[1,2-Bis(diphenyl­phosphino)ethane]{2-[bis­(diphenyl­phosphinometh­yl)amino]pyridinium}fluoridohydrazidato­molybdenum(IV) bis­(tetra­fluoridoborate)

Stephan, G.; Näther, C.; Tuczek, F.

doi:10.1107/S1600536808008635

metal-organic compounds

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ISSN: 2056-9890

Volume 64| Part 5| May 2008| Page m629

doi:10.1107/S1600536808008635

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[1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate)

Gerald Stephan,^a Christian Näther ^a and Felix Tuczek ^a ^*

^aInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany
^*Correspondence e-mail: cnaether@ac.uni-kiel.de

(Received 19 March 2008; accepted 31 March 2008; online 10 April 2008)

In the crystal structure of the title compound, [MoF(N₂H₂)(C₃₁H₂₉N₂P₂)(C₂₆H₂₄P₂)](BF₄)₂, each Mo atom is surrounded by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one 2-[bis(diphenylphosphinomethyl)amino]pyridinium ligand. The remaining binding sites of the distorted octahedron are occupied by a hydrazidate (NNH₂²⁻) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

Related literature

For related literature, see: Hidai et al. (1976 ); Stephan et al. (2008 ).

Experimental

Crystal data

[MoF(N₂H₂)(C₃₁H₂₉N₂P₂)(C₂₆H₂₄P₂)](BF₄)₂
M_r = 1208.49
Monoclinic, P 2₁ /n
a = 12.5791 (6) Å
b = 31.2199 (16) Å
c = 13.8330 (9) Å
β = 94.438 (7)°
V = 5416.2 (5) Å³
Z = 4
Mo Kα radiation
μ = 0.43 mm⁻¹
T = 170 (2) K
0.2 × 0.08 × 0.06 mm

Data collection

Stoe IPDS-1 diffractometer
Absorption correction: numerical (X-SHAPE; Stoe & Cie, 1998a ) T_min = 0.949, T_max = 0.969
24176 measured reflections
8538 independent reflections
6783 reflections with I > 2σ(I)
R_int = 0.032
θ_max = 24.1°

Refinement

R[F² > 2σ(F²)] = 0.039
wR(F²) = 0.108
S = 1.02
8538 reflections
706 parameters
39 restraints
H-atom parameters constrained
Δρ_max = 0.94 e Å⁻³
Δρ_min = −0.54 e Å⁻³

Table 1
Selected geometric parameters (Å, °)

Mo1—N1	1.755 (3)
Mo1—F1	1.9889 (18)
Mo1—P1	2.5032 (9)
Mo1—P2	2.5353 (9)
Mo1—P3	2.5698 (8)
Mo1—P4	2.5754 (9)

N1—Mo1—F1	178.70 (11)
N1—Mo1—P1	86.88 (10)
F1—Mo1—P1	91.94 (6)
N1—Mo1—P2	86.22 (9)
F1—Mo1—P2	94.33 (6)
P1—Mo1—P2	89.65 (3)
N1—Mo1—P3	94.46 (9)
F1—Mo1—P3	85.10 (5)
P1—Mo1—P3	95.38 (3)
P2—Mo1—P3	174.95 (3)
N1—Mo1—P4	101.62 (10)
F1—Mo1—P4	79.52 (6)
P1—Mo1—P4	170.35 (3)
P2—Mo1—P4	95.42 (3)
P3—Mo1—P4	79.53 (3)
N2—N1—Mo1	177.1 (3)

Data collection: IPDS Program package (Stoe & Cie, 1998b ); cell refinement: IPDS Program package; data reduction: IPDS Program package; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 1999 ); software used to prepare material for publication: CIFTAB in SHELXTL (Sheldrick, 2008).

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808008635/bt2688sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536808008635/bt2688Isup2.hkl

checkCIF report

Comment top

The structure determination of this compound was undertaken as part of a project on nitrogen fixation on molybdenum(0) centers with PNP co-ligands. The compound was synthesized by protonation of the Mo(0) complex [Mo(N₂)₂(dppe)(pyNP₂)] (Stephan et al., 2008) with HBF₄.Et₂O in analogy to the known procedure (Hidai et al., 1976). Beside the double protonation of one dinitrogen ligand the complex is secondary protonated at the pyridine N atom of the pyNP₂ ligand. The second N₂ ligand is exchanged against a fluoride ligand during the protonation.

The crystal structure of the title compound consists of discrete [Mo(F)(NNH₂)(P₂C₂₆H₂₄)(P₂C₃₁H₂₉N₂)]²⁺ cations and tetrafluoroborate anions. Each molybdenum atom is coordinated by four P atoms of one 1,2-bis(diphenylphosphino)ethane and one N,N-bis(diphenylphosphinomethyl)-2-aminopyridinium ligand, one N atom a hydrazido ligand and a fluoro ligand within a distorted octahetral geometry. The bite angles of the phosphine ligands are 79.53 (2)° for the dppe ligand and 89.66 (2)° for the pyHNP₂ ligand. The Mo—N distance is 1.755 (2)Å and the N—N distance is 1.326 (4) Å.

Related literature top

For related literature, see: Hidai et al. (1976); Stephan et al. (2008).

Experimental top

Under an inert gas atmosphere 0.115 ml HBF₄*Et₂O were added to 300 mg of [Mo(N₂)₂(dppe)(pyNP₂)] in 8 ml Dichloromethane at -15°C. The brown solution was stirred for 15 min and 15 ml of n-Hexane were added. The brown solid was filtered off, washed four times with diethylether and dried under vacuum. Yield: 270 mg (82%). Single crystals were obtained by diffusion of diethylether into a methanolic solution of the complex over a period of one week. ³¹P NMR (CD₂Cl₂, 20°C): 43.5 (2 P, dppe), 16.9 (2 P, pyHNP₂), ²J_PP,_trans= 132.0 Hz (P1—P4, P2—P4), ²J_PP,_cis= -26.5 Hz (P2—P3, P1—P4), ²J_PP,_cis= -33.0 Hz (P1—P2), ²J_PP,_cis= 3.0 Hz (P3—P4), ²J_PF,_cis= -31.0 Hz. ¹⁹F NMR (CD₂Cl₂, 20°C) 148.1 (Mo—F), q, 31 Hz), 149.5 (BF₄^-, s)

Computing details top

Data collection: IPDS program package (Stoe & Cie, 1998b); cell refinement: IPDS program package; data reduction: IPDS program package; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: CIFTAB in SHELXTL (Sheldrick, 2008).

Figures top

Fig. 1. : Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. The H atoms are omitted for clarity.

[1,2-Bis(diphenylphosphino)ethane]{2- [bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) top

Crystal data top

[MoF(N₂H₂)(C₃₁H₂₉N₂P₂)(C₂₆H₂₄P₂)](BF₄)₂	F(000) = 2472
M_r = 1208.49	D_x = 1.482 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
a = 12.5791 (6) Å	Cell parameters from 8000 reflections
b = 31.2199 (16) Å	θ = 10–22°
c = 13.8330 (9) Å	µ = 0.44 mm⁻¹
β = 94.438 (7)°	T = 170 K
V = 5416.2 (5) Å³	Needle, colourless
Z = 4	0.2 × 0.08 × 0.06 mm

Data collection top

Stoe IPDS-1 diffractometer	8538 independent reflections
Radiation source: fine-focus sealed tube	6783 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.032
ϕ scans	θ_max = 24.1°, θ_min = 1.8°
Absorption correction: numerical (X-SHAPE; Stoe & Cie, 1998a)	h = −14→14
T_min = 0.949, T_max = 0.969	k = −35→35
24176 measured reflections	l = −15→15

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.039	H-atom parameters constrained
wR(F²) = 0.108	w = 1/[σ²(F_o²) + (0.0748P)²] where P = (F_o² + 2F_c²)/3
S = 1.02	(Δ/σ)_max = 0.001
8538 reflections	Δρ_max = 0.94 e Å⁻³
706 parameters	Δρ_min = −0.54 e Å⁻³
39 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0045 (4)

Crystal data top

[MoF(N₂H₂)(C₃₁H₂₉N₂P₂)(C₂₆H₂₄P₂)](BF₄)₂	V = 5416.2 (5) Å³
M_r = 1208.49	Z = 4
Monoclinic, P2₁/n	Mo Kα radiation
a = 12.5791 (6) Å	µ = 0.44 mm⁻¹
b = 31.2199 (16) Å	T = 170 K
c = 13.8330 (9) Å	0.2 × 0.08 × 0.06 mm
β = 94.438 (7)°

Data collection top

Stoe IPDS-1 diffractometer	8538 independent reflections
Absorption correction: numerical (X-SHAPE; Stoe & Cie, 1998a)	6783 reflections with I > 2σ(I)
T_min = 0.949, T_max = 0.969	R_int = 0.032
24176 measured reflections	θ_max = 24.1°

Refinement top

R[F² > 2σ(F²)] = 0.039	39 restraints
wR(F²) = 0.108	H-atom parameters constrained
S = 1.02	Δρ_max = 0.94 e Å⁻³
8538 reflections	Δρ_min = −0.54 e Å⁻³
706 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Mo1	0.10191 (2)	0.148150 (8)	0.284941 (19)	0.01774 (12)
F1	0.20855 (15)	0.17169 (6)	0.20023 (13)	0.0234 (4)
N1	0.0094 (2)	0.12792 (9)	0.3620 (2)	0.0251 (6)
N2	−0.0567 (5)	0.11290 (17)	0.4239 (3)	0.094 (2)
H1N2	−0.0661	0.1300	0.4759	0.13 (3)*
H2N2	−0.0890	0.0868	0.4206	0.11 (2)*
C1	0.2510 (3)	0.09669 (10)	0.4909 (2)	0.0232 (7)
H1A	0.3011	0.0995	0.5493	0.028*
H1B	0.1817	0.0866	0.5117	0.028*
N3	0.2925 (2)	0.06529 (8)	0.4248 (2)	0.0250 (6)
C2	0.2109 (3)	0.04163 (10)	0.3656 (2)	0.0261 (8)
H2A	0.1529	0.0339	0.4068	0.031*
H2B	0.2427	0.0146	0.3440	0.031*
P1	0.23297 (7)	0.14991 (2)	0.43059 (6)	0.0184 (2)
P2	0.15116 (7)	0.07070 (3)	0.25607 (6)	0.0205 (2)
C11	0.1921 (3)	0.18206 (10)	0.5315 (2)	0.0205 (7)
C12	0.1252 (3)	0.16457 (12)	0.5967 (3)	0.0301 (8)
H12	0.1071	0.1351	0.5928	0.036*
C13	0.0849 (3)	0.19017 (13)	0.6676 (3)	0.0376 (10)
H13	0.0390	0.1780	0.7116	0.045*
C14	0.1109 (3)	0.23297 (12)	0.6747 (3)	0.0331 (9)
H14	0.0832	0.2502	0.7234	0.040*
C15	0.1775 (3)	0.25078 (11)	0.6104 (3)	0.0289 (8)
H15	0.1961	0.2802	0.6154	0.035*
C16	0.2171 (3)	0.22555 (11)	0.5385 (2)	0.0249 (7)
H16	0.2617	0.2380	0.4938	0.030*
C21	0.3723 (3)	0.16364 (10)	0.4168 (2)	0.0199 (7)
C22	0.4412 (3)	0.17702 (11)	0.4954 (3)	0.0282 (8)
H22	0.4140	0.1820	0.5566	0.034*
C23	0.5490 (3)	0.18301 (13)	0.4845 (3)	0.0391 (10)
H23	0.5953	0.1919	0.5383	0.047*
C24	0.5890 (3)	0.17612 (14)	0.3955 (3)	0.0431 (10)
H24	0.6627	0.1803	0.3879	0.052*
C25	0.5212 (3)	0.16314 (14)	0.3172 (3)	0.0387 (10)
H25	0.5489	0.1584	0.2562	0.046*
C26	0.4132 (3)	0.15695 (11)	0.3272 (2)	0.0279 (8)
H26	0.3674	0.1482	0.2730	0.034*
C31	0.3978 (3)	0.05601 (11)	0.4229 (3)	0.0275 (8)
N4	0.4696 (3)	0.07235 (9)	0.4921 (2)	0.0323 (7)
H4	0.4453	0.0885	0.5377	0.039*
C32	0.5761 (3)	0.06524 (14)	0.4949 (3)	0.0443 (10)
H32	0.6221	0.0780	0.5445	0.053*
C33	0.6175 (4)	0.04001 (15)	0.4273 (4)	0.0520 (12)
H33	0.6920	0.0348	0.4287	0.062*
C34	0.5476 (4)	0.02198 (13)	0.3558 (3)	0.0477 (11)
H34	0.5751	0.0041	0.3081	0.057*
C35	0.4399 (3)	0.02946 (12)	0.3524 (3)	0.0382 (9)
H35	0.3937	0.0168	0.3028	0.046*
C41	0.2374 (3)	0.05482 (11)	0.1619 (2)	0.0248 (7)
C42	0.2806 (3)	0.08551 (12)	0.1042 (3)	0.0279 (8)
H42	0.2661	0.1150	0.1141	0.034*
C43	0.3453 (3)	0.07327 (13)	0.0314 (3)	0.0348 (9)
H43	0.3731	0.0944	−0.0091	0.042*
C44	0.3689 (3)	0.03079 (14)	0.0183 (3)	0.0385 (10)
H44	0.4139	0.0227	−0.0307	0.046*
C45	0.3275 (3)	−0.00026 (13)	0.0759 (3)	0.0392 (10)
H45	0.3447	−0.0296	0.0670	0.047*
C46	0.2603 (3)	0.01148 (12)	0.1473 (3)	0.0337 (9)
H46	0.2303	−0.0099	0.1858	0.040*
C51	0.0310 (3)	0.03842 (10)	0.2289 (2)	0.0242 (7)
C52	−0.0067 (3)	0.03302 (11)	0.1324 (3)	0.0304 (8)
H52	0.0346	0.0432	0.0825	0.037*
C53	−0.1037 (3)	0.01295 (13)	0.1077 (3)	0.0388 (9)
H53	−0.1286	0.0098	0.0415	0.047*
C54	−0.1641 (3)	−0.00240 (12)	0.1797 (3)	0.0391 (10)
H54	−0.2308	−0.0158	0.1631	0.047*
C55	−0.1271 (3)	0.00183 (13)	0.2755 (3)	0.0382 (9)
H55	−0.1678	−0.0093	0.3249	0.046*
C56	−0.0302 (3)	0.02239 (12)	0.3006 (3)	0.0337 (9)
H56	−0.0058	0.0255	0.3670	0.040*
C61	−0.0634 (3)	0.23553 (11)	0.2013 (2)	0.0263 (8)
H61A	−0.1315	0.2229	0.2191	0.032*
H61B	−0.0743	0.2667	0.1916	0.032*
C62	−0.0315 (3)	0.21521 (11)	0.1075 (2)	0.0260 (8)
H62A	0.0361	0.2280	0.0892	0.031*
H62B	−0.0872	0.2208	0.0545	0.031*
P3	0.04148 (7)	0.22633 (3)	0.30016 (6)	0.0194 (2)
P4	−0.01447 (7)	0.15685 (3)	0.12462 (6)	0.0210 (2)
C71	0.1408 (3)	0.26775 (10)	0.2819 (2)	0.0219 (7)
C72	0.2489 (3)	0.25795 (11)	0.2986 (2)	0.0240 (7)
H72	0.2701	0.2295	0.3154	0.029*
C73	0.3259 (3)	0.28937 (11)	0.2910 (3)	0.0297 (8)
H73	0.3991	0.2824	0.3038	0.036*
C74	0.2969 (3)	0.33074 (12)	0.2649 (3)	0.0334 (9)
H74	0.3498	0.3521	0.2592	0.040*
C75	0.1905 (3)	0.34069 (11)	0.2474 (3)	0.0337 (9)
H75	0.1704	0.3691	0.2296	0.040*
C76	0.1119 (3)	0.30973 (11)	0.2552 (3)	0.0288 (8)
H76	0.0388	0.3171	0.2425	0.035*
C81	−0.0282 (3)	0.24415 (11)	0.4045 (2)	0.0238 (7)
C82	−0.0130 (3)	0.28421 (12)	0.4469 (3)	0.0380 (9)
H82	0.0382	0.3033	0.4238	0.046*
C83	−0.0724 (4)	0.29663 (14)	0.5233 (3)	0.0476 (11)
H83	−0.0632	0.3245	0.5501	0.057*
C84	−0.1438 (3)	0.26910 (15)	0.5600 (3)	0.0453 (11)
H84	−0.1829	0.2776	0.6129	0.054*
C85	−0.1585 (4)	0.22907 (16)	0.5197 (3)	0.0510 (12)
H85	−0.2075	0.2097	0.5453	0.061*
C86	−0.1020 (3)	0.21664 (14)	0.4415 (3)	0.0441 (11)
H86	−0.1140	0.1892	0.4133	0.053*
C91	−0.1518 (3)	0.13741 (11)	0.1137 (3)	0.0252 (8)
C92	−0.1915 (3)	0.11545 (12)	0.1905 (3)	0.0342 (9)
H92	−0.1479	0.1114	0.2490	0.041*
C93	−0.2950 (3)	0.09930 (14)	0.1819 (3)	0.0464 (11)
H93	−0.3218	0.0846	0.2350	0.056*
C94	−0.3590 (3)	0.10451 (14)	0.0970 (4)	0.0488 (12)
H94	−0.4291	0.0930	0.0913	0.059*
C95	−0.3208 (3)	0.12639 (13)	0.0209 (3)	0.0428 (10)
H95	−0.3649	0.1301	−0.0374	0.051*
C96	−0.2178 (3)	0.14327 (12)	0.0284 (3)	0.0323 (9)
H96	−0.1925	0.1588	−0.0243	0.039*
C101	0.0390 (3)	0.14118 (11)	0.0102 (2)	0.0259 (8)
C102	−0.0050 (3)	0.10789 (12)	−0.0474 (2)	0.0315 (8)
H102	−0.0669	0.0935	−0.0293	0.038*
C103	0.0417 (4)	0.09577 (13)	−0.1312 (3)	0.0426 (10)
H103	0.0106	0.0735	−0.1707	0.051*
C104	0.1324 (4)	0.11582 (15)	−0.1572 (3)	0.0486 (12)
H104	0.1652	0.1068	−0.2133	0.058*
C105	0.1758 (4)	0.14918 (15)	−0.1015 (3)	0.0462 (11)
H105	0.2377	0.1634	−0.1205	0.055*
C106	0.1299 (3)	0.16213 (13)	−0.0178 (3)	0.0348 (9)
H106	0.1602	0.1851	0.0200	0.042*
B1	0.8583 (5)	0.07358 (16)	0.6061 (4)	0.0541 (15)
F11	0.8620 (2)	0.04255 (7)	0.53264 (17)	0.0507 (6)
F12	0.8016 (3)	0.10857 (9)	0.5658 (2)	0.0746 (9)
F13	0.9582 (3)	0.08731 (11)	0.6351 (2)	0.0925 (12)
F14	0.8083 (4)	0.05738 (10)	0.6817 (2)	0.1209 (19)
B2	0.4315 (4)	0.09191 (16)	0.7490 (3)	0.0497 (14)
F21	0.3459 (3)	0.06624 (9)	0.7323 (3)	0.0867 (12)
F22	0.4582 (3)	0.11052 (11)	0.66855 (19)	0.0921 (13)
F23	0.4439 (5)	0.11424 (17)	0.8310 (3)	0.099 (3)	0.737 (9)
F24	0.5265 (4)	0.06407 (15)	0.7551 (6)	0.127 (3)	0.737 (9)
F23'	0.3739 (10)	0.1356 (3)	0.7658 (10)	0.080 (5)*	0.263 (9)
F24'	0.4862 (11)	0.0855 (5)	0.8262 (9)	0.104 (6)*	0.263 (9)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Mo1	0.02013 (18)	0.01895 (17)	0.01402 (17)	−0.00276 (11)	0.00048 (11)	0.00024 (10)
F1	0.0252 (11)	0.0248 (9)	0.0203 (10)	−0.0029 (8)	0.0036 (8)	0.0021 (7)
N1	0.0319 (17)	0.0252 (14)	0.0188 (14)	−0.0091 (13)	0.0066 (12)	−0.0024 (11)
N2	0.137 (5)	0.091 (4)	0.063 (3)	−0.066 (3)	0.062 (3)	−0.020 (3)
C1	0.027 (2)	0.0224 (17)	0.0201 (17)	−0.0012 (14)	0.0023 (14)	0.0033 (13)
N3	0.0283 (18)	0.0211 (14)	0.0250 (16)	−0.0007 (12)	−0.0015 (12)	−0.0007 (11)
C2	0.031 (2)	0.0235 (16)	0.0233 (18)	−0.0019 (15)	−0.0013 (15)	0.0011 (14)
P1	0.0201 (5)	0.0209 (4)	0.0141 (4)	−0.0019 (3)	0.0004 (3)	0.0007 (3)
P2	0.0250 (5)	0.0196 (4)	0.0169 (4)	−0.0027 (3)	0.0016 (3)	−0.0010 (3)
C11	0.0166 (17)	0.0289 (17)	0.0155 (16)	0.0003 (14)	−0.0027 (13)	−0.0003 (13)
C12	0.030 (2)	0.0307 (18)	0.030 (2)	0.0013 (16)	0.0106 (16)	0.0008 (15)
C13	0.039 (2)	0.045 (2)	0.031 (2)	0.0063 (18)	0.0168 (18)	0.0038 (17)
C14	0.035 (2)	0.036 (2)	0.029 (2)	0.0121 (17)	0.0058 (17)	−0.0061 (16)
C15	0.029 (2)	0.0280 (18)	0.029 (2)	0.0034 (15)	−0.0028 (16)	−0.0059 (15)
C16	0.0246 (19)	0.0280 (18)	0.0220 (18)	−0.0012 (14)	0.0016 (14)	−0.0010 (14)
C21	0.0189 (18)	0.0209 (15)	0.0200 (17)	0.0010 (13)	0.0009 (13)	0.0017 (13)
C22	0.024 (2)	0.0356 (19)	0.0248 (19)	−0.0012 (15)	0.0017 (15)	−0.0049 (15)
C23	0.025 (2)	0.050 (2)	0.041 (2)	−0.0065 (18)	−0.0040 (17)	−0.0108 (19)
C24	0.025 (2)	0.061 (3)	0.045 (3)	−0.0055 (19)	0.0092 (19)	−0.004 (2)
C25	0.031 (2)	0.056 (2)	0.030 (2)	0.0044 (19)	0.0115 (18)	−0.0018 (18)
C26	0.027 (2)	0.037 (2)	0.0198 (18)	0.0027 (16)	0.0016 (15)	0.0005 (15)
C31	0.031 (2)	0.0244 (17)	0.0263 (19)	0.0024 (15)	−0.0007 (15)	0.0067 (14)
N4	0.0311 (19)	0.0309 (16)	0.0340 (18)	0.0045 (14)	−0.0024 (14)	0.0025 (13)
C32	0.032 (2)	0.047 (2)	0.052 (3)	0.0032 (19)	−0.008 (2)	0.012 (2)
C33	0.035 (3)	0.055 (3)	0.067 (3)	0.011 (2)	0.005 (2)	0.010 (2)
C34	0.051 (3)	0.039 (2)	0.055 (3)	0.014 (2)	0.015 (2)	0.001 (2)
C35	0.044 (3)	0.035 (2)	0.036 (2)	0.0047 (18)	0.0039 (18)	−0.0032 (17)
C41	0.0238 (19)	0.0290 (17)	0.0211 (17)	0.0008 (14)	−0.0021 (14)	−0.0029 (14)
C42	0.024 (2)	0.0333 (19)	0.0266 (19)	0.0006 (15)	0.0009 (15)	0.0007 (15)
C43	0.027 (2)	0.050 (2)	0.028 (2)	−0.0006 (18)	0.0044 (16)	−0.0005 (17)
C44	0.028 (2)	0.060 (3)	0.028 (2)	0.0065 (19)	0.0032 (16)	−0.0080 (19)
C45	0.041 (3)	0.040 (2)	0.037 (2)	0.0110 (18)	−0.0002 (18)	−0.0117 (18)
C46	0.042 (2)	0.0311 (19)	0.028 (2)	0.0027 (17)	0.0016 (17)	−0.0041 (16)
C51	0.027 (2)	0.0181 (16)	0.0275 (19)	−0.0019 (14)	0.0017 (15)	−0.0029 (13)
C52	0.028 (2)	0.0332 (19)	0.029 (2)	−0.0045 (16)	−0.0004 (16)	−0.0050 (15)
C53	0.035 (2)	0.043 (2)	0.037 (2)	−0.0061 (18)	−0.0040 (18)	−0.0131 (18)
C54	0.025 (2)	0.035 (2)	0.057 (3)	−0.0069 (17)	0.0002 (18)	−0.0109 (19)
C55	0.031 (2)	0.040 (2)	0.044 (2)	−0.0077 (18)	0.0096 (18)	0.0010 (18)
C56	0.034 (2)	0.037 (2)	0.031 (2)	−0.0071 (17)	0.0044 (17)	−0.0010 (16)
C61	0.026 (2)	0.0261 (17)	0.0256 (18)	0.0020 (15)	−0.0032 (15)	0.0012 (14)
C62	0.029 (2)	0.0288 (18)	0.0195 (18)	−0.0007 (15)	−0.0033 (15)	0.0051 (14)
P3	0.0191 (5)	0.0207 (4)	0.0184 (4)	−0.0002 (3)	0.0024 (3)	−0.0002 (3)
P4	0.0211 (5)	0.0264 (4)	0.0152 (4)	−0.0011 (4)	−0.0001 (3)	−0.0007 (3)
C71	0.0247 (19)	0.0226 (16)	0.0191 (17)	−0.0020 (14)	0.0055 (14)	−0.0007 (13)
C72	0.028 (2)	0.0237 (17)	0.0208 (17)	0.0033 (15)	0.0051 (14)	0.0025 (13)
C73	0.023 (2)	0.037 (2)	0.029 (2)	−0.0033 (16)	0.0066 (15)	0.0008 (16)
C74	0.037 (2)	0.033 (2)	0.031 (2)	−0.0112 (17)	0.0091 (17)	0.0015 (16)
C75	0.040 (2)	0.0245 (18)	0.037 (2)	−0.0011 (17)	0.0070 (18)	0.0071 (16)
C76	0.029 (2)	0.0268 (18)	0.0307 (19)	0.0021 (15)	0.0020 (16)	0.0048 (15)
C81	0.0196 (18)	0.0315 (18)	0.0201 (17)	0.0045 (14)	0.0007 (14)	−0.0002 (14)
C82	0.047 (3)	0.035 (2)	0.033 (2)	0.0011 (18)	0.0119 (19)	−0.0032 (17)
C83	0.064 (3)	0.045 (2)	0.035 (2)	0.016 (2)	0.012 (2)	−0.0095 (19)
C84	0.037 (3)	0.069 (3)	0.031 (2)	0.022 (2)	0.0100 (19)	0.001 (2)
C85	0.035 (3)	0.077 (3)	0.044 (3)	−0.010 (2)	0.020 (2)	−0.005 (2)
C86	0.039 (3)	0.052 (2)	0.045 (3)	−0.012 (2)	0.019 (2)	−0.012 (2)
C91	0.0223 (19)	0.0250 (17)	0.0282 (19)	0.0020 (14)	0.0001 (15)	−0.0078 (14)
C92	0.024 (2)	0.042 (2)	0.036 (2)	0.0008 (17)	0.0035 (16)	−0.0002 (17)
C93	0.031 (2)	0.052 (3)	0.058 (3)	−0.0053 (19)	0.015 (2)	0.005 (2)
C94	0.021 (2)	0.046 (2)	0.080 (4)	−0.0039 (18)	0.003 (2)	−0.011 (2)
C95	0.030 (2)	0.043 (2)	0.052 (3)	0.0058 (19)	−0.0138 (19)	−0.013 (2)
C96	0.030 (2)	0.034 (2)	0.032 (2)	0.0044 (16)	−0.0054 (16)	−0.0035 (16)
C101	0.0238 (19)	0.0367 (19)	0.0169 (17)	0.0055 (15)	0.0001 (14)	0.0027 (14)
C102	0.037 (2)	0.036 (2)	0.0211 (19)	0.0094 (17)	−0.0016 (16)	−0.0006 (15)
C103	0.057 (3)	0.044 (2)	0.027 (2)	0.017 (2)	−0.0007 (19)	−0.0054 (17)
C104	0.065 (3)	0.059 (3)	0.023 (2)	0.024 (2)	0.014 (2)	0.0039 (19)
C105	0.040 (3)	0.070 (3)	0.030 (2)	0.009 (2)	0.0145 (19)	0.015 (2)
C106	0.035 (2)	0.047 (2)	0.0225 (19)	0.0027 (18)	0.0051 (16)	0.0057 (16)
B1	0.090 (5)	0.032 (2)	0.042 (3)	−0.023 (3)	0.015 (3)	−0.006 (2)
F11	0.0766 (19)	0.0377 (12)	0.0389 (13)	−0.0116 (12)	0.0123 (13)	−0.0034 (10)
F12	0.093 (2)	0.0527 (17)	0.083 (2)	0.0031 (16)	0.0340 (19)	−0.0054 (15)
F13	0.112 (3)	0.089 (2)	0.070 (2)	−0.045 (2)	−0.037 (2)	0.0137 (18)
F14	0.247 (5)	0.0607 (19)	0.067 (2)	−0.070 (3)	0.088 (3)	−0.0181 (16)
B2	0.062 (4)	0.056 (3)	0.033 (3)	−0.027 (3)	0.016 (2)	−0.009 (2)
F21	0.071 (2)	0.0651 (18)	0.131 (3)	−0.0384 (16)	0.055 (2)	−0.0372 (19)
F22	0.133 (3)	0.111 (3)	0.0303 (15)	−0.076 (2)	−0.0069 (17)	0.0020 (15)
F23	0.175 (6)	0.090 (4)	0.041 (3)	−0.075 (4)	0.059 (3)	−0.037 (2)
F24	0.102 (5)	0.062 (3)	0.200 (7)	0.015 (3)	−0.088 (4)	−0.012 (4)

Geometric parameters (Å, º) top

Mo1—N1	1.755 (3)	C53—H53	0.9500
Mo1—F1	1.9889 (18)	C54—C55	1.377 (6)
Mo1—P1	2.5032 (9)	C54—H54	0.9500
Mo1—P2	2.5353 (9)	C55—C56	1.398 (6)
Mo1—P3	2.5698 (8)	C55—H55	0.9500
Mo1—P4	2.5754 (9)	C56—H56	0.9500
N1—N2	1.325 (5)	C61—C62	1.526 (5)
N2—H1N2	0.9101	C61—P3	1.848 (4)
N2—H2N2	0.9100	C61—H61A	0.9900
C1—N3	1.464 (4)	C61—H61B	0.9900
C1—P1	1.865 (3)	C62—P4	1.847 (3)
C1—H1A	0.9900	C62—H62A	0.9900
C1—H1B	0.9900	C62—H62B	0.9900
N3—C31	1.358 (5)	P3—C71	1.829 (3)
N3—C2	1.463 (4)	P3—C81	1.832 (3)
C2—P2	1.873 (3)	P4—C91	1.826 (4)
C2—H2A	0.9900	P4—C101	1.833 (3)
C2—H2B	0.9900	C71—C72	1.396 (5)
P1—C11	1.826 (3)	C71—C76	1.402 (5)
P1—C21	1.828 (3)	C72—C73	1.388 (5)
P2—C41	1.827 (3)	C72—H72	0.9500
P2—C51	1.831 (3)	C73—C74	1.382 (5)
C11—C12	1.392 (5)	C73—H73	0.9500
C11—C16	1.396 (5)	C74—C75	1.377 (6)
C12—C13	1.390 (5)	C74—H74	0.9500
C12—H12	0.9500	C75—C76	1.393 (5)
C13—C14	1.377 (6)	C75—H75	0.9500
C13—H13	0.9500	C76—H76	0.9500
C14—C15	1.384 (5)	C81—C82	1.388 (5)
C14—H14	0.9500	C81—C86	1.391 (5)
C15—C16	1.391 (5)	C82—C83	1.395 (6)
C15—H15	0.9500	C82—H82	0.9500
C16—H16	0.9500	C83—C84	1.369 (6)
C21—C26	1.395 (5)	C83—H83	0.9500
C21—C22	1.401 (5)	C84—C85	1.375 (7)
C22—C23	1.388 (5)	C84—H84	0.9500
C22—H22	0.9500	C85—C86	1.394 (6)
C23—C24	1.383 (6)	C85—H85	0.9500
C23—H23	0.9500	C86—H86	0.9500
C24—C25	1.385 (6)	C91—C92	1.389 (5)
C24—H24	0.9500	C91—C96	1.401 (5)
C25—C26	1.389 (5)	C92—C93	1.393 (6)
C25—H25	0.9500	C92—H92	0.9500
C26—H26	0.9500	C93—C94	1.382 (7)
C31—N4	1.363 (5)	C93—H93	0.9500
C31—C35	1.413 (5)	C94—C95	1.372 (7)
N4—C32	1.356 (5)	C94—H94	0.9500
N4—H4	0.8800	C95—C96	1.395 (6)
C32—C33	1.357 (6)	C95—H95	0.9500
C32—H32	0.9500	C96—H96	0.9500
C33—C34	1.391 (7)	C101—C106	1.397 (5)
C33—H33	0.9500	C101—C102	1.398 (5)
C34—C35	1.372 (6)	C102—C103	1.392 (5)
C34—H34	0.9500	C102—H102	0.9500
C35—H35	0.9500	C103—C104	1.374 (7)
C41—C42	1.385 (5)	C103—H103	0.9500
C41—C46	1.401 (5)	C104—C105	1.383 (7)
C42—C43	1.396 (5)	C104—H104	0.9500
C42—H42	0.9500	C105—C106	1.393 (6)
C43—C44	1.374 (6)	C105—H105	0.9500
C43—H43	0.9500	C106—H106	0.9500
C44—C45	1.383 (6)	B1—F14	1.358 (6)
C44—H44	0.9500	B1—F13	1.359 (7)
C45—C46	1.397 (5)	B1—F12	1.397 (7)
C45—H45	0.9500	B1—F11	1.407 (6)
C46—H46	0.9500	B2—F24'	1.241 (10)
C51—C52	1.393 (5)	B2—F22	1.322 (5)
C51—C56	1.394 (5)	B2—F23	1.330 (6)
C52—C53	1.391 (5)	B2—F21	1.348 (5)
C52—H52	0.9500	B2—F24	1.475 (7)
C53—C54	1.384 (6)	B2—F23'	1.570 (10)

N1—Mo1—F1	178.70 (11)	C55—C54—C53	119.8 (4)
N1—Mo1—P1	86.88 (10)	C55—C54—H54	120.1
F1—Mo1—P1	91.94 (6)	C53—C54—H54	120.1
N1—Mo1—P2	86.22 (9)	C54—C55—C56	120.4 (4)
F1—Mo1—P2	94.33 (6)	C54—C55—H55	119.8
P1—Mo1—P2	89.65 (3)	C56—C55—H55	119.8
N1—Mo1—P3	94.46 (9)	C51—C56—C55	120.5 (4)
F1—Mo1—P3	85.10 (5)	C51—C56—H56	119.8
P1—Mo1—P3	95.38 (3)	C55—C56—H56	119.8
P2—Mo1—P3	174.95 (3)	C62—C61—P3	110.1 (2)
N1—Mo1—P4	101.62 (10)	C62—C61—H61A	109.6
F1—Mo1—P4	79.52 (6)	P3—C61—H61A	109.6
P1—Mo1—P4	170.35 (3)	C62—C61—H61B	109.6
P2—Mo1—P4	95.42 (3)	P3—C61—H61B	109.6
P3—Mo1—P4	79.53 (3)	H61A—C61—H61B	108.1
N2—N1—Mo1	177.1 (3)	C61—C62—P4	109.7 (2)
N1—N2—H1N2	115.4	C61—C62—H62A	109.7
N1—N2—H2N2	125.8	P4—C62—H62A	109.7
H1N2—N2—H2N2	118.7	C61—C62—H62B	109.7
N3—C1—P1	110.7 (2)	P4—C62—H62B	109.7
N3—C1—H1A	109.5	H62A—C62—H62B	108.2
P1—C1—H1A	109.5	C71—P3—C81	105.51 (15)
N3—C1—H1B	109.5	C71—P3—C61	104.13 (16)
P1—C1—H1B	109.5	C81—P3—C61	100.27 (16)
H1A—C1—H1B	108.1	C71—P3—Mo1	116.78 (11)
C31—N3—C2	121.6 (3)	C81—P3—Mo1	121.04 (11)
C31—N3—C1	123.4 (3)	C61—P3—Mo1	106.61 (11)
C2—N3—C1	114.7 (3)	C91—P4—C101	104.34 (16)
N3—C2—P2	115.4 (2)	C91—P4—C62	102.59 (16)
N3—C2—H2A	108.4	C101—P4—C62	101.48 (16)
P2—C2—H2A	108.4	C91—P4—Mo1	120.50 (12)
N3—C2—H2B	108.4	C101—P4—Mo1	119.52 (12)
P2—C2—H2B	108.4	C62—P4—Mo1	105.48 (11)
H2A—C2—H2B	107.5	C72—C71—C76	118.6 (3)
C11—P1—C21	106.26 (15)	C72—C71—P3	119.3 (2)
C11—P1—C1	100.35 (15)	C76—C71—P3	122.1 (3)
C21—P1—C1	99.87 (15)	C73—C72—C71	120.6 (3)
C11—P1—Mo1	114.87 (11)	C73—C72—H72	119.7
C21—P1—Mo1	119.87 (11)	C71—C72—H72	119.7
C1—P1—Mo1	112.95 (11)	C74—C73—C72	120.6 (4)
C41—P2—C51	103.36 (15)	C74—C73—H73	119.7
C41—P2—C2	102.80 (16)	C72—C73—H73	119.7
C51—P2—C2	99.92 (16)	C75—C74—C73	119.4 (3)
C41—P2—Mo1	122.48 (11)	C75—C74—H74	120.3
C51—P2—Mo1	110.44 (11)	C73—C74—H74	120.3
C2—P2—Mo1	114.99 (11)	C74—C75—C76	121.0 (3)
C12—C11—C16	118.8 (3)	C74—C75—H75	119.5
C12—C11—P1	120.0 (3)	C76—C75—H75	119.5
C16—C11—P1	120.8 (2)	C75—C76—C71	119.9 (3)
C13—C12—C11	120.2 (3)	C75—C76—H76	120.1
C13—C12—H12	119.9	C71—C76—H76	120.1
C11—C12—H12	119.9	C82—C81—C86	118.3 (3)
C14—C13—C12	120.7 (3)	C82—C81—P3	123.3 (3)
C14—C13—H13	119.7	C86—C81—P3	118.4 (3)
C12—C13—H13	119.7	C81—C82—C83	120.4 (4)
C13—C14—C15	119.7 (3)	C81—C82—H82	119.8
C13—C14—H14	120.1	C83—C82—H82	119.8
C15—C14—H14	120.1	C84—C83—C82	120.8 (4)
C14—C15—C16	120.0 (3)	C84—C83—H83	119.6
C14—C15—H15	120.0	C82—C83—H83	119.6
C16—C15—H15	120.0	C83—C84—C85	119.4 (4)
C15—C16—C11	120.6 (3)	C83—C84—H84	120.3
C15—C16—H16	119.7	C85—C84—H84	120.3
C11—C16—H16	119.7	C84—C85—C86	120.5 (4)
C26—C21—C22	119.1 (3)	C84—C85—H85	119.8
C26—C21—P1	118.7 (3)	C86—C85—H85	119.8
C22—C21—P1	122.0 (3)	C81—C86—C85	120.5 (4)
C23—C22—C21	120.4 (3)	C81—C86—H86	119.7
C23—C22—H22	119.8	C85—C86—H86	119.7
C21—C22—H22	119.8	C92—C91—C96	118.9 (3)
C24—C23—C22	120.1 (4)	C92—C91—P4	119.6 (3)
C24—C23—H23	119.9	C96—C91—P4	121.5 (3)
C22—C23—H23	119.9	C91—C92—C93	120.2 (4)
C23—C24—C25	119.8 (4)	C91—C92—H92	119.9
C23—C24—H24	120.1	C93—C92—H92	119.9
C25—C24—H24	120.1	C94—C93—C92	120.6 (4)
C24—C25—C26	120.7 (4)	C94—C93—H93	119.7
C24—C25—H25	119.6	C92—C93—H93	119.7
C26—C25—H25	119.6	C95—C94—C93	119.6 (4)
C25—C26—C21	119.9 (3)	C95—C94—H94	120.2
C25—C26—H26	120.1	C93—C94—H94	120.2
C21—C26—H26	120.1	C94—C95—C96	120.6 (4)
N3—C31—N4	120.0 (3)	C94—C95—H95	119.7
N3—C31—C35	123.8 (3)	C96—C95—H95	119.7
N4—C31—C35	116.2 (3)	C95—C96—C91	120.0 (4)
C32—N4—C31	123.9 (4)	C95—C96—H96	120.0
C32—N4—H4	118.0	C91—C96—H96	120.0
C31—N4—H4	118.0	C106—C101—C102	119.1 (3)
N4—C32—C33	120.4 (4)	C106—C101—P4	118.5 (3)
N4—C32—H32	119.8	C102—C101—P4	122.3 (3)
C33—C32—H32	119.8	C103—C102—C101	120.2 (4)
C32—C33—C34	118.0 (4)	C103—C102—H102	119.9
C32—C33—H33	121.0	C101—C102—H102	119.9
C34—C33—H33	121.0	C104—C103—C102	120.4 (4)
C35—C34—C33	121.6 (4)	C104—C103—H103	119.8
C35—C34—H34	119.2	C102—C103—H103	119.8
C33—C34—H34	119.2	C103—C104—C105	119.9 (4)
C34—C35—C31	119.9 (4)	C103—C104—H104	120.1
C34—C35—H35	120.1	C105—C104—H104	120.1
C31—C35—H35	120.1	C104—C105—C106	120.7 (4)
C42—C41—C46	119.4 (3)	C104—C105—H105	119.7
C42—C41—P2	120.3 (3)	C106—C105—H105	119.7
C46—C41—P2	120.3 (3)	C105—C106—C101	119.7 (4)
C41—C42—C43	120.2 (3)	C105—C106—H106	120.1
C41—C42—H42	119.9	C101—C106—H106	120.1
C43—C42—H42	119.9	F14—B1—F13	111.3 (5)
C44—C43—C42	120.2 (4)	F14—B1—F12	110.2 (5)
C44—C43—H43	119.9	F13—B1—F12	107.7 (4)
C42—C43—H43	119.9	F14—B1—F11	110.0 (4)
C43—C44—C45	120.3 (4)	F13—B1—F11	110.5 (5)
C43—C44—H44	119.8	F12—B1—F11	107.1 (4)
C45—C44—H44	119.8	F24'—B2—F22	129.4 (8)
C44—C45—C46	120.0 (4)	F24'—B2—F23	47.9 (8)
C44—C45—H45	120.0	F22—B2—F23	117.8 (4)
C46—C45—H45	120.0	F24'—B2—F21	115.8 (8)
C45—C46—C41	119.8 (4)	F22—B2—F21	111.7 (4)
C45—C46—H46	120.1	F23—B2—F21	119.8 (4)
C41—C46—H46	120.1	F24'—B2—F24	57.5 (8)
C52—C51—C56	118.2 (3)	F22—B2—F24	92.9 (5)
C52—C51—P2	118.5 (3)	F23—B2—F24	102.6 (5)
C56—C51—P2	123.0 (3)	F21—B2—F24	107.0 (4)
C53—C52—C51	121.1 (4)	F24'—B2—F23'	104.1 (9)
C53—C52—H52	119.4	F22—B2—F23'	83.9 (6)
C51—C52—H52	119.4	F23—B2—F23'	56.2 (5)
C54—C53—C52	120.0 (4)	F21—B2—F23'	99.8 (6)
C54—C53—H53	120.0	F24—B2—F23'	152.2 (6)
C52—C53—H53	120.0

Experimental details

Crystal data
Chemical formula	[MoF(N₂H₂)(C₃₁H₂₉N₂P₂)(C₂₆H₂₄P₂)](BF₄)₂
M_r	1208.49
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	170
a, b, c (Å)	12.5791 (6), 31.2199 (16), 13.8330 (9)
β (°)	94.438 (7)
V (Å³)	5416.2 (5)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	0.44
Crystal size (mm)	0.2 × 0.08 × 0.06

Data collection
Diffractometer	Stoe IPDS1 diffractometer
Absorption correction	Numerical (X-SHAPE; Stoe & Cie, 1998a)
T_min, T_max	0.949, 0.969
No. of measured, independent and observed [I > 2σ(I)] reflections	24176, 8538, 6783
R_int	0.032
θ_max (°)	24.1
(sin θ/λ)_max (Å⁻¹)	0.575

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.039, 0.108, 1.02
No. of reflections	8538
No. of parameters	706
No. of restraints	39
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.94, −0.54

Computer programs: IPDS program package (Stoe & Cie, 1998b), IPDS program package, SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), DIAMOND (Brandenburg, 1999), CIFTAB in SHELXTL (Sheldrick, 2008).

Selected geometric parameters (Å, º) top

Mo1—N1	1.755 (3)	Mo1—P2	2.5353 (9)
Mo1—F1	1.9889 (18)	Mo1—P3	2.5698 (8)
Mo1—P1	2.5032 (9)	Mo1—P4	2.5754 (9)

N1—Mo1—F1	178.70 (11)	P1—Mo1—P3	95.38 (3)
N1—Mo1—P1	86.88 (10)	P2—Mo1—P3	174.95 (3)
F1—Mo1—P1	91.94 (6)	N1—Mo1—P4	101.62 (10)
N1—Mo1—P2	86.22 (9)	F1—Mo1—P4	79.52 (6)
F1—Mo1—P2	94.33 (6)	P1—Mo1—P4	170.35 (3)
P1—Mo1—P2	89.65 (3)	P2—Mo1—P4	95.42 (3)
N1—Mo1—P3	94.46 (9)	P3—Mo1—P4	79.53 (3)
F1—Mo1—P3	85.10 (5)	N2—N1—Mo1	177.1 (3)

Acknowledgements

This work is supported by the state of Schleswig-Holstein and the DFG (project number: Tu58/13–2, SPP1118).

References

Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany. Google Scholar
Hidai, M., Kodama, T., Sato, M., Harakawa, M. & Uchida, Y. (1976). Inorg. Chem. 15, 2694–2697. CSD CrossRef CAS Web of Science Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Stephan, G. C., Näther, C., Sivasankar, C. & Tuczek, F. (2008). Inorg. Chim. Acta, 361, 1008–1019. Web of Science CSD CrossRef CAS Google Scholar
Stoe & Cie (1998a). X-SHAPE. Stoe & Cie, Darmstadt, Germany. Google Scholar
Stoe & Cie (1998b). IPDS Program package. Stoe & Cie, Darmstadt, Germany Google Scholar

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