Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]

Becker, E.; Kirchner, K.; Mereiter, K.

doi:10.1107/S1600536809036198

inorganic compounds

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ISSN: 2056-9890

Volume 65| Part 10| October 2009| Page i71

doi:10.1107/S1600536809036198

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Hexaaquairon(II) bis[fac-tribromidotricarbonylferrate(II)]

Eva Becker,^a Karl Kirchner ^a and Kurt Mereiter ^b ^*

^aInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, Austria, and ^bInstitute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164SC, A-1060 Vienna, Austria
^*Correspondence e-mail: kurt.mereiter@tuwien.ac.at

(Received 3 September 2009; accepted 7 September 2009; online 12 September 2009)

In the title compound, [Fe(H₂O)₆][FeBr₃(CO)₃]₂, both Fe atoms have an octahedral coordination and the bromide carbonyl complex has a fac-stereochemistry. The [Fe(H₂O)₆]²⁺ octahedron has point symmetry $[\overline{1}]$ and is slightly compressed along one O—Fe—O axis. The [FeBr₃(CO)₃]⁻ anion has point symmetry 1 and mean bond lengths of Fe—Br = 2.455 (5) Å and Fe—C = 1.809 (2) Å. The cation and anion complexes are mutually linked via O—H⋯Br hydrogen bonds with O⋯Br distances of 3.340 (3) to 3.388 (3) Å.

Related literature

For the chemistry of FeBr₂(CO)₄, see: Hieber & Bader (1928 ); Robertson et al. (2000 ). For the syntheses and crystal structures of anologous compounds with [(Fe/Co/Ru)(H₂O)₆]²⁺ cations and [(Ru/Os)(Cl/I)₃(CO)₃]⁻ complexes, see: Allen (2002 ); Taimisto et al. (2003 ); Haukka et al. (2006 ); Jakonen et al. (2007 ).

Experimental

Crystal data

[Fe(H₂O)₆][FeBr₃(CO)₃]₂
M_r = 923.17
Orthorhombic, P b c a
a = 11.9334 (8) Å
b = 9.3394 (6) Å
c = 20.5775 (14) Å
V = 2293.4 (3) Å³
Z = 4
Mo Kα radiation
μ = 12.37 mm⁻¹
T = 100 K
0.26 × 0.10 × 0.08 mm

Data collection

Bruker SMART APEX CCD diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2003 ) T_min = 0.15, T_max = 0.37
24075 measured reflections
3316 independent reflections
2674 reflections with I > 2σ(I)
R_int = 0.061

Refinement

R[F² > 2σ(F²)] = 0.034
wR(F²) = 0.070
S = 1.04
3316 reflections
145 parameters
18 restraints
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.98 e Å⁻³
Δρ_min = −0.68 e Å⁻³

Table 1
Selected bond lengths (Å)

Fe1—O1W	2.137 (3)
Fe1—O2W	2.128 (3)
Fe1—O3W	2.098 (3)
Fe2—C1	1.812 (4)
Fe2—C2	1.807 (4)
Fe2—C3	1.808 (4)
Fe2—Br1	2.4479 (6)
Fe2—Br2	2.4605 (6)
Fe2—Br3	2.4558 (6)

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1A⋯Br1	0.821 (19)	2.52 (2)	3.340 (3)	174 (4)
O1W—H1B⋯Br2ⁱ	0.821 (19)	2.69 (2)	3.475 (3)	162 (5)
O2W—H2A⋯Br2ⁱⁱ	0.821 (19)	2.55 (2)	3.373 (3)	177 (5)
O2W—H2B⋯Br2ⁱ	0.821 (19)	2.56 (2)	3.341 (3)	160 (5)
O3W—H3A⋯Br3	0.821 (19)	2.58 (2)	3.388 (3)	169 (5)
O3W—H3B⋯Br3ⁱⁱⁱ	0.821 (19)	2.53 (2)	3.346 (3)	177 (4)
Symmetry codes: (i) -x, -y+1, -z; (ii) $[x+{\script{1\over 2}}, -y+{\script{1\over 2}}, -z]$ ; (iii) $[-x+{\script{1\over 2}}, y-{\script{1\over 2}}, z]$ .

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT and XPREP (Bruker, 2003); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809036198/om2275sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536809036198/om2275Isup2.hkl

checkCIF report

Comment top

FeBr₂(CO)₄, easily accessible by reaction of Fe(CO)₅ with bromine (Hieber & Bader, 1928; Robertson et al., 2000), is stable under dry conditions but reacts readily with various protic or coordinating solvents and thus turned out to be an interesting precursor for iron complexes which are otherwise difficult to obtain. By treatment of FeBr₂(CO)₄ with wet benzene the title compound was obtained according to the equation: 3 FeBr₂(CO)₄ + 6H₂O → Fe(H₂O)₆ + 2 FeBr₃(CO)₃ + 6 CO. The structure (Fig. 1) contains a [Fe(H₂O)₆]²⁺ octahedron with point symmetry 1 and a [FeBr₃(CO)₃]^- octahedron with iron with point symmetry 1 (Fig. 1). The Fe—O bond lengths in [Fe(H₂O)₆]²⁺ (Table 1) correspond well with high-spin iron(II) in an axially weakly compressed octahedron. The [FeBr₃(CO)₃]^- anion has a facial disposition of the bromide and carbonyl ligands and shows each three very uniform Fe—Br and Fe—C bond distances with mean values of Fe—Br = 2.455 (5) Å and Fe—C = 1.809 (2) Å (Table 1) consistent with a low-spin state. The bond angles about this iron deviate up to 5.6° from 90 and 180°. C—O bond lengths average to 1.128 (1) Å, and Fe—C—O angles 177.9 (10)°. Each of the three independent water molecules is coordinated by Fe1 and by pair of bromine atoms as hydrogen bond acceptors. Their coordination environments are pyramidal to flat pyramidal (O2w). The six independent O—H···Br bonds (Table 2) are quite uniform in distances and angles, all being essentially linear. The structure has various architectural aspects, but is best regarded as consisting of double layers of [FeBr₃(CO)₃] octahedra held together by interactions between the mainly inward-oriented CO groups whereas the bromine atoms define their outer surfaces (Fig. 2). These double layers are oriented parallel to (100) and centered at y = 1/4 and 3/4. Intercalated between these double layers are single layers of [Fe(H₂O)₆]²⁺ octahedra at z = 0, 1/2 and 1, which bridge the double layers via the O—H···Br hydrogen bonds. The title compound has no precedents in iron structural chemistry, but a few analogous [MX₃(CO)₃]^- complexes are known for M = Ru, Os, Re, and X = Cl, Br, I (Cambridge Structural Database - CSD; Version 5.30 of November 2008; Allen, 2002). Most related to the title compound is [Ru(H₂O)₆]²⁺[RuCl₃(CO)₃]^-₂.2H₂O (Taimisto et al., 2003), obtained from [RuCl₂(CO)₃]₂ in wet CH₂Cl₂. It has, despite being triclinic (title compound is orthorhombic), an additional uncoordinated H₂O, a structural architecture analogous to the title compound. More recently, this formerly unique compound was expanded into three isomorphous series of type 1, [(Fe/Co)(H₂O)₆]²⁺[(Ru/Os)Cl₃(CO)₃]^-₂, triclinic, space group P1, of type 2, [(Ru/Fe/Co)(H₂O)₆]²⁺[(Ru/Os)Cl₃(CO)₃]^-₂.2H₂O, triclinic, space group P1, and of type 3, [(Fe/Co)(H₂O)₆]²⁺[RuI₃(CO)₃]^-₂.2H₂O, monoclinic, space group P2₁/c (Haukka et al., 2006; Jakonen et al., 2007). All these compounds share the [MX₃(CO)₃]^- (X = Cl, Br, I) double layer plus [M(H₂O)₆]²⁺ single layer architecture of the title compound with additional non-coordinated water molecules (structure types 2 and 3) being involved in the [M(H₂O)₆]²⁺ layers.

Related literature top

For the chemistry of FeBr₂(CO)₄, see: Hieber & Bader (1928); Robertson et al. (2000). For the syntheses and crystal structures of anologous compounds with [(Fe/Co/Ru)(H₂O)₆]²⁺ cations and [(Ru/Os)(Cl/I)₃(CO)₃]^- complexes, see: Allen (2002); Taimisto et al. (2003); Haukka et al. (2006); Jakonen et al. (2007).

Experimental top

The title compound was synthesized as follows: FeBr₂(CO)₄ (200 mg, 0.610 mmol; Hieber & Bader, 1928) was dissolved in wet benzene (20 ml, containing 1.67 mmol water) resulting in significant CO gas evolution. The solution was allowed to stand for 15 minutes until no further gas evolution was observed. The solution was set aside for about 1 h to give orange crystals of the title copound. Yield: 75 mg (40%).

Computing details top

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT (Bruker, 2003) and XPREP (Bruker, 2003); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL ((Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

	Fig. 1. Perspective view of the title compound with the atom numbering scheme. Atoms with primed labels are generated by inversion (-x,-y,-z). Displacement ellipsoids are at the 50% probability level.
	Fig. 2. Packing diagram of the title compound viewed down the a axis. [Fe(H₂O)₆] octahedra in green and stick bond representation, [FeBr₃(CO)₃] in ball-and-stick representation, hydrogen bonds shown as red broken lines.

Hexaaquairon(II) bis[fac-tribromidotricarbonylferrate(II)] top

Crystal data top

[Fe(H₂O)₆][FeBr₃(CO)₃]₂	F(000) = 1728
M_r = 923.17	D_x = 2.674 Mg m⁻³
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 4102 reflections
a = 11.9334 (8) Å	θ = 2.6–29.5°
b = 9.3394 (6) Å	µ = 12.37 mm⁻¹
c = 20.5775 (14) Å	T = 100 K
V = 2293.4 (3) Å³	Prism, brown
Z = 4	0.26 × 0.10 × 0.08 mm

Data collection top

Bruker SMART APEX CCD diffractometer	3316 independent reflections
Radiation source: fine-focus sealed tube	2674 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.061
ω and ϕ scans	θ_max = 30.0°, θ_min = 2.6°
Absorption correction: multi-scan (SADABS; Bruker, 2003)	h = −16→16
T_min = 0.15, T_max = 0.37	k = −12→12
24075 measured reflections	l = −28→28

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.034	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.070	H atoms treated by a mixture of independent and constrained refinement
S = 1.04	w = 1/[σ²(F_o²) + (0.0343P)²] where P = (F_o² + 2F_c²)/3
3316 reflections	(Δ/σ)_max = 0.001
145 parameters	Δρ_max = 0.98 e Å⁻³
18 restraints	Δρ_min = −0.68 e Å⁻³

Crystal data top

[Fe(H₂O)₆][FeBr₃(CO)₃]₂	V = 2293.4 (3) Å³
M_r = 923.17	Z = 4
Orthorhombic, Pbca	Mo Kα radiation
a = 11.9334 (8) Å	µ = 12.37 mm⁻¹
b = 9.3394 (6) Å	T = 100 K
c = 20.5775 (14) Å	0.26 × 0.10 × 0.08 mm

Data collection top

Bruker SMART APEX CCD diffractometer	3316 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2003)	2674 reflections with I > 2σ(I)
T_min = 0.15, T_max = 0.37	R_int = 0.061
24075 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.034	18 restraints
wR(F²) = 0.070	H atoms treated by a mixture of independent and constrained refinement
S = 1.04	Δρ_max = 0.98 e Å⁻³
3316 reflections	Δρ_min = −0.68 e Å⁻³
145 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Fe1	0.0000	0.0000	0.0000	0.01291 (15)
O1W	−0.0694 (2)	0.2102 (3)	0.00795 (12)	0.0182 (5)
O2W	0.1316 (2)	0.0750 (3)	−0.06090 (15)	0.0232 (6)
O3W	0.0994 (2)	0.0389 (3)	0.08220 (14)	0.0215 (6)
H1A	−0.077 (4)	0.227 (5)	0.0468 (10)	0.054 (12)*
H1B	−0.037 (4)	0.277 (4)	−0.010 (2)	0.054 (12)*
H2A	0.194 (2)	0.039 (4)	−0.067 (2)	0.052 (12)*
H2B	0.132 (4)	0.157 (3)	−0.075 (2)	0.052 (12)*
H3A	0.104 (4)	0.124 (2)	0.091 (2)	0.043 (11)*
H3B	0.161 (2)	0.001 (4)	0.086 (2)	0.043 (11)*
Fe2	−0.00342 (4)	0.48304 (5)	0.17284 (2)	0.01109 (11)
Br1	−0.09906 (3)	0.25138 (4)	0.168259 (17)	0.01518 (9)
Br2	−0.11162 (3)	0.57039 (4)	0.079096 (17)	0.01582 (9)
Br3	0.14630 (3)	0.39406 (4)	0.101623 (18)	0.01610 (9)
C1	0.0671 (3)	0.6547 (4)	0.17014 (16)	0.0147 (7)
O1	0.1100 (2)	0.7616 (3)	0.16509 (13)	0.0217 (6)
C2	0.0777 (3)	0.4172 (4)	0.24072 (18)	0.0146 (7)
O2	0.1272 (2)	0.3740 (3)	0.28314 (13)	0.0205 (6)
C3	−0.1149 (3)	0.5406 (3)	0.22633 (18)	0.0147 (7)
O3	−0.1840 (2)	0.5739 (3)	0.26062 (13)	0.0194 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Fe1	0.0130 (4)	0.0108 (3)	0.0149 (3)	0.0008 (3)	−0.0008 (3)	−0.0007 (3)
O1W	0.0231 (15)	0.0132 (12)	0.0182 (14)	0.0015 (11)	−0.0009 (11)	−0.0008 (10)
O2W	0.0206 (15)	0.0173 (13)	0.0317 (16)	0.0026 (12)	0.0083 (13)	0.0042 (12)
O3W	0.0220 (15)	0.0165 (13)	0.0260 (15)	0.0059 (11)	−0.0072 (12)	−0.0062 (11)
Fe2	0.0113 (2)	0.0102 (2)	0.0117 (2)	−0.00088 (19)	0.00038 (19)	−0.00026 (17)
Br1	0.01807 (18)	0.01203 (17)	0.01544 (17)	−0.00387 (13)	0.00183 (14)	−0.00048 (12)
Br2	0.01585 (18)	0.01523 (17)	0.01639 (17)	−0.00118 (13)	−0.00296 (14)	0.00300 (13)
Br3	0.01316 (18)	0.01727 (17)	0.01787 (18)	−0.00097 (14)	0.00263 (14)	−0.00377 (13)
C1	0.0114 (17)	0.0197 (18)	0.0131 (17)	0.0020 (14)	−0.0001 (13)	0.0008 (13)
O1	0.0247 (15)	0.0175 (14)	0.0229 (14)	−0.0057 (11)	0.0047 (11)	0.0014 (10)
C2	0.0141 (18)	0.0108 (15)	0.0188 (18)	−0.0040 (13)	0.0031 (14)	−0.0023 (13)
O2	0.0209 (14)	0.0191 (13)	0.0216 (14)	0.0000 (11)	−0.0051 (12)	0.0006 (10)
C3	0.0187 (19)	0.0087 (15)	0.0167 (18)	−0.0036 (13)	−0.0032 (14)	0.0016 (12)
O3	0.0188 (14)	0.0184 (13)	0.0209 (13)	0.0018 (11)	0.0031 (11)	−0.0011 (10)

Geometric parameters (Å, º) top

Fe1—O1W	2.137 (3)	O3W—H3B	0.821 (19)
Fe1—O2W	2.128 (3)	Fe2—C1	1.812 (4)
Fe1—O3W	2.098 (3)	Fe2—C2	1.807 (4)
Fe1—O1Wⁱ	2.137 (3)	Fe2—C3	1.808 (4)
Fe1—O2Wⁱ	2.128 (3)	Fe2—Br1	2.4479 (6)
Fe1—O3Wⁱ	2.098 (3)	Fe2—Br2	2.4605 (6)
O1W—H1A	0.821 (19)	Fe2—Br3	2.4558 (6)
O1W—H1B	0.821 (19)	C1—O1	1.126 (4)
O2W—H2A	0.821 (19)	C2—O2	1.128 (4)
O2W—H2B	0.821 (19)	C3—O3	1.129 (4)
O3W—H3A	0.821 (19)

O3W—Fe1—O3Wⁱ	180.00 (18)	Fe1—O3W—H3A	113 (3)
O3W—Fe1—O2Wⁱ	89.97 (12)	Fe1—O3W—H3B	121 (3)
O3Wⁱ—Fe1—O2Wⁱ	90.03 (12)	H3A—O3W—H3B	109 (3)
O3W—Fe1—O2W	90.03 (12)	C2—Fe2—C3	91.43 (16)
O3Wⁱ—Fe1—O2W	89.97 (12)	C2—Fe2—C1	94.35 (15)
O2Wⁱ—Fe1—O2W	180.00 (16)	C3—Fe2—C1	95.59 (15)
O3W—Fe1—O1W	89.91 (10)	C2—Fe2—Br1	88.80 (11)
O3Wⁱ—Fe1—O1W	90.09 (10)	C3—Fe2—Br1	86.75 (11)
O2Wⁱ—Fe1—O1W	88.35 (10)	C1—Fe2—Br1	176.03 (11)
O2W—Fe1—O1W	91.65 (10)	C2—Fe2—Br3	87.49 (11)
O3W—Fe1—O1Wⁱ	90.09 (10)	C3—Fe2—Br3	177.51 (11)
O3Wⁱ—Fe1—O1Wⁱ	89.91 (10)	C1—Fe2—Br3	86.74 (11)
O2Wⁱ—Fe1—O1Wⁱ	91.65 (10)	Br1—Fe2—Br3	90.981 (19)
O2W—Fe1—O1Wⁱ	88.35 (10)	C2—Fe2—Br2	178.97 (12)
O1W—Fe1—O1Wⁱ	180.00 (14)	C3—Fe2—Br2	89.57 (11)
Fe1—O1W—H1A	107 (3)	C1—Fe2—Br2	85.77 (11)
Fe1—O1W—H1B	119 (4)	Br1—Fe2—Br2	91.04 (2)
H1A—O1W—H1B	109 (3)	Br3—Fe2—Br2	91.50 (2)
Fe1—O2W—H2A	128 (3)	O1—C1—Fe2	176.4 (3)
Fe1—O2W—H2B	121 (3)	O2—C2—Fe2	178.8 (3)
H2A—O2W—H2B	109 (3)	O3—C3—Fe2	178.4 (3)

Symmetry code: (i) −x, −y, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1A···Br1	0.82 (2)	2.52 (2)	3.340 (3)	174 (4)
O1W—H1B···Br2ⁱⁱ	0.82 (2)	2.69 (2)	3.475 (3)	162 (5)
O2W—H2A···Br2ⁱⁱⁱ	0.82 (2)	2.55 (2)	3.373 (3)	177 (5)
O2W—H2B···Br2ⁱⁱ	0.82 (2)	2.56 (2)	3.341 (3)	160 (5)
O3W—H3A···Br3	0.82 (2)	2.58 (2)	3.388 (3)	169 (5)
O3W—H3B···Br3^iv	0.82 (2)	2.53 (2)	3.346 (3)	177 (4)

Symmetry codes: (ii) −x, −y+1, −z; (iii) x+1/2, −y+1/2, −z; (iv) −x+1/2, y−1/2, z.

Experimental details

Crystal data
Chemical formula	[Fe(H₂O)₆][FeBr₃(CO)₃]₂
M_r	923.17
Crystal system, space group	Orthorhombic, Pbca
Temperature (K)	100
a, b, c (Å)	11.9334 (8), 9.3394 (6), 20.5775 (14)
V (Å³)	2293.4 (3)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	12.37
Crystal size (mm)	0.26 × 0.10 × 0.08

Data collection
Diffractometer	Bruker SMART APEX CCD diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 2003)
T_min, T_max	0.15, 0.37
No. of measured, independent and observed [I > 2σ(I)] reflections	24075, 3316, 2674
R_int	0.061
(sin θ/λ)_max (Å⁻¹)	0.703

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.034, 0.070, 1.04
No. of reflections	3316
No. of parameters	145
No. of restraints	18
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρ_max, Δρ_min (e Å⁻³)	0.98, −0.68

Computer programs: SMART (Bruker, 2003), SAINT (Bruker, 2003) and XPREP (Bruker, 2003), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL ((Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Selected bond lengths (Å) top

Fe1—O1W	2.137 (3)	Fe2—C3	1.808 (4)
Fe1—O2W	2.128 (3)	Fe2—Br1	2.4479 (6)
Fe1—O3W	2.098 (3)	Fe2—Br2	2.4605 (6)
Fe2—C1	1.812 (4)	Fe2—Br3	2.4558 (6)
Fe2—C2	1.807 (4)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1A···Br1	0.821 (19)	2.52 (2)	3.340 (3)	174 (4)
O1W—H1B···Br2ⁱ	0.821 (19)	2.69 (2)	3.475 (3)	162 (5)
O2W—H2A···Br2ⁱⁱ	0.821 (19)	2.55 (2)	3.373 (3)	177 (5)
O2W—H2B···Br2ⁱ	0.821 (19)	2.56 (2)	3.341 (3)	160 (5)
O3W—H3A···Br3	0.821 (19)	2.58 (2)	3.388 (3)	169 (5)
O3W—H3B···Br3ⁱⁱⁱ	0.821 (19)	2.53 (2)	3.346 (3)	177 (4)

Symmetry codes: (i) −x, −y+1, −z; (ii) x+1/2, −y+1/2, −z; (iii) −x+1/2, y−1/2, z.

Acknowledgements

Financial support by the FWF Austrian Science Fund (project No. P16600-N11) is gratefully acknowledged.

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