Figure 17
The molecular structures of (a) F5PhS-BsubPc molecule A (14-A) and (b) F5PhS-BsubPc molecule B (14-B), with displacement ellipsoids drawn at the 50% probability level and H atoms removed for clarity. (c) The unit-cell packing and (d) significant intermolecular interactions in the crystal structure of 14. π–π interactions are shown in blue, weak hydrogen bonds are shown in red and all other intermolecular interactions are shown in green. Atom colours: carbon – gray, hydrogen – white, nitrogen – blue, boron – light pink, sulfur – orange and fluorine – green. |