Extensive hydrogen and halogen bonding, and absence of intra­molecular hydrogen bonding between alcohol and nitro groups in a series of endo-nitro­norbornanol compounds

Lemmerer, A.; Michael, J.P.

doi:10.1107/S0108270111024140

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 6
The C(7) hydrogen-bonded chain of (V)

. Note how the halogen bonding connects every second molecule involved in hydrogen-bonded interactions within the chain (by translation only). Only the hydrogen bonding of molecule A is shown. Molecule B has similar interactions but is not shown in the figure. Atoms marked with the superscripts `i' and `ii' are at the symmetry positions (−x + 1, y + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ) and (x, y + 1, z), respectively. H atoms not involved in hydrogen-bonding interactions have been omitted for clarity.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 67| Part 8| July 2011| Pages o288-o293

doi:10.1107/S0108270111024140

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