Figure 5
The conformational flexibility of the title compounds and the CSD structures. (a) The CSD structures corresponding to compounds (I) and (II) are shown along with (I) and (II) , which are coloured as in Fig. 4 . (b) Superposition of the CSD structures, which belong to the −ap and −ap conformations, along with compound (I) , with slightly deviating structures marked. (c) Representative structures that adopt ±ap conformations in comparison with compound (I) . (d) Superposition of the CSD structures which belong to the +sc and ±ap conformations, along with compound (II) . For clarity, the P(O)(OPh)2N skeletons of the CSD structures have been retained and other substitutions have been removed for most of the structures. |