Single-crystal structure determination of two new ternary bis­muthides: Rh6Mn5Bi18 and RhMnBi3

Kainzbauer, P.; Richter, K.W.; Effenberger, H.S.; Marker, M.C.J.; Ipser, H.

doi:10.1107/S2053229618009087

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
A schematic representation of the distinct atomic coordination spheres in the Rh₆Mn₅Bi₁₈ structure. All neighbours within 3.2 Å are shown. (a) The bicapped square prism around the Mn1 atom [CN (coordination number) = 10]. (b) The distorted cuboctahedron around the Mn2 atom (CN = 12). (c) The distorted cuboctahedron around the Mn3 atom (CN = 12). (d) The tricapped trigonal prism (alternatively monocapped tetragonal antiprism) around the Rh1 atom (CN = 9). (e) The capped square antiprism (alternatively tricapped trigonal prism) around the Rh2 atom (CN = 9). The colour coding is as in Fig. 1

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 74| Part 7| July 2018| Pages 863-869

https://doi.org/10.1107/S2053229618009087

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