Octa­hedral–tetra­hedral framework structures of InAsO4·H2O and PbIn(AsO4)(AsO3OH)

Kolitsch, U.; Schwendtner, K.

doi:10.1107/S0108270105022894

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 3
A view of PbIn(AsO₄)(AsO₃OH) along [100]. AsO₄ and AsO₃OH tetrahedra are corner-linked to InO₆ octahedra. Voids in the resulting octahedral–tetrahedral framework are occupied by Pb₂O₁₀(OH)₂ dimers, which are built of two edge-sharing highly distorted PbO₆(OH) polyhedra [Pb⋯Pb = 4.069 (1) Å]. The unit cell is outlined.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 61| Part 9| August 2005| Pages i86-i89

doi:10.1107/S0108270105022894

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