Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ4O,N,N′,O′}manganese(III)

Liu, Y.

doi:10.1107/S1600536811004594

metal-organic compounds

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ISSN: 2056-9890

Volume 67| Part 3| March 2011| Page m322

doi:10.1107/S1600536811004594

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Azido{4,4′-dibromo-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ⁴O,N,N′,O′}manganese(III)

Yingxia Liu ^a ^*

^aSchool of Environmental and Material Engineering, Yantai University, Yantai 264005, People's Republic of China
^*Correspondence e-mail: liuyxytu@gmail.com

(Received 13 January 2011; accepted 7 February 2011; online 12 February 2011)

In the title compound, [Mn(C₁₆H₁₂Br₂N₂O₂)(N₃)], the Mn^III ion is chelated by a tetradentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O_phenolate distances of 2.667 (2) Å between pairs of inversion-related molecules. In the crystal, there are offset inter-complex face-to-face π–π interactions [centroid–centroid distances = 3.598 (2) Å] involving one of the benzene rings of the ligands.

Related literature

For related structures, see: Mikuriya et al. (1992 ); Li et al. (1997 ); Lu et al. (2006 ); Wang et al. (2008 ).

Experimental

Crystal data

[Mn(C₁₆H₁₂Br₂N₂O₂)(N₃)]
M_r = 1042.13
Monoclinic, P 2₁ /n
a = 8.7068 (17) Å
b = 15.269 (3) Å
c = 13.684 (3) Å
β = 107.47 (3)°
V = 1735.4 (6) Å³
Z = 2
Mo Kα radiation
μ = 5.39 mm⁻¹
T = 153 K
0.20 × 0.17 × 0.10 mm

Data collection

Nonius KappaCCD diffractometer
Absorption correction: multi-scan (SORTAV; Blessing, 1995 ) T_min = 0.352, T_max = 0.583
7747 measured reflections
3961 independent reflections
3093 reflections with I > 2σ(I)
R_int = 0.015

Refinement

R[F² > 2σ(F²)] = 0.030
wR(F²) = 0.074
S = 1.04
3961 reflections
235 parameters
H-atom parameters constrained
Δρ_max = 0.82 e Å⁻³
Δρ_min = −0.90 e Å⁻³

Data collection: COLLECT (Nonius, 1998 ); cell refinement: SCALEPACK (Otwinowski & Minor, 1997 ); data reduction: DENZO (Otwinowski & Minor, 1997) and maXus (Mackay et al., 1998 ); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536811004594/pk2299sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536811004594/pk2299Isup2.hkl

checkCIF report

Comment top

In the past decade there has been much interest in the magneto-chemistry of manganese because of its special magnetic properties. As is well known, manganese (III) Schiff base complexes display interesting structural, magnetic properties and electronic effects which rank it among the most appealing candidates as a building paramagnetic motif for multidimensional expanded structures. The variation of in-plane chelating and axial sites often leads to a change in the spin state of the metal ions: high-spin, low-spin or spin-crossover state. The nature and the tuning of magnetic interactions between metal centers are crucial points in the conception of molecular-based magnetic materials.

The molecular structure of the title compound is shown in Figure 1. The Mn^III ion is involved in a distorted square-pyramidal arrangement by a N3O2 unit, in which the four basal sites are occupied by two N atoms and two O atoms from the Schiff base ligand, and the apical position is occupied by the N atom of an azido ligand. The bond distances are comparable to those found in related structures (Lu, et al., 2006; Mikuriya, et al., 1992; Li, et al., 1997; Wang, et al., 2008). The Mn^III ion lies above the basal plane formed by N2O2 unit by 0.228 (1) Å. The short intermolecular distance of Mn···O_phenolate 2.667 (2) Å indicates that there exists weak interaction between the two complexes related by inversion centers in the crystal (Figure 2). The phenyl groups of the Schiff base are involved in an offset face-to-face π-π inter-complexes stacking interaction (ring centroid separation Cg···Cgⁱ, 3.598 (2) Å) [symmetry code: 2 - x,1 - y,1 - z].

Related literature top

For related structures, see: Mikuriya et al. (1992); Li et al. (1997); Lu et al. (2006); Wang et al. (2008).

Experimental top

This compound was synthesized by mixing a solution of Schiff base (2,2'-((1E,1'E)-(ethane-1,2-diylbis(azanylylidene)) bis(methanylylidene))bis(4-bromophenol)) (0.5 mmol) in methanol (5 ml) with a solution of MnCl₂.4H₂O (0.5 mmol) in methanol (5 ml), followed by the dropwise addition of an aqueous solution NaN₃(0.6 mmol, 2 mL) without stirring. The black mixture was allowed to stand for several days until good quality black block crystals of the compound were obtained in a yield of 68.3%.

Computing details top

Data collection: COLLECT (Nonius, 1998); cell refinement: SCALEPACK (Otwinowski & Minor, 1997); data reduction: DENZO (Otwinowski & Minor, 1997) and maXus (Mackay et al., 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure (30% thermal probability ellipsoids) of the compound showing the atom numbering.
	Fig. 2. A pair of inversion-related molecules, showing the intermolecular weak interactions between Mn and O_phenolate atoms. The 'A' molecule is related to the 'B' molecule by [A: (x, y, z) —> B: (2-x, 1-y, -z)].

Azido{4,4'-dibromo-2,2'-[ethane-1,2- diylbis(nitrilomethanylylidene)]diphenolato- κ⁴O,N,N',O'}manganese(III) top

Crystal data top

[Mn(C₁₆H₁₂Br₂N₂O₂)(N₃)]	F(000) = 1016
M_r = 1042.13	D_x = 1.994 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 19417 reflections
a = 8.7068 (17) Å	θ = 3.4–27.5°
b = 15.269 (3) Å	µ = 5.39 mm⁻¹
c = 13.684 (3) Å	T = 153 K
β = 107.47 (3)°	Block, black
V = 1735.4 (6) Å³	0.20 × 0.17 × 0.10 mm
Z = 2

Data collection top

Nonius KappaCCD diffractometer	3961 independent reflections
Radiation source: fine-focus sealed tube	3093 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.015
ω scans	θ_max = 27.5°, θ_min = 3.5°
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	h = −11→11
T_min = 0.352, T_max = 0.583	k = −19→19
7747 measured reflections	l = −17→17

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.074	H-atom parameters constrained
S = 1.04	w = 1/[σ²(F_o²) + (0.0376P)² + 0.8161P] where P = (F_o² + 2F_c²)/3
3961 reflections	(Δ/σ)_max = 0.001
235 parameters	Δρ_max = 0.82 e Å⁻³
0 restraints	Δρ_min = −0.90 e Å⁻³

Crystal data top

[Mn(C₁₆H₁₂Br₂N₂O₂)(N₃)]	V = 1735.4 (6) Å³
M_r = 1042.13	Z = 2
Monoclinic, P2₁/n	Mo Kα radiation
a = 8.7068 (17) Å	µ = 5.39 mm⁻¹
b = 15.269 (3) Å	T = 153 K
c = 13.684 (3) Å	0.20 × 0.17 × 0.10 mm
β = 107.47 (3)°

Data collection top

Nonius KappaCCD diffractometer	3961 independent reflections
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	3093 reflections with I > 2σ(I)
T_min = 0.352, T_max = 0.583	R_int = 0.015
7747 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.030	0 restraints
wR(F²) = 0.074	H-atom parameters constrained
S = 1.04	Δρ_max = 0.82 e Å⁻³
3961 reflections	Δρ_min = −0.90 e Å⁻³
235 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Mn1	0.85052 (5)	0.50918 (2)	0.38001 (3)	0.02912 (10)
Br1	1.11255 (4)	0.95137 (2)	0.37896 (3)	0.05433 (11)
Br2	0.43251 (4)	0.106181 (19)	0.44904 (2)	0.04785 (10)
C1	0.9787 (3)	0.67065 (17)	0.46365 (19)	0.0282 (5)
C2	0.9438 (3)	0.74469 (17)	0.5129 (2)	0.0323 (6)
H2	0.8919	0.7381	0.5627	0.039*
C3	0.9851 (3)	0.82750 (18)	0.4890 (2)	0.0358 (6)
H3	0.9580	0.8764	0.5208	0.043*
C4	1.0675 (3)	0.83713 (17)	0.4168 (2)	0.0336 (6)
C5	1.1113 (3)	0.76578 (18)	0.3710 (2)	0.0321 (6)
H5	1.1715	0.7732	0.3258	0.039*
C6	1.0655 (3)	0.68135 (17)	0.39187 (19)	0.0279 (5)
C7	1.1100 (3)	0.60754 (17)	0.33963 (19)	0.0307 (5)
H7	1.1928	0.6147	0.3104	0.037*
C8	1.0902 (4)	0.45714 (18)	0.2823 (2)	0.0403 (7)
H8A	1.1603	0.4191	0.3333	0.048*
H8B	1.1476	0.4763	0.2354	0.048*
C9	0.9380 (4)	0.4093 (2)	0.2250 (2)	0.0446 (7)
H9A	0.8813	0.4411	0.1634	0.054*
H9B	0.9636	0.3512	0.2056	0.054*
C10	0.7619 (3)	0.33187 (17)	0.30160 (19)	0.0314 (5)
H10	0.7730	0.2845	0.2615	0.038*
C11	0.6617 (3)	0.32053 (16)	0.36746 (19)	0.0274 (5)
C12	0.6028 (3)	0.23581 (17)	0.37468 (19)	0.0309 (5)
H12	0.6289	0.1898	0.3380	0.037*
C13	0.5066 (3)	0.22139 (16)	0.4361 (2)	0.0316 (6)
C14	0.4649 (3)	0.28895 (18)	0.4908 (2)	0.0348 (6)
H14	0.3986	0.2780	0.5315	0.042*
C15	0.5215 (3)	0.37191 (18)	0.4848 (2)	0.0344 (6)
H15	0.4912	0.4173	0.5204	0.041*
C16	0.6248 (3)	0.38931 (16)	0.4256 (2)	0.0285 (5)
N1	1.0407 (3)	0.53307 (14)	0.33190 (16)	0.0304 (5)
N2	0.8372 (3)	0.40293 (14)	0.29446 (16)	0.0314 (5)
N3	0.7109 (3)	0.60055 (17)	0.2717 (2)	0.0449 (6)
N4	0.5810 (3)	0.62722 (17)	0.26329 (18)	0.0412 (6)
N5	0.4533 (4)	0.6552 (3)	0.2518 (3)	0.0747 (10)
O1	0.9342 (2)	0.59151 (11)	0.48779 (14)	0.0333 (4)
O2	0.6852 (2)	0.46910 (12)	0.42930 (15)	0.0362 (4)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Mn1	0.0366 (2)	0.02311 (19)	0.0337 (2)	−0.00517 (16)	0.01976 (18)	−0.00327 (16)
Br1	0.0655 (2)	0.02778 (16)	0.0791 (3)	−0.00838 (14)	0.03595 (19)	0.00547 (15)
Br2	0.0672 (2)	0.02952 (16)	0.05173 (19)	−0.01626 (14)	0.02536 (16)	−0.00135 (13)
C1	0.0296 (12)	0.0273 (13)	0.0273 (12)	−0.0038 (10)	0.0079 (11)	0.0013 (10)
C2	0.0329 (13)	0.0305 (13)	0.0362 (14)	−0.0032 (11)	0.0147 (12)	−0.0028 (11)
C3	0.0336 (14)	0.0287 (14)	0.0472 (16)	−0.0010 (11)	0.0154 (13)	−0.0036 (12)
C4	0.0332 (14)	0.0243 (12)	0.0417 (15)	−0.0062 (11)	0.0090 (12)	0.0028 (11)
C5	0.0304 (13)	0.0330 (14)	0.0331 (14)	−0.0066 (11)	0.0096 (11)	0.0033 (11)
C6	0.0284 (12)	0.0273 (13)	0.0285 (13)	−0.0026 (10)	0.0092 (11)	0.0025 (10)
C7	0.0322 (13)	0.0331 (14)	0.0293 (13)	−0.0012 (11)	0.0129 (11)	0.0040 (11)
C8	0.0549 (18)	0.0305 (14)	0.0490 (17)	0.0016 (13)	0.0359 (15)	−0.0012 (12)
C9	0.070 (2)	0.0367 (16)	0.0416 (16)	−0.0095 (14)	0.0383 (16)	−0.0092 (13)
C10	0.0389 (14)	0.0269 (13)	0.0282 (13)	0.0003 (11)	0.0101 (11)	−0.0034 (10)
C11	0.0288 (12)	0.0250 (13)	0.0282 (13)	−0.0032 (10)	0.0080 (11)	−0.0008 (10)
C12	0.0363 (14)	0.0244 (13)	0.0305 (13)	−0.0038 (11)	0.0076 (11)	−0.0027 (10)
C13	0.0355 (14)	0.0239 (13)	0.0327 (13)	−0.0065 (10)	0.0061 (12)	0.0009 (10)
C14	0.0326 (14)	0.0335 (14)	0.0417 (15)	−0.0060 (11)	0.0162 (13)	−0.0004 (12)
C15	0.0349 (14)	0.0295 (14)	0.0438 (16)	−0.0020 (11)	0.0194 (13)	−0.0047 (12)
C16	0.0290 (12)	0.0219 (12)	0.0357 (14)	−0.0037 (10)	0.0112 (11)	−0.0011 (10)
N1	0.0386 (12)	0.0272 (11)	0.0309 (11)	−0.0008 (9)	0.0189 (10)	0.0017 (9)
N2	0.0432 (12)	0.0282 (11)	0.0283 (11)	−0.0045 (10)	0.0190 (10)	−0.0033 (9)
N3	0.0442 (15)	0.0419 (15)	0.0490 (15)	−0.0026 (12)	0.0146 (12)	0.0109 (12)
N4	0.0473 (15)	0.0413 (14)	0.0349 (13)	−0.0036 (12)	0.0121 (12)	0.0038 (11)
N5	0.061 (2)	0.105 (3)	0.060 (2)	0.028 (2)	0.0223 (17)	0.0147 (19)
O1	0.0480 (11)	0.0255 (9)	0.0327 (9)	−0.0090 (8)	0.0215 (9)	−0.0016 (7)
O2	0.0427 (11)	0.0239 (9)	0.0514 (12)	−0.0061 (8)	0.0283 (10)	−0.0083 (8)

Geometric parameters (Å, º) top

Mn1—O2	1.8669 (18)	C8—C9	1.511 (4)
Mn1—O1	1.9083 (19)	C8—H8A	0.9700
Mn1—N2	1.984 (2)	C8—H8B	0.9700
Mn1—N1	1.991 (2)	C9—N2	1.478 (3)
Mn1—N3	2.130 (3)	C9—H9A	0.9700
Br1—C4	1.894 (3)	C9—H9B	0.9700
Br2—C13	1.900 (2)	C10—N2	1.286 (3)
C1—O1	1.340 (3)	C10—C11	1.441 (3)
C1—C2	1.396 (4)	C10—H10	0.9300
C1—C6	1.418 (3)	C11—C12	1.406 (3)
C2—C3	1.381 (4)	C11—C16	1.411 (3)
C2—H2	0.9300	C12—C13	1.371 (4)
C3—C4	1.392 (4)	C12—H12	0.9300
C3—H3	0.9300	C13—C14	1.385 (4)
C4—C5	1.367 (4)	C14—C15	1.371 (4)
C5—C6	1.404 (4)	C14—H14	0.9300
C5—H5	0.9300	C15—C16	1.405 (4)
C6—C7	1.448 (4)	C15—H15	0.9300
C7—N1	1.277 (3)	C16—O2	1.322 (3)
C7—H7	0.9300	N3—N4	1.175 (3)
C8—N1	1.472 (3)	N4—N5	1.157 (4)

O2—Mn1—O1	95.38 (8)	N2—C9—C8	107.2 (2)
O2—Mn1—N2	91.73 (8)	N2—C9—H9A	110.3
O1—Mn1—N2	159.40 (9)	C8—C9—H9A	110.3
O2—Mn1—N1	171.04 (9)	N2—C9—H9B	110.3
O1—Mn1—N1	88.41 (9)	C8—C9—H9B	110.3
N2—Mn1—N1	82.06 (9)	H9A—C9—H9B	108.5
O2—Mn1—N3	97.19 (10)	N2—C10—C11	124.5 (2)
O1—Mn1—N3	96.43 (10)	N2—C10—H10	117.7
N2—Mn1—N3	101.83 (10)	C11—C10—H10	117.7
N1—Mn1—N3	90.43 (9)	C12—C11—C16	119.7 (2)
O1—C1—C2	119.4 (2)	C12—C11—C10	117.2 (2)
O1—C1—C6	121.9 (2)	C16—C11—C10	123.1 (2)
C2—C1—C6	118.7 (2)	C13—C12—C11	119.6 (2)
C3—C2—C1	121.2 (2)	C13—C12—H12	120.2
C3—C2—H2	119.4	C11—C12—H12	120.2
C1—C2—H2	119.4	C12—C13—C14	121.3 (2)
C2—C3—C4	119.4 (3)	C12—C13—Br2	119.5 (2)
C2—C3—H3	120.3	C14—C13—Br2	119.22 (19)
C4—C3—H3	120.3	C15—C14—C13	119.9 (2)
C5—C4—C3	121.0 (2)	C15—C14—H14	120.0
C5—C4—Br1	119.94 (19)	C13—C14—H14	120.0
C3—C4—Br1	119.0 (2)	C14—C15—C16	120.9 (2)
C4—C5—C6	120.2 (2)	C14—C15—H15	119.6
C4—C5—H5	119.9	C16—C15—H15	119.6
C6—C5—H5	119.9	O2—C16—C15	117.9 (2)
C5—C6—C1	119.3 (2)	O2—C16—C11	123.6 (2)
C5—C6—C7	118.7 (2)	C15—C16—C11	118.5 (2)
C1—C6—C7	122.0 (2)	C7—N1—C8	122.9 (2)
N1—C7—C6	123.0 (2)	C7—N1—Mn1	123.72 (18)
N1—C7—H7	118.5	C8—N1—Mn1	113.33 (16)
C6—C7—H7	118.5	C10—N2—C9	121.2 (2)
N1—C8—C9	106.7 (2)	C10—N2—Mn1	125.88 (17)
N1—C8—H8A	110.4	C9—N2—Mn1	112.66 (17)
C9—C8—H8A	110.4	N4—N3—Mn1	128.8 (2)
N1—C8—H8B	110.4	N5—N4—N3	177.5 (3)
C9—C8—H8B	110.4	C1—O1—Mn1	118.36 (16)
H8A—C8—H8B	108.6	C16—O2—Mn1	128.97 (16)

O1—C1—C2—C3	−178.9 (3)	O1—Mn1—N1—C7	−33.1 (2)
C6—C1—C2—C3	3.3 (4)	N2—Mn1—N1—C7	165.2 (2)
C1—C2—C3—C4	−2.1 (4)	N3—Mn1—N1—C7	63.3 (2)
C2—C3—C4—C5	−1.4 (4)	O2—Mn1—N1—C8	34.1 (7)
C2—C3—C4—Br1	176.4 (2)	O1—Mn1—N1—C8	149.32 (19)
C3—C4—C5—C6	3.6 (4)	N2—Mn1—N1—C8	−12.37 (19)
Br1—C4—C5—C6	−174.3 (2)	N3—Mn1—N1—C8	−114.3 (2)
C4—C5—C6—C1	−2.3 (4)	C11—C10—N2—C9	179.9 (3)
C4—C5—C6—C7	178.2 (2)	C11—C10—N2—Mn1	6.0 (4)
O1—C1—C6—C5	−178.9 (2)	C8—C9—N2—C10	−137.6 (3)
C2—C1—C6—C5	−1.2 (4)	C8—C9—N2—Mn1	37.1 (3)
O1—C1—C6—C7	0.6 (4)	O2—Mn1—N2—C10	−13.6 (2)
C2—C1—C6—C7	178.3 (2)	O1—Mn1—N2—C10	96.7 (3)
C5—C6—C7—N1	−161.0 (3)	N1—Mn1—N2—C10	159.9 (2)
C1—C6—C7—N1	19.5 (4)	N3—Mn1—N2—C10	−111.3 (2)
N1—C8—C9—N2	−45.4 (3)	O2—Mn1—N2—C9	172.0 (2)
N2—C10—C11—C12	−173.0 (3)	O1—Mn1—N2—C9	−77.7 (3)
N2—C10—C11—C16	5.3 (4)	N1—Mn1—N2—C9	−14.4 (2)
C16—C11—C12—C13	1.7 (4)	N3—Mn1—N2—C9	74.3 (2)
C10—C11—C12—C13	−179.9 (2)	O2—Mn1—N3—N4	12.9 (3)
C11—C12—C13—C14	0.5 (4)	O1—Mn1—N3—N4	−83.4 (3)
C11—C12—C13—Br2	−178.1 (2)	N2—Mn1—N3—N4	106.2 (3)
C12—C13—C14—C15	−0.7 (4)	N1—Mn1—N3—N4	−171.8 (3)
Br2—C13—C14—C15	178.0 (2)	Mn1—N3—N4—N5	−177 (100)
C13—C14—C15—C16	−1.5 (4)	C2—C1—O1—Mn1	139.8 (2)
C14—C15—C16—O2	−174.8 (3)	C6—C1—O1—Mn1	−42.5 (3)
C14—C15—C16—C11	3.7 (4)	O2—Mn1—O1—C1	−138.02 (18)
C12—C11—C16—O2	174.7 (2)	N2—Mn1—O1—C1	112.3 (3)
C10—C11—C16—O2	−3.6 (4)	N1—Mn1—O1—C1	50.12 (18)
C12—C11—C16—C15	−3.8 (4)	N3—Mn1—O1—C1	−40.14 (19)
C10—C11—C16—C15	177.9 (2)	C15—C16—O2—Mn1	168.3 (2)
C6—C7—N1—C8	−177.5 (2)	C11—C16—O2—Mn1	−10.2 (4)
C6—C7—N1—Mn1	5.1 (4)	O1—Mn1—O2—C16	−144.9 (2)
C9—C8—N1—C7	−142.4 (3)	N2—Mn1—O2—C16	15.7 (2)
C9—C8—N1—Mn1	35.2 (3)	N1—Mn1—O2—C16	−30.2 (7)
O2—Mn1—N1—C7	−148.3 (5)	N3—Mn1—O2—C16	117.9 (2)

Experimental details

Crystal data
Chemical formula	[Mn(C₁₆H₁₂Br₂N₂O₂)(N₃)]
M_r	1042.13
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	153
a, b, c (Å)	8.7068 (17), 15.269 (3), 13.684 (3)
β (°)	107.47 (3)
V (Å³)	1735.4 (6)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	5.39
Crystal size (mm)	0.20 × 0.17 × 0.10

Data collection
Diffractometer	Nonius KappaCCD diffractometer
Absorption correction	Multi-scan (SORTAV; Blessing, 1995)
T_min, T_max	0.352, 0.583
No. of measured, independent and observed [I > 2σ(I)] reflections	7747, 3961, 3093
R_int	0.015
(sin θ/λ)_max (Å⁻¹)	0.649

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.030, 0.074, 1.04
No. of reflections	3961
No. of parameters	235
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.82, −0.90

Computer programs: COLLECT (Nonius, 1998), SCALEPACK (Otwinowski & Minor, 1997), DENZO (Otwinowski & Minor, 1997) and maXus (Mackay et al., 1998), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

References

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