Dichlorido{2-[2-(piperidin-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate

Zhang, D.-F.; Zhou, M.-H.; Yuan, C.-J.

doi:10.1107/S1600536808014311

metal-organic compounds

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ISSN: 2056-9890

Volume 64| Part 6| June 2008| Pages m825-m826

doi:10.1107/S1600536808014311

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Dichlorido{2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate

Dong-Fang Zhang,^a ^* Mei-Huan Zhou ^b and Chang-Ji Yuan ^a

^aSchool of Pharmaceutical Sciences, China Medical University, Shenyang 110001, People's Republic of China, and ^bNortheast Pharmaceutical Group Co. Ltd, Shenyang 110026, People's Republic of China
^*Correspondence e-mail: lnsyzdf@sohu.com

(Received 11 May 2008; accepted 13 May 2008; online 17 May 2008)

In the title mononuclear zinc(II) complex, [ZnCl₂(C₁₄H₂₀N₂O)]·H₂O, the Zn^II atom is four-coordinated by the phenolate O and imine N atoms of the Schiff base ligand and by two Cl atoms in a tetrahedral geometry. In the crystal structure, O—H⋯Cl, O—H⋯O and N—H⋯O hydrogen bonds involving the water molecules bridge adjacent complexes into a ladder-like structure running along the c axis.

Related literature

For general background on Schiff base complexes, see: Kawamoto et al. (2008 ); Tomat et al. (2007 ). For biological properties of Schiff base compounds, see: Abd-Elzaher (2004 ); Iqbal et al. (2005 ); Osowole et al. (2005 ); Raman & Thangaraja (2005 ). For related structures, see: Ali et al. (2008 ); Li (2007 ); Tatar et al. (2002 ); Wang (2007 ).

Experimental

Crystal data

[ZnCl₂(C₁₄H₂₀N₂O)]·H₂O
M_r = 386.61
Monoclinic, P 2₁ /c
a = 9.1860 (18) Å
b = 19.875 (4) Å
c = 9.966 (2) Å
β = 110.20 (3)°
V = 1707.6 (7) Å³
Z = 4
Mo Kα radiation
μ = 1.76 mm⁻¹
T = 298 (2) K
0.20 × 0.18 × 0.17 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2000 ) T_min = 0.720, T_max = 0.754
14151 measured reflections
3882 independent reflections
2685 reflections with I > 2σ(I)
R_int = 0.056

Refinement

R[F² > 2σ(F²)] = 0.045
wR(F²) = 0.104
S = 0.97
3882 reflections
199 parameters
4 restraints
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.49 e Å⁻³
Δρ_min = −0.58 e Å⁻³

Table 1
Selected geometric parameters (Å, °)

Zn1—O1	1.929 (2)
Zn1—N1	2.024 (2)
Zn1—Cl2	2.2066 (10)
Zn1—Cl1	2.2523 (10)

O1—Zn1—N1	95.83 (10)
O1—Zn1—Cl2	113.80 (8)
N1—Zn1—Cl2	111.04 (8)
O1—Zn1—Cl1	109.48 (8)
N1—Zn1—Cl1	109.22 (8)
Cl2—Zn1—Cl1	115.66 (4)

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H2C⋯O2	0.90 (4)	1.81 (4)	2.712 (3)	177 (4)
O2—H2B⋯O1ⁱ	0.84 (3)	1.91 (3)	2.741 (3)	168 (4)
O2—H2A⋯Cl1ⁱⁱ	0.85 (3)	2.44 (3)	3.272 (3)	168 (4)
Symmetry codes: (i) x, y, z-1; (ii) -x+1, -y+1, -z+1.

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808014311/ci2598sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536808014311/ci2598Isup2.hkl

checkCIF report

Comment top

Zinc(II) complexes with Schiff base ligands have received much attention in recent years (Tomat et al., 2007; Kawamoto et al., 2008). Some of the complexes have been found to have biological properties (Osowole et al., 2005; Iqbal et al., 2005; Raman & Thangaraja, 2005; Abd-Elzaher, 2004). In this paper, the crystal structure of the title new zinc(II) complex with the Schiff base ligand 2-[(2-piperidin-1-ylethylimino)methyl]phenol is reported.

The title compound consists of a mononuclear Schiff base zinc(II) complex molecule and a water of hydration (Fig. 1). The Zn^II atom in the complex is four-coordinate in a tetrahedral geometry with one phenolate O and one imine N atoms of the Schiff base ligand, and with two Cl atoms. Bond lengths and angles (Table 1) about the Zn^II centre are comparable with the values observed in other Schiff base zinc(II) complexes (Wang, 2007; Ali et al., 2008; Li, 2007; Tatar et al., 2002). The crystal structure is stabilized by intermolecular O–H···Cl, O–H···O and N—H···O hydrogen bonds (Table 2 and Fig. 2).

Related literature top

For general background on Schiff base complexes, see: Kawamoto et al. (2008); Tomat et al. (2007). For biological properties of Schiff base compounds, see: Abd-Elzaher (2004); Iqbal et al. (2005); Osowole et al. (2005); Raman & Thangaraja (2005). For related structures, see: Ali et al. (2008); Li (2007); Tatar et al. (2002); Wang (2007).

Experimental top

A mixture of salicylaldehyde (0.1 mmol, 12.2 mg), 2-piperidin-1-ylethylamine (0.1 mmol, 12.8 mg) and ZnCl₂ (0.1 mmol, 13.6 mg) in methanol was stirred for 30 min at room temperature to give a yellow solution. After keeping the solution in air for 12 d, yellow block-shaped crystals were formed.

Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT (Bruker, 2000); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure of the title compound, showing 30% probability displacement ellipsoids.
	Fig. 2. Crystal packing of the title compound. Intermolecular hydrogen bonds are shown as dashed lines. H atoms not involved in the interactions have been omitted for clarity.

Dichlorido{2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate top

Crystal data top

[ZnCl₂(C₁₄H₂₀N₂O)]·H₂O	F(000) = 800
M_r = 386.61	D_x = 1.504 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 2461 reflections
a = 9.1860 (18) Å	θ = 2.4–25.0°
b = 19.875 (4) Å	µ = 1.76 mm⁻¹
c = 9.966 (2) Å	T = 298 K
β = 110.20 (3)°	Block, yellow
V = 1707.6 (7) Å³	0.20 × 0.18 × 0.17 mm
Z = 4

Data collection top

Bruker SMART CCD area-detector diffractometer	3882 independent reflections
Radiation source: fine-focus sealed tube	2685 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.056
ω scans	θ_max = 27.5°, θ_min = 2.1°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −11→11
T_min = 0.720, T_max = 0.755	k = −25→25
14151 measured reflections	l = −12→12

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.045	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.104	H atoms treated by a mixture of independent and constrained refinement
S = 0.97	w = 1/[σ²(F_o²) + (0.0472P)²] where P = (F_o² + 2F_c²)/3
3882 reflections	(Δ/σ)_max = 0.001
199 parameters	Δρ_max = 0.49 e Å⁻³
4 restraints	Δρ_min = −0.59 e Å⁻³

Crystal data top

[ZnCl₂(C₁₄H₂₀N₂O)]·H₂O	V = 1707.6 (7) Å³
M_r = 386.61	Z = 4
Monoclinic, P2₁/c	Mo Kα radiation
a = 9.1860 (18) Å	µ = 1.76 mm⁻¹
b = 19.875 (4) Å	T = 298 K
c = 9.966 (2) Å	0.20 × 0.18 × 0.17 mm
β = 110.20 (3)°

Data collection top

Bruker SMART CCD area-detector diffractometer	3882 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2000)	2685 reflections with I > 2σ(I)
T_min = 0.720, T_max = 0.755	R_int = 0.056
14151 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.045	4 restraints
wR(F²) = 0.104	H atoms treated by a mixture of independent and constrained refinement
S = 0.97	Δρ_max = 0.49 e Å⁻³
3882 reflections	Δρ_min = −0.59 e Å⁻³
199 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Zn1	0.30417 (4)	0.444609 (17)	0.67776 (4)	0.03531 (13)
Cl1	0.53819 (11)	0.40618 (5)	0.68728 (10)	0.0547 (3)
Cl2	0.13426 (12)	0.36691 (5)	0.68208 (10)	0.0566 (3)
O1	0.3309 (3)	0.51454 (10)	0.8185 (2)	0.0466 (6)
O2	0.2673 (3)	0.48851 (13)	0.0627 (3)	0.0540 (7)
N1	0.2172 (3)	0.50529 (13)	0.5054 (2)	0.0330 (6)
N2	0.1661 (3)	0.38887 (13)	0.1946 (3)	0.0322 (6)
C6	0.2940 (3)	0.60705 (15)	0.6525 (3)	0.0349 (7)
C1	0.3412 (4)	0.57904 (16)	0.7920 (3)	0.0360 (7)
C2	0.3972 (4)	0.62356 (17)	0.9080 (3)	0.0423 (8)
H2	0.4311	0.6063	1.0004	0.051*
C3	0.4035 (4)	0.69155 (18)	0.8893 (4)	0.0494 (9)
H3	0.4404	0.7197	0.9684	0.059*
C4	0.3549 (4)	0.71867 (18)	0.7520 (4)	0.0553 (10)
H4	0.3586	0.7649	0.7392	0.066*
C5	0.3019 (4)	0.67719 (17)	0.6368 (4)	0.0481 (9)
H5	0.2702	0.6956	0.5454	0.058*
C7	0.2314 (4)	0.56952 (15)	0.5204 (3)	0.0351 (7)
H7	0.1976	0.5948	0.4367	0.042*
C8	0.1417 (4)	0.48009 (16)	0.3607 (3)	0.0420 (8)
H8A	0.1519	0.5126	0.2919	0.050*
H8B	0.0321	0.4730	0.3428	0.050*
C9	0.2177 (4)	0.41441 (16)	0.3450 (3)	0.0379 (8)
H9A	0.3293	0.4206	0.3789	0.045*
H9B	0.1945	0.3807	0.4051	0.045*
C10	0.2450 (4)	0.32330 (17)	0.1916 (3)	0.0414 (8)
H10A	0.2136	0.2904	0.2482	0.050*
H10B	0.3564	0.3292	0.2339	0.050*
C11	0.2048 (4)	0.29752 (17)	0.0403 (3)	0.0454 (9)
H11A	0.2538	0.2542	0.0419	0.054*
H11B	0.2446	0.3284	−0.0141	0.054*
C12	0.0304 (4)	0.29045 (18)	−0.0318 (4)	0.0507 (9)
H12A	0.0064	0.2773	−0.1308	0.061*
H12B	−0.0082	0.2558	0.0158	0.061*
C13	−0.0471 (4)	0.35675 (18)	−0.0247 (3)	0.0476 (9)
H13A	−0.1587	0.3514	−0.0667	0.057*
H13B	−0.0156	0.3900	−0.0805	0.057*
C14	−0.0063 (4)	0.38173 (17)	0.1267 (3)	0.0422 (8)
H14A	−0.0555	0.4249	0.1267	0.051*
H14B	−0.0442	0.3503	0.1814	0.051*
H2C	0.198 (5)	0.4214 (14)	0.148 (4)	0.080*
H2B	0.295 (4)	0.492 (2)	−0.009 (2)	0.080*
H2A	0.330 (4)	0.5124 (18)	0.128 (3)	0.080*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Zn1	0.0448 (3)	0.0329 (2)	0.0281 (2)	0.00015 (17)	0.01246 (17)	0.00067 (15)
Cl1	0.0473 (6)	0.0665 (6)	0.0490 (5)	0.0112 (5)	0.0150 (4)	0.0005 (5)
Cl2	0.0635 (6)	0.0507 (5)	0.0599 (6)	−0.0155 (5)	0.0266 (5)	0.0007 (4)
O1	0.0800 (18)	0.0341 (13)	0.0296 (12)	−0.0072 (12)	0.0238 (12)	−0.0028 (10)
O2	0.0692 (19)	0.0562 (16)	0.0411 (14)	−0.0195 (13)	0.0248 (14)	−0.0026 (12)
N1	0.0398 (16)	0.0353 (14)	0.0255 (13)	0.0008 (12)	0.0132 (12)	−0.0010 (11)
N2	0.0331 (15)	0.0381 (14)	0.0252 (13)	0.0002 (12)	0.0099 (11)	0.0004 (11)
C6	0.0319 (18)	0.0368 (17)	0.0374 (18)	0.0024 (14)	0.0138 (15)	0.0022 (14)
C1	0.0355 (19)	0.0385 (17)	0.0386 (19)	0.0004 (14)	0.0187 (15)	−0.0065 (14)
C2	0.046 (2)	0.047 (2)	0.0370 (19)	−0.0021 (16)	0.0183 (16)	−0.0113 (15)
C3	0.037 (2)	0.045 (2)	0.068 (3)	−0.0056 (16)	0.0200 (19)	−0.0248 (19)
C4	0.050 (2)	0.0339 (19)	0.080 (3)	0.0040 (17)	0.020 (2)	−0.0045 (19)
C5	0.049 (2)	0.0342 (18)	0.060 (2)	0.0049 (16)	0.0171 (19)	0.0042 (17)
C7	0.0336 (18)	0.0404 (19)	0.0336 (18)	0.0073 (14)	0.0145 (15)	0.0088 (14)
C8	0.047 (2)	0.048 (2)	0.0294 (17)	0.0098 (17)	0.0113 (16)	0.0019 (15)
C9	0.043 (2)	0.0495 (19)	0.0190 (16)	0.0072 (16)	0.0082 (14)	−0.0001 (13)
C10	0.039 (2)	0.0447 (19)	0.0378 (19)	0.0078 (16)	0.0102 (16)	0.0010 (15)
C11	0.045 (2)	0.045 (2)	0.045 (2)	0.0031 (16)	0.0135 (17)	−0.0076 (16)
C12	0.049 (2)	0.053 (2)	0.047 (2)	−0.0069 (18)	0.0124 (18)	−0.0116 (17)
C13	0.036 (2)	0.063 (2)	0.0363 (19)	−0.0028 (17)	0.0029 (16)	−0.0081 (17)
C14	0.0313 (19)	0.050 (2)	0.041 (2)	0.0048 (16)	0.0077 (15)	−0.0008 (16)

Geometric parameters (Å, º) top

Zn1—O1	1.929 (2)	C4—H4	0.93
Zn1—N1	2.024 (2)	C5—H5	0.93
Zn1—Cl2	2.2066 (10)	C7—H7	0.93
Zn1—Cl1	2.2523 (10)	C8—C9	1.514 (4)
O1—C1	1.319 (4)	C8—H8A	0.97
O2—H2B	0.84 (3)	C8—H8B	0.97
O2—H2A	0.85 (3)	C9—H9A	0.97
N1—C7	1.287 (4)	C9—H9B	0.97
N1—C8	1.457 (4)	C10—C11	1.512 (4)
N2—C9	1.496 (4)	C10—H10A	0.97
N2—C10	1.496 (4)	C10—H10B	0.97
N2—C14	1.499 (4)	C11—C12	1.520 (5)
N2—H2C	0.90 (4)	C11—H11A	0.97
C6—C5	1.407 (4)	C11—H11B	0.97
C6—C1	1.420 (4)	C12—C13	1.511 (5)
C6—C7	1.448 (4)	C12—H12A	0.97
C1—C2	1.404 (4)	C12—H12B	0.97
C2—C3	1.368 (5)	C13—C14	1.507 (4)
C2—H2	0.93	C13—H13A	0.97
C3—C4	1.393 (5)	C13—H13B	0.97
C3—H3	0.93	C14—H14A	0.97
C4—C5	1.360 (5)	C14—H14B	0.97

O1—Zn1—N1	95.83 (10)	C9—C8—H8A	110.0
O1—Zn1—Cl2	113.80 (8)	N1—C8—H8B	110.0
N1—Zn1—Cl2	111.04 (8)	C9—C8—H8B	110.0
O1—Zn1—Cl1	109.48 (8)	H8A—C8—H8B	108.3
N1—Zn1—Cl1	109.22 (8)	N2—C9—C8	113.5 (2)
Cl2—Zn1—Cl1	115.66 (4)	N2—C9—H9A	108.9
C1—O1—Zn1	123.71 (18)	C8—C9—H9A	108.9
H2B—O2—H2A	106 (2)	N2—C9—H9B	108.9
C7—N1—C8	116.8 (3)	C8—C9—H9B	108.9
C7—N1—Zn1	119.9 (2)	H9A—C9—H9B	107.7
C8—N1—Zn1	123.31 (19)	N2—C10—C11	111.2 (2)
C9—N2—C10	109.1 (2)	N2—C10—H10A	109.4
C9—N2—C14	113.8 (2)	C11—C10—H10A	109.4
C10—N2—C14	110.6 (2)	N2—C10—H10B	109.4
C9—N2—H2C	103 (3)	C11—C10—H10B	109.4
C10—N2—H2C	112 (3)	H10A—C10—H10B	108.0
C14—N2—H2C	108 (3)	C10—C11—C12	110.9 (3)
C5—C6—C1	119.1 (3)	C10—C11—H11A	109.4
C5—C6—C7	115.4 (3)	C12—C11—H11A	109.4
C1—C6—C7	125.4 (3)	C10—C11—H11B	109.4
O1—C1—C2	118.6 (3)	C12—C11—H11B	109.4
O1—C1—C6	123.9 (3)	H11A—C11—H11B	108.0
C2—C1—C6	117.4 (3)	C13—C12—C11	109.5 (3)
C3—C2—C1	122.1 (3)	C13—C12—H12A	109.8
C3—C2—H2	119.0	C11—C12—H12A	109.8
C1—C2—H2	119.0	C13—C12—H12B	109.8
C2—C3—C4	120.1 (3)	C11—C12—H12B	109.8
C2—C3—H3	120.0	H12A—C12—H12B	108.2
C4—C3—H3	120.0	C12—C13—C14	112.1 (3)
C5—C4—C3	119.7 (3)	C12—C13—H13A	109.2
C5—C4—H4	120.2	C14—C13—H13A	109.2
C3—C4—H4	120.2	C12—C13—H13B	109.2
C4—C5—C6	121.6 (3)	C14—C13—H13B	109.2
C4—C5—H5	119.2	H13A—C13—H13B	107.9
C6—C5—H5	119.2	N2—C14—C13	110.0 (3)
N1—C7—C6	127.5 (3)	N2—C14—H14A	109.7
N1—C7—H7	116.2	C13—C14—H14A	109.7
C6—C7—H7	116.2	N2—C14—H14B	109.7
N1—C8—C9	108.6 (2)	C13—C14—H14B	109.7
N1—C8—H8A	110.0	H14A—C14—H14B	108.2

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2C···O2	0.90 (4)	1.81 (4)	2.712 (3)	177 (4)
O2—H2B···O1ⁱ	0.84 (3)	1.91 (3)	2.741 (3)	168 (4)
O2—H2A···Cl1ⁱⁱ	0.85 (3)	2.44 (3)	3.272 (3)	168 (4)

Symmetry codes: (i) x, y, z−1; (ii) −x+1, −y+1, −z+1.

Experimental details

Crystal data
Chemical formula	[ZnCl₂(C₁₄H₂₀N₂O)]·H₂O
M_r	386.61
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	298
a, b, c (Å)	9.1860 (18), 19.875 (4), 9.966 (2)
β (°)	110.20 (3)
V (Å³)	1707.6 (7)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.76
Crystal size (mm)	0.20 × 0.18 × 0.17

Data collection
Diffractometer	Bruker SMART CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 2000)
T_min, T_max	0.720, 0.755
No. of measured, independent and observed [I > 2σ(I)] reflections	14151, 3882, 2685
R_int	0.056
(sin θ/λ)_max (Å⁻¹)	0.650

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.045, 0.104, 0.97
No. of reflections	3882
No. of parameters	199
No. of restraints	4
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρ_max, Δρ_min (e Å⁻³)	0.49, −0.59

Computer programs: SMART (Bruker, 2000), SAINT (Bruker, 2000), SHELXTL (Sheldrick, 2008).

Selected geometric parameters (Å, º) top

Zn1—O1	1.929 (2)	Zn1—Cl2	2.2066 (10)
Zn1—N1	2.024 (2)	Zn1—Cl1	2.2523 (10)

O1—Zn1—N1	95.83 (10)	O1—Zn1—Cl1	109.48 (8)
O1—Zn1—Cl2	113.80 (8)	N1—Zn1—Cl1	109.22 (8)
N1—Zn1—Cl2	111.04 (8)	Cl2—Zn1—Cl1	115.66 (4)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2C···O2	0.90 (4)	1.81 (4)	2.712 (3)	177 (4)
O2—H2B···O1ⁱ	0.84 (3)	1.91 (3)	2.741 (3)	168 (4)
O2—H2A···Cl1ⁱⁱ	0.85 (3)	2.44 (3)	3.272 (3)	168 (4)

Symmetry codes: (i) x, y, z−1; (ii) −x+1, −y+1, −z+1.

Acknowledgements

The authors acknowledge China Medical University for support of this research.

References

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Volume 64| Part 6| June 2008| Pages m825-m826

doi:10.1107/S1600536808014311

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Di­chlorido{2-[2-(piperidin-1-yl)ethyl­imino­meth­yl]phenolato}zinc(II) monohydrate

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

Dichlorido{2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate