Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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CRYSTALLOGRAPHIC
COMMUNICATIONS

Volume 66| Part 12

ISSN: 2056-9890

December 2010 issue

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Cover illustration: Stabilization of various transition metal cations with bulky alkoxides can be achieved through metathesis reactions between alkali metal alkoxides and transition metal halogenides. In most cases these reactions are not quantitative. Instead of alkali alkoxides, thallium(I) alkoxides can alternatively be used. These compounds react almost quantitatively with transition metal chlorides due to the poor solubility of TlCl. In the high-symmetric title compound, [Tl₄(C₄H₉O)₄], two different molecules featuring a distorted (Tl-O)₄ cube are found, one with site symmetry -4.., and one with site symmetry 23. . All O-Tl-O bond angles are smaller than 90° whereas the Tl-O-Tl angles are wider than 90°. See Blasberg, Lerner & Bolte [Acta Cryst. (2010). E66, m1621].

inorganic compounds

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K₂LaCl₅

C. M. Schurz, T. Schleid and G. Meyer

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Zn_1.86Cd_0.14(OH)VO₄

T. Đorđević, J. Stojanović and L. Karanović

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(Ca_xNd_11-x)Ru₄O₂₄ (x = 4.175)

T. Sakakura, K. Okada, H. Iguchi, J. Wang and N. Ishizawa

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Dibarium tricadmium bismuthide(-I,-III) oxide, Ba₂Cd_3−δBi₃O

S.-Q. Xia and S. Bobev

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TbNb₆Sn₆: the first ternary compound from the rare earth–niobium–tin system

I. Oshchapovsky, V. Pavlyuk, T. Fässler and V. Hlukhyy

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Kôzulite, an Mn-rich alkali amphibole

M. C. Barkley, H. Yang and R. T. Downs

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Hydrothermally synthesized α-Ba₂P₂O₇

C. Heyward, M. Mann and J. Kolis

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β-Nd₂Mo₄O₁₅

D. Zhao, F.-F. Li, Y.-M. Yao, C.-A. Huan and E.-X. Zhao

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Ni₂Sr(PO₄)₂·2H₂O

A. Assani, M. Saadi, M. Zriouil and L. El Ammari

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metal-organic compounds

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Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ²N³:N^3′]diformatomanganese(II)]

S.-S. Chen, S.-L. Yang, S.-P. Zhang and Z.-Q. Lu

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Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-κN)ethylidene]thiosemicarbazidato-κ²N¹,S}phenyltin(IV)

M. A. Salam, M. A. Affan, F. B. Ahmad, M. I. M. Tahir and E. R. T. Tiekink

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Bis[μ-2-(4-hydroxyphenyl)acetato]-κ³O,O′:O;κ³O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ²O,O′]dysprosium(III)} monohydrate

J.-L. Liu, J.-F. Liu and G.-L. Zhao

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Piperidinium N-(ferrocenylcarbonyl)glycinate

P. Štěpnička, M. Zábranský and I. Císařová

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Bis[2-(methylamino)troponato]copper(II)

G. Steyl, T. J. Muller and A. Roodt

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Poly[μ₂-aqua-diaqua(μ₈-3-nitrobenzene-1,2-dicarboxylato)(μ₆-3-nitrobenzene-1,2-dicarboxylato)tetrasodium]

Q. Shuai, Y.-Y. Di, Z.-B. Li, L. Li and D.-H. He

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Bis[μ-2-(4-hydroxyphenyl)acetato]-κ³O,O′:O;κ³O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ²O,O′]samarium(III)} monohydrate

J.-L. Liu, J.-F. Liu and G.-L. Zhao

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Bis[μ-2-(4-hydroxyphenyl)acetato]-κ³O,O′:O;κ³O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ²O,O′]erbium(III)} monohydrate

J.-L. Liu, J.-F. Liu and G.-L. Zhao

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catena-Poly[[triaquachlorido-μ₃-malonato-cerium(III)] hemihydrate]

P. Silva, J. A. Fernandes and F. A. Almeida Paz

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Poly[hexaaquahexakis(μ-pyridine-2,4-dicarboxylato)tricopper(II)dieuropium(III)]

S. F. Lush and F. M. Shen

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catena-Poly[[dichloridozinc(II)]-μ-1,4-bis(1H-imidazol-1-yl)benzene]

Y. Nan, L. Yuan, C.-B. Xu, S.-J. Nan and Y. Niu

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Bis[μ-3-(2-hydroxyphenyl)propenoato]bis{aqua(4,4′-bipyridine)bis[3-(2-hydroxyphenyl)propenoato]yttrium(III)} 4,4′-bipyridine disolvate

C.-Y. Zhang, J.-D. Fu and Y.-H. Wen

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[μ-1,3-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN²)propan-2-olato-κ²O:O]bis[(ethanol-κO)zinc(II)] bis(perchlorate)

D.-M. Tian and C.-Y. Shi

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Bis(nitrato-κ²O,O′)bis[N-(triphenylmethyl)pyridin-2-amine-κN¹]nickel(II)

G.-N. Zhang and C. Jiang

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catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ²N⁸,N⁹)zinc(II)]-μ-pentanedioato] monohydrate]

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Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ²N,N′}zinc(II) dihydrate

Y. Bing, X. Li, M. Zha and Y. Lu

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Tetraaquabis[4-(pyrazin-2-ylsulfanylmethyl)benzoato]manganese(II) dihydrate

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μ₂-Acetone-diacetone[μ₃-tris(trifluoromethyl)methanolato]bis[μ₂-tris(trifluoromethyl)methanolato]trilithium

H. Vitze, H.-W. Lerner and M. Bolte

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6-(4-Methylphenyl)-2,10-dioxo-3,9-dioxa-6-aza-1(1,1′)-ferrocenacyclodecaphane

X. Leng, B. Yang, L. Cui and B. Liu

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catena-Poly[[tetraaqua[μ₂-1,4-bis(1,2,4-triazol-1-yl)butane-κ²N⁴:N^4′]cadmium(II)] sulfate]

J.-J. Song, K.-L. Zhang and S. W. Ng

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Aqua(2,2′-bipyridine-κ²N,N′)bis(4-iodobenzoato-κO)copper(II)

M. I. Mohamadin, N. Abdullah, K. M. Lo and S. W. Ng

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Dichlorido[μ-10,21-dimethyl-2,7,13,18-tetraphenyl-3,6,14,17-tetraazatricyclo[17.3.1.1^8,12]tetracosa-1(23),2,6,8,10,12(24),13,17,19,21-decaene-23,24-diolato]dicopper(II) ethanol hemisolvate dihydrate

S. K. Gupta, C. Anjana, R. J. Butcher and N. Sen

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trans-Bis[(1-ammoniopentane-1,1-diyl)diphosphonato-κ²O,O′]diaquacopper(II)

N. V. Tsaryk, A. V. Dudko, A. N. Kozachkova, V. V. Bon and V. I. Pekhnyo

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(Benzyldiphenylphosphane)chloridogold(I)

O. bin Shawkataly, A. Tariq, C. S. Yeap and H.-K. Fun

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(μ-Butane-1,2,3,4-tetracarboxylato)bis[triaqua(1,10-phenanthroline)nickel(II)] hexahydrate

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catena-Poly[[[(1,10-phenanthroline)copper(I)]-μ-cyanido] ethanol hemisolvate]

J. Nie, J. Wang and C. Dai

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Poly[[hexaaqua(μ₂-fumarato-κ⁴O¹,O^1′:O⁴,O^4′)bis(μ₃-maleato-κ⁴O¹,O^1′:O⁴:O^4′)disamarium(III)] hexahydrate]

B. Li and L.-X. Wu

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Bis(4-cyanophenolato)[hydrotris(3,5-dimethylpyrazolyl)borato]nitrosylmolybdenum(II)–4-hydroxybenzonitrile–dichloromethane (1/1/1)

M. B. Kassim and J. A. McCleverty

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19-Ferrocenyl-18-oxa-8,16-diazapentacyclo[8.6.3.0^1,10.0^2,7.0^12,16]nonadeca-2(7),3,5-triene-9,17-dione

B. Gunasekaran, S. Kathiravan, R. Raghunathan and V. Manivannan

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Diaquabis[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)

Z. Zhang, J.-Z. Liu, P. Gao and Z.-J. Huang

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Poly[di-μ₂-aqua-μ₄-chlorido-μ₄-(2-mercaptopyrimidine-4,6-diolato-κ⁴O:O:O′:O′)-disodium(I)]

B. Li, W. Li, L. Ye, G.-F. Hou and L.-X. Wu

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(N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ²N,O²)phenylbismuth(III)

V. Stavila and K. H. Whitmire

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Bis[μ-2,2′-dimethyl-1,1′-(3-oxapentane-1,5-diyl)di-1H-benzimidazole-κ²N³:N^3′]bis[bis(4-methoxybenzoato)-κO;κ²O,O′-cobalt(II)]

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Aqua(4-nitrophthalato-κO¹)bis[2-(1H-pyrazol-3-yl-κN²)pyridine-κN]manganese(II) hemihydrate

L. Ni, J.-L. Zhao and H. Wei

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Bis(2-hydroxyethanaminium) tetrachloridopalladate(II)

I. A. Guzei, L. C. Spencer, M. Yankey and J. Darkwa

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[N-(3-Methoxy-2-oxidobenzylidene-κO²)leucinato-κ²N,O](1,10-phenanthroline-κ²N,N′)copper(II) monohydrate

L. Huang, J. Dong, B. Jing, L. Li and D. Wang

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Poly[[diaqua(μ₂-5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxylato)(μ₂-ethylene glycol)manganese(II)] dimethylacetamide solvate]

X.-C. Yi, L. Yan and E.-Q. Gao

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Poly[μ-bromido-μ-(2,2-dimethylpropane-1,3-diyl diisocyanide)-silver(I)]: a powder diffraction study

M. Al-Ktaifani and M. Rukiah

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Chlorido(pyridine-2-carboximidamide-κ²N¹,N²)zinc(II) chloride dihydrate

G.-H. Dong, R.-D. Xue and J. Li

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(4-Chlorobenzohydrazidato-κ²N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ²N¹,O)-3-phenylpropionato(2−)-κO¹]oxidovanadium(V) methanol monosolvate

H. W. Wong, K. M. Lo and S. W. Ng

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Bis[μ-4-(methylamino)benzoato]-κ³O,O′:O;κ³O:O,O′-bis{aqua[4-(methylamino)benzoato-κ²O,O′](nicotinamide-κN)cadmium(II)}

T. Hökelek, E. G. Sağlam, B. Tercan, Ö. Aybirdi and H. Necefoğlu

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catena-Poly[[(3,5-dicarboxypyrazine-2,6-dicarboxylato-κ³O²,N¹,O⁶)lithium(I)]-μ-aqua-[triaqualithium(I)]-μ-aqua]

W. Starosta and J. Leciejewicz

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Bis(μ-2,2′-disulfanediyldibenzoato)bis[aqua(2,2′-bipyridine)nickel(II)]

Z. Liu, B. Qu, J. Yu, L. Yuan and W. Liu

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(η⁵-Pentamethylcyclopentadienyl)(η⁶-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate

B. T. Loughrey, M. L. Williams and P. C. Healy

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Tetra-μ-acetato-κ⁴O:O′;κ³O,O′:O;κ³O:O,O′-bis[(acetato-κ²O,O′)(1,10-phenanthroline-κ²N,N′)europium(III)]

R.-Q. Fan, C.-F. Sun and Y.-L. Yang

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Tetraaquadiazidocobalt(II) 3,3′-dicarboxylato-1,1′-ethylenedipyridinium

Y.-Q. Wen, C.-Y. Tian and E.-Q. Gao

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Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate

D. Wu, Y. Zhao, H. Ye and G. Wu

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Diaquabis{2-hydroxy-5-[(pyridin-2-yl)methylideneamino]benzoato-κ²N,N′}nickel(II) dihydrate

M. Zha, X. Li, Y. Bing and Z. Luo

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{2,2′-[4-Chloro-5-methyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)

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Triaqua(benzene-1,3-dicarboxylato)(4,5-diazafluoren-9-one)cadmium(II) pentahydrate

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catena-Poly[[(2,2′-bipyridine)nickel(II)]-μ-2,4′-oxydibenzoato]

J.-K. Xu, X.-C. Sun and F. Guo

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(2,2′-Bipyridine-κ²N,N′)chlorido(1,4,7-trithiacyclononane-κ³S,S′,S′′)ruthenium(II) nitrate monohydrate

J. A. Fernandes, F. A. Almeida Paz, M. J. P. Mota, S. S. Braga and T. M. Santos

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Poly[diaquabis[μ-1-hydroxy-2-(imidazol-3-ium-1-yl)ethane-1,1-diyldiphosphonato]tricopper(II)]

Y. Li, D. Sun, H. Zang, L. Han and G. Su

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Bis[tetraaqua(1,10-phenanthroline-κ²N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate