metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

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ISSN: 2056-9890

Poly[di-μ2-acetato-di­aquabis(2,2′-bi­pyridine)bis­(μ3-5-nitroisophthalato)tricobalt(II)]

aBiological and Chemical Engineering School of Jiaxing University, Jiaxing 314001, People's Republic of China
*Correspondence e-mail: hhy123@163.com

(Received 1 April 2009; accepted 3 April 2009; online 10 April 2009)

The title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydro­thermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octa­hedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitro­isophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H⋯O hydrogen bonds.

Related literature

For related structures, see: He et al. (2004[He, H.-Y., Zhou, Y.-L. & Zhu, L.-G. (2004). Acta Cryst. C60, m569-m571.], 2005[He, H.-Y., Zhu, L.-G. & Ng, S. W. (2005). Acta Cryst. E61, m601-m602.]); Zhang et al. (2006[Zhang, Z., Zhou, Y.-L. & He, H.-Y. (2006). Acta Cryst. E62, m2591-m2593.]).

[Scheme 1]

Experimental

Crystal data
  • [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2]

  • Mr = 1061.51

  • Triclinic, [P \overline 1]

  • a = 10.0084 (1) Å

  • b = 10.0781 (1) Å

  • c = 11.3941 (1) Å

  • α = 81.196 (1)°

  • β = 67.685 (1)°

  • γ = 69.472 (1)°

  • V = 995.43 (2) Å3

  • Z = 1

  • Mo Kα radiation

  • μ = 1.33 mm−1

  • T = 296 K

  • 0.26 × 0.13 × 0.10 mm

Data collection
  • Bruker SMART 1K CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2002[Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, USA.]) Tmin = 0.724, Tmax = 0.883

  • 10424 measured reflections

  • 3679 independent reflections

  • 3296 reflections with I > 2σ(I)

  • Rint = 0.020

Refinement
  • R[F2 > 2σ(F2)] = 0.030

  • wR(F2) = 0.077

  • S = 1.03

  • 3679 reflections

  • 310 parameters

  • 3 restraints

  • H atoms treated by a mixture of independent and constrained refinement

  • Δρmax = 0.53 e Å−3

  • Δρmin = −0.45 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
O1W—H1WA⋯O3i 0.83 (2) 1.99 (2) 2.755 (3) 154 (2)
O1W—H1WB⋯O3ii 0.826 (18) 1.96 (2) 2.762 (3) 163 (3)
Symmetry codes: (i) x-1, y, z; (ii) -x+1, -y+1, -z+1.

Data collection: SMART (Bruker, 2002[Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, USA.]); cell refinement: SAINT (Bruker, 2002[Bruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997[Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.]); software used to prepare material for publication: PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]).

Supporting information


Comment top

Recently, we were interested in polymers formed by isophthalate ligands and the complexes the form with transition metals because of their diverse topologies and potential applications as functional materials (He et al., 2004, 2005, Zhang et al., 2006).

The structure features a centrosymmetric complex with three Co(II) centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitroisophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O-H···O hydrogen bonds (Tab. 1).

Related literature top

For related structures, see: He et al. (2004, 2005); Zhang et al. (2006).

Experimental top

A mixture of Co(Ac)2.4H2O (0.1240g, 0.5 mmol), 2,2'-bipyridine (0.0790g, 0.5 mmol), 5-nitroisophthalic acid (0.1050g, 0.5mmol), 8 ml H2O and 8ml EtOH was heated at 413 K for three days in a 20 ml Teflon-lined stainless-steel autoclave. After cooling, a red plate shaped crystals of the title compound were obstained.

Refinement top

The H atoms of aromatic and methyl group were positioned geometrically, and included in the refinement in the riding model approximation with C-H = 0.93 Å for aromatic H atoms and C-H = 0.96 Å for H atoms of methyl groups and Uiso=1.2Ueq(C). The H atoms of the water molecule were found in a difference Fourier map and refined isotropically with the O-H bonds restrained to 0.82 (1)Å and the H···H distance restrained to 1.4 (1)Å.

Computing details top

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT (Bruker, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: PLATON (Spek, 2009).

Figures top
[Figure 1] Fig. 1. View of the title complex view. Displacement ellipsoids are drawn at the 30% probability level. H atoms are omitted for clarity. Symmetry codes for generating equivalent atoms: (v) x-1, y, z. (vi) x, -y, 1-z. (vii) 1-x, 2-y, 1-z.
Poly[di-µ2-acetato-diaquabis(2,2'-bipyridine)bis(µ3-5-nitroisophthalato)tricobalt(II)] top
Crystal data top
[Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2]Z = 1
Mr = 1061.51F(000) = 539
Triclinic, P1Dx = 1.771 Mg m3
a = 10.0084 (1) ÅMo Kα radiation, λ = 0.71073 Å
b = 10.0781 (1) ÅCell parameters from 10424 reflections
c = 11.3941 (1) Åθ = 1.9–25.5°
α = 81.196 (1)°µ = 1.33 mm1
β = 67.685 (1)°T = 296 K
γ = 69.472 (1)°Plate, red
V = 995.43 (2) Å30.26 × 0.13 × 0.10 mm
Data collection top
Bruker SMART 1K CCD
diffractometer
3679 independent reflections
Radiation source: fine-focus sealed tube3296 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.020
phi/ω scansθmax = 25.5°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2002)
h = 1212
Tmin = 0.724, Tmax = 0.883k = 1212
10424 measured reflectionsl = 1313
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.077H atoms treated by a mixture of independent and constrained refinement
S = 1.03 w = 1/[σ2(Fo2) + (0.0358P)2 + 1.058P]
where P = (Fo2 + 2Fc2)/3
3679 reflections(Δ/σ)max < 0.001
310 parametersΔρmax = 0.53 e Å3
3 restraintsΔρmin = 0.45 e Å3
Crystal data top
[Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2]γ = 69.472 (1)°
Mr = 1061.51V = 995.43 (2) Å3
Triclinic, P1Z = 1
a = 10.0084 (1) ÅMo Kα radiation
b = 10.0781 (1) ŵ = 1.33 mm1
c = 11.3941 (1) ÅT = 296 K
α = 81.196 (1)°0.26 × 0.13 × 0.10 mm
β = 67.685 (1)°
Data collection top
Bruker SMART 1K CCD
diffractometer
3679 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2002)
3296 reflections with I > 2σ(I)
Tmin = 0.724, Tmax = 0.883Rint = 0.020
10424 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0303 restraints
wR(F2) = 0.077H atoms treated by a mixture of independent and constrained refinement
S = 1.03Δρmax = 0.53 e Å3
3679 reflectionsΔρmin = 0.45 e Å3
310 parameters
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.00001.00000.50000.02056 (11)
Co20.29863 (3)0.66172 (3)0.34001 (3)0.02348 (10)
N10.5014 (2)0.4947 (2)0.26205 (19)0.0264 (4)
N20.2395 (2)0.5533 (2)0.23098 (19)0.0271 (4)
C60.3533 (3)0.4463 (2)0.1610 (2)0.0259 (5)
O10.38924 (18)0.74188 (17)0.43457 (16)0.0283 (4)
O90.10814 (18)0.86327 (17)0.34394 (15)0.0263 (4)
C110.5544 (3)0.8074 (2)0.5603 (2)0.0218 (5)
H11A0.60880.73530.50170.026*
C170.3124 (3)0.8272 (2)0.5243 (2)0.0233 (5)
C160.3980 (3)0.8686 (2)0.5891 (2)0.0219 (5)
C190.8024 (3)0.7950 (3)0.5801 (2)0.0269 (5)
C120.6310 (3)0.8526 (2)0.6180 (2)0.0233 (5)
O30.8695 (2)0.67757 (19)0.5289 (2)0.0414 (5)
C50.5033 (3)0.4180 (2)0.1738 (2)0.0256 (5)
C40.6363 (3)0.3199 (3)0.1018 (2)0.0337 (6)
H4A0.63610.27030.03950.040*
C140.3935 (3)1.0141 (2)0.7364 (2)0.0273 (5)
C130.5491 (3)0.9578 (3)0.7079 (2)0.0272 (5)
H13A0.59770.98940.74780.033*
C150.3160 (3)0.9740 (2)0.6786 (2)0.0262 (5)
H15A0.21141.01630.69890.031*
C90.0689 (3)0.5133 (3)0.1519 (3)0.0382 (6)
H9A0.02880.53890.14950.046*
C70.3293 (3)0.3687 (3)0.0849 (3)0.0352 (6)
H7A0.40920.29510.03690.042*
C100.1008 (3)0.5858 (3)0.2260 (3)0.0328 (6)
H10A0.02250.66010.27420.039*
C10.6309 (3)0.4698 (3)0.2832 (3)0.0327 (6)
H1A0.62950.52170.34470.039*
C80.1844 (3)0.4028 (3)0.0818 (3)0.0406 (7)
H8A0.16520.35120.03240.049*
C20.7661 (3)0.3707 (3)0.2180 (3)0.0379 (6)
H2A0.85330.35390.23690.046*
N30.3069 (3)1.1250 (3)0.8321 (2)0.0462 (6)
C30.7690 (3)0.2970 (3)0.1241 (3)0.0392 (6)
H3A0.85980.23230.07610.047*
O60.1710 (3)1.1769 (3)0.8577 (3)0.0776 (9)
O20.17072 (18)0.88101 (19)0.56665 (16)0.0318 (4)
O40.8652 (2)0.8704 (2)0.60355 (17)0.0369 (4)
O50.3732 (3)1.1514 (4)0.8890 (3)0.1161 (15)
O1W0.17349 (19)0.56964 (19)0.50084 (18)0.0318 (4)
H1WA0.0831 (15)0.620 (2)0.523 (3)0.048*
H1WB0.180 (3)0.4895 (15)0.486 (3)0.048*
O80.31763 (19)0.80788 (18)0.17845 (16)0.0334 (4)
C320.1871 (3)0.8911 (2)0.2305 (2)0.0263 (5)
C330.1213 (4)1.0190 (3)0.1602 (3)0.0468 (7)
H33A0.19491.02390.07720.070*
H33B0.09521.10250.20560.070*
H33C0.03141.01290.15240.070*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0155 (2)0.0220 (2)0.0263 (2)0.00532 (16)0.00810 (17)0.00619 (17)
Co20.02330 (17)0.02240 (17)0.02775 (18)0.00702 (13)0.01024 (13)0.00655 (13)
N10.0258 (10)0.0226 (10)0.0315 (11)0.0068 (8)0.0108 (8)0.0030 (8)
N20.0270 (10)0.0274 (10)0.0295 (11)0.0090 (8)0.0106 (9)0.0057 (8)
C60.0327 (13)0.0215 (11)0.0249 (12)0.0087 (10)0.0114 (10)0.0010 (9)
O10.0230 (8)0.0311 (9)0.0350 (9)0.0075 (7)0.0115 (7)0.0123 (7)
O90.0279 (9)0.0240 (8)0.0270 (9)0.0078 (7)0.0085 (7)0.0052 (7)
C110.0251 (11)0.0195 (11)0.0236 (11)0.0089 (9)0.0092 (9)0.0022 (9)
C170.0251 (12)0.0214 (11)0.0255 (12)0.0074 (9)0.0121 (9)0.0016 (9)
C160.0243 (11)0.0212 (11)0.0221 (11)0.0085 (9)0.0093 (9)0.0001 (9)
C190.0258 (12)0.0310 (13)0.0279 (12)0.0145 (10)0.0099 (10)0.0027 (10)
C120.0256 (12)0.0219 (11)0.0256 (11)0.0115 (9)0.0099 (9)0.0020 (9)
O30.0261 (9)0.0334 (10)0.0636 (13)0.0083 (8)0.0114 (9)0.0124 (9)
C50.0301 (12)0.0213 (11)0.0248 (12)0.0083 (10)0.0093 (10)0.0005 (9)
C40.0369 (14)0.0273 (13)0.0303 (13)0.0046 (11)0.0087 (11)0.0040 (10)
C140.0327 (13)0.0255 (12)0.0241 (12)0.0113 (10)0.0063 (10)0.0070 (10)
C130.0337 (13)0.0317 (13)0.0246 (12)0.0182 (11)0.0113 (10)0.0029 (10)
C150.0239 (12)0.0250 (12)0.0274 (12)0.0058 (9)0.0073 (9)0.0040 (10)
C90.0380 (15)0.0400 (15)0.0478 (16)0.0155 (12)0.0235 (13)0.0031 (13)
C70.0434 (15)0.0287 (13)0.0365 (14)0.0074 (11)0.0180 (12)0.0090 (11)
C100.0288 (13)0.0325 (13)0.0387 (14)0.0082 (11)0.0117 (11)0.0098 (11)
C10.0318 (13)0.0284 (13)0.0433 (15)0.0104 (11)0.0180 (11)0.0015 (11)
C80.0552 (18)0.0359 (15)0.0451 (16)0.0165 (13)0.0280 (14)0.0090 (12)
C20.0274 (13)0.0329 (14)0.0530 (17)0.0102 (11)0.0160 (12)0.0063 (13)
N30.0444 (15)0.0481 (14)0.0441 (14)0.0132 (12)0.0057 (11)0.0256 (12)
C30.0300 (14)0.0309 (14)0.0419 (15)0.0007 (11)0.0053 (12)0.0006 (12)
O60.0595 (16)0.0778 (18)0.0809 (18)0.0265 (13)0.0342 (14)0.0527 (15)
O20.0200 (8)0.0421 (10)0.0341 (9)0.0035 (7)0.0137 (7)0.0073 (8)
O40.0339 (10)0.0497 (11)0.0392 (10)0.0286 (9)0.0109 (8)0.0037 (9)
O50.0539 (16)0.176 (3)0.130 (3)0.0378 (19)0.0024 (16)0.128 (3)
O1W0.0276 (9)0.0288 (9)0.0382 (10)0.0091 (7)0.0093 (8)0.0044 (8)
O80.0297 (9)0.0333 (9)0.0322 (9)0.0078 (8)0.0055 (8)0.0059 (8)
C320.0309 (13)0.0255 (12)0.0277 (12)0.0107 (10)0.0125 (10)0.0058 (10)
C330.0542 (18)0.0416 (16)0.0379 (16)0.0079 (14)0.0182 (14)0.0054 (13)
Geometric parameters (Å, º) top
Co1—O22.0503 (16)C5—C41.384 (3)
Co1—O2i2.0503 (16)C4—C31.381 (4)
Co1—O9i2.1153 (15)C4—H4A0.9300
Co1—O92.1153 (15)C14—C151.375 (3)
Co1—O4ii2.1154 (17)C14—C131.380 (4)
Co1—O4iii2.1154 (17)C14—N31.471 (3)
Co2—O12.0392 (15)C13—H13A0.9300
Co2—O1W2.0831 (18)C15—H15A0.9300
Co2—N12.1053 (19)C9—C81.372 (4)
Co2—N22.1249 (19)C9—C101.380 (4)
Co2—O82.1668 (18)C9—H9A0.9300
Co2—O92.2382 (16)C7—C81.382 (4)
N1—C11.338 (3)C7—H7A0.9300
N1—C51.350 (3)C10—H10A0.9300
N2—C101.331 (3)C1—C21.377 (4)
N2—C61.345 (3)C1—H1A0.9300
C6—C71.385 (3)C8—H8A0.9300
C6—C51.487 (3)C2—C31.380 (4)
O1—C171.259 (3)C2—H2A0.9300
O9—C321.281 (3)N3—O51.199 (3)
C11—C161.391 (3)N3—O61.206 (3)
C11—C121.395 (3)C3—H3A0.9300
C11—H11A0.9300O4—Co1iv2.1154 (17)
C17—O21.248 (3)O1W—H1WA0.826 (10)
C17—C161.508 (3)O1W—H1WB0.824 (10)
C16—C151.388 (3)O8—C321.248 (3)
C19—O31.244 (3)C32—C331.493 (4)
C19—O41.252 (3)C33—H33A0.9600
C19—C121.510 (3)C33—H33B0.9600
C12—C131.390 (3)C33—H33C0.9600
O2—Co1—O2i180.0C13—C12—C19119.0 (2)
O2—Co1—O9i92.58 (6)C11—C12—C19121.4 (2)
O2i—Co1—O9i87.42 (6)N1—C5—C4121.7 (2)
O2—Co1—O987.42 (6)N1—C5—C6115.1 (2)
O2i—Co1—O992.58 (6)C4—C5—C6123.2 (2)
O9i—Co1—O9180.000 (1)C3—C4—C5119.0 (2)
O2—Co1—O4ii90.67 (7)C3—C4—H4A120.5
O2i—Co1—O4ii89.33 (7)C5—C4—H4A120.5
O9i—Co1—O4ii88.72 (7)C15—C14—C13123.5 (2)
O9—Co1—O4ii91.28 (7)C15—C14—N3118.4 (2)
O2—Co1—O4iii89.33 (7)C13—C14—N3118.1 (2)
O2i—Co1—O4iii90.67 (7)C14—C13—C12118.1 (2)
O9i—Co1—O4iii91.28 (7)C14—C13—H13A120.9
O9—Co1—O4iii88.72 (7)C12—C13—H13A120.9
O4ii—Co1—O4iii180.0C14—C15—C16118.3 (2)
O1—Co2—O1W94.98 (7)C14—C15—H15A120.9
O1—Co2—N194.01 (7)C16—C15—H15A120.9
O1W—Co2—N1103.72 (7)C8—C9—C10118.6 (2)
O1—Co2—N2170.78 (7)C8—C9—H9A120.7
O1W—Co2—N287.41 (7)C10—C9—H9A120.7
N1—Co2—N276.77 (7)C8—C7—C6118.7 (2)
O1—Co2—O898.32 (7)C8—C7—H7A120.7
O1W—Co2—O8152.53 (7)C6—C7—H7A120.7
N1—Co2—O899.22 (7)N2—C10—C9122.5 (2)
N2—Co2—O883.29 (7)N2—C10—H10A118.8
O1—Co2—O994.50 (6)C9—C10—H10A118.8
O1W—Co2—O995.80 (7)N1—C1—C2123.0 (2)
N1—Co2—O9157.91 (7)N1—C1—H1A118.5
N2—Co2—O994.12 (7)C2—C1—H1A118.5
O8—Co2—O959.37 (6)C9—C8—C7119.6 (2)
C1—N1—C5118.4 (2)C9—C8—H8A120.2
C1—N1—Co2124.99 (16)C7—C8—H8A120.2
C5—N1—Co2116.21 (15)C1—C2—C3118.4 (2)
C10—N2—C6119.0 (2)C1—C2—H2A120.8
C10—N2—Co2124.78 (16)C3—C2—H2A120.8
C6—N2—Co2116.22 (15)O5—N3—O6122.5 (3)
N2—C6—C7121.6 (2)O5—N3—C14117.9 (3)
N2—C6—C5114.8 (2)O6—N3—C14119.3 (2)
C7—C6—C5123.6 (2)C2—C3—C4119.5 (2)
C17—O1—Co2124.66 (14)C2—C3—H3A120.3
C32—O9—Co1126.76 (14)C4—C3—H3A120.3
C32—O9—Co288.61 (13)C17—O2—Co1138.15 (16)
Co1—O9—Co2121.97 (8)C19—O4—Co1iv137.23 (17)
C16—C11—C12121.0 (2)Co2—O1W—H1WA109 (2)
C16—C11—H11A119.5Co2—O1W—H1WB111 (2)
C12—C11—H11A119.5H1WA—O1W—H1WB109 (2)
O2—C17—O1126.4 (2)C32—O8—Co292.74 (15)
O2—C17—C16116.0 (2)O8—C32—O9119.2 (2)
O1—C17—C16117.6 (2)O8—C32—C33120.5 (2)
C15—C16—C11119.6 (2)O9—C32—C33120.2 (2)
C15—C16—C17117.9 (2)C32—C33—H33A109.5
C11—C16—C17122.5 (2)C32—C33—H33B109.5
O3—C19—O4125.4 (2)H33A—C33—H33B109.5
O3—C19—C12118.0 (2)C32—C33—H33C109.5
O4—C19—C12116.6 (2)H33A—C33—H33C109.5
C13—C12—C11119.5 (2)H33B—C33—H33C109.5
Symmetry codes: (i) x, y+2, z+1; (ii) x1, y, z; (iii) x+1, y+2, z+1; (iv) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1WA···O3ii0.83 (2)1.99 (2)2.755 (3)154 (2)
O1W—H1WB···O3v0.83 (2)1.96 (2)2.762 (3)163 (3)
Symmetry codes: (ii) x1, y, z; (v) x+1, y+1, z+1.

Experimental details

Crystal data
Chemical formula[Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2]
Mr1061.51
Crystal system, space groupTriclinic, P1
Temperature (K)296
a, b, c (Å)10.0084 (1), 10.0781 (1), 11.3941 (1)
α, β, γ (°)81.196 (1), 67.685 (1), 69.472 (1)
V3)995.43 (2)
Z1
Radiation typeMo Kα
µ (mm1)1.33
Crystal size (mm)0.26 × 0.13 × 0.10
Data collection
DiffractometerBruker SMART 1K CCD
diffractometer
Absorption correctionMulti-scan
(SADABS; Bruker, 2002)
Tmin, Tmax0.724, 0.883
No. of measured, independent and
observed [I > 2σ(I)] reflections
10424, 3679, 3296
Rint0.020
(sin θ/λ)max1)0.606
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.030, 0.077, 1.03
No. of reflections3679
No. of parameters310
No. of restraints3
H-atom treatmentH atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å3)0.53, 0.45

Computer programs: SMART (Bruker, 2002), SAINT (Bruker, 2002), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), ORTEP-3 for Windows (Farrugia, 1997), PLATON (Spek, 2009).

Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1WA···O3i0.83 (2)1.99 (2)2.755 (3)154 (2)
O1W—H1WB···O3ii0.826 (18)1.96 (2)2.762 (3)163 (3)
Symmetry codes: (i) x1, y, z; (ii) x+1, y+1, z+1.
 

References

First citationBruker (2002). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, USA.  Google Scholar
First citationFarrugia, L. J. (1997). J. Appl. Cryst. 30, 565.  CrossRef IUCr Journals Google Scholar
First citationHe, H.-Y., Zhou, Y.-L. & Zhu, L.-G. (2004). Acta Cryst. C60, m569–m571.  Web of Science CSD CrossRef CAS IUCr Journals Google Scholar
First citationHe, H.-Y., Zhu, L.-G. & Ng, S. W. (2005). Acta Cryst. E61, m601–m602.  Web of Science CSD CrossRef IUCr Journals Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationSpek, A. L. (2009). Acta Cryst. D65, 148–155.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationZhang, Z., Zhou, Y.-L. & He, H.-Y. (2006). Acta Cryst. E62, m2591–m2593.  Web of Science CSD CrossRef IUCr Journals Google Scholar

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