Crystal structure of K0.75[FeII3.75FeIII1.25(HPO3)6]·0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions

Larrea, E.S.; Mesa, J.L.; Legarra, E.; Aguayo, A.T.; Arriortua, M.I.

doi:10.1107/S2056989015024007

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 3
Crystal structure of K_0.75[Fe^II_3.75Fe^III_1.25(HPO₃)₆]·0.5H₂O in polyhedral representation, in a projection along [001]. Colour code: Fe1O₆ octahedra are blue, Fe2O₆ octahedra are magenta, HPO₃ tetrahedra are orange, O atoms are red and K⁺ ions are grey. Hydrogen-bonding interactions between O1 from the framework and O1W are shown with dashed lines.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 72| Part 1| January 2016| Pages 63-65

doi:10.1107/S2056989015024007

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