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Figure 2
The phase diagram of thiourea. Phase transitions were first reported by Bridgman (1938BB6) (V → VI), Goldsmith & White (1959BB16) (I → II, II → III, III → IV and IV → V), Moudden et al. (1979BB26) (phase II′′) and Banerji & Deb (2007BB2) (VI → VII, VII → VIII and VIII → IX). Phase boundaries were investigated by Klimowski et al. (1976BB20) and Benoit et al. (1983BB4). Phase V crystallizes in Pnma (Wyckoff & Corey, 1932BB39) and phase I in Pmc21 (Goldsmith & White, 1959BB16).

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