Solvent-free thallium(I) tetra­kis­[3,5-bis­(tri­fluoro­meth­yl)phen­yl]borate: crystal structure, supra­molecular inter­actions and anisotropic thermal expansion

Stephan, J.; Schröck, L.; Petersen, E.E.; Ettlinger, R.L.; Pöthig, A.

doi:10.1107/S2053229626008454

Figure 5
(a) Packing diagram of Tl(BAr^F), viewed along the a axis, showing a zigzag alignment of Tl atoms. (b) The expanded unit cell exhibits a virtually cubic arrangement of eight BAr^F anions around the central Tl atom. Tl atoms, as well as B atoms and short-contact F atoms in part (b), are displayed as displacement ellipsoids at the 50% probability level; the remaining atoms are displayed in wireframe mode.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 82| Part 10| October 2026|

https://doi.org/10.1107/S2053229626008454

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