Figure 2
(a) Arrangement of NaOx polyhedra into edge-sharing clusters comprised of two Na1O6 octahedra and two Na2O5 square pyramids; (b) Arrangement of the clusters shown in (a) by corner sharing to form `slabs' parallel (010). Ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) 1 − x, 1 − y, 1 − z; (ii) + x, − y, 1 − z; (iii) − + x, − y, 1 − z; (iv) − x, − + y, z; (v) + x, y, − z; (vi) − x, 1 − y, + z; (vii) − x, − + y, z.] |