Distinct coordination geometries in bis­[N,N-bis­(2-meth­oxy­eth­yl)di­thio­carbamato-κ2S,S′]di­phenyltin(IV) and bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ2S,S′]di­phenyl­tin(IV): crystal structures and Hirshfeld surface analysis

Mohamad, R.; Awang, N.; Jotani, M.M.; Tiekink, E.R.T.

doi:10.1107/S2056989016011385

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 9
Four structural motifs for molecules of the general composition R₂Sn(S₂CNR′R′′)₂: (a) skew trapezoidal bipyramidal, (b) five-coordinate trigonal–bipyramidal owing to a monodentate dithiocarbamate ligand, (c) cis-octahedral and (d) seven-coordinate pentagonal–bipyramidal owing to additional coordination by a heteroatom of the tin-bound residue. In all images, H atoms have been omitted, only the α-C atoms bound to nitrogen included and, in all but (d), only the α-C atom of the tin-bound residues shown.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 72| Part 8| August 2016| Pages 1130-1137

https://doi.org/10.1107/S2056989016011385

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