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Figure 1 (a) Three dimensional crystal structure of Mn[Fe(CN)6]2/3·5H2O, showing the distribution of zeolitic water molecules (teal spheres). The –Mn–NC–Fe– framework is described in stick form for clarity. Blue, red, dark gray, light gray and teal represent Fe, Mn, C, N and O atoms, respectively. (b) Projection of the structure in the ab plane. The value g is the occupancy for each atom. [Symmetry codes: (i) − z, − x, 1 − y; (ii) z, −x, 1 − y; (iii) z, −y, x; (iv) z, − x, + y.] |