Tetra­kis[(4-meth­oxy­carbon­yl)anilinium] hexa­chloridostannate(IV) dichloride

Xiao, W.; Xue, R.; Yin, Y.

doi:10.1107/S1600536811003692

metal-organic compounds

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ISSN: 2056-9890

Volume 67| Part 3| March 2011| Page m297

doi:10.1107/S1600536811003692

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Tetrakis[(4-methoxycarbonyl)anilinium] hexachloridostannate(IV) dichloride

Wenzhi Xiao,^a Ruiting Xue ^b and Yansheng Yin ^b ^*

^aDepartment of Physics and Mathematics, Hunan Institute of Engineering, Xiangtan 411104, People's Republic of China, and ^bInstitute of Material Science and Engineering, Ocean University of China, Qingdao, Shandong 266100, People's Republic of China
^*Correspondence e-mail: yys2004@ouc.edu.cn

(Received 4 January 2011; accepted 28 January 2011; online 2 February 2011)

The asymmetric unit of the title compound, (C₈H₁₀NO₂)₄[SnCl₆]Cl₂, contains two (4-methoxycarbonyl)anilinium cations, one chloride anion and one half of a hexachloridostannate(IV) dianion situated on a twofold rotation axis. All aminium H atoms are involved in N—H⋯Cl hydrogen bonding, which consolidate the crystal packing along with weak C—H⋯O interactions.

Related literature

For general background to inorganic–organic hybrid compounds, see: Zhang et al. (2009 ); Descalzo et al. (2006 ); Li et al. (2007 ), Sanchez et al. (2005 ).

Experimental

Crystal data

(C₈H₁₀NO₂)₄[SnCl₆]Cl₂
M_r = 1010.97
Monoclinic, C 2/c
a = 30.748 (3) Å
b = 7.1172 (8) Å
c = 22.113 (2) Å
β = 119.424 (2)°
V = 4215.0 (7) Å³
Z = 4
Mo Kα radiation
μ = 1.16 mm⁻¹
T = 298 K
0.50 × 0.46 × 0.46 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ) T_min = 0.594, T_max = 0.617
10221 measured reflections
3719 independent reflections
2969 reflections with I > 2σ(I)
R_int = 0.035

Refinement

R[F² > 2σ(F²)] = 0.031
wR(F²) = 0.090
S = 1.01
3719 reflections
245 parameters
H-atom parameters constrained
Δρ_max = 0.51 e Å⁻³
Δρ_min = −0.44 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1A⋯Cl3	0.89	2.78	3.659 (4)	170
N2—H2B⋯Cl3	0.89	2.71	3.479 (3)	145
N2—H2C⋯Cl4	0.89	2.21	3.098 (4)	177
N1—H1B⋯Cl4ⁱ	0.89	2.29	3.155 (4)	165
N1—H1C⋯Cl4ⁱⁱ	0.89	2.22	3.092 (4)	166
N2—H2A⋯Cl1ⁱⁱⁱ	0.89	3.01	3.482 (3)	115
C3—H3⋯O4^iv	0.93	2.39	3.148 (6)	139
C15—H15⋯O2^v	0.93	2.38	3.130 (5)	138
Symmetry codes: (i) -x, -y+1, -z; (ii) x, y+1, z; (iii) x, y-1, z; (iv) $[x+{\script{1\over 2}}, -y+{\script{3\over 2}}, z+{\script{1\over 2}}]$ ; (v) $[x-{\script{1\over 2}}, y-{\script{1\over 2}}, z]$ .

Data collection: SMART (Bruker, 2007 ); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536811003692/cv5035sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536811003692/cv5035Isup2.hkl

checkCIF report

Comment top

Considerable attention has been devoted to inorganic-organic hybrid materials over recent years (Zhang et al., 2009). These hybrid materials have potential applications in many areas including gas storage, separation, catalysis, magnetism, optics as well as electrical conductivity (Descalzo et al., 2006; Li et al., 2007; Sanchez et al., 2005]. Herein we report the structure of the title compound (Fig.1.),

This title compound contains SnCl₆ inorganic anions, organic cations and dissociated chloride anions. The SnCl₆ inorganic anion adopts a regular octahedron geometry, with average Sn—Cl distance of 2.4262 Å. In the organic cation, the dihedral angle between the ester group and the phenyl ring is 14.86(0.19)°.

In the crystal structure, intermolecular N—H···Cl and C—H···O hydrogen bonds (Table 1) link cations and anions into layers with alternating inorganic and organic species.

Related literature top

For general background to inorganic–organic hybrid compounds, see: Zhang et al. (2009); Descalzo et al. (2006); Li et al. (2007), Sanchez et al. (2005).

Experimental top

4-Aminobenzoic acid (10 mmol) was dissolved to acid methanol solution (10 ml). Ten minutes later, a methanol solution (10 ml) of tin tetrachloride(5 mmol) was added with stirring. The mixture was stirred for 4 h. Crystals of the title compound suitable for X-ray analysis were grown from the saturation ethanol solution after about two weeks.

Computing details top

Data collection: SMART (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top

Fig. 1. A portion of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme in asymmetric unit [symmetry code (A): -x, y, -z + 1/2]. Dashed lines denote N—H···Cl hydrogen bonds.

Tetrakis[(4-methoxycarbonyl)anilinium] hexachloridostannate(IV) dichloride top

Crystal data top

(C₈H₁₀NO₂)₄[SnCl₆]Cl₂	F(000) = 2040
M_r = 1010.97	D_x = 1.593 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
a = 30.748 (3) Å	Cell parameters from 4623 reflections
b = 7.1172 (8) Å	θ = 2.7–27.7°
c = 22.113 (2) Å	µ = 1.16 mm⁻¹
β = 119.424 (2)°	T = 298 K
V = 4215.0 (7) Å³	Block, yellow
Z = 4	0.50 × 0.46 × 0.46 mm

Data collection top

Bruker SMART CCD area-detector diffractometer	3719 independent reflections
Radiation source: fine-focus sealed tube	2969 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.035
ϕ and ω scans	θ_max = 25.0°, θ_min = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −29→36
T_min = 0.594, T_max = 0.617	k = −7→8
10221 measured reflections	l = −26→25

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.031	H-atom parameters constrained
wR(F²) = 0.090	w = 1/[σ²(F_o²) + (0.045P)² + 5.2918P] where P = (F_o² + 2F_c²)/3
S = 1.01	(Δ/σ)_max < 0.001
3719 reflections	Δρ_max = 0.51 e Å⁻³
245 parameters	Δρ_min = −0.44 e Å⁻³
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.00204 (13)

Crystal data top

(C₈H₁₀NO₂)₄[SnCl₆]Cl₂	V = 4215.0 (7) Å³
M_r = 1010.97	Z = 4
Monoclinic, C2/c	Mo Kα radiation
a = 30.748 (3) Å	µ = 1.16 mm⁻¹
b = 7.1172 (8) Å	T = 298 K
c = 22.113 (2) Å	0.50 × 0.46 × 0.46 mm
β = 119.424 (2)°

Data collection top

Bruker SMART CCD area-detector diffractometer	3719 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	2969 reflections with I > 2σ(I)
T_min = 0.594, T_max = 0.617	R_int = 0.035
10221 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.031	0 restraints
wR(F²) = 0.090	H-atom parameters constrained
S = 1.01	Δρ_max = 0.51 e Å⁻³
3719 reflections	Δρ_min = −0.44 e Å⁻³
245 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Sn1	0.0000	0.88525 (4)	0.2500	0.03147 (14)
Cl1	0.05414 (3)	1.12542 (12)	0.24657 (5)	0.0448 (2)
Cl2	0.04668 (3)	0.88401 (13)	0.37614 (4)	0.0446 (2)
Cl3	0.05329 (3)	0.64043 (12)	0.24497 (5)	0.0452 (2)
Cl4	0.01937 (4)	0.27991 (19)	0.05504 (6)	0.0745 (4)
N1	0.05296 (13)	0.8682 (5)	0.09640 (19)	0.0681 (11)
H1A	0.0488	0.8145	0.1295	0.102*
H1B	0.0354	0.8058	0.0568	0.102*
H1C	0.0425	0.9868	0.0908	0.102*
O1	0.28945 (11)	0.8266 (5)	0.23899 (19)	0.0801 (9)
O2	0.27319 (15)	0.8654 (6)	0.1308 (2)	0.1100 (15)
C1	0.25910 (17)	0.8534 (6)	0.1724 (3)	0.0614 (12)
C2	0.20539 (15)	0.8609 (5)	0.1534 (2)	0.0488 (9)
C3	0.19023 (15)	0.8011 (7)	0.1997 (2)	0.0596 (11)
H3	0.2138	0.7596	0.2437	0.071*
C4	0.14066 (15)	0.8028 (7)	0.1808 (2)	0.0627 (12)
H4	0.1305	0.7621	0.2119	0.075*
C5	0.10627 (15)	0.8642 (5)	0.1165 (2)	0.0510 (10)
C6	0.12064 (16)	0.9276 (6)	0.0699 (2)	0.0563 (10)
H6	0.0971	0.9721	0.0265	0.068*
C7	0.17023 (16)	0.9236 (6)	0.0889 (2)	0.0571 (11)
H7	0.1803	0.9640	0.0577	0.069*
C8	0.34155 (17)	0.8066 (9)	0.2610 (3)	0.0977 (18)
H8A	0.3466	0.6959	0.2404	0.146*
H8B	0.3601	0.7958	0.3107	0.146*
H8C	0.3528	0.9148	0.2467	0.146*
N2	−0.04641 (12)	0.3799 (4)	0.12080 (17)	0.0549 (8)
H2A	−0.0469	0.2835	0.1461	0.082*
H2B	−0.0329	0.4794	0.1481	0.082*
H2C	−0.0284	0.3495	0.1008	0.082*
O3	−0.27704 (11)	0.5652 (5)	−0.06223 (17)	0.0754 (9)
O4	−0.25318 (15)	0.6482 (7)	−0.1379 (2)	0.1235 (17)
C9	−0.24390 (17)	0.5845 (7)	−0.0834 (2)	0.0649 (12)
C10	−0.19295 (13)	0.5235 (6)	−0.03008 (18)	0.0475 (9)
C11	−0.15324 (15)	0.5639 (6)	−0.0409 (2)	0.0530 (10)
H11	−0.1591	0.6244	−0.0814	0.064*
C12	−0.10518 (13)	0.5155 (5)	0.00777 (19)	0.0460 (9)
H12	−0.0785	0.5435	0.0007	0.055*
C13	−0.09772 (13)	0.4248 (5)	0.06700 (18)	0.0412 (8)
C14	−0.13659 (14)	0.3806 (5)	0.07820 (19)	0.0484 (9)
H14	−0.1306	0.3179	0.1185	0.058*
C15	−0.18453 (14)	0.4296 (6)	0.0293 (2)	0.0538 (10)
H15	−0.2112	0.3995	0.0363	0.065*
C16	−0.32747 (17)	0.6233 (8)	−0.1111 (3)	0.100 (2)
H16A	−0.3402	0.5467	−0.1521	0.150*
H16B	−0.3274	0.7526	−0.1234	0.150*
H16C	−0.3483	0.6091	−0.0903	0.150*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.0315 (2)	0.0292 (2)	0.0350 (2)	0.000	0.01734 (15)	0.000
Cl1	0.0388 (5)	0.0417 (5)	0.0498 (5)	−0.0108 (4)	0.0187 (4)	0.0027 (4)
Cl2	0.0430 (5)	0.0531 (6)	0.0319 (5)	0.0061 (4)	0.0138 (4)	0.0043 (4)
Cl3	0.0441 (5)	0.0385 (5)	0.0611 (6)	0.0090 (4)	0.0322 (5)	0.0006 (4)
Cl4	0.0609 (7)	0.0948 (9)	0.0812 (8)	0.0232 (6)	0.0452 (6)	0.0309 (7)
N1	0.054 (2)	0.094 (3)	0.063 (2)	0.0182 (18)	0.0344 (19)	0.021 (2)
O1	0.0490 (18)	0.115 (3)	0.080 (2)	0.0101 (17)	0.0348 (18)	−0.003 (2)
O2	0.084 (3)	0.174 (4)	0.107 (3)	0.001 (2)	0.074 (3)	0.016 (3)
C1	0.063 (3)	0.055 (3)	0.086 (4)	−0.006 (2)	0.052 (3)	−0.008 (2)
C2	0.056 (2)	0.045 (2)	0.060 (3)	0.0003 (17)	0.040 (2)	−0.0021 (18)
C3	0.051 (2)	0.083 (3)	0.052 (2)	0.013 (2)	0.031 (2)	0.017 (2)
C4	0.056 (3)	0.091 (3)	0.056 (3)	0.019 (2)	0.038 (2)	0.028 (2)
C5	0.052 (2)	0.056 (3)	0.055 (2)	0.0110 (18)	0.034 (2)	0.0093 (19)
C6	0.063 (3)	0.065 (3)	0.047 (2)	0.009 (2)	0.032 (2)	0.0141 (19)
C7	0.072 (3)	0.062 (3)	0.056 (3)	0.003 (2)	0.046 (2)	0.008 (2)
C8	0.053 (3)	0.114 (4)	0.128 (5)	0.012 (3)	0.046 (3)	−0.002 (4)
N2	0.0470 (19)	0.057 (2)	0.052 (2)	0.0027 (15)	0.0173 (16)	−0.0006 (16)
O3	0.0418 (16)	0.094 (2)	0.075 (2)	0.0087 (16)	0.0164 (16)	−0.0012 (18)
O4	0.081 (3)	0.201 (5)	0.063 (2)	0.034 (3)	0.015 (2)	0.051 (3)
C9	0.055 (3)	0.073 (3)	0.047 (3)	0.008 (2)	0.010 (2)	−0.002 (2)
C10	0.046 (2)	0.053 (2)	0.039 (2)	0.0024 (17)	0.0163 (18)	−0.0014 (18)
C11	0.063 (3)	0.055 (2)	0.041 (2)	0.0008 (19)	0.025 (2)	0.0055 (18)
C12	0.046 (2)	0.046 (2)	0.051 (2)	−0.0042 (17)	0.0277 (19)	0.0003 (18)
C13	0.040 (2)	0.042 (2)	0.038 (2)	0.0015 (15)	0.0161 (16)	−0.0023 (16)
C14	0.048 (2)	0.056 (2)	0.040 (2)	0.0017 (18)	0.0207 (18)	0.0097 (17)
C15	0.042 (2)	0.070 (3)	0.048 (2)	−0.0043 (19)	0.0216 (19)	0.004 (2)
C16	0.039 (3)	0.114 (5)	0.103 (4)	0.013 (3)	0.002 (3)	−0.023 (3)

Geometric parameters (Å, º) top

Sn1—Cl1	2.4131 (8)	C8—H8A	0.9600
Sn1—Cl1ⁱ	2.4131 (8)	C8—H8B	0.9600
Sn1—Cl2ⁱ	2.4305 (9)	C8—H8C	0.9600
Sn1—Cl2	2.4305 (9)	N2—C13	1.471 (4)
Sn1—Cl3	2.4315 (8)	N2—H2A	0.8900
Sn1—Cl3ⁱ	2.4315 (8)	N2—H2B	0.8900
N1—C5	1.473 (5)	N2—H2C	0.8900
N1—H1A	0.8900	O3—C9	1.320 (5)
N1—H1B	0.8900	O3—C16	1.448 (5)
N1—H1C	0.8900	O4—C9	1.185 (5)
O1—C1	1.314 (6)	C9—C10	1.489 (5)
O1—C8	1.434 (5)	C10—C15	1.380 (5)
O2—C1	1.197 (5)	C10—C11	1.384 (5)
C1—C2	1.492 (5)	C11—C12	1.377 (5)
C2—C7	1.373 (6)	C11—H11	0.9300
C2—C3	1.384 (5)	C12—C13	1.375 (5)
C3—C4	1.368 (5)	C12—H12	0.9300
C3—H3	0.9300	C13—C14	1.371 (5)
C4—C5	1.362 (5)	C14—C15	1.378 (5)
C4—H4	0.9300	C14—H14	0.9300
C5—C6	1.380 (5)	C15—H15	0.9300
C6—C7	1.369 (5)	C16—H16A	0.9600
C6—H6	0.9300	C16—H16B	0.9600
C7—H7	0.9300	C16—H16C	0.9600

Cl1—Sn1—Cl1ⁱ	89.79 (5)	C2—C7—H7	119.5
Cl1—Sn1—Cl2ⁱ	89.66 (3)	O1—C8—H8A	109.5
Cl1ⁱ—Sn1—Cl2ⁱ	90.63 (3)	O1—C8—H8B	109.5
Cl1—Sn1—Cl2	90.63 (3)	H8A—C8—H8B	109.5
Cl1ⁱ—Sn1—Cl2	89.66 (3)	O1—C8—H8C	109.5
Cl2ⁱ—Sn1—Cl2	179.58 (4)	H8A—C8—H8C	109.5
Cl1—Sn1—Cl3	90.88 (3)	H8B—C8—H8C	109.5
Cl1ⁱ—Sn1—Cl3	179.00 (3)	C13—N2—H2A	109.5
Cl2ⁱ—Sn1—Cl3	88.64 (3)	C13—N2—H2B	109.5
Cl2—Sn1—Cl3	91.06 (3)	H2A—N2—H2B	109.5
Cl1—Sn1—Cl3ⁱ	179.00 (3)	C13—N2—H2C	109.5
Cl1ⁱ—Sn1—Cl3ⁱ	90.88 (3)	H2A—N2—H2C	109.5
Cl2ⁱ—Sn1—Cl3ⁱ	91.06 (3)	H2B—N2—H2C	109.5
Cl2—Sn1—Cl3ⁱ	88.64 (3)	C9—O3—C16	115.8 (4)
Cl3—Sn1—Cl3ⁱ	88.45 (4)	O4—C9—O3	124.0 (4)
C5—N1—H1A	109.5	O4—C9—C10	123.4 (5)
C5—N1—H1B	109.5	O3—C9—C10	112.6 (4)
H1A—N1—H1B	109.5	C15—C10—C11	119.7 (3)
C5—N1—H1C	109.5	C15—C10—C9	121.8 (4)
H1A—N1—H1C	109.5	C11—C10—C9	118.5 (4)
H1B—N1—H1C	109.5	C12—C11—C10	120.8 (4)
C1—O1—C8	117.0 (4)	C12—C11—H11	119.6
O2—C1—O1	123.1 (4)	C10—C11—H11	119.6
O2—C1—C2	123.4 (5)	C13—C12—C11	118.3 (3)
O1—C1—C2	113.5 (4)	C13—C12—H12	120.9
C7—C2—C3	119.2 (4)	C11—C12—H12	120.9
C7—C2—C1	120.1 (4)	C14—C13—C12	121.8 (3)
C3—C2—C1	120.6 (4)	C14—C13—N2	119.2 (3)
C4—C3—C2	120.1 (4)	C12—C13—N2	118.9 (3)
C4—C3—H3	120.0	C13—C14—C15	119.5 (4)
C2—C3—H3	120.0	C13—C14—H14	120.3
C5—C4—C3	119.9 (4)	C15—C14—H14	120.3
C5—C4—H4	120.0	C14—C15—C10	119.8 (4)
C3—C4—H4	120.0	C14—C15—H15	120.1
C4—C5—C6	121.0 (4)	C10—C15—H15	120.1
C4—C5—N1	119.9 (3)	O3—C16—H16A	109.5
C6—C5—N1	119.0 (4)	O3—C16—H16B	109.5
C7—C6—C5	118.8 (4)	H16A—C16—H16B	109.5
C7—C6—H6	120.6	O3—C16—H16C	109.5
C5—C6—H6	120.6	H16A—C16—H16C	109.5
C6—C7—C2	121.0 (3)	H16B—C16—H16C	109.5
C6—C7—H7	119.5

Symmetry code: (i) −x, y, −z+1/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1A···Cl3	0.89	2.78	3.659 (4)	170
N2—H2B···Cl3	0.89	2.71	3.479 (3)	145
N2—H2C···Cl4	0.89	2.21	3.098 (4)	177
N1—H1B···Cl4ⁱⁱ	0.89	2.29	3.155 (4)	165
N1—H1C···Cl4ⁱⁱⁱ	0.89	2.22	3.092 (4)	166
N2—H2A···Cl1^iv	0.89	3.01	3.482 (3)	115
C3—H3···O4^v	0.93	2.39	3.148 (6)	139
C15—H15···O2^vi	0.93	2.38	3.130 (5)	138

Symmetry codes: (ii) −x, −y+1, −z; (iii) x, y+1, z; (iv) x, y−1, z; (v) x+1/2, −y+3/2, z+1/2; (vi) x−1/2, y−1/2, z.

Experimental details

Crystal data
Chemical formula	(C₈H₁₀NO₂)₄[SnCl₆]Cl₂
M_r	1010.97
Crystal system, space group	Monoclinic, C2/c
Temperature (K)	298
a, b, c (Å)	30.748 (3), 7.1172 (8), 22.113 (2)
β (°)	119.424 (2)
V (Å³)	4215.0 (7)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.16
Crystal size (mm)	0.50 × 0.46 × 0.46

Data collection
Diffractometer	Bruker SMART CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Sheldrick, 1996)
T_min, T_max	0.594, 0.617
No. of measured, independent and observed [I > 2σ(I)] reflections	10221, 3719, 2969
R_int	0.035
(sin θ/λ)_max (Å⁻¹)	0.595

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.031, 0.090, 1.01
No. of reflections	3719
No. of parameters	245
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.51, −0.44

Computer programs: SMART (Bruker, 2007), SAINT (Bruker, 2007), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), XP in SHELXTL (Sheldrick, 2008).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1A···Cl3	0.89	2.78	3.659 (4)	170
N2—H2B···Cl3	0.89	2.71	3.479 (3)	145
N2—H2C···Cl4	0.89	2.21	3.098 (4)	177
N1—H1B···Cl4ⁱ	0.89	2.29	3.155 (4)	165
N1—H1C···Cl4ⁱⁱ	0.89	2.22	3.092 (4)	166
N2—H2A···Cl1ⁱⁱⁱ	0.89	3.01	3.482 (3)	115
C3—H3···O4^iv	0.93	2.39	3.148 (6)	139
C15—H15···O2^v	0.93	2.38	3.130 (5)	138

Symmetry codes: (i) −x, −y+1, −z; (ii) x, y+1, z; (iii) x, y−1, z; (iv) x+1/2, −y+3/2, z+1/2; (v) x−1/2, y−1/2, z.

Acknowledgements

The authors acknowledge the financial support of the National Science Foundation of China (grant Nos. 50672090 and 50702053).

References

Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Descalzo, A. B., Martinez-Manez, R., Sancenón, F., Hoffmann, K. & Rurack, K. (2006). Angew. Chem. Int. Ed. 45, 5924–5948. Web of Science CrossRef CAS Google Scholar
Li, Y. Y., Zheng, G. L., Lin, C. K. & Lin, J. (2007). Solid State Sci. 9, 855–861. Web of Science CSD CrossRef Google Scholar
Sanchez, C., Julián, B., Belleville, P. & Popall, M. (2005). J. Mater. Chem. 15, 3559–3592. Web of Science CrossRef CAS Google Scholar
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany. Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Zhang, S. J., Lanty, G., Lauret, J. S., Deleporte, E., Audebert, P. & Galmiche, L. (2009). Acta Mater. 57, 3301–3309. Web of Science CrossRef CAS Google Scholar

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Volume 67| Part 3| March 2011| Page m297

doi:10.1107/S1600536811003692

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Tetra­kis[(4-meth­­oxy­carbon­yl)anilinium] hexa­chloridostannate(IV) dichloride

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

Tetrakis[(4-methoxycarbonyl)anilinium] hexachloridostannate(IV) dichloride