Formation of extended polyiodides at large cation templates

Blake, A.J.; Castellano, C.; Lippolis, V.; Podda, E.; Schröder, M.

doi:10.1107/S2053229624004194

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
View of a chain of interacting [Pd₂I₂([18]aneN₂S₄)]²⁺ dications found in the crystal structure of (I)

. The dications are arranged into chains via I⋯I interactions of 3.545 (2) Å running along the b axis. [Symmetry codes: (i) −x + $[{3\over 2}]$ , −y + $[{1\over 2}]$ , −z + 1; (ii) −x + $[{3\over 2}]$ , −y − $[{1\over 2}]$ , −z + 1.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 80| Part 7| July 2024| Pages 311-318

https://doi.org/10.1107/S2053229624004194

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