Poly[[aqua­tris­(μ3-hexa­methyl­ene­tetra­mine-κ3N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]

Wu, H.; Shang, M.-X.; ShangGuan, S.-P.

doi:10.1107/S1600536810048567

metal-organic compounds

CRYSTALLOGRAPHIC
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ISSN: 2056-9890

Volume 66| Part 12| December 2010| Pages m1665-m1666

https://doi.org/10.1107/S1600536810048567

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Poly[[aquatris(μ₃-hexamethylenetetramine-κ³N,N′,N′′)tris(p-toluenesulfonato-κO)trisilver(I)] trihydrate]

Hua Wu,^a ^* Meng-Xiang Shang ^a and Shao-Ping ShangGuan ^a

^aHeilongjiang Agricultural Vocational and Technical College, JiaMuSi, HeiLongJiang 154007, People's Republic of China
^*Correspondence e-mail: hljwuhua@yahoo.com.cn

(Received 11 November 2010; accepted 22 November 2010; online 27 November 2010)

There are three Ag^I cations, three p-toluenesulfonate (pts) anions, three hexamethylenetetramine (hmt) molecules and four water molecules in the asymmetric unit of the title coordination polymer, {[Ag₃(C₇H₇O₃S)₃(C₆H₁₂N₄)₃(H₂O)]·3H₂O}_n. Two of the pts anions show positional disorder of their O atoms in 0.60:0.40 and 0.50:0.50 ratios. The Ag^I ion is coordinated by three hmt molecules in an approximate trigonal–planar AgN₃ arrangement. In each case, longer Ag—O bonds to a water molecule and a pts anion complete a distorted trigonal–bipyramidal AgN₃O₂ geometry for the metal ion. In the crystal, the bridging hmt molecules and pts ions generate a wave-like layer parallel to (001) and O—H⋯O hydrogen-bonding interactions consolidate the packing.

Related literature

For background to metal-coordination networks containing both sulfonate anions and N-bonded ligands, see: Côté & Shimizu (2003 ); Zhang et al. (2001 ).

Experimental

Crystal data

[Ag₃(C₇H₇O₃S)₃(C₆H₁₂N₄)₃(H₂O)]·3H₂O
M_r = 1329.82
Monoclinic, P 2₁ /n
a = 17.3181 (5) Å
b = 10.7028 (3) Å
c = 26.9110 (11) Å
β = 95.657 (3)°
V = 4963.7 (3) Å³
Z = 4
Mo Kα radiation
μ = 1.37 mm⁻¹
T = 293 K
0.30 × 0.25 × 0.22 mm

Data collection

Oxford Diffraction Gemini R Ultra diffractometer
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006 $[Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England.]$ ) T_min = 0.672, T_max = 0.728
21413 measured reflections
11446 independent reflections
7890 reflections with I > 2σ(I)
R_int = 0.021

Refinement

R[F² > 2σ(F²)] = 0.038
wR(F²) = 0.097
S = 0.99
11446 reflections
650 parameters
12 restraints
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.90 e Å⁻³
Δρ_min = −1.05 e Å⁻³

Table 1
Selected bond lengths (Å)

Ag1—N1	2.362 (2)
Ag1—N9ⁱ	2.367 (3)
Ag1—N10ⁱⁱ	2.388 (3)
Ag2—N5	2.347 (2)
Ag2—N7ⁱⁱ	2.365 (3)
Ag2—N4	2.374 (2)
Ag3—N3ⁱⁱ	2.315 (3)
Ag3—N8	2.358 (3)
Ag3—N11	2.394 (2)
Symmetry codes: (i) x-1, y, z; (ii) $[-x+{\script{3\over 2}}, y-{\script{1\over 2}}, -z+{\script{3\over 2}}]$ .

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1WA⋯O8ⁱⁱ	0.87 (2)	1.92 (2)	2.782 (5)	175 (4)
O1W—H1WB⋯O6ⁱⁱ	0.82 (2)	2.10 (2)	2.907 (4)	166 (4)
O2W—H2WA⋯O5ⁱⁱⁱ	0.83 (2)	2.16 (2)	2.958 (4)	163 (4)
O2W—H2WB⋯O1^iv	0.84 (2)	1.83 (3)	2.612 (6)	155 (4)
O3W—H3WA⋯O2^v	0.80 (2)	2.45 (3)	3.096 (7)	139 (4)
O3W—H3WB⋯O5	0.80 (2)	2.15 (2)	2.908 (5)	160 (4)
O4W—H4WB⋯O7ⁱⁱⁱ	0.88 (2)	1.99 (3)	2.838 (7)	160 (4)
Symmetry codes: (ii) $[-x+{\script{3\over 2}}, y-{\script{1\over 2}}, -z+{\script{3\over 2}}]$ ; (iii) $[-x+{\script{3\over 2}}, y+{\script{1\over 2}}, -z+{\script{3\over 2}}]$ ; (iv) x+1, y, z; (v) $[-x+{\script{1\over 2}}, y+{\script{1\over 2}}, -z+{\script{3\over 2}}]$ .

Data collection: CrysAlis CCD (Oxford Diffraction, 2006 $[Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England.]$ ); cell refinement: CrysAlis CCD; data reduction: CrysAlis RED (Oxford Diffraction, 2006 $[Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England.]$ ); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL-Plus (Sheldrick, 2008); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks I, global. DOI: https://doi.org/10.1107/S1600536810048567/hb5739sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536810048567/hb5739Isup2.hkl

checkCIF report

Comment top

Metal sulfonate complexes modified by different nitrogen-containing secondary ligands have been of great interest due to their abilities to form various structures, possible extended supramolecular system and good properties (Côté & Shimizu, 2003). Currently, there are some Ag^I sulfonate coordination polymers building from hexamethylenetetramine ligand because of its multidentate coordination mode (Zhang et al., 2001).

In the crystal structure of the title compound, C₃₉H₆₅Ag₃N₁₂O₁₃S₃, there are three Ag^I cations, three p-toluenesulfonate anions, three hexamethylenetetramine and four water molecules (Fig. 1). Ag1 cation is four-coordinated by three N atoms from three different hexamethylenetetramine ligands [Ag1—N1 = 2.362 (2), Ag1—N9ⁱ = 2.367 (2), and Ag1—N10ⁱⁱ = 2.388 (3)] and one O atom from one p-toluenesulfonate ligand [Ag1—O = 2.644 (6) Å] in a distorted tetrahedral coordination geometry. Ag2 cation is five-coordinated by three N atoms from three different hexamethylenetetramine ligands [Ag2—N5 = 2.347 (2), Ag2—N4 = 2.374 (2) and Ag2—N7ⁱⁱ = 2.365 (2) Å], one O atom from one p-toluenesulfonate ligand and one water molecule [Ag2—O4 = 2.622 (3) and Ag2—O1W = 2.622 (4) Å] in a trigonalbiyramid coordination geometry. Ag3 cation is also four-coordinated by three N atoms from hexamethylenetetramine ligands [Ag3—N3ⁱⁱ = 2.315 (3), Ag3—N8 = 2.358 (3), and Ag3—N11 = 2.394 (2) Å] and one p-toluenesulfonate ligand [Ag3—O9 = 2.438 (5) Å] in a distorted tetrahedral coordination geometry. The Ag^I cations are bridged by hexamethylenetetramine molecules in tridentate modes to generate a two dimensional wave like layer with the p-toluenesulfonate ligands hanged up and down (Fig. 2). The intermoleclar hydrogen bonding interactions consolidate the layer.

Related literature top

For background to metal-coordination networks containing both sulfonate anions and N-bonded ligands, see: Côté & Shimizu (2003); Zhang et al. (2001).

Experimental top

An aqueous solution (10 ml) of p-toluenesulfonic acid (0.038 g, 0.3 mmol) was added to solid Ag₂CO₃ (0.041 g, 0.15 mmol) and stirred for several stirred for several minutes until no further CO₂ was given off; and hexamethylenetetramine (0.028 g, 0.2 mmol) was added in. The white precipitate was dissolved by dropwise addition of an aqueous solution of NH₃ (14 M). Colourless blocks were obtained by evaporation of the solution for several days at room temperature.

Structure description top

For background to metal-coordination networks containing both sulfonate anions and N-bonded ligands, see: Côté & Shimizu (2003); Zhang et al. (2001).

Computing details top

Data collection: CrysAlis CCD (Oxford Diffraction, 2006); cell refinement: CrysAlis CCD (Oxford Diffraction, 2006); data reduction: CrysAlis RED (Oxford Diffraction, 2006); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL-Plus (Sheldrick, 2008); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level. [Symmetry codes: (i) x - 1, y, z; (ii) -x + 3/2, y - 1/2, -z + 3/2].
	Fig. 2. The two dimensional wave like layer of the title compound.

Poly[[aquatris(µ₃-hexamethylenetetramine- κ³N,N',N'')tris(p-toluenesulfonato- κO)trisilver(I)] trihydrate] top

Crystal data top

[Ag₃(C₇H₇O₃S)₃(C₆H₁₂N₄)₃(H₂O)]·3H₂O	F(000) = 2704
M_r = 1329.82	D_x = 1.779 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 11446 reflections
a = 17.3181 (5) Å	θ = 3.0–29.3°
b = 10.7028 (3) Å	µ = 1.37 mm⁻¹
c = 26.9110 (11) Å	T = 293 K
β = 95.657 (3)°	Block, colorless
V = 4963.7 (3) Å³	0.30 × 0.25 × 0.22 mm
Z = 4

Data collection top

Oxford Diffraction Gemini R Ultra diffractometer	11446 independent reflections
Radiation source: fine-focus sealed tube	7890 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.021
Detector resolution: 10.0 pixels mm^-1	θ_max = 29.3°, θ_min = 3.0°
ω scans	h = −23→19
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006)	k = −13→8
T_min = 0.672, T_max = 0.728	l = −24→36
21413 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.038	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.097	H atoms treated by a mixture of independent and constrained refinement
S = 0.99	w = 1/[σ²(F_o²) + (0.054P)²] where P = (F_o² + 2F_c²)/3
11446 reflections	(Δ/σ)_max = 0.002
650 parameters	Δρ_max = 0.90 e Å⁻³
12 restraints	Δρ_min = −1.05 e Å⁻³

Crystal data top

[Ag₃(C₇H₇O₃S)₃(C₆H₁₂N₄)₃(H₂O)]·3H₂O	V = 4963.7 (3) Å³
M_r = 1329.82	Z = 4
Monoclinic, P2₁/n	Mo Kα radiation
a = 17.3181 (5) Å	µ = 1.37 mm⁻¹
b = 10.7028 (3) Å	T = 293 K
c = 26.9110 (11) Å	0.30 × 0.25 × 0.22 mm
β = 95.657 (3)°

Data collection top

Oxford Diffraction Gemini R Ultra diffractometer	11446 independent reflections
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006)	7890 reflections with I > 2σ(I)
T_min = 0.672, T_max = 0.728	R_int = 0.021
21413 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.038	12 restraints
wR(F²) = 0.097	H atoms treated by a mixture of independent and constrained refinement
S = 0.99	Δρ_max = 0.90 e Å⁻³
11446 reflections	Δρ_min = −1.05 e Å⁻³
650 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ag1	0.314657 (14)	0.08332 (2)	0.713161 (11)	0.03692 (8)
Ag2	0.667686 (12)	0.06405 (2)	0.717069 (11)	0.03702 (8)
Ag3	1.009181 (14)	0.07397 (3)	0.816707 (13)	0.04627 (9)
C1	0.10904 (18)	0.1984 (3)	0.57691 (13)	0.0351 (8)
C2	0.1425 (2)	0.1533 (4)	0.53604 (14)	0.0463 (9)
H2	0.1955	0.1370	0.5383	0.056*
C3	0.0967 (3)	0.1325 (4)	0.49154 (15)	0.0538 (11)
H3	0.1199	0.1021	0.4642	0.065*
C4	0.0182 (3)	0.1555 (4)	0.48654 (15)	0.0530 (11)
C5	−0.0141 (2)	0.1996 (4)	0.52791 (17)	0.0565 (11)
H5	−0.0672	0.2149	0.5256	0.068*
C6	0.0298 (2)	0.2218 (4)	0.57274 (15)	0.0469 (10)
H6	0.0064	0.2523	0.6000	0.056*
C7	−0.0295 (3)	0.1341 (5)	0.43795 (17)	0.0801 (16)
H7A	−0.0827	0.1542	0.4414	0.120*
H7B	−0.0257	0.0480	0.4285	0.120*
H7C	−0.0108	0.1863	0.4127	0.120*
C8	1.03065 (19)	0.2536 (4)	0.96495 (12)	0.0377 (8)
C9	1.0778 (2)	0.1596 (4)	0.98513 (14)	0.0471 (10)
H9	1.0612	0.0769	0.9830	0.057*
C10	1.1501 (2)	0.1887 (5)	1.00856 (15)	0.0591 (12)
H10	1.1816	0.1252	1.0227	0.071*
C11	1.1766 (2)	0.3103 (6)	1.01136 (16)	0.0645 (13)
C12	1.1281 (3)	0.4044 (5)	0.99292 (17)	0.0628 (12)
H12	1.1443	0.4871	0.9960	0.075*
C13	1.0550 (2)	0.3767 (4)	0.96963 (15)	0.0506 (10)
H13	1.0223	0.4407	0.9572	0.061*
C14	1.2587 (3)	0.3412 (8)	1.0342 (2)	0.105 (2)
H14A	1.2669	0.4298	1.0328	0.157*
H14B	1.2957	0.2992	1.0157	0.157*
H14C	1.2651	0.3140	1.0683	0.157*
C15	0.6257 (2)	0.1507 (3)	0.89555 (14)	0.0399 (8)
C16	0.5692 (2)	0.0757 (4)	0.91222 (15)	0.0472 (9)
H16	0.5222	0.0651	0.8928	0.057*
C17	0.5822 (3)	0.0165 (4)	0.95755 (16)	0.0578 (11)
H17	0.5434	−0.0338	0.9685	0.069*
C18	0.6505 (3)	0.0297 (4)	0.98689 (17)	0.0608 (12)
C19	0.7078 (3)	0.1047 (5)	0.96987 (19)	0.0638 (12)
H19	0.7547	0.1148	0.9894	0.077*
C20	0.6959 (2)	0.1644 (4)	0.92434 (16)	0.0514 (10)
H20	0.7349	0.2136	0.9131	0.062*
C21	0.6636 (4)	−0.0304 (6)	1.03776 (19)	0.0922 (18)
H21A	0.7148	−0.0104	1.0526	0.138*
H21B	0.6585	−0.1194	1.0344	0.138*
H21C	0.6259	0.0003	1.0586	0.138*
C22	0.42034 (16)	0.3050 (3)	0.68223 (13)	0.0289 (7)
H22A	0.4236	0.3202	0.7179	0.035*
H22B	0.3727	0.3426	0.6672	0.035*
C23	0.41350 (18)	0.1495 (3)	0.61824 (13)	0.0340 (8)
H23A	0.4117	0.0605	0.6113	0.041*
H23B	0.3661	0.1866	0.6026	0.041*
C24	0.55120 (18)	0.1488 (3)	0.61999 (13)	0.0369 (8)
H24A	0.5952	0.1855	0.6057	0.044*
H24B	0.5510	0.0598	0.6131	0.044*
C25	0.55931 (16)	0.3047 (3)	0.68477 (13)	0.0290 (7)
H25A	0.6039	0.3428	0.6716	0.035*
H25B	0.5637	0.3189	0.7205	0.035*
C26	0.49138 (16)	0.1145 (3)	0.69615 (13)	0.0302 (7)
H26A	0.4958	0.1293	0.7319	0.036*
H26B	0.4907	0.0249	0.6908	0.036*
C27	0.48138 (19)	0.3383 (3)	0.60693 (13)	0.0386 (8)
H27A	0.4345	0.3764	0.5910	0.046*
H27B	0.5253	0.3755	0.5927	0.046*
C28	0.77641 (16)	0.2991 (3)	0.73890 (13)	0.0299 (7)
H28A	0.7571	0.2935	0.7715	0.036*
H28B	0.7382	0.3438	0.7169	0.036*
C29	0.84460 (16)	0.1052 (3)	0.75281 (14)	0.0316 (7)
H29A	0.8264	0.0977	0.7856	0.038*
H29B	0.8515	0.0216	0.7400	0.038*
C30	0.81468 (19)	0.1839 (3)	0.66969 (14)	0.0384 (8)
H30A	0.8211	0.1012	0.6559	0.046*
H30B	0.7767	0.2283	0.6474	0.046*
C31	0.94465 (18)	0.1821 (3)	0.70622 (15)	0.0424 (9)
H31A	0.9943	0.2245	0.7080	0.051*
H31B	0.9515	0.0990	0.6929	0.051*
C32	0.90727 (17)	0.2980 (3)	0.77631 (14)	0.0347 (8)
H32A	0.9563	0.3426	0.7797	0.042*
H32B	0.8892	0.2916	0.8092	0.042*
C33	0.87806 (19)	0.3752 (3)	0.69322 (14)	0.0385 (8)
H33A	0.8409	0.4213	0.6709	0.046*
H33B	0.9270	0.4199	0.6952	0.046*
C34	1.17915 (16)	0.1141 (3)	0.78134 (13)	0.0294 (7)
H34A	1.1504	0.1247	0.7488	0.035*
H34B	1.1854	0.0252	0.7875	0.035*
C35	1.29800 (17)	0.1580 (3)	0.83154 (13)	0.0333 (8)
H35A	1.3052	0.0697	0.8388	0.040*
H35B	1.3489	0.1960	0.8322	0.040*
C36	1.24515 (17)	0.3086 (3)	0.77130 (12)	0.0267 (7)
H36A	1.2953	0.3488	0.7711	0.032*
H36B	1.2170	0.3202	0.7387	0.032*
C37	1.18014 (18)	0.1554 (3)	0.86903 (13)	0.0340 (8)
H37A	1.1516	0.1921	0.8946	0.041*
H37B	1.1871	0.0672	0.8765	0.041*
C38	1.12622 (16)	0.3044 (3)	0.80919 (13)	0.0297 (7)
H38A	1.0974	0.3154	0.7767	0.036*
H38B	1.0966	0.3426	0.8339	0.036*
C39	1.24502 (18)	0.3481 (3)	0.85897 (13)	0.0334 (8)
H39A	1.2953	0.3883	0.8597	0.040*
H39B	1.2170	0.3865	0.8845	0.040*
O1'	0.1480 (4)	0.3411 (7)	0.6499 (3)	0.0744 (19)*	0.50
O1	0.1172 (3)	0.2996 (5)	0.66542 (19)	0.0419 (12)*	0.50
O2'	0.1309 (5)	0.1218 (9)	0.6678 (3)	0.108 (3)*	0.50
O2	0.1813 (3)	0.1080 (5)	0.6571 (2)	0.0513 (14)*	0.50
O1W	0.70784 (18)	−0.0600 (3)	0.63965 (14)	0.0704 (10)
O3'	0.2382 (4)	0.1850 (9)	0.6303 (3)	0.096 (2)*	0.50
O3	0.2377 (3)	0.2902 (6)	0.6240 (2)	0.0566 (14)*	0.50
O2W	1.06791 (15)	0.4929 (3)	0.71250 (11)	0.0543 (7)
O4	0.6619 (2)	0.1634 (3)	0.80569 (12)	0.0881 (12)
O3W	0.4316 (2)	0.4268 (4)	0.79689 (14)	0.0760 (10)
O5	0.53010 (19)	0.2102 (3)	0.81959 (11)	0.0735 (10)
O4W	0.6873 (2)	0.4746 (4)	0.62992 (15)	0.0830 (11)
O6	0.63193 (17)	0.3562 (3)	0.84465 (11)	0.0600 (8)
O7'	0.8959 (6)	0.1405 (12)	0.9688 (4)	0.109 (3)*	0.40
O7	0.9210 (3)	0.0947 (5)	0.9404 (2)	0.0670 (14)*	0.60
O8	0.89252 (18)	0.3193 (4)	0.93192 (15)	0.0903 (12)
O9	0.9709 (3)	0.2271 (5)	0.8767 (2)	0.0475 (13)*	0.50
O9'	0.9462 (6)	0.1437 (11)	0.8920 (4)	0.124 (3)*	0.50
S1	0.16466 (5)	0.22358 (10)	0.63466 (4)	0.0441 (2)
S2	0.61121 (6)	0.22628 (9)	0.83691 (4)	0.0481 (2)
S3	0.94276 (6)	0.21884 (11)	0.92946 (5)	0.0599 (3)
N1	0.41778 (13)	0.1693 (2)	0.67309 (10)	0.0260 (6)
N2	0.47982 (16)	0.2043 (3)	0.59677 (11)	0.0382 (7)
N3	0.48729 (13)	0.3647 (2)	0.66152 (10)	0.0280 (6)
N4	0.55957 (13)	0.1691 (2)	0.67493 (10)	0.0262 (6)
N5	0.78586 (13)	0.1722 (2)	0.71920 (10)	0.0280 (6)
N6	0.88871 (15)	0.2504 (3)	0.67246 (11)	0.0395 (7)
N7	0.85025 (13)	0.3702 (2)	0.74346 (11)	0.0298 (6)
N8	0.91990 (13)	0.1713 (2)	0.75711 (11)	0.0331 (7)
N9	1.25674 (13)	0.1725 (2)	0.78090 (10)	0.0258 (6)
N10	1.20165 (13)	0.3685 (2)	0.80957 (10)	0.0253 (5)
N11	1.13457 (13)	0.1694 (2)	0.81992 (10)	0.0276 (6)
N12	1.25592 (14)	0.2151 (3)	0.87016 (10)	0.0328 (6)
H1WA	0.6786 (17)	−0.097 (4)	0.6160 (12)	0.049*
H1WB	0.7504 (15)	−0.094 (4)	0.6411 (14)	0.049*
H2WA	1.042 (2)	0.549 (3)	0.6976 (14)	0.049*
H2WB	1.088 (2)	0.448 (3)	0.6915 (13)	0.049*
H3WA	0.425 (2)	0.485 (3)	0.8145 (14)	0.049*
H3WB	0.460 (2)	0.375 (3)	0.8101 (15)	0.049*
H4WA	0.7258 (14)	0.504 (4)	0.6231 (15)	0.049*
H4WB	0.6512 (16)	0.522 (4)	0.6144 (14)	0.049*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.03300 (13)	0.02596 (14)	0.05419 (18)	−0.00300 (10)	0.01635 (12)	−0.00403 (12)
Ag2	0.02446 (12)	0.02352 (13)	0.06195 (19)	−0.00263 (9)	−0.00151 (11)	0.00299 (13)
Ag3	0.03051 (13)	0.02299 (14)	0.0846 (2)	0.00125 (10)	0.00192 (13)	0.00676 (14)
C1	0.0398 (17)	0.0307 (19)	0.034 (2)	0.0014 (14)	−0.0005 (15)	0.0044 (16)
C2	0.048 (2)	0.045 (2)	0.046 (2)	−0.0009 (18)	0.0078 (18)	−0.0004 (19)
C3	0.082 (3)	0.047 (3)	0.034 (2)	−0.019 (2)	0.012 (2)	−0.0011 (19)
C4	0.074 (3)	0.037 (2)	0.045 (3)	−0.019 (2)	−0.012 (2)	0.0112 (19)
C5	0.041 (2)	0.063 (3)	0.062 (3)	−0.0016 (19)	−0.014 (2)	0.005 (2)
C6	0.0402 (18)	0.053 (3)	0.046 (2)	0.0076 (17)	−0.0029 (17)	−0.001 (2)
C7	0.113 (4)	0.068 (4)	0.052 (3)	−0.034 (3)	−0.027 (3)	0.017 (3)
C8	0.0446 (18)	0.041 (2)	0.0289 (19)	0.0084 (16)	0.0097 (15)	0.0040 (17)
C9	0.050 (2)	0.051 (3)	0.041 (2)	0.0123 (18)	0.0073 (18)	0.0049 (19)
C10	0.054 (2)	0.082 (4)	0.042 (2)	0.026 (2)	0.0055 (19)	0.010 (2)
C11	0.053 (2)	0.101 (4)	0.040 (3)	0.002 (3)	0.006 (2)	0.001 (3)
C12	0.069 (3)	0.063 (3)	0.057 (3)	−0.020 (2)	0.012 (2)	0.000 (2)
C13	0.057 (2)	0.045 (2)	0.050 (2)	0.0084 (19)	0.0067 (19)	0.009 (2)
C14	0.070 (3)	0.159 (7)	0.083 (4)	−0.020 (4)	−0.004 (3)	−0.016 (4)
C15	0.052 (2)	0.0293 (19)	0.040 (2)	0.0067 (16)	0.0141 (17)	−0.0023 (17)
C16	0.060 (2)	0.041 (2)	0.041 (2)	−0.0041 (18)	0.0108 (18)	0.0017 (19)
C17	0.084 (3)	0.045 (3)	0.047 (3)	0.002 (2)	0.018 (2)	0.011 (2)
C18	0.089 (3)	0.046 (3)	0.048 (3)	0.026 (2)	0.013 (2)	0.008 (2)
C19	0.068 (3)	0.055 (3)	0.066 (3)	0.022 (2)	−0.008 (2)	0.000 (2)
C20	0.051 (2)	0.046 (2)	0.059 (3)	0.0081 (18)	0.013 (2)	0.002 (2)
C21	0.141 (5)	0.075 (4)	0.058 (3)	0.022 (4)	0.001 (3)	0.029 (3)
C22	0.0247 (14)	0.0204 (16)	0.043 (2)	0.0010 (12)	0.0083 (14)	−0.0054 (14)
C23	0.0317 (16)	0.0312 (19)	0.038 (2)	−0.0032 (14)	−0.0018 (15)	−0.0071 (16)
C24	0.0321 (16)	0.036 (2)	0.045 (2)	0.0018 (14)	0.0124 (15)	−0.0059 (17)
C25	0.0249 (14)	0.0228 (16)	0.0388 (19)	−0.0020 (12)	0.0007 (13)	0.0013 (15)
C26	0.0277 (15)	0.0214 (16)	0.042 (2)	−0.0001 (12)	0.0031 (14)	0.0052 (15)
C27	0.0376 (17)	0.036 (2)	0.041 (2)	−0.0004 (15)	0.0019 (16)	0.0133 (17)
C28	0.0247 (14)	0.0209 (16)	0.045 (2)	−0.0018 (12)	0.0051 (14)	−0.0032 (15)
C29	0.0284 (15)	0.0175 (15)	0.049 (2)	−0.0039 (12)	0.0036 (14)	0.0021 (15)
C30	0.0391 (17)	0.0300 (19)	0.047 (2)	−0.0062 (14)	0.0077 (16)	−0.0074 (17)
C31	0.0277 (16)	0.0317 (19)	0.070 (3)	0.0022 (14)	0.0169 (17)	−0.0070 (19)
C32	0.0290 (15)	0.0192 (16)	0.054 (2)	−0.0006 (12)	−0.0035 (15)	−0.0016 (16)
C33	0.0324 (16)	0.0243 (17)	0.060 (2)	−0.0059 (14)	0.0101 (16)	0.0052 (17)
C34	0.0310 (15)	0.0217 (16)	0.0355 (19)	−0.0044 (12)	0.0032 (14)	−0.0023 (14)
C35	0.0260 (15)	0.0293 (18)	0.044 (2)	0.0036 (13)	−0.0010 (14)	0.0061 (16)
C36	0.0279 (14)	0.0200 (16)	0.0319 (18)	−0.0024 (12)	0.0017 (13)	0.0038 (14)
C37	0.0413 (18)	0.0284 (18)	0.0333 (19)	−0.0011 (14)	0.0083 (15)	0.0053 (15)
C38	0.0249 (14)	0.0253 (17)	0.0388 (19)	0.0015 (12)	0.0022 (13)	0.0016 (15)
C39	0.0340 (16)	0.0301 (18)	0.036 (2)	−0.0040 (14)	0.0019 (14)	−0.0043 (16)
O1W	0.0576 (18)	0.065 (2)	0.087 (3)	0.0022 (16)	0.0022 (17)	−0.0355 (19)
O2W	0.0479 (16)	0.061 (2)	0.0547 (19)	0.0042 (14)	0.0067 (13)	−0.0006 (16)
O4	0.155 (3)	0.054 (2)	0.067 (2)	−0.031 (2)	0.069 (2)	−0.0153 (17)
O3W	0.072 (2)	0.080 (3)	0.072 (3)	−0.0049 (19)	−0.0161 (19)	−0.003 (2)
O5	0.088 (2)	0.079 (2)	0.0488 (18)	−0.0349 (19)	−0.0164 (16)	0.0206 (17)
O4W	0.064 (2)	0.089 (3)	0.098 (3)	−0.003 (2)	0.018 (2)	0.047 (2)
O6	0.088 (2)	0.0288 (15)	0.0622 (19)	−0.0083 (14)	0.0010 (15)	0.0022 (14)
O8	0.0663 (19)	0.076 (3)	0.123 (3)	0.0312 (18)	−0.021 (2)	−0.020 (2)
S1	0.0402 (5)	0.0503 (6)	0.0398 (5)	0.0153 (4)	−0.0062 (4)	−0.0039 (5)
S2	0.0757 (6)	0.0340 (5)	0.0365 (5)	−0.0147 (5)	0.0151 (5)	−0.0004 (4)
S3	0.0599 (6)	0.0515 (7)	0.0640 (7)	0.0196 (5)	−0.0161 (5)	−0.0143 (6)
N1	0.0223 (11)	0.0190 (13)	0.0370 (16)	−0.0010 (10)	0.0041 (11)	−0.0018 (12)
N2	0.0402 (15)	0.0409 (18)	0.0337 (16)	0.0007 (13)	0.0051 (13)	−0.0021 (14)
N3	0.0253 (12)	0.0176 (13)	0.0416 (17)	−0.0008 (10)	0.0059 (11)	0.0019 (12)
N4	0.0200 (11)	0.0194 (13)	0.0393 (16)	−0.0001 (10)	0.0037 (11)	0.0003 (12)
N5	0.0218 (11)	0.0210 (13)	0.0412 (17)	−0.0042 (10)	0.0027 (11)	−0.0024 (12)
N6	0.0364 (14)	0.0339 (17)	0.0500 (19)	−0.0061 (13)	0.0140 (13)	−0.0014 (15)
N7	0.0211 (12)	0.0187 (13)	0.0487 (18)	−0.0009 (10)	−0.0002 (12)	−0.0014 (13)
N8	0.0220 (12)	0.0204 (14)	0.057 (2)	0.0025 (10)	0.0030 (12)	−0.0024 (13)
N9	0.0237 (12)	0.0189 (13)	0.0351 (16)	0.0001 (10)	0.0049 (11)	0.0012 (12)
N10	0.0238 (11)	0.0223 (13)	0.0295 (15)	−0.0006 (10)	0.0011 (11)	−0.0004 (12)
N11	0.0242 (12)	0.0230 (14)	0.0358 (16)	−0.0018 (10)	0.0036 (11)	0.0014 (12)
N12	0.0312 (13)	0.0338 (16)	0.0325 (16)	0.0013 (12)	−0.0016 (12)	0.0067 (13)

Geometric parameters (Å, º) top

Ag1—N1	2.362 (2)	C28—N7	1.483 (4)
Ag1—N9ⁱ	2.367 (3)	C28—H28A	0.9700
Ag1—N10ⁱⁱ	2.388 (3)	C28—H28B	0.9700
Ag2—N5	2.347 (2)	C29—N8	1.478 (4)
Ag2—N7ⁱⁱ	2.365 (3)	C29—N5	1.478 (4)
Ag2—N4	2.374 (2)	C29—H29A	0.9700
Ag3—N3ⁱⁱ	2.315 (3)	C29—H29B	0.9700
Ag3—N8	2.358 (3)	C30—N6	1.462 (4)
Ag3—N11	2.394 (2)	C30—N5	1.474 (4)
Ag3—O9	2.438 (5)	C30—H30A	0.9700
Ag3—O9'	2.507 (11)	C30—H30B	0.9700
C1—C2	1.380 (5)	C31—N6	1.458 (5)
C1—C6	1.389 (5)	C31—N8	1.479 (5)
C1—S1	1.767 (3)	C31—H31A	0.9700
C2—C3	1.388 (6)	C31—H31B	0.9700
C2—H2	0.9300	C32—N8	1.475 (4)
C3—C4	1.375 (6)	C32—N7	1.477 (4)
C3—H3	0.9300	C32—H32A	0.9700
C4—C5	1.378 (6)	C32—H32B	0.9700
C4—C7	1.494 (6)	C33—N6	1.467 (4)
C5—C6	1.381 (6)	C33—N7	1.480 (4)
C5—H5	0.9300	C33—H33A	0.9700
C6—H6	0.9300	C33—H33B	0.9700
C7—H7A	0.9600	C34—N11	1.477 (4)
C7—H7B	0.9600	C34—N9	1.483 (4)
C7—H7C	0.9600	C34—H34A	0.9700
C8—C9	1.374 (5)	C34—H34B	0.9700
C8—C13	1.385 (5)	C35—N12	1.461 (4)
C8—S3	1.755 (4)	C35—N9	1.483 (4)
C9—C10	1.381 (6)	C35—H35A	0.9700
C9—H9	0.9300	C35—H35B	0.9700
C10—C11	1.379 (7)	C36—N10	1.481 (4)
C10—H10	0.9300	C36—N9	1.489 (4)
C11—C12	1.372 (7)	C36—H36A	0.9700
C11—C14	1.529 (6)	C36—H36B	0.9700
C12—C13	1.388 (6)	C37—N12	1.458 (4)
C12—H12	0.9300	C37—N11	1.479 (4)
C13—H13	0.9300	C37—H37A	0.9700
C14—H14A	0.9600	C37—H37B	0.9700
C14—H14B	0.9600	C38—N10	1.475 (4)
C14—H14C	0.9600	C38—N11	1.477 (4)
C15—C16	1.374 (5)	C38—H38A	0.9700
C15—C20	1.384 (5)	C38—H38B	0.9700
C15—S2	1.769 (4)	C39—N12	1.463 (4)
C16—C17	1.373 (6)	C39—N10	1.477 (4)
C16—H16	0.9300	C39—H39A	0.9700
C17—C18	1.364 (6)	C39—H39B	0.9700
C17—H17	0.9300	O1'—O1	0.837 (7)
C18—C19	1.388 (7)	O1'—S1	1.363 (7)
C18—C21	1.509 (6)	O1—S1	1.469 (5)
C19—C20	1.379 (6)	O2'—O2	0.956 (9)
C19—H19	0.9300	O2'—S1	1.558 (10)
C20—H20	0.9300	O2—S1	1.394 (6)
C21—H21A	0.9600	O2—O3'	1.520 (10)
C21—H21B	0.9600	O1W—H1WA	0.87 (2)
C21—H21C	0.9600	O1W—H1WB	0.82 (2)
C22—N1	1.473 (4)	O3'—O3	1.139 (9)
C22—N3	1.480 (4)	O3'—S1	1.354 (8)
C22—H22A	0.9700	O3—S1	1.504 (6)
C22—H22B	0.9700	O2W—H2WA	0.83 (2)
C23—N2	1.459 (4)	O2W—H2WB	0.84 (2)
C23—N1	1.486 (4)	O4—S2	1.441 (3)
C23—H23A	0.9700	O3W—H3WA	0.80 (2)
C23—H23B	0.9700	O3W—H3WB	0.80 (2)
C24—N2	1.456 (4)	O5—S2	1.446 (3)
C24—N4	1.487 (4)	O4W—H4WA	0.78 (2)
C24—H24A	0.9700	O4W—H4WB	0.88 (2)
C24—H24B	0.9700	O6—S2	1.446 (3)
C25—N4	1.476 (4)	O7'—O7	1.036 (11)
C25—N3	1.485 (4)	O7'—S3	1.628 (12)
C25—H25A	0.9700	O7—S3	1.420 (6)
C25—H25B	0.9700	O7—O9'	1.509 (12)
C26—N4	1.481 (4)	O8—S3	1.389 (3)
C26—N1	1.482 (4)	O9—O9'	1.089 (11)
C26—H26A	0.9700	O9—S3	1.549 (5)
C26—H26B	0.9700	O9'—S3	1.296 (11)
C27—N2	1.460 (5)	N3—Ag3ⁱⁱⁱ	2.315 (3)
C27—N3	1.489 (4)	N7—Ag2ⁱⁱⁱ	2.365 (3)
C27—H27A	0.9700	N9—Ag1^iv	2.367 (2)
C27—H27B	0.9700	N10—Ag1ⁱⁱⁱ	2.388 (3)
C28—N5	1.474 (4)

N1—Ag1—N9ⁱ	126.27 (9)	N9—C34—H34B	109.2
N1—Ag1—N10ⁱⁱ	109.49 (8)	H34A—C34—H34B	107.9
N9ⁱ—Ag1—N10ⁱⁱ	122.48 (8)	N12—C35—N9	112.4 (2)
N5—Ag2—N7ⁱⁱ	125.05 (9)	N12—C35—H35A	109.1
N5—Ag2—N4	115.03 (9)	N9—C35—H35A	109.1
N7ⁱⁱ—Ag2—N4	119.83 (8)	N12—C35—H35B	109.1
N3ⁱⁱ—Ag3—N8	126.79 (9)	N9—C35—H35B	109.1
N3ⁱⁱ—Ag3—N11	113.74 (8)	H35A—C35—H35B	107.9
N8—Ag3—N11	111.58 (9)	N10—C36—N9	111.9 (2)
N3ⁱⁱ—Ag3—O9	119.04 (15)	N10—C36—H36A	109.2
N8—Ag3—O9	87.16 (14)	N9—C36—H36A	109.2
N11—Ag3—O9	89.64 (14)	N10—C36—H36B	109.2
N3ⁱⁱ—Ag3—O9'	94.9 (3)	N9—C36—H36B	109.2
N8—Ag3—O9'	96.3 (2)	H36A—C36—H36B	107.9
N11—Ag3—O9'	108.0 (3)	N12—C37—N11	112.0 (3)
O9—Ag3—O9'	25.4 (3)	N12—C37—H37A	109.2
C2—C1—C6	119.2 (3)	N11—C37—H37A	109.2
C2—C1—S1	121.3 (3)	N12—C37—H37B	109.2
C6—C1—S1	119.5 (3)	N11—C37—H37B	109.2
C1—C2—C3	119.6 (4)	H37A—C37—H37B	107.9
C1—C2—H2	120.2	N10—C38—N11	112.6 (2)
C3—C2—H2	120.2	N10—C38—H38A	109.1
C4—C3—C2	122.1 (4)	N11—C38—H38A	109.1
C4—C3—H3	119.0	N10—C38—H38B	109.1
C2—C3—H3	119.0	N11—C38—H38B	109.1
C3—C4—C5	117.3 (4)	H38A—C38—H38B	107.8
C3—C4—C7	121.0 (4)	N12—C39—N10	111.9 (3)
C5—C4—C7	121.7 (4)	N12—C39—H39A	109.2
C4—C5—C6	122.2 (4)	N10—C39—H39A	109.2
C4—C5—H5	118.9	N12—C39—H39B	109.2
C6—C5—H5	118.9	N10—C39—H39B	109.2
C5—C6—C1	119.5 (4)	H39A—C39—H39B	107.9
C5—C6—H6	120.2	O1—O1'—S1	79.9 (7)
C1—C6—H6	120.2	O1'—O1—S1	66.0 (6)
C4—C7—H7A	109.5	O2—O2'—S1	62.0 (7)
C4—C7—H7B	109.5	O2'—O2—S1	80.7 (7)
H7A—C7—H7B	109.5	O2'—O2—O3'	135.4 (9)
C4—C7—H7C	109.5	S1—O2—O3'	55.2 (4)
H7A—C7—H7C	109.5	H1WA—O1W—H1WB	107 (3)
H7B—C7—H7C	109.5	O3—O3'—S1	73.6 (6)
C9—C8—C13	119.8 (4)	O3—O3'—O2	127.6 (7)
C9—C8—S3	120.6 (3)	S1—O3'—O2	57.7 (4)
C13—C8—S3	119.4 (3)	O3'—O3—S1	59.8 (5)
C8—C9—C10	119.4 (4)	H2WA—O2W—H2WB	109 (3)
C8—C9—H9	120.3	H3WA—O3W—H3WB	113 (4)
C10—C9—H9	120.3	H4WA—O4W—H4WB	104 (3)
C11—C10—C9	121.3 (4)	O7—O7'—S3	59.6 (7)
C11—C10—H10	119.4	O7'—O7—S3	81.4 (8)
C9—C10—H10	119.4	O7'—O7—O9'	130.5 (10)
C12—C11—C10	119.0 (4)	S3—O7—O9'	52.4 (5)
C12—C11—C14	119.9 (6)	O9'—O9—S3	55.6 (6)
C10—C11—C14	121.1 (5)	O9'—O9—Ag3	80.9 (7)
C11—C12—C13	120.3 (5)	S3—O9—Ag3	134.4 (3)
C11—C12—H12	119.9	O9—O9'—S3	80.5 (8)
C13—C12—H12	119.9	O9—O9'—O7	140.3 (10)
C8—C13—C12	120.0 (4)	S3—O9'—O7	60.2 (5)
C8—C13—H13	120.0	O9—O9'—Ag3	73.7 (6)
C12—C13—H13	120.0	S3—O9'—Ag3	150.6 (7)
C11—C14—H14A	109.5	O7—O9'—Ag3	141.3 (7)
C11—C14—H14B	109.5	O3'—S1—O1'	122.4 (5)
H14A—C14—H14B	109.5	O3'—S1—O2	67.1 (4)
C11—C14—H14C	109.5	O1'—S1—O2	136.8 (4)
H14A—C14—H14C	109.5	O3'—S1—O1	143.2 (4)
H14B—C14—H14C	109.5	O1'—S1—O1	34.1 (3)
C16—C15—C20	119.6 (4)	O2—S1—O1	110.5 (3)
C16—C15—S2	121.0 (3)	O3'—S1—O3	46.6 (4)
C20—C15—S2	119.4 (3)	O1'—S1—O3	80.0 (4)
C17—C16—C15	120.0 (4)	O2—S1—O3	111.2 (3)
C17—C16—H16	120.0	O1—S1—O3	111.8 (3)
C15—C16—H16	120.0	O3'—S1—O2'	104.2 (5)
C18—C17—C16	121.5 (4)	O1'—S1—O2'	111.7 (5)
C18—C17—H17	119.2	O2—S1—O2'	37.3 (3)
C16—C17—H17	119.2	O1—S1—O2'	78.6 (4)
C17—C18—C19	118.4 (4)	O3—S1—O2'	144.1 (4)
C17—C18—C21	121.7 (5)	O3'—S1—C1	108.2 (4)
C19—C18—C21	119.8 (5)	O1'—S1—C1	107.0 (3)
C20—C19—C18	120.9 (4)	O2—S1—C1	108.5 (3)
C20—C19—H19	119.6	O1—S1—C1	107.1 (2)
C18—C19—H19	119.6	O3—S1—C1	107.5 (2)
C19—C20—C15	119.6 (4)	O2'—S1—C1	101.2 (4)
C19—C20—H20	120.2	O4—S2—O5	112.7 (2)
C15—C20—H20	120.2	O4—S2—O6	112.10 (18)
C18—C21—H21A	109.5	O5—S2—O6	112.3 (2)
C18—C21—H21B	109.5	O4—S2—C15	105.4 (2)
H21A—C21—H21B	109.5	O5—S2—C15	106.32 (17)
C18—C21—H21C	109.5	O6—S2—C15	107.46 (17)
H21A—C21—H21C	109.5	O9'—S3—O8	126.5 (5)
H21B—C21—H21C	109.5	O9'—S3—O7	67.3 (6)
N1—C22—N3	112.0 (2)	O8—S3—O7	122.3 (3)
N1—C22—H22A	109.2	O9'—S3—O9	43.9 (5)
N3—C22—H22A	109.2	O8—S3—O9	104.8 (3)
N1—C22—H22B	109.2	O7—S3—O9	111.0 (3)
N3—C22—H22B	109.2	O9'—S3—O7'	104.5 (7)
H22A—C22—H22B	107.9	O8—S3—O7'	90.8 (5)
N2—C23—N1	111.8 (3)	O7—S3—O7'	39.0 (4)
N2—C23—H23A	109.2	O9—S3—O7'	147.9 (5)
N1—C23—H23A	109.2	O9'—S3—C8	116.8 (4)
N2—C23—H23B	109.2	O8—S3—C8	108.9 (2)
N1—C23—H23B	109.2	O7—S3—C8	108.6 (3)
H23A—C23—H23B	107.9	O9—S3—C8	98.7 (2)
N2—C24—N4	111.3 (2)	O7'—S3—C8	102.5 (4)
N2—C24—H24A	109.4	C22—N1—C26	108.0 (2)
N4—C24—H24A	109.4	C22—N1—C23	107.7 (3)
N2—C24—H24B	109.4	C26—N1—C23	108.4 (2)
N4—C24—H24B	109.4	C22—N1—Ag1	108.63 (17)
H24A—C24—H24B	108.0	C26—N1—Ag1	108.22 (18)
N4—C25—N3	111.5 (2)	C23—N1—Ag1	115.60 (18)
N4—C25—H25A	109.3	C24—N2—C23	109.5 (3)
N3—C25—H25A	109.3	C24—N2—C27	108.7 (3)
N4—C25—H25B	109.3	C23—N2—C27	108.8 (3)
N3—C25—H25B	109.3	C22—N3—C25	108.1 (2)
H25A—C25—H25B	108.0	C22—N3—C27	108.0 (2)
N4—C26—N1	111.6 (2)	C25—N3—C27	107.9 (2)
N4—C26—H26A	109.3	C22—N3—Ag3ⁱⁱⁱ	108.95 (17)
N1—C26—H26A	109.3	C25—N3—Ag3ⁱⁱⁱ	108.15 (18)
N4—C26—H26B	109.3	C27—N3—Ag3ⁱⁱⁱ	115.50 (19)
N1—C26—H26B	109.3	C25—N4—C26	107.6 (2)
H26A—C26—H26B	108.0	C25—N4—C24	108.7 (3)
N2—C27—N3	111.7 (3)	C26—N4—C24	108.8 (2)
N2—C27—H27A	109.3	C25—N4—Ag2	113.34 (17)
N3—C27—H27A	109.3	C26—N4—Ag2	104.51 (18)
N2—C27—H27B	109.3	C24—N4—Ag2	113.63 (18)
N3—C27—H27B	109.3	C30—N5—C28	107.9 (2)
H27A—C27—H27B	107.9	C30—N5—C29	108.7 (2)
N5—C28—N7	112.2 (2)	C28—N5—C29	108.7 (2)
N5—C28—H28A	109.2	C30—N5—Ag2	113.08 (18)
N7—C28—H28A	109.2	C28—N5—Ag2	109.63 (16)
N5—C28—H28B	109.2	C29—N5—Ag2	108.77 (18)
N7—C28—H28B	109.2	C31—N6—C30	108.2 (3)
H28A—C28—H28B	107.9	C31—N6—C33	108.7 (3)
N8—C29—N5	111.4 (2)	C30—N6—C33	108.7 (2)
N8—C29—H29A	109.4	C32—N7—C33	107.9 (2)
N5—C29—H29A	109.4	C32—N7—C28	107.5 (2)
N8—C29—H29B	109.4	C33—N7—C28	107.4 (3)
N5—C29—H29B	109.4	C32—N7—Ag2ⁱⁱⁱ	107.44 (19)
H29A—C29—H29B	108.0	C33—N7—Ag2ⁱⁱⁱ	116.58 (19)
N6—C30—N5	111.6 (3)	C28—N7—Ag2ⁱⁱⁱ	109.70 (17)
N6—C30—H30A	109.3	C32—N8—C29	107.9 (2)
N5—C30—H30A	109.3	C32—N8—C31	108.6 (3)
N6—C30—H30B	109.3	C29—N8—C31	107.4 (3)
N5—C30—H30B	109.3	C32—N8—Ag3	106.1 (2)
H30A—C30—H30B	108.0	C29—N8—Ag3	110.9 (2)
N6—C31—N8	112.4 (2)	C31—N8—Ag3	115.70 (18)
N6—C31—H31A	109.1	C34—N9—C35	107.7 (2)
N8—C31—H31A	109.1	C34—N9—C36	107.9 (2)
N6—C31—H31B	109.1	C35—N9—C36	107.8 (2)
N8—C31—H31B	109.1	C34—N9—Ag1^iv	106.83 (18)
H31A—C31—H31B	107.9	C35—N9—Ag1^iv	117.58 (17)
N8—C32—N7	112.6 (3)	C36—N9—Ag1^iv	108.72 (18)
N8—C32—H32A	109.1	C38—N10—C39	108.0 (2)
N7—C32—H32A	109.1	C38—N10—C36	107.7 (2)
N8—C32—H32B	109.1	C39—N10—C36	108.3 (2)
N7—C32—H32B	109.1	C38—N10—Ag1ⁱⁱⁱ	111.35 (17)
H32A—C32—H32B	107.8	C39—N10—Ag1ⁱⁱⁱ	114.17 (19)
N6—C33—N7	112.3 (3)	C36—N10—Ag1ⁱⁱⁱ	107.13 (18)
N6—C33—H33A	109.1	C34—N11—C38	107.6 (2)
N7—C33—H33A	109.1	C34—N11—C37	108.5 (2)
N6—C33—H33B	109.1	C38—N11—C37	107.9 (2)
N7—C33—H33B	109.1	C34—N11—Ag3	109.81 (18)
H33A—C33—H33B	107.9	C38—N11—Ag3	109.83 (16)
N11—C34—N9	111.9 (2)	C37—N11—Ag3	113.03 (18)
N11—C34—H34A	109.2	C37—N12—C35	108.2 (3)
N9—C34—H34A	109.2	C37—N12—C39	109.0 (2)
N11—C34—H34B	109.2	C35—N12—C39	108.9 (3)

C6—C1—C2—C3	0.2 (6)	O7—O7'—S3—O9	26.1 (12)
S1—C1—C2—C3	178.8 (3)	O7—O7'—S3—C8	−104.2 (6)
C1—C2—C3—C4	0.0 (6)	C9—C8—S3—O9'	−54.3 (7)
C2—C3—C4—C5	−0.5 (6)	C13—C8—S3—O9'	121.2 (6)
C2—C3—C4—C7	179.1 (4)	C9—C8—S3—O8	154.4 (3)
C3—C4—C5—C6	0.8 (7)	C13—C8—S3—O8	−30.1 (4)
C7—C4—C5—C6	−178.8 (4)	C9—C8—S3—O7	19.1 (4)
C4—C5—C6—C1	−0.5 (7)	C13—C8—S3—O7	−165.4 (4)
C2—C1—C6—C5	0.0 (6)	C9—C8—S3—O9	−96.6 (4)
S1—C1—C6—C5	−178.6 (3)	C13—C8—S3—O9	78.9 (4)
C13—C8—C9—C10	−2.0 (5)	C9—C8—S3—O7'	59.2 (5)
S3—C8—C9—C10	173.5 (3)	C13—C8—S3—O7'	−125.3 (5)
C8—C9—C10—C11	−1.2 (6)	N3—C22—N1—C26	58.5 (3)
C9—C10—C11—C12	3.7 (6)	N3—C22—N1—C23	−58.4 (3)
C9—C10—C11—C14	−175.8 (4)	N3—C22—N1—Ag1	175.7 (2)
C10—C11—C12—C13	−3.1 (7)	N4—C26—N1—C22	−59.4 (3)
C14—C11—C12—C13	176.4 (4)	N4—C26—N1—C23	57.0 (3)
C9—C8—C13—C12	2.5 (6)	N4—C26—N1—Ag1	−176.8 (2)
S3—C8—C13—C12	−173.0 (3)	N2—C23—N1—C22	59.0 (3)
C11—C12—C13—C8	0.0 (6)	N2—C23—N1—C26	−57.7 (3)
C20—C15—C16—C17	1.0 (6)	N2—C23—N1—Ag1	−179.3 (2)
S2—C15—C16—C17	179.0 (3)	N9ⁱ—Ag1—N1—C22	−22.2 (2)
C15—C16—C17—C18	−0.2 (6)	N10ⁱⁱ—Ag1—N1—C22	172.70 (19)
C16—C17—C18—C19	−0.3 (7)	N9ⁱ—Ag1—N1—C26	94.8 (2)
C16—C17—C18—C21	177.1 (4)	N10ⁱⁱ—Ag1—N1—C26	−70.3 (2)
C17—C18—C19—C20	−0.1 (7)	N9ⁱ—Ag1—N1—C23	−143.4 (2)
C21—C18—C19—C20	−177.5 (4)	N10ⁱⁱ—Ag1—N1—C23	51.5 (2)
C18—C19—C20—C15	0.8 (6)	N4—C24—N2—C23	−59.0 (4)
C16—C15—C20—C19	−1.3 (6)	N4—C24—N2—C27	59.8 (3)
S2—C15—C20—C19	−179.4 (3)	N1—C23—N2—C24	59.1 (4)
S1—O2'—O2—O3'	7.9 (10)	N1—C23—N2—C27	−59.7 (3)
O2'—O2—O3'—O3	15.1 (17)	N3—C27—N2—C24	−60.2 (3)
S1—O2—O3'—O3	24.6 (8)	N3—C27—N2—C23	59.0 (3)
O2'—O2—O3'—S1	−9.5 (12)	N1—C22—N3—C25	−58.4 (3)
O2—O3'—O3—S1	−21.5 (6)	N1—C22—N3—C27	58.1 (3)
S3—O7'—O7—O9'	−19.8 (9)	N1—C22—N3—Ag3ⁱⁱⁱ	−175.7 (2)
N3ⁱⁱ—Ag3—O9—O9'	−20.0 (6)	N4—C25—N3—C22	59.0 (3)
N8—Ag3—O9—O9'	111.2 (6)	N4—C25—N3—C27	−57.6 (3)
N11—Ag3—O9—O9'	−137.2 (6)	N4—C25—N3—Ag3ⁱⁱⁱ	176.85 (19)
N3ⁱⁱ—Ag3—O9—S3	−3.3 (4)	N2—C27—N3—C22	−58.0 (3)
N8—Ag3—O9—S3	127.9 (4)	N2—C27—N3—C25	58.7 (3)
N11—Ag3—O9—S3	−120.5 (4)	N2—C27—N3—Ag3ⁱⁱⁱ	179.78 (19)
O9'—Ag3—O9—S3	16.7 (5)	N3—C25—N4—C26	−59.8 (3)
Ag3—O9—O9'—S3	165.5 (4)	N3—C25—N4—C24	57.9 (3)
S3—O9—O9'—O7	−8.3 (10)	N3—C25—N4—Ag2	−174.78 (18)
Ag3—O9—O9'—O7	157.3 (14)	N1—C26—N4—C25	60.1 (3)
S3—O9—O9'—Ag3	−165.5 (4)	N1—C26—N4—C24	−57.5 (3)
O7'—O7—O9'—O9	34 (2)	N1—C26—N4—Ag2	−179.2 (2)
S3—O7—O9'—O9	9.4 (12)	N2—C24—N4—C25	−58.8 (3)
O7'—O7—O9'—S3	25.1 (11)	N2—C24—N4—C26	58.1 (3)
O7'—O7—O9'—Ag3	178.1 (10)	N2—C24—N4—Ag2	174.1 (2)
S3—O7—O9'—Ag3	153.0 (11)	N5—Ag2—N4—C25	−39.8 (2)
N3ⁱⁱ—Ag3—O9'—O9	162.5 (6)	N7ⁱⁱ—Ag2—N4—C25	136.98 (19)
N8—Ag3—O9'—O9	−69.6 (6)	N5—Ag2—N4—C26	−156.63 (18)
N11—Ag3—O9'—O9	45.6 (6)	N7ⁱⁱ—Ag2—N4—C26	20.2 (2)
N3ⁱⁱ—Ag3—O9'—S3	132.5 (14)	N5—Ag2—N4—C24	84.9 (2)
N8—Ag3—O9'—S3	−99.6 (14)	N7ⁱⁱ—Ag2—N4—C24	−98.3 (2)
N11—Ag3—O9'—S3	15.5 (15)	N6—C30—N5—C28	59.2 (3)
O9—Ag3—O9'—S3	−30.1 (10)	N6—C30—N5—C29	−58.5 (3)
N3ⁱⁱ—Ag3—O9'—O7	5.8 (10)	N6—C30—N5—Ag2	−179.4 (2)
N8—Ag3—O9'—O7	133.7 (9)	N7—C28—N5—C30	−59.2 (3)
N11—Ag3—O9'—O7	−111.2 (9)	N7—C28—N5—C29	58.5 (3)
O9—Ag3—O9'—O7	−156.8 (14)	N7—C28—N5—Ag2	177.2 (2)
O3—O3'—S1—O1'	−27.9 (7)	N8—C29—N5—C30	58.5 (3)
O2—O3'—S1—O1'	132.0 (5)	N8—C29—N5—C28	−58.7 (3)
O3—O3'—S1—O2	−159.9 (6)	N8—C29—N5—Ag2	−178.0 (2)
O3—O3'—S1—O1	−65.9 (9)	N7ⁱⁱ—Ag2—N5—C30	115.7 (2)
O2—O3'—S1—O1	94.1 (7)	N4—Ag2—N5—C30	−67.7 (2)
O2—O3'—S1—O3	159.9 (6)	N7ⁱⁱ—Ag2—N5—C28	−123.9 (2)
O3—O3'—S1—O2'	−155.7 (5)	N4—Ag2—N5—C28	52.7 (2)
O2—O3'—S1—O2'	4.2 (5)	N7ⁱⁱ—Ag2—N5—C29	−5.1 (2)
O3—O3'—S1—C1	97.2 (5)	N4—Ag2—N5—C29	171.48 (19)
O2—O3'—S1—C1	−102.9 (3)	N8—C31—N6—C30	−59.7 (4)
O1—O1'—S1—O3'	−138.9 (7)	N8—C31—N6—C33	58.1 (3)
O1—O1'—S1—O2	−48.7 (9)	N5—C30—N6—C31	58.7 (4)
O1—O1'—S1—O3	−159.1 (7)	N5—C30—N6—C33	−59.1 (4)
O1—O1'—S1—O2'	−14.5 (8)	N7—C33—N6—C31	−58.9 (3)
O1—O1'—S1—C1	95.5 (6)	N7—C33—N6—C30	58.7 (4)
O2'—O2—S1—O3'	173.3 (8)	N8—C32—N7—C33	−57.1 (3)
O2'—O2—S1—O1'	59.7 (9)	N8—C32—N7—C28	58.5 (3)
O3'—O2—S1—O1'	−113.6 (6)	N8—C32—N7—Ag2ⁱⁱⁱ	176.5 (2)
O2'—O2—S1—O1	32.9 (7)	N6—C33—N7—C32	58.0 (3)
O3'—O2—S1—O1	−140.3 (4)	N6—C33—N7—C28	−57.6 (3)
O2'—O2—S1—O3	157.7 (7)	N6—C33—N7—Ag2ⁱⁱⁱ	178.89 (19)
O3'—O2—S1—O3	−15.5 (5)	N5—C28—N7—C32	−57.7 (4)
O3'—O2—S1—O2'	−173.3 (8)	N5—C28—N7—C33	58.2 (3)
O2'—O2—S1—C1	−84.2 (7)	N5—C28—N7—Ag2ⁱⁱⁱ	−174.2 (2)
O3'—O2—S1—C1	102.5 (4)	N7—C32—N8—C29	−59.4 (4)
O1'—O1—S1—O3'	67.8 (10)	N7—C32—N8—C31	56.7 (3)
O1'—O1—S1—O2	146.7 (6)	N7—C32—N8—Ag3	−178.3 (2)
O1'—O1—S1—O3	22.2 (7)	N5—C29—N8—C32	58.7 (4)
O1'—O1—S1—O2'	166.3 (7)	N5—C29—N8—C31	−58.2 (3)
O1'—O1—S1—C1	−95.3 (6)	N5—C29—N8—Ag3	174.5 (2)
O3'—O3—S1—O1'	156.3 (6)	N6—C31—N8—C32	−57.1 (3)
O3'—O3—S1—O2	19.8 (6)	N6—C31—N8—C29	59.4 (3)
O3'—O3—S1—O1	143.9 (5)	N6—C31—N8—Ag3	−176.2 (2)
O3'—O3—S1—O2'	42.9 (9)	N3ⁱⁱ—Ag3—N8—C32	145.73 (18)
O3'—O3—S1—C1	−98.8 (5)	N11—Ag3—N8—C32	−67.5 (2)
O2—O2'—S1—O3'	−6.4 (8)	O9—Ag3—N8—C32	21.0 (2)
O2—O2'—S1—O1'	−140.5 (6)	O9'—Ag3—N8—C32	44.7 (3)
O2—O2'—S1—O1	−148.7 (7)	N3ⁱⁱ—Ag3—N8—C29	28.8 (2)
O2—O2'—S1—O3	−37.1 (11)	N11—Ag3—N8—C29	175.6 (2)
O2—O2'—S1—C1	105.9 (6)	O9—Ag3—N8—C29	−95.9 (2)
C2—C1—S1—O3'	−3.4 (5)	O9'—Ag3—N8—C29	−72.2 (3)
C6—C1—S1—O3'	175.2 (5)	N3ⁱⁱ—Ag3—N8—C31	−93.7 (2)
C2—C1—S1—O1'	130.3 (4)	N11—Ag3—N8—C31	53.0 (2)
C6—C1—S1—O1'	−51.1 (5)	O9—Ag3—N8—C31	141.5 (2)
C2—C1—S1—O2	−74.7 (4)	O9'—Ag3—N8—C31	165.2 (3)
C6—C1—S1—O2	103.9 (4)	N11—C34—N9—C35	57.2 (3)
C2—C1—S1—O1	166.0 (4)	N11—C34—N9—C36	−59.0 (3)
C6—C1—S1—O1	−15.4 (4)	N11—C34—N9—Ag1^iv	−175.7 (2)
C2—C1—S1—O3	45.7 (4)	N12—C35—N9—C34	−58.5 (3)
C6—C1—S1—O3	−135.7 (4)	N12—C35—N9—C36	57.6 (3)
C2—C1—S1—O2'	−112.6 (5)	N12—C35—N9—Ag1^iv	−179.08 (19)
C6—C1—S1—O2'	66.0 (5)	N10—C36—N9—C34	58.6 (3)
C16—C15—S2—O4	−109.5 (3)	N10—C36—N9—C35	−57.4 (3)
C20—C15—S2—O4	68.6 (3)	N10—C36—N9—Ag1^iv	174.05 (17)
C16—C15—S2—O5	10.3 (4)	N11—C38—N10—C39	−57.6 (3)
C20—C15—S2—O5	−171.6 (3)	N11—C38—N10—C36	59.1 (3)
C16—C15—S2—O6	130.8 (3)	N11—C38—N10—Ag1ⁱⁱⁱ	176.3 (2)
C20—C15—S2—O6	−51.1 (3)	N12—C39—N10—C38	57.8 (3)
O9—O9'—S3—O8	71.8 (8)	N12—C39—N10—C36	−58.6 (3)
O7—O9'—S3—O8	−114.3 (5)	N12—C39—N10—Ag1ⁱⁱⁱ	−177.78 (18)
Ag3—O9'—S3—O8	101.0 (13)	N9—C36—N10—C38	−58.4 (3)
O9—O9'—S3—O7	−173.9 (8)	N9—C36—N10—C39	58.1 (3)
Ag3—O9'—S3—O7	−144.8 (15)	N9—C36—N10—Ag1ⁱⁱⁱ	−178.29 (18)
O7—O9'—S3—O9	173.9 (8)	N9—C34—N11—C38	59.0 (3)
Ag3—O9'—S3—O9	29.2 (10)	N9—C34—N11—C37	−57.5 (3)
O9—O9'—S3—O7'	173.8 (6)	N9—C34—N11—Ag3	178.53 (19)
O7—O9'—S3—O7'	−12.2 (6)	N10—C38—N11—C34	−59.3 (3)
Ag3—O9'—S3—O7'	−157.0 (13)	N10—C38—N11—C37	57.6 (3)
O9—O9'—S3—C8	−73.8 (7)	N10—C38—N11—Ag3	−178.8 (2)
O7—O9'—S3—C8	100.2 (4)	N12—C37—N11—C34	58.4 (3)
Ag3—O9'—S3—C8	−44.6 (15)	N12—C37—N11—C38	−57.9 (3)
O7'—O7—S3—O9'	−161.0 (9)	N12—C37—N11—Ag3	−179.5 (2)
O7'—O7—S3—O8	−41.1 (8)	N3ⁱⁱ—Ag3—N11—C34	66.1 (2)
O9'—O7—S3—O8	119.9 (5)	N8—Ag3—N11—C34	−85.2 (2)
O7'—O7—S3—O9	−165.5 (7)	O9—Ag3—N11—C34	−172.0 (2)
O9'—O7—S3—O9	−4.5 (6)	O9'—Ag3—N11—C34	170.1 (3)
O9'—O7—S3—O7'	161.0 (9)	N3ⁱⁱ—Ag3—N11—C38	−175.77 (19)
O7'—O7—S3—C8	87.0 (7)	N8—Ag3—N11—C38	32.9 (2)
O9'—O7—S3—C8	−112.0 (5)	O9—Ag3—N11—C38	−53.9 (2)
Ag3—O9—S3—O9'	−20.2 (6)	O9'—Ag3—N11—C38	−71.8 (3)
O9'—O9—S3—O8	−127.9 (7)	N3ⁱⁱ—Ag3—N11—C37	−55.2 (2)
Ag3—O9—S3—O8	−148.0 (3)	N8—Ag3—N11—C37	153.4 (2)
O9'—O9—S3—O7	6.0 (7)	O9—Ag3—N11—C37	66.6 (2)
Ag3—O9—S3—O7	−14.2 (5)	O9'—Ag3—N11—C37	48.8 (3)
O9'—O9—S3—O7'	−11.3 (11)	N11—C37—N12—C35	−59.2 (3)
Ag3—O9—S3—O7'	−31.5 (10)	N11—C37—N12—C39	59.1 (3)
O9'—O9—S3—C8	119.9 (7)	N9—C35—N12—C37	59.7 (3)
Ag3—O9—S3—C8	99.7 (4)	N9—C35—N12—C39	−58.6 (3)
O7—O7'—S3—O9'	18.1 (8)	N10—C39—N12—C37	−59.0 (3)
O7—O7'—S3—O8	146.3 (6)	N10—C39—N12—C35	58.8 (3)

Symmetry codes: (i) x−1, y, z; (ii) −x+3/2, y−1/2, −z+3/2; (iii) −x+3/2, y+1/2, −z+3/2; (iv) x+1, y, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1WA···O8ⁱⁱ	0.87 (2)	1.92 (2)	2.782 (5)	175 (4)
O1W—H1WB···O6ⁱⁱ	0.82 (2)	2.10 (2)	2.907 (4)	166 (4)
O2W—H2WA···O5ⁱⁱⁱ	0.83 (2)	2.16 (2)	2.958 (4)	163 (4)
O2W—H2WB···O1^iv	0.84 (2)	1.83 (3)	2.612 (6)	155 (4)
O3W—H3WA···O2^v	0.80 (2)	2.45 (3)	3.096 (7)	139 (4)
O3W—H3WB···O5	0.80 (2)	2.15 (2)	2.908 (5)	160 (4)
O4W—H4WB···O7ⁱⁱⁱ	0.88 (2)	1.99 (3)	2.838 (7)	160 (4)

Symmetry codes: (ii) −x+3/2, y−1/2, −z+3/2; (iii) −x+3/2, y+1/2, −z+3/2; (iv) x+1, y, z; (v) −x+1/2, y+1/2, −z+3/2.

Experimental details

Crystal data
Chemical formula	[Ag₃(C₇H₇O₃S)₃(C₆H₁₂N₄)₃(H₂O)]·3H₂O
M_r	1329.82
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	293
a, b, c (Å)	17.3181 (5), 10.7028 (3), 26.9110 (11)
β (°)	95.657 (3)
V (Å³)	4963.7 (3)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.37
Crystal size (mm)	0.30 × 0.25 × 0.22

Data collection
Diffractometer	Oxford Diffraction Gemini R Ultra
Absorption correction	Multi-scan (CrysAlis RED; Oxford Diffraction, 2006)
T_min, T_max	0.672, 0.728
No. of measured, independent and observed [I > 2σ(I)] reflections	21413, 11446, 7890
R_int	0.021
(sin θ/λ)_max (Å⁻¹)	0.688

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.038, 0.097, 0.99
No. of reflections	11446
No. of parameters	650
No. of restraints	12
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρ_max, Δρ_min (e Å⁻³)	0.90, −1.05

Computer programs: CrysAlis CCD (Oxford Diffraction, 2006), CrysAlis RED (Oxford Diffraction, 2006), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL-Plus (Sheldrick, 2008).

Selected bond lengths (Å) top

Ag1—N1	2.362 (2)	Ag2—N4	2.374 (2)
Ag1—N9ⁱ	2.367 (3)	Ag3—N3ⁱⁱ	2.315 (3)
Ag1—N10ⁱⁱ	2.388 (3)	Ag3—N8	2.358 (3)
Ag2—N5	2.347 (2)	Ag3—N11	2.394 (2)
Ag2—N7ⁱⁱ	2.365 (3)

Symmetry codes: (i) x−1, y, z; (ii) −x+3/2, y−1/2, −z+3/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1WA···O8ⁱⁱ	0.87 (2)	1.92 (2)	2.782 (5)	175 (4)
O1W—H1WB···O6ⁱⁱ	0.82 (2)	2.10 (2)	2.907 (4)	166 (4)
O2W—H2WA···O5ⁱⁱⁱ	0.83 (2)	2.16 (2)	2.958 (4)	163 (4)
O2W—H2WB···O1^iv	0.84 (2)	1.83 (3)	2.612 (6)	155 (4)
O3W—H3WA···O2^v	0.80 (2)	2.45 (3)	3.096 (7)	139 (4)
O3W—H3WB···O5	0.80 (2)	2.15 (2)	2.908 (5)	160 (4)
O4W—H4WB···O7ⁱⁱⁱ	0.88 (2)	1.99 (3)	2.838 (7)	160 (4)

Symmetry codes: (ii) −x+3/2, y−1/2, −z+3/2; (iii) −x+3/2, y+1/2, −z+3/2; (iv) x+1, y, z; (v) −x+1/2, y+1/2, −z+3/2.

Acknowledgements

We thank the Heilongjiang Province Education Department for support (project `The Study of Silver Sulfonates containing Neutral Ligands', serial No. 11535035).

References

Côté, A. P. & Shimizu, G. K. H. (2003). Coord. Chem. Rev., 245, 49-64. Google Scholar
Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England. Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Zhang, S.-L., Tong, M.-L., Fu, R.-W., Cheng, X.-M. & Ng, S.-W. (2001). Inorg. Chem. 40, 3562–3569. Web of Science PubMed Google Scholar

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