Poly[hexa­aqua­hexa­kis­(μ-pyridine-2,4-dicarboxyl­ato)tricopper(II)dieuropium(III)]

Lush, S.F.; Shen, F.M.

doi:10.1107/S1600536810044594

metal-organic compounds

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ISSN: 2056-9890

Volume 66| Part 12| December 2010| Pages m1516-m1517

https://doi.org/10.1107/S1600536810044594

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Poly[hexaaquahexakis(μ-pyridine-2,4-dicarboxylato)tricopper(II)dieuropium(III)]

Shie Fu Lush ^a and Fwu Ming Shen ^b ^*

^aDepartment of General Education Center, Yuanpei University, HsinChu, 30015 Taiwan, and ^bDepartment of Biotechnology, Yuanpei University, No. 306, Yuanpei St, HsinChu, 30015 Taiwan
^*Correspondence e-mail: fmshen@mail.ypu.edu.tw

(Received 26 October 2010; accepted 1 November 2010; online 6 November 2010)

The asymmetric unit of the title heterometallic coordination polymer, [Cu₃Eu₂(C₇H₃NO₄)₆(H₂O)₆]_n, contains one Eu^III and two Cu^II atoms, three pyridine-2,4-dicarboxylate (pdc)²⁻ anions and three water molecules. One Cu^II atom is located on an inversion center and is N,O-chelated by two pdc²⁻ anions in the equatorial plane and further coordinated by two carboxylate O atoms from another two pdc anions in the axial positions, with an elongated octahedral geometry [Cu—O = 2.409 (3) Å in the axial direction]; the other Cu atom is N,O-chelated by two pdc anions in the coordination basal plane and coordinated by a carboxyl O atom at the apical position with a distorted square-pyramidal geometry [Cu—O = 2.359 (3) Å in the apical direction]. The Eu atom is eight-coordinated with a distorted square-antiprismatic geometry formed by five carboxylate O atoms from five pdc anions and three water molecules. The carboxylate anions bridge adjacent Eu and Cu atoms, forming the coordination polymer. Inter- and intramolecular O—H⋯O hydrogen bonding occurs in the structure. π–π stacking further consolidates the crystal structure, the centroid–centroid distance between parallel pyridine rings being 3.367 (2) Å.

Related literature

For structures and applications of related heterometallic lanthanide-transition metal coordination polymers, see: Huang et al. (2008a ,b ). For the coordination modes of the pyridine-2,6-dicarboxylate ligand, see: Ma et al. (2010 ); Zhao et al. (2007 ); Wang et al. (2007 ). For the coordination modes of the pyridine-2,5-dicarboxylate ligand, see: Song et al. (2006 ); Wang et al. (2009 ). For the coordination modes of the pyridine-2,3-dicarboxylate ligand, see: Wang et al. (2010 ).

Experimental

Crystal data

[Cu₃Eu₂(C₇H₃NO₄)₆(H₂O)₆]
M_r = 1593.29
Triclinic, $[P \overline 1]$
a = 9.4296 (10) Å
b = 10.7002 (11) Å
c = 12.2874 (13) Å
α = 86.186 (2)°
β = 81.556 (2)°
γ = 86.561 (2)°
V = 1222.0 (2) Å³
Z = 1
Mo Kα radiation
μ = 3.92 mm⁻¹
T = 294 K
0.24 × 0.20 × 0.20 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2000 ) T_min = 0.659, T_max = 0.977
12982 measured reflections
5780 independent reflections
4828 reflections with I > 2σ(I)
R_int = 0.044

Refinement

R[F² > 2σ(F²)] = 0.028
wR(F²) = 0.066
S = 0.98
5780 reflections
376 parameters
H-atom parameters constrained
Δρ_max = 1.69 e Å⁻³
Δρ_min = −0.94 e Å⁻³

Table 1
Selected bond lengths (Å)

Eu1—O6ⁱ	2.485 (2)
Eu1—O8	2.386 (3)
Eu1—O10ⁱⁱ	2.404 (2)
Eu1—O11ⁱⁱⁱ	2.385 (2)
Eu1—O12ⁱ	2.328 (2)
Eu1—O13	2.454 (3)
Eu1—O14	2.442 (3)
Eu1—O15	2.510 (3)
Cu1—O1	1.932 (3)
Cu1—O5^iv	1.944 (2)
Cu1—O7	2.359 (3)
Cu1—N1	1.975 (3)
Cu1—N2^iv	1.975 (3)
Cu2—O2	2.409 (3)
Cu2—O9	1.968 (2)
Cu2—N3	1.969 (3)
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x+1, -y+2, -z; (iii) x, y, z+1; (iv) -x, -y+1, -z.

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O13—H13A⋯O5ⁱ	0.82	2.00	2.769 (3)	155
O13—H13B⋯O15^v	0.82	2.02	2.822 (4)	164
O14—H14A⋯O7	0.82	1.89	2.690 (4)	164
O14—H14B⋯O4^vi	0.82	1.88	2.667 (4)	161
O15—H15A⋯O3^vii	0.82	1.83	2.630 (4)	164
O15—H15B⋯O4^vi	0.82	2.06	2.814 (4)	153
Symmetry codes: (i) -x+1, -y+1, -z; (v) -x+1, -y+1, -z+1; (vi) -x, -y+2, -z+1; (vii) x, y-1, z.

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 1999 ); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ); program(s) used to refine structure: SHELXTL; molecular graphics: PLATON (Spek, 2009 ); software used to prepare material for publication: PLATON.

Supporting information

Crystal structure: contains datablocks global, I. DOI: https://doi.org/10.1107/S1600536810044594/xu5066sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536810044594/xu5066Isup2.hkl

checkCIF report

Comment top

In recent years, many research groups have devoted their work to the design and synthesis of lanthanide–transition(3 d-4f) heterometallic coordination frameworks with bridging multifunctional organic ligands, such as pyridinedicarboxylic acid (Ma et al., 2010; Song et al., 2006; Wang et al.,2007; Wang et al., 2009; Wang et al., 2010; Zhao et al.,2007). Pyridine-2,4-dicarboxylic acid (pdaH₂) ligand is a good candidate due to its flexible and various coordination donors containing either N– or O–atom donors. Some examples of coordination with pdaH₂ have been reported (Huang et al., 2008a; Huang et al., 2008b.).

Herein we report a new 3 d-4f heterometallic coordination polymer based on pdaH₂ ligand, formulated as [Eu₂Cu₃(C₇H₃NO₄)₆(H₂O)₆]_n. The symmetric unit of the title compound contains one octa-coordinated Eu^III atom and two types of environments of Cu^II center, the penta-coordinate Cu^II atom is in a square- pyramidal geometry, the other Cu^II atom is in a slightly distorted octahedral geometry. The Eu^III ion presents a EuO₈ square antiprismatic coordination geometry, formed by five mono-dentate pda O atoms and three coordinate water molecules, the Cu1^IIion presents a CuN₂O₃ square- pyramidal coordination geometry, formed by two bidentate pda (–NO–) ligand (2-carboxy) in the equatorial plane, and one O atom from monodentate pda (4-carboxy) ligand at the axial sites, the other Cu2^II ion presents a slightly distorted (CuN₂O₄) octahedral coordination geometry, formed by two bidentate pda (–NO–) ligand (2-carboxy) in the equatorial plane, and two monodentate pda(2-carboxy) ligands at the axial sites (Table 1, Fig 1). The pda One carboxyl group bridges the neighboring Eu or Cu cations, forming the 3-D polymeric architecture.

In the title crystal structure, a three-dimensional network is formed via intra- intermolecular O—H···O hydrogen bonds (Table 2, Fig. 2). In addition, C—H···O hydrogen bonds (full details and symmetry codes are given in Table 2), C7—O3···Cg8 (N3/C15—C19) interactions are also present. The π···π, π···Metal stacking interactions are also observed, the centroid-centroid distance between the pyridine rings being 3.367 (2)Å [Cg7^iv···Cg7 (N2/C8—C12)] [symmetry codes: -x, 1 - y, -z]. The Cg1 (Cu1/O1—N1—C1—C6)···Cu1 interaction is 3.905Å [symmetry codes: -x, 2 - y, -z].

Related literature top

For structures and applications of related heterometallic lanthanide-transition metal coordination polymers, see: Huang et al. (2008a,b). For the coordination modes of the pyridine-2,6-dicarboxylate ligand, see: Ma et al. (2010); Zhao et al. (2007); Wang et al. (2007). For the coordination modes of the pyridine-2,5-dicarboxylate ligand, see: Song et al. (2006); Wang et al. (2009). For the coordination modes of the pyridine-2,3-dicarboxylate ligand, see: Wang et al. (2010).

Experimental top

A mixture of europium chloride hexahydrate (0.25 mmol, 0.0916 g), copper acetate hydrate (0.25 mmol, 0.050 g), pyridine-2,4-dicarboxylic acid (0.25 mmol, 0.0418 g) and 10 ml H₂O were put in a 23-ml Teflon liner reactor and heated at 418 K in oven for 48 h. The resulting solution was slowly cooled to room temperature. The blue transparent single crystals of the title complex were obtained in 43.21% yield (based on Eu).

Structure description top

For structures and applications of related heterometallic lanthanide-transition metal coordination polymers, see: Huang et al. (2008a,b). For the coordination modes of the pyridine-2,6-dicarboxylate ligand, see: Ma et al. (2010); Zhao et al. (2007); Wang et al. (2007). For the coordination modes of the pyridine-2,5-dicarboxylate ligand, see: Song et al. (2006); Wang et al. (2009). For the coordination modes of the pyridine-2,3-dicarboxylate ligand, see: Wang et al. (2010).

Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT (Bruker, 1999); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: PLATON (Spek, 2009); software used to prepare material for publication: PLATON (Spek, 2009).

Figures top

	Fig. 1. View of the title compound with the atom numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 50% probability level. H atoms have been omitted for clarity. [Symmetry codes: (i) x, y, z + 1; (ii) -x + 1, -y + 1, -z; (iii) -x + 1, -y + 2, -z; (iv) -x, -y + 1, -z].
	Fig. 2. The molecular packing for the title compound, viewed along the c axis. Hydrogen bonds are shown as dashed lines.

Poly[hexaaquahexakis(µ-pyridine-2,4-dicarboxylato)tricopper(II)dieuropium(III)] top

Crystal data top

[Cu₃Eu₂(C₇H₃NO₄)₆(H₂O)₆]	Z = 1
M_r = 1593.29	F(000) = 777
Triclinic, P1	D_x = 2.165 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.4296 (10) Å	Cell parameters from 6583 reflections
b = 10.7002 (11) Å	θ = 2.5–25.0°
c = 12.2874 (13) Å	µ = 3.92 mm⁻¹
α = 86.186 (2)°	T = 294 K
β = 81.556 (2)°	Equant, blue
γ = 86.561 (2)°	0.24 × 0.20 × 0.20 mm
V = 1222.0 (2) Å³

Data collection top

Bruker SMART CCD area-detector diffractometer	5780 independent reflections
Radiation source: fine-focus sealed tube	4828 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.044
Detector resolution: 9 pixels mm^-1	θ_max = 28.3°, θ_min = 1.7°
φ and ω scans	h = −12→12
Absorption correction: multi-scan (SADABS; Bruker, 2000)	k = −13→13
T_min = 0.659, T_max = 0.977	l = −15→16
12982 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.028	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.066	H-atom parameters constrained
S = 0.98	w = 1/[σ²(F_o²) + (0.0323P)²] where P = (F_o² + 2F_c²)/3
5780 reflections	(Δ/σ)_max = 0.001
376 parameters	Δρ_max = 1.69 e Å⁻³
0 restraints	Δρ_min = −0.94 e Å⁻³

Crystal data top

[Cu₃Eu₂(C₇H₃NO₄)₆(H₂O)₆]	γ = 86.561 (2)°
M_r = 1593.29	V = 1222.0 (2) Å³
Triclinic, P1	Z = 1
a = 9.4296 (10) Å	Mo Kα radiation
b = 10.7002 (11) Å	µ = 3.92 mm⁻¹
c = 12.2874 (13) Å	T = 294 K
α = 86.186 (2)°	0.24 × 0.20 × 0.20 mm
β = 81.556 (2)°

Data collection top

Bruker SMART CCD area-detector diffractometer	5780 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2000)	4828 reflections with I > 2σ(I)
T_min = 0.659, T_max = 0.977	R_int = 0.044
12982 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.028	0 restraints
wR(F²) = 0.066	H-atom parameters constrained
S = 0.98	Δρ_max = 1.69 e Å⁻³
5780 reflections	Δρ_min = −0.94 e Å⁻³
376 parameters

Special details top

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F² for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The observed criterion of F² > σ(F²) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Eu1	0.42924 (2)	0.65169 (1)	0.35169 (1)	0.0161 (1)
Cu1	−0.04296 (4)	0.81387 (4)	0.11987 (3)	0.0220 (1)
Cu2	0.50000	1.00000	0.00000	0.0188 (2)
O1	0.1188 (3)	0.8879 (2)	0.0288 (2)	0.0274 (8)
O2	0.2474 (3)	1.0583 (2)	0.0150 (2)	0.0272 (8)
O3	0.1716 (3)	1.3256 (3)	0.3467 (2)	0.0406 (10)
O4	−0.0222 (3)	1.2972 (3)	0.4696 (3)	0.0524 (11)
O5	0.2216 (2)	0.2480 (2)	−0.19845 (19)	0.0238 (7)
O6	0.3969 (2)	0.3742 (2)	−0.18098 (19)	0.0236 (8)
O7	0.0882 (3)	0.6635 (2)	0.2196 (2)	0.0313 (8)
O8	0.3149 (3)	0.5865 (2)	0.2057 (2)	0.0258 (8)
O9	0.5336 (3)	1.1177 (2)	−0.13010 (19)	0.0230 (7)
O10	0.5037 (3)	1.1358 (2)	−0.30699 (19)	0.0235 (7)
O11	0.3895 (3)	0.7209 (2)	−0.46529 (19)	0.0254 (8)
O12	0.4790 (3)	0.5533 (2)	−0.3775 (2)	0.0269 (8)
O13	0.6647 (3)	0.6702 (3)	0.4101 (2)	0.0318 (9)
O14	0.2105 (3)	0.7873 (2)	0.3621 (2)	0.0285 (8)
O15	0.2311 (3)	0.5207 (2)	0.4481 (2)	0.0262 (8)
N1	−0.0265 (3)	0.9489 (3)	0.2186 (2)	0.0222 (9)
N2	0.0738 (3)	0.3055 (3)	−0.0108 (2)	0.0190 (8)
N3	0.4749 (3)	0.8802 (3)	−0.1097 (2)	0.0179 (8)
C1	0.0834 (3)	1.0218 (3)	0.1776 (3)	0.0193 (10)
C2	0.1182 (4)	1.1211 (3)	0.2322 (3)	0.0232 (10)
C3	0.0356 (4)	1.1510 (3)	0.3314 (3)	0.0260 (11)
C4	−0.0795 (4)	1.0771 (4)	0.3712 (3)	0.0344 (12)
C5	−0.1064 (4)	0.9764 (4)	0.3138 (3)	0.0314 (12)
C6	0.1590 (4)	0.9878 (3)	0.0650 (3)	0.0213 (10)
C7	0.0646 (4)	1.2678 (4)	0.3881 (3)	0.0282 (12)
C8	−0.0144 (4)	0.3380 (3)	0.0799 (3)	0.0214 (10)
C9	0.0190 (4)	0.4295 (3)	0.1443 (3)	0.0225 (10)
C10	0.1511 (4)	0.4835 (3)	0.1200 (3)	0.0200 (10)
C11	0.2450 (3)	0.4447 (3)	0.0287 (3)	0.0199 (10)
C12	0.2009 (3)	0.3591 (3)	−0.0364 (3)	0.0177 (9)
C13	0.2824 (3)	0.3236 (3)	−0.1467 (3)	0.0187 (10)
C14	0.1878 (4)	0.5861 (3)	0.1875 (3)	0.0209 (10)
C15	0.4789 (3)	0.9361 (3)	−0.2116 (3)	0.0177 (9)
C16	0.4629 (4)	0.8712 (3)	−0.3016 (3)	0.0195 (10)
C17	0.4471 (4)	0.7427 (3)	−0.2868 (3)	0.0193 (10)
C18	0.4458 (4)	0.6855 (3)	−0.1819 (3)	0.0248 (10)
C19	0.4564 (4)	0.7580 (3)	−0.0948 (3)	0.0233 (10)
C20	0.5063 (3)	1.0751 (3)	−0.2176 (3)	0.0178 (9)
C21	0.4380 (4)	0.6657 (3)	−0.3837 (3)	0.0195 (10)
H2A	0.19630	1.16800	0.20320	0.0280*
H4A	−0.13820	1.09550	0.43650	0.0410*
H5A	−0.18220	0.92660	0.34220	0.0380*
H8A	−0.10000	0.29790	0.09970	0.0260*
H9A	−0.04660	0.45500	0.20380	0.0270*
H11A	0.33600	0.47600	0.01220	0.0240*
H13A	0.71830	0.70010	0.35740	0.0480*
H13B	0.70360	0.60960	0.44030	0.0480*
H14A	0.16690	0.76300	0.31500	0.0430*
H14B	0.15520	0.77690	0.41960	0.0430*
H15A	0.19680	0.46590	0.41800	0.0390*
H15B	0.15630	0.55220	0.48000	0.0390*
H16A	0.46260	0.91230	−0.37070	0.0230*
H18A	0.43800	0.59920	−0.17040	0.0300*
H19A	0.45030	0.72020	−0.02400	0.0280*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Eu1	0.0202 (1)	0.0122 (1)	0.0166 (1)	−0.0010 (1)	−0.0040 (1)	−0.0033 (1)
Cu1	0.0214 (2)	0.0212 (2)	0.0238 (2)	−0.0061 (2)	0.0003 (2)	−0.0088 (2)
Cu2	0.0269 (3)	0.0140 (3)	0.0167 (3)	−0.0032 (2)	−0.0048 (2)	−0.0041 (2)
O1	0.0258 (13)	0.0283 (15)	0.0280 (14)	−0.0073 (11)	0.0036 (11)	−0.0125 (11)
O2	0.0224 (13)	0.0206 (14)	0.0364 (15)	−0.0039 (10)	0.0047 (11)	−0.0022 (11)
O3	0.0470 (18)	0.0376 (17)	0.0378 (16)	−0.0199 (14)	0.0054 (14)	−0.0160 (13)
O4	0.0512 (19)	0.046 (2)	0.057 (2)	−0.0178 (15)	0.0228 (16)	−0.0343 (16)
O5	0.0226 (12)	0.0271 (14)	0.0222 (12)	−0.0056 (10)	−0.0001 (10)	−0.0089 (10)
O6	0.0211 (12)	0.0235 (14)	0.0258 (13)	−0.0055 (10)	0.0027 (10)	−0.0073 (10)
O7	0.0308 (14)	0.0296 (15)	0.0369 (15)	0.0100 (12)	−0.0139 (12)	−0.0169 (12)
O8	0.0222 (13)	0.0320 (15)	0.0250 (13)	−0.0017 (11)	−0.0061 (11)	−0.0095 (11)
O9	0.0349 (14)	0.0140 (12)	0.0215 (12)	−0.0062 (10)	−0.0067 (11)	−0.0016 (10)
O10	0.0352 (14)	0.0145 (12)	0.0207 (12)	−0.0031 (10)	−0.0032 (11)	−0.0002 (10)
O11	0.0367 (14)	0.0211 (13)	0.0190 (12)	0.0028 (11)	−0.0064 (11)	−0.0042 (10)
O12	0.0392 (15)	0.0133 (13)	0.0285 (14)	0.0033 (11)	−0.0062 (12)	−0.0056 (10)
O13	0.0287 (14)	0.0401 (17)	0.0280 (14)	−0.0078 (12)	−0.0103 (11)	0.0068 (12)
O14	0.0282 (14)	0.0287 (15)	0.0301 (14)	0.0032 (11)	−0.0076 (11)	−0.0084 (11)
O15	0.0264 (13)	0.0219 (13)	0.0304 (14)	−0.0060 (10)	0.0002 (11)	−0.0076 (11)
N1	0.0215 (15)	0.0211 (16)	0.0239 (15)	−0.0018 (12)	0.0000 (12)	−0.0070 (12)
N2	0.0182 (14)	0.0165 (14)	0.0220 (15)	0.0014 (11)	−0.0025 (12)	−0.0018 (11)
N3	0.0223 (14)	0.0156 (14)	0.0159 (14)	−0.0019 (11)	−0.0018 (11)	−0.0034 (11)
C1	0.0178 (16)	0.0178 (17)	0.0229 (17)	0.0008 (13)	−0.0037 (14)	−0.0049 (13)
C2	0.0240 (18)	0.0167 (17)	0.0295 (19)	−0.0045 (14)	−0.0036 (15)	−0.0030 (14)
C3	0.0252 (19)	0.024 (2)	0.029 (2)	−0.0025 (15)	−0.0016 (16)	−0.0078 (16)
C4	0.037 (2)	0.034 (2)	0.031 (2)	−0.0092 (18)	0.0076 (17)	−0.0137 (17)
C5	0.029 (2)	0.032 (2)	0.032 (2)	−0.0102 (17)	0.0068 (17)	−0.0101 (17)
C6	0.0179 (17)	0.0220 (18)	0.0242 (18)	0.0047 (14)	−0.0054 (14)	−0.0030 (14)
C7	0.035 (2)	0.022 (2)	0.029 (2)	−0.0021 (16)	−0.0053 (17)	−0.0090 (16)
C8	0.0175 (16)	0.0229 (19)	0.0233 (17)	−0.0030 (13)	−0.0005 (14)	−0.0022 (14)
C9	0.0218 (17)	0.0253 (19)	0.0202 (17)	0.0024 (14)	−0.0017 (14)	−0.0061 (14)
C10	0.0215 (17)	0.0199 (18)	0.0197 (17)	0.0032 (14)	−0.0074 (14)	−0.0040 (13)
C11	0.0157 (16)	0.0218 (18)	0.0229 (17)	−0.0012 (13)	−0.0040 (14)	−0.0040 (14)
C12	0.0167 (16)	0.0178 (17)	0.0187 (16)	0.0004 (13)	−0.0027 (13)	−0.0021 (13)
C13	0.0188 (16)	0.0173 (17)	0.0207 (17)	0.0024 (13)	−0.0050 (14)	−0.0037 (13)
C14	0.0253 (18)	0.0232 (18)	0.0147 (16)	0.0010 (14)	−0.0046 (14)	−0.0036 (13)
C15	0.0205 (16)	0.0133 (16)	0.0195 (16)	−0.0003 (13)	−0.0030 (13)	−0.0026 (13)
C16	0.0272 (18)	0.0164 (17)	0.0154 (16)	0.0005 (13)	−0.0056 (14)	−0.0010 (13)
C17	0.0216 (17)	0.0158 (17)	0.0208 (17)	0.0016 (13)	−0.0033 (14)	−0.0048 (13)
C18	0.040 (2)	0.0151 (17)	0.0200 (17)	−0.0041 (15)	−0.0046 (16)	−0.0028 (13)
C19	0.036 (2)	0.0182 (18)	0.0160 (16)	−0.0015 (15)	−0.0051 (15)	0.0006 (13)
C20	0.0169 (16)	0.0136 (16)	0.0220 (17)	−0.0005 (12)	0.0009 (13)	−0.0031 (13)
C21	0.0209 (17)	0.0193 (18)	0.0184 (16)	−0.0049 (13)	−0.0001 (14)	−0.0043 (13)

Geometric parameters (Å, º) top

Eu1—O6ⁱ	2.485 (2)	O15—H15B	0.8200
Eu1—O8	2.386 (3)	O15—H15A	0.8200
Eu1—O10ⁱⁱ	2.404 (2)	N1—C5	1.335 (5)
Eu1—O11ⁱⁱⁱ	2.385 (2)	N1—C1	1.352 (4)
Eu1—O12ⁱ	2.328 (2)	N2—C8	1.341 (4)
Eu1—O13	2.454 (3)	N2—C12	1.346 (4)
Eu1—O14	2.442 (3)	N3—C15	1.348 (4)
Eu1—O15	2.510 (3)	N3—C19	1.327 (5)
Cu1—O1	1.932 (3)	C1—C6	1.517 (5)
Cu1—O5^iv	1.944 (2)	C1—C2	1.374 (5)
Cu1—O7	2.359 (3)	C2—C3	1.392 (5)
Cu1—N1	1.975 (3)	C3—C7	1.528 (5)
Cu1—N2^iv	1.975 (3)	C3—C4	1.392 (5)
Cu2—O2	2.409 (3)	C4—C5	1.382 (6)
Cu2—O9	1.968 (2)	C8—C9	1.377 (5)
Cu2—N3	1.969 (3)	C9—C10	1.389 (5)
Cu2—O2ⁱⁱ	2.409 (3)	C10—C11	1.393 (5)
Cu2—O9ⁱⁱ	1.968 (2)	C10—C14	1.505 (5)
Cu2—N3ⁱⁱ	1.969 (3)	C11—C12	1.376 (5)
O1—C6	1.283 (4)	C12—C13	1.516 (5)
O2—C6	1.227 (4)	C15—C20	1.520 (5)
O3—C7	1.242 (5)	C15—C16	1.375 (5)
O4—C7	1.242 (5)	C16—C17	1.389 (5)
O5—C13	1.272 (4)	C17—C21	1.508 (5)
O6—C13	1.242 (4)	C17—C18	1.388 (5)
O7—C14	1.251 (4)	C18—C19	1.381 (5)
O8—C14	1.251 (5)	C2—H2A	0.9300
O9—C20	1.261 (4)	C4—H4A	0.9300
O10—C20	1.241 (4)	C5—H5A	0.9300
O11—C21	1.260 (4)	C8—H8A	0.9300
O12—C21	1.242 (4)	C9—H9A	0.9300
O13—H13B	0.8200	C11—H11A	0.9300
O13—H13A	0.8200	C16—H16A	0.9300
O14—H14A	0.8200	C18—H18A	0.9300
O14—H14B	0.8200	C19—H19A	0.9300

O8—Eu1—O13	143.07 (9)	H15A—O15—H15B	99.00
O8—Eu1—O14	76.92 (8)	Eu1—O15—H15A	123.00
O8—Eu1—O15	75.96 (8)	Eu1—O15—H15B	122.00
O8—Eu1—O11ⁱⁱⁱ	144.45 (9)	C1—N1—C5	118.9 (3)
O6ⁱ—Eu1—O8	68.55 (8)	Cu1—N1—C1	111.1 (2)
O8—Eu1—O12ⁱ	88.94 (8)	Cu1—N1—C5	130.0 (3)
O8—Eu1—O10ⁱⁱ	108.10 (8)	Cu1^iv—N2—C8	128.5 (2)
O13—Eu1—O14	133.64 (9)	C8—N2—C12	119.2 (3)
O13—Eu1—O15	126.29 (9)	Cu1^iv—N2—C12	112.3 (2)
O11ⁱⁱⁱ—Eu1—O13	72.28 (9)	Cu2—N3—C19	128.7 (2)
O6ⁱ—Eu1—O13	75.67 (8)	Cu2—N3—C15	111.9 (2)
O12ⁱ—Eu1—O13	74.51 (10)	C15—N3—C19	119.4 (3)
O10ⁱⁱ—Eu1—O13	72.65 (10)	N1—C1—C6	114.2 (3)
O14—Eu1—O15	73.99 (8)	C2—C1—C6	123.6 (3)
O11ⁱⁱⁱ—Eu1—O14	74.60 (9)	N1—C1—C2	122.2 (3)
O6ⁱ—Eu1—O14	124.22 (8)	C1—C2—C3	119.5 (3)
O12ⁱ—Eu1—O14	144.83 (9)	C2—C3—C4	117.7 (3)
O10ⁱⁱ—Eu1—O14	71.70 (9)	C2—C3—C7	120.2 (3)
O11ⁱⁱⁱ—Eu1—O15	76.07 (8)	C4—C3—C7	122.0 (3)
O6ⁱ—Eu1—O15	132.71 (7)	C3—C4—C5	120.0 (3)
O12ⁱ—Eu1—O15	71.37 (9)	N1—C5—C4	121.7 (4)
O10ⁱⁱ—Eu1—O15	143.28 (8)	O1—C6—C1	115.5 (3)
O6ⁱ—Eu1—O11ⁱⁱⁱ	146.55 (8)	O1—C6—O2	125.7 (3)
O11ⁱⁱⁱ—Eu1—O12ⁱ	102.40 (8)	O2—C6—C1	118.8 (3)
O10ⁱⁱ—Eu1—O11ⁱⁱⁱ	82.57 (8)	O3—C7—C3	116.6 (3)
O6ⁱ—Eu1—O12ⁱ	77.62 (8)	O3—C7—O4	126.3 (4)
O6ⁱ—Eu1—O10ⁱⁱ	79.02 (8)	O4—C7—C3	117.1 (3)
O10ⁱⁱ—Eu1—O12ⁱ	143.40 (10)	N2—C8—C9	121.5 (3)
O1—Cu1—O7	97.47 (10)	C8—C9—C10	119.7 (3)
O1—Cu1—N1	84.50 (11)	C9—C10—C11	118.4 (3)
O1—Cu1—O5^iv	172.30 (10)	C9—C10—C14	120.4 (3)
O1—Cu1—N2^iv	94.73 (11)	C11—C10—C14	121.1 (3)
O1—Cu1—O2^v	92.14 (9)	C10—C11—C12	118.9 (3)
O7—Cu1—N1	93.91 (10)	C11—C12—C13	124.3 (3)
O5^iv—Cu1—O7	90.08 (9)	N2—C12—C13	113.4 (3)
O7—Cu1—N2^iv	93.32 (10)	N2—C12—C11	122.1 (3)
O2^v—Cu1—O7	164.52 (8)	O5—C13—C12	115.7 (3)
O5^iv—Cu1—N1	96.55 (10)	O6—C13—C12	118.4 (3)
N1—Cu1—N2^iv	172.76 (12)	O5—C13—O6	125.9 (3)
O2^v—Cu1—N1	99.09 (10)	O8—C14—C10	117.1 (3)
O5^iv—Cu1—N2^iv	83.28 (10)	O7—C14—O8	126.2 (3)
O2^v—Cu1—O5^iv	80.16 (8)	O7—C14—C10	116.7 (3)
O2^v—Cu1—N2^iv	73.73 (10)	N3—C15—C20	113.9 (3)
O2—Cu2—O9	88.97 (10)	C16—C15—C20	123.7 (3)
O2—Cu2—N3	88.99 (10)	N3—C15—C16	122.4 (3)
O2—Cu2—O2ⁱⁱ	180.00	C15—C16—C17	118.4 (3)
O2—Cu2—O9ⁱⁱ	91.03 (10)	C16—C17—C21	120.6 (3)
O2—Cu2—N3ⁱⁱ	91.01 (10)	C18—C17—C21	120.5 (3)
O9—Cu2—N3	83.49 (11)	C16—C17—C18	118.9 (3)
O2ⁱⁱ—Cu2—O9	91.03 (10)	C17—C18—C19	119.3 (3)
O9—Cu2—O9ⁱⁱ	180.00	N3—C19—C18	121.6 (3)
O9—Cu2—N3ⁱⁱ	96.51 (10)	O9—C20—C15	115.9 (3)
O2ⁱⁱ—Cu2—N3	91.01 (10)	O10—C20—C15	118.3 (3)
O9ⁱⁱ—Cu2—N3	96.51 (11)	O9—C20—O10	125.7 (3)
N3—Cu2—N3ⁱⁱ	180.00	O12—C21—C17	117.9 (3)
O2ⁱⁱ—Cu2—O9ⁱⁱ	88.97 (10)	O11—C21—O12	124.9 (3)
O2ⁱⁱ—Cu2—N3ⁱⁱ	88.99 (10)	O11—C21—C17	117.2 (3)
O9ⁱⁱ—Cu2—N3ⁱⁱ	83.49 (10)	C1—C2—H2A	120.00
Cu1—O1—C6	114.4 (2)	C3—C2—H2A	120.00
Cu2—O2—C6	120.1 (2)	C3—C4—H4A	120.00
Cu1^v—O2—Cu2	138.98 (10)	C5—C4—H4A	120.00
Cu1^v—O2—C6	94.1 (2)	N1—C5—H5A	119.00
Cu1^iv—O5—C13	115.0 (2)	C4—C5—H5A	119.00
Eu1ⁱ—O6—C13	131.3 (2)	N2—C8—H8A	119.00
Cu1—O7—C14	130.9 (2)	C9—C8—H8A	119.00
Eu1—O8—C14	134.9 (2)	C8—C9—H9A	120.00
Cu2—O9—C20	113.9 (2)	C10—C9—H9A	120.00
Eu1ⁱⁱ—O10—C20	127.0 (2)	C10—C11—H11A	121.00
Eu1^vi—O11—C21	125.3 (2)	C12—C11—H11A	121.00
Eu1ⁱ—O12—C21	173.8 (3)	C15—C16—H16A	121.00
H13A—O13—H13B	112.00	C17—C16—H16A	121.00
Eu1—O13—H13A	108.00	C17—C18—H18A	120.00
Eu1—O13—H13B	120.00	C19—C18—H18A	120.00
H14A—O14—H14B	104.00	N3—C19—H19A	119.00
Eu1—O14—H14A	105.00	C18—C19—H19A	119.00
Eu1—O14—H14B	114.00

O13—Eu1—O8—C14	−178.0 (3)	Cu1—O7—C14—C10	−65.8 (4)
O14—Eu1—O8—C14	−27.5 (3)	Eu1—O8—C14—O7	31.0 (5)
O15—Eu1—O8—C14	49.0 (3)	Eu1—O8—C14—C10	−149.5 (2)
O11ⁱⁱⁱ—Eu1—O8—C14	9.9 (4)	Cu2—O9—C20—O10	171.5 (3)
O6ⁱ—Eu1—O8—C14	−162.9 (3)	Cu2—O9—C20—C15	−10.4 (3)
O12ⁱ—Eu1—O8—C14	120.0 (3)	Eu1ⁱⁱ—O10—C20—O9	6.3 (5)
O10ⁱⁱ—Eu1—O8—C14	−93.0 (3)	Eu1ⁱⁱ—O10—C20—C15	−171.72 (19)
O8—Eu1—O11ⁱⁱⁱ—C21ⁱⁱⁱ	119.5 (3)	Eu1^vi—O11—C21—O12	−20.8 (5)
O13—Eu1—O11ⁱⁱⁱ—C21ⁱⁱⁱ	−55.5 (3)	Eu1^vi—O11—C21—C17	159.0 (2)
O14—Eu1—O11ⁱⁱⁱ—C21ⁱⁱⁱ	157.4 (3)	Cu1—N1—C1—C2	−179.0 (3)
O15—Eu1—O11ⁱⁱⁱ—C21ⁱⁱⁱ	80.5 (3)	Cu1—N1—C1—C6	3.7 (3)
O8—Eu1—O6ⁱ—C13ⁱ	152.9 (3)	C5—N1—C1—C2	1.9 (5)
O13—Eu1—O6ⁱ—C13ⁱ	−36.4 (3)	C5—N1—C1—C6	−175.5 (3)
O14—Eu1—O6ⁱ—C13ⁱ	97.0 (3)	Cu1—N1—C5—C4	−179.0 (3)
O15—Eu1—O6ⁱ—C13ⁱ	−163.0 (3)	C1—N1—C5—C4	0.0 (5)
O8—Eu1—O10ⁱⁱ—C20ⁱⁱ	−10.3 (3)	C12—N2—C8—C9	3.3 (5)
O13—Eu1—O10ⁱⁱ—C20ⁱⁱ	130.9 (3)	Cu1^iv—N2—C8—C9	−175.7 (3)
O14—Eu1—O10ⁱⁱ—C20ⁱⁱ	−79.3 (3)	C8—N2—C12—C11	1.3 (5)
O15—Eu1—O10ⁱⁱ—C20ⁱⁱ	−100.9 (3)	C8—N2—C12—C13	−174.1 (3)
O7—Cu1—O1—C6	−96.6 (2)	Cu1^iv—N2—C12—C11	−179.6 (3)
N1—Cu1—O1—C6	−3.3 (2)	Cu1^iv—N2—C12—C13	5.0 (3)
N2^iv—Cu1—O1—C6	169.5 (3)	Cu2—N3—C15—C16	−179.6 (3)
O2^v—Cu1—O1—C6	95.6 (2)	Cu2—N3—C15—C20	1.9 (3)
O1—Cu1—O7—C14	−48.9 (3)	C19—N3—C15—C16	0.7 (5)
N1—Cu1—O7—C14	−133.9 (3)	C19—N3—C15—C20	−177.8 (3)
O5^iv—Cu1—O7—C14	129.6 (3)	Cu2—N3—C19—C18	−177.5 (3)
N2^iv—Cu1—O7—C14	46.3 (3)	C15—N3—C19—C18	2.2 (5)
O1—Cu1—N1—C1	−0.5 (2)	N1—C1—C2—C3	−2.1 (5)
O1—Cu1—N1—C5	178.5 (3)	C6—C1—C2—C3	175.1 (3)
O7—Cu1—N1—C1	96.6 (2)	N1—C1—C6—O1	−6.7 (4)
O7—Cu1—N1—C5	−84.4 (3)	N1—C1—C6—O2	170.7 (3)
O5^iv—Cu1—N1—C1	−172.9 (2)	C2—C1—C6—O1	176.0 (3)
O5^iv—Cu1—N1—C5	6.2 (3)	C2—C1—C6—O2	−6.7 (5)
O2^v—Cu1—N1—C1	−91.8 (2)	C1—C2—C3—C4	0.4 (5)
O2^v—Cu1—N1—C5	87.2 (3)	C1—C2—C3—C7	−174.7 (3)
O7—Cu1—O5^iv—C13^iv	−98.6 (2)	C2—C3—C4—C5	1.4 (6)
N1—Cu1—O5^iv—C13^iv	167.5 (2)	C7—C3—C4—C5	176.3 (4)
O1—Cu1—N2^iv—C8^iv	14.0 (3)	C2—C3—C7—O3	−6.4 (5)
O1—Cu1—N2^iv—C12^iv	−166.9 (2)	C2—C3—C7—O4	172.3 (4)
O7—Cu1—N2^iv—C8^iv	−83.8 (3)	C4—C3—C7—O3	178.8 (4)
O7—Cu1—N2^iv—C12^iv	95.3 (2)	C4—C3—C7—O4	−2.5 (6)
O1—Cu1—O2^v—C6^v	−12.3 (2)	C3—C4—C5—N1	−1.6 (6)
N1—Cu1—O2^v—C6^v	72.5 (2)	N2—C8—C9—C10	−4.7 (5)
O9—Cu2—O2—C6	158.3 (3)	C8—C9—C10—C11	1.4 (5)
O9—Cu2—O2—Cu1^v	15.88 (14)	C8—C9—C10—C14	178.3 (3)
N3—Cu2—O2—C6	74.8 (3)	C9—C10—C11—C12	2.9 (5)
N3—Cu2—O2—Cu1^v	−67.63 (15)	C14—C10—C11—C12	−173.9 (3)
O9ⁱⁱ—Cu2—O2—C6	−21.7 (3)	C9—C10—C14—O7	−37.3 (5)
N3ⁱⁱ—Cu2—O2—C6	−105.2 (3)	C9—C10—C14—O8	143.1 (3)
O2—Cu2—O9—C20	−80.0 (2)	C11—C10—C14—O7	139.4 (3)
N3—Cu2—O9—C20	9.1 (2)	C11—C10—C14—O8	−40.2 (5)
O2ⁱⁱ—Cu2—O9—C20	100.0 (2)	C10—C11—C12—N2	−4.4 (5)
N3ⁱⁱ—Cu2—O9—C20	−170.9 (2)	C10—C11—C12—C13	170.5 (3)
O2—Cu2—N3—C15	83.5 (2)	N2—C12—C13—O5	−0.9 (4)
O2—Cu2—N3—C19	−96.9 (3)	N2—C12—C13—O6	175.6 (3)
O9—Cu2—N3—C15	−5.6 (2)	C11—C12—C13—O5	−176.2 (3)
O9—Cu2—N3—C19	174.1 (3)	C11—C12—C13—O6	0.3 (5)
O2ⁱⁱ—Cu2—N3—C15	−96.5 (2)	N3—C15—C16—C17	−2.3 (5)
O2ⁱⁱ—Cu2—N3—C19	83.1 (3)	C20—C15—C16—C17	176.1 (3)
O9ⁱⁱ—Cu2—N3—C15	174.4 (2)	N3—C15—C20—O9	5.8 (4)
O9ⁱⁱ—Cu2—N3—C19	−6.0 (3)	N3—C15—C20—O10	−176.0 (3)
Cu1—O1—C6—O2	−171.0 (3)	C16—C15—C20—O9	−172.7 (3)
Cu1—O1—C6—C1	6.1 (4)	C16—C15—C20—O10	5.5 (5)
Cu2—O2—C6—O1	−76.7 (4)	C15—C16—C17—C18	1.0 (5)
Cu2—O2—C6—C1	106.3 (3)	C15—C16—C17—C21	−176.4 (3)
Cu1^v—O2—C6—O1	79.6 (4)	C16—C17—C18—C19	1.7 (6)
Cu1^v—O2—C6—C1	−97.4 (3)	C21—C17—C18—C19	179.1 (3)
Cu1^iv—O5—C13—O6	179.9 (3)	C16—C17—C21—O11	−27.2 (5)
Cu1^iv—O5—C13—C12	−3.9 (3)	C16—C17—C21—O12	152.6 (4)
Eu1ⁱ—O6—C13—O5	−4.7 (5)	C18—C17—C21—O11	155.5 (4)
Eu1ⁱ—O6—C13—C12	179.13 (19)	C18—C17—C21—O12	−24.7 (5)
Cu1—O7—C14—O8	113.8 (4)	C17—C18—C19—N3	−3.4 (6)

Symmetry codes: (i) −x+1, −y+1, −z; (ii) −x+1, −y+2, −z; (iii) x, y, z+1; (iv) −x, −y+1, −z; (v) −x, −y+2, −z; (vi) x, y, z−1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O13—H13A···O5ⁱ	0.82	2.00	2.769 (3)	155
O13—H13B···O15^vii	0.82	2.02	2.822 (4)	164
O14—H14A···O7	0.82	1.89	2.690 (4)	164
O14—H14B···O4^viii	0.82	1.88	2.667 (4)	161
O15—H15A···O3^ix	0.82	1.83	2.630 (4)	164
O15—H15B···O4^viii	0.82	2.06	2.814 (4)	153
C18—H18A···O6	0.93	2.48	3.389 (4)	167

Symmetry codes: (i) −x+1, −y+1, −z; (vii) −x+1, −y+1, −z+1; (viii) −x, −y+2, −z+1; (ix) x, y−1, z.

Experimental details

Crystal data
Chemical formula	[Cu₃Eu₂(C₇H₃NO₄)₆(H₂O)₆]
M_r	1593.29
Crystal system, space group	Triclinic, P1
Temperature (K)	294
a, b, c (Å)	9.4296 (10), 10.7002 (11), 12.2874 (13)
α, β, γ (°)	86.186 (2), 81.556 (2), 86.561 (2)
V (Å³)	1222.0 (2)
Z	1
Radiation type	Mo Kα
µ (mm⁻¹)	3.92
Crystal size (mm)	0.24 × 0.20 × 0.20

Data collection
Diffractometer	Bruker SMART CCD area-detector
Absorption correction	Multi-scan (SADABS; Bruker, 2000)
T_min, T_max	0.659, 0.977
No. of measured, independent and observed [I > 2σ(I)] reflections	12982, 5780, 4828
R_int	0.044
(sin θ/λ)_max (Å⁻¹)	0.667

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.028, 0.066, 0.98
No. of reflections	5780
No. of parameters	376
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	1.69, −0.94

Computer programs: SMART (Bruker, 2000), SAINT (Bruker, 1999), SHELXTL (Sheldrick, 2008), PLATON (Spek, 2009).

Selected bond lengths (Å) top

Eu1—O6ⁱ	2.485 (2)	Cu1—O1	1.932 (3)
Eu1—O8	2.386 (3)	Cu1—O5^iv	1.944 (2)
Eu1—O10ⁱⁱ	2.404 (2)	Cu1—O7	2.359 (3)
Eu1—O11ⁱⁱⁱ	2.385 (2)	Cu1—N1	1.975 (3)
Eu1—O12ⁱ	2.328 (2)	Cu1—N2^iv	1.975 (3)
Eu1—O13	2.454 (3)	Cu2—O2	2.409 (3)
Eu1—O14	2.442 (3)	Cu2—O9	1.968 (2)
Eu1—O15	2.510 (3)	Cu2—N3	1.969 (3)

Symmetry codes: (i) −x+1, −y+1, −z; (ii) −x+1, −y+2, −z; (iii) x, y, z+1; (iv) −x, −y+1, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O13—H13A···O5ⁱ	0.82	2.00	2.769 (3)	155
O13—H13B···O15^v	0.82	2.02	2.822 (4)	164
O14—H14A···O7	0.82	1.89	2.690 (4)	164
O14—H14B···O4^vi	0.82	1.88	2.667 (4)	161
O15—H15A···O3^vii	0.82	1.83	2.630 (4)	164
O15—H15B···O4^vi	0.82	2.06	2.814 (4)	153

Symmetry codes: (i) −x+1, −y+1, −z; (v) −x+1, −y+1, −z+1; (vi) −x, −y+2, −z+1; (vii) x, y−1, z.

Acknowledgements

This work was financial supported by Yuanpei University, Taiwan.

References

Bruker (1999). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Bruker (2000). SMART. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Huang, Y.-G., Wu, M.-Y., Lian, F.-Y., Jiang, F.-L. & Hong, M.-C. (2008a). Inorg. Chem. Commun. 11, 840–842. Web of Science CSD CrossRef CAS Google Scholar
Huang, Y.-G., Wu, M.-Y., Wei, W., Gao, Q., Yuan, D.-Q., Jiang, F.-L. & Hong, M.-C. (2008b). J. Mol. Struct. 885, 23–27. Web of Science CSD CrossRef CAS Google Scholar
Ma, D.-Y., Wang, W.-X. & Li, Y.-W. (2010). J. Coord. Chem. 63, 448–456. Web of Science CSD CrossRef CAS Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Song, Y.-S., Yan, B. & Weng, L.-H. (2006). Inorg. Chem. Commun. 9, 567–570. Web of Science CSD CrossRef CAS Google Scholar
Spek, A. L. (2009). Acta Cryst. D65, 148–155. Web of Science CrossRef CAS IUCr Journals Google Scholar
Wang, N., Yue, S.-T., Liu, Y.-L., Yang, H.-Y. & Wu, H.-Y. (2009). Cryst. Growth Des. 9, 368–371. Web of Science CSD CrossRef CAS Google Scholar
Wang, N., Yue, S.-T., Wu, H.-Y., Li, X.-X. & Liu, Y.-L. (2010). Inorg. Chim. Acta, 363, 1008–1012. Web of Science CrossRef CAS Google Scholar
Wang, F.-Q., Zheng, X.-J., Wan, Y.-H., Sun, C.-Y., Wang, Z.-M., Wang, K.-Z. & Jin, L.-P. (2007). Inorg. Chem. 46, 2956–2958. Web of Science CSD CrossRef PubMed CAS Google Scholar
Zhao, X.-Q., Zhao, B., Ma, Y., Shi, W., Cheng, P., Jiang, Z.-H., Liao, D.-Z. & Yan, S.-P. (2007). Inorg. Chem. 46, 5832–5834. Web of Science CSD CrossRef PubMed CAS Google Scholar

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Volume 66| Part 12| December 2010| Pages m1516-m1517

https://doi.org/10.1107/S1600536810044594

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Poly[hexa­aqua­hexa­kis­(μ-pyridine-2,4-di­carboxyl­ato)tricopper(II)dieuropium(III)]

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Experimental

Crystal data

Data collection

Refinement

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metal-organic compounds

Poly[hexaaquahexakis(μ-pyridine-2,4-dicarboxylato)tricopper(II)dieuropium(III)]