 (3)Pb1—N2A—C30A—C29A164.6 (9)
S1—Pb1—N1—C212.7 (3)P2—O3—C31—C32104.4 (4)
S4—Pb1—N1—C21153.7 (3)P2—O3—C31—C3678.1 (4)
S2—Pb1—N1—C2164.5 (3)C36—C31—C32—C330.2 (6)
P1—O1—C1—C6112.6 (3)O3—C31—C32—C33177.3 (3)
P1—O1—C1—C273.9 (4)C31—C32—C33—C340.2 (6)
C6—C1—C2—C30.9 (6)C32—C33—C34—C350.4 (6)
O1—C1—C2—C3174.3 (4)C32—C33—C34—C37178.9 (4)
C1—C2—C3—C41.3 (7)C33—C34—C35—C360.3 (7)
C2—C3—C4—C50.4 (7)C37—C34—C35—C36178.8 (4)
C2—C3—C4—C7178.7 (4)C32—C31—C36—C350.3 (6)
C3—C4—C5—C60.9 (6)O3—C31—C36—C35177.1 (4)
C7—C4—C5—C6180.0 (4)C34—C35—C36—C310.0 (7)
C2—C1—C6—C50.4 (6)C35—C34—C37—C38176.2 (4)
O1—C1—C6—C5173.1 (3)C33—C34—C37—C385.5 (5)
C4—C5—C6—C11.3 (6)C35—C34—C37—C4063.1 (5)
C5—C4—C7—C10114.9 (5)C33—C34—C37—C40115.3 (4)
C3—C4—C7—C1066.1 (5)C35—C34—C37—C3956.1 (5)
C5—C4—C7—C10A173 (3)C33—C34—C37—C39125.5 (4)
C3—C4—C7—C10A8 (3)P2—O4—C41—C4697.9 (3)
C5—C4—C7—C8126.8 (5)P2—O4—C41—C4286.4 (4)
C3—C4—C7—C852.3 (6)C46—C41—C42—C430.7 (6)
C5—C4—C7—C9A36 (3)O4—C41—C42—C43175.0 (3)
C3—C4—C7—C9A145 (3)C41—C42—C43—C440.2 (6)
C5—C4—C7—C95.0 (6)C42—C43—C44—C450.9 (6)
C3—C4—C7—C9174.0 (5)C42—C43—C44—C47177.2 (4)
C5—C4—C7—C8A71 (3)C43—C44—C45—C460.7 (5)
C3—C4—C7—C8A108 (3)C47—C44—C45—C46177.4 (3)
P1—O2—C11—C16140.5 (3)C42—C41—C46—C450.8 (5)
P1—O2—C11—C1241.8 (4)O4—C41—C46—C45174.9 (3)
C16—C11—C12—C131.5 (5)C44—C45—C46—C410.1 (5)
O2—C11—C12—C13176.1 (3)C45—C44—C47—C5066.9 (5)
C11—C12—C13—C140.2 (6)C43—C44—C47—C50111.1 (5)
C12—C13—C14—C151.6 (6)C45—C44—C47—C49171.8 (4)
C12—C13—C14—C17176.7 (4)C43—C44—C47—C4910.2 (6)
C13—C14—C15—C161.3 (5)C45—C44—C47—C4853.3 (5)
C17—C14—C15—C16177.0 (3)C43—C44—C47—C48128.8 (4)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C12—H12···O10.952.453.083 (5)124
Selected bond lengths (Å) top
Pb1—N12.711 (3)Pb1—S12.9009 (9)
Pb1—N22.732 (18)Pb1—S43.0577 (9)
Pb1—S32.8090 (9)Pb1—S23.0742 (9)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C12—H12···O10.952.453.083 (5)124
 

Acknowledgements

The authors acknowledge financial assistance from Sichuan University of Science and Engineering, the Institute of Functionalized Materials (grant No. 2009xjkPL004) and the Education Committee of Sichuan Province (No. 13ZB0134)

References

First citationBondi, A. (1964). J. Phys. Chem. 68, 441–451.  CrossRef CAS Web of Science
First citationBruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
First citationLi, J.-S. & Xie, B. (1997). Acta Chim. Sin. 55, 892–896.  CAS
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals

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