research communications
κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1)
of tetrakis(isonicotinamide-aInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany
*Correspondence e-mail: t.neumann@ac.uni-kiel.de
The 2(C6H6N2O)4]·2C6H6N2O·C2H5OH, comprises one CoII cation, two thiocyanate anions, four coordinating and two solvent isonicotinamide molecules and one ethanol solvent molecule. The CoII cations are octahedrally coordinated by four N-coordinating isonicotinamide ligands and two terminally N-bonded thiocyanate anions. These discrete complexes are linked by intermolecular N—H⋯O and N—H⋯S hydrogen-bonding interactions into a three-dimensional network. The two isonicotinamide and the ethanol solvent molecules are embedded in channels of this network and are linked through further N—H⋯O and N—H⋯N hydrogen bonds to the network. The ethanol solvent molecule is disordered over two sets of sites (occupancy ratio 0.6:0.4).
of the title compound, [Co(NCS)Keywords: crystal structure; hydrogen bonding; isonicotinamide; cobalt.
CCDC reference: 1491089
1. Chemical context
There is an increasing interest in compounds showing cooperative magnetic properties, such as ferromagnetism, antiferromagnetism and metamagnetism or a slow relaxation of the magnetization, indicative of single-molecule or single-chain magnetism (Gao et al., 2009; Ma et al., 2009; Palion-Gazda et al., 2015; Näther et al., 2013). In this context we have reported on a number of one-dimensional cobalt(II) thiocyanate coordination compounds with different N-donor co-ligands that show slow relaxations of the magnetization which in some compounds can be traced back to the behaviour of single-chain magnets (SCM) (Wöhlert et al., 2014; Werner et al., 2014, 2015a,b,c,). In the course of our systematic investigation of these materials, we became interested in the monodentate ligand isonicotinamide, which can coordinate with the N atom to the CoII atoms, forming the desired one-dimensional compounds. However, instead of the expected chain compound, a discrete complex with additional solvate molecules of composition [Co(NCS)2(C6H6N2O)4]·2C6H6N2O·C2H5OH was obtained in the current study and characterized by single-crystal X-ray diffraction.
2. Structural commentary
The II cation, two thiocyanate ligands, six isonicotinamide molecules (four coordinating, two non-coordinating) and one positionally disordered ethanol solvent molecule. The CoII cation is coordinated by two terminal N-bonded thiocyanate anions and four N-coordinating isonicotinamide ligands, forming a slightly distorted octahedron (Fig. 1). Bond lengths [Co—N range: 2.074 (3)–2.185 (2) Å] and angles [N—Co—N range: 88.09 (9)–91.91 (10)° for cis and 177.27 (10)–178.32 (11)° for trans angles] are indicative for a slight distortion and are comparable with those in similar coordination compounds with CoII, thiocyanate anions and N-bound co-ligands.
of the title compound consists of one Co3. Supramolecular features
In the a axis by intermolecular N—H⋯O hydrogen-bonding interactions (Fig. 2, Table 1). These chains are further linked into a three-dimensional network by interchain N—H⋯S hydrogen bonding between the thiocyanate anions and the amide H atoms of neighboring complexes (Fig. 3, Table 1). In this way, two types of channels are formed along the a axis. In the larger channels, the isonicotinamide solvent molecules are embedded whereas the smaller channels are occupied by the disordered ethanol molecules (Figs. 2 and 3). The solvent molecules are linked by O—H⋯O, N—H⋯O and N—H⋯N hydrogen-bonding interactions to the the isonicotinamide ligands that form the channels. Weak C—H⋯O and C—H⋯S interactions are also observed, consolidating the packing of the crystal structure.
of the title compound, neighboring complexes are linked into chains extending along the4. Database survey
In the Cambridge Structure Database (Version 5.37, last update 2015; Groom et al., 2016) only five structures of coordination compounds with isonicotinamide and thiocyanate as ligands are reported: two of nickel coordination polymers, in which the metal atoms are connected into chains by μ-1,3-bridging thiocyanate ligands of which one contains 9,10-anthraquinone and the other pyrene as clathrate molecules (Sekiya et al., 2009). Furthermore, a one-dimensional cadmium 9,10-dichloroanthracene-clathrate with bridging μ-1,3-thiocyanate ligands between the metal atoms is reported (Sekiya & Nishikiori, 2005), as well as a three-dimensional network consisting of cadmium cations with μ-1,3-bridging thiocyanate ligands (Yang et al., 2001), and finally one Cu coordination polymer in which Cu–NCS sheets are observed (Đaković et al., 2010). In this context we have reported recently on a Zn complex in which the Zn cations are tetrahedrally coordinated by two terminal N-bonded thiocyanate anions and two isonicotinamide ligands (Neumann et al., 2016).
5. Synthesis and crystallization
Cobalt(II) thiocyanate and isonicotinamide were obtained from Alfa Aesar and were used without further purification. Single crystals suitable for structure analysis were obtained by the reaction of 26.3 mg Co(NCS)2 (0.15 mmol) with 73.3 mg isonicotinamide (0.6 mmol) in ethanol (1.5 ml) after being allowed to stand for a few days at room temperature.
6. Refinement
Crystal data, data collection and structure . The C—H, O—H and N—H hydrogen atoms were located in a difference map but were positioned with idealized geometry (methyl and O—H hydrogen atoms were allowed to rotate but not to tip) and were refined with Uiso(H) = 1.2Ueq(C,N) (1.5 for methyl and O—H hydrogen atoms) using a riding model with C—H = 0.95 Å for aromatic, C—H = 0.98 Å for methyl, N—H = 0.88 Å and O— H = 0.84 Å, respectively. The ethanol molecule was found to be disordered over two sets of sites and was refined with fixed occupation factors of 0.6 and 0.4, respectively.
details are summarized in Table 2
|
Supporting information
CCDC reference: 1491089
https://doi.org/10.1107/S2056989016010951/wm5305sup1.cif
contains datablock I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989016010951/wm5305Isup2.hkl
Data collection: X-AREA (Stoe, 2008); cell
X-AREA (Stoe, 2008); data reduction: X-AREA (Stoe, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: XP in SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 1999); software used to prepare material for publication: publCIF (Westrip, 2010).[Co(NCS)2(C6H6N2O)4]·2C6H6N2O·C2H6O | Z = 2 |
Mr = 953.92 | F(000) = 990 |
Triclinic, P1 | Dx = 1.394 Mg m−3 |
a = 9.1877 (4) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 13.6779 (5) Å | Cell parameters from 9885 reflections |
c = 20.3185 (8) Å | θ = 3.3–54.0° |
α = 104.027 (3)° | µ = 0.53 mm−1 |
β = 97.256 (3)° | T = 200 K |
γ = 109.576 (3)° | Block, red |
V = 2273.12 (17) Å3 | 0.42 × 0.35 × 0.25 mm |
Stoe IPDS-2 diffractometer | 8035 reflections with I > 2σ(I) |
ω scans | Rint = 0.044 |
Absorption correction: numerical (X-SHAPE and X-RED32; Stoe, 2008) | θmax = 27.0°, θmin = 1.7° |
Tmin = 0.637, Tmax = 0.805 | h = −11→10 |
23938 measured reflections | k = −17→17 |
9885 independent reflections | l = −24→25 |
Refinement on F2 | 0 restraints |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.054 | H-atom parameters constrained |
wR(F2) = 0.142 | w = 1/[σ2(Fo2) + (0.0507P)2 + 3.0411P] where P = (Fo2 + 2Fc2)/3 |
S = 1.10 | (Δ/σ)max = 0.001 |
9885 reflections | Δρmax = 0.75 e Å−3 |
606 parameters | Δρmin = −0.39 e Å−3 |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Co1 | 0.61592 (5) | 0.35492 (3) | 0.21691 (2) | 0.02592 (11) | |
N1 | 0.8459 (3) | 0.4542 (2) | 0.22065 (14) | 0.0336 (6) | |
C1 | 0.9652 (4) | 0.4826 (2) | 0.20375 (15) | 0.0304 (6) | |
S1 | 1.13121 (10) | 0.52353 (9) | 0.17835 (5) | 0.0467 (2) | |
N2 | 0.3879 (3) | 0.2543 (2) | 0.21571 (14) | 0.0361 (6) | |
C2 | 0.2534 (4) | 0.2022 (2) | 0.20567 (15) | 0.0307 (6) | |
S2 | 0.06525 (11) | 0.12699 (8) | 0.18989 (5) | 0.0497 (2) | |
N11 | 0.5978 (3) | 0.4880 (2) | 0.29563 (13) | 0.0297 (5) | |
C11 | 0.4652 (4) | 0.5085 (3) | 0.29031 (16) | 0.0357 (7) | |
H11 | 0.3771 | 0.4615 | 0.2530 | 0.043* | |
C12 | 0.4506 (4) | 0.5955 (3) | 0.33693 (17) | 0.0363 (7) | |
H12 | 0.3547 | 0.6080 | 0.3310 | 0.044* | |
C13 | 0.5767 (4) | 0.6641 (2) | 0.39224 (16) | 0.0302 (6) | |
C14 | 0.7152 (4) | 0.6439 (3) | 0.39744 (16) | 0.0335 (6) | |
H14 | 0.8048 | 0.6895 | 0.4344 | 0.040* | |
C15 | 0.7213 (4) | 0.5563 (2) | 0.34796 (16) | 0.0316 (6) | |
H15 | 0.8175 | 0.5442 | 0.3514 | 0.038* | |
C16 | 0.5541 (4) | 0.7534 (3) | 0.44494 (16) | 0.0335 (6) | |
O11 | 0.4191 (3) | 0.7524 (2) | 0.44465 (12) | 0.0401 (5) | |
N12 | 0.6808 (4) | 0.8311 (3) | 0.49009 (18) | 0.0560 (9) | |
H12A | 0.6701 | 0.8842 | 0.5211 | 0.067* | |
H12B | 0.7755 | 0.8297 | 0.4891 | 0.067* | |
N21 | 0.6386 (3) | 0.2271 (2) | 0.13538 (13) | 0.0307 (5) | |
C21 | 0.5924 (4) | 0.1226 (2) | 0.13461 (16) | 0.0312 (6) | |
H21 | 0.5311 | 0.1002 | 0.1665 | 0.037* | |
C22 | 0.6302 (4) | 0.0461 (2) | 0.08948 (16) | 0.0319 (6) | |
H22 | 0.5951 | −0.0271 | 0.0906 | 0.038* | |
C23 | 0.7195 (3) | 0.0771 (2) | 0.04279 (15) | 0.0282 (6) | |
C24 | 0.7621 (4) | 0.1837 (2) | 0.04143 (16) | 0.0344 (7) | |
H24 | 0.8198 | 0.2074 | 0.0088 | 0.041* | |
C25 | 0.7195 (4) | 0.2552 (2) | 0.08825 (16) | 0.0346 (7) | |
H25 | 0.7494 | 0.3280 | 0.0868 | 0.041* | |
C26 | 0.7649 (4) | −0.0066 (2) | −0.00419 (15) | 0.0309 (6) | |
O21 | 0.7255 (3) | −0.09870 (17) | 0.00063 (12) | 0.0410 (5) | |
N22 | 0.8473 (4) | 0.0237 (2) | −0.04995 (15) | 0.0406 (6) | |
H22A | 0.8752 | −0.0233 | −0.0781 | 0.049* | |
H22B | 0.8739 | 0.0907 | −0.0522 | 0.049* | |
N31 | 0.7061 (3) | 0.2929 (2) | 0.29549 (13) | 0.0303 (5) | |
C31 | 0.6391 (4) | 0.2855 (3) | 0.34932 (16) | 0.0313 (6) | |
H31 | 0.5510 | 0.3067 | 0.3519 | 0.038* | |
C32 | 0.6913 (4) | 0.2485 (3) | 0.40192 (16) | 0.0318 (6) | |
H32 | 0.6415 | 0.2460 | 0.4400 | 0.038* | |
C33 | 0.8176 (4) | 0.2152 (2) | 0.39785 (15) | 0.0300 (6) | |
C34 | 0.8853 (4) | 0.2197 (3) | 0.34056 (17) | 0.0365 (7) | |
H34 | 0.9702 | 0.1957 | 0.3353 | 0.044* | |
C35 | 0.8271 (4) | 0.2594 (3) | 0.29166 (16) | 0.0348 (7) | |
H35 | 0.8752 | 0.2634 | 0.2531 | 0.042* | |
C36 | 0.8902 (4) | 0.1787 (3) | 0.45389 (16) | 0.0335 (6) | |
O31 | 1.0142 (3) | 0.1628 (2) | 0.44981 (13) | 0.0444 (6) | |
N32 | 0.8179 (4) | 0.1652 (3) | 0.50476 (16) | 0.0490 (8) | |
H32A | 0.8575 | 0.1440 | 0.5379 | 0.059* | |
H32B | 0.7299 | 0.1774 | 0.5056 | 0.059* | |
N41 | 0.5176 (3) | 0.4126 (2) | 0.13757 (13) | 0.0306 (5) | |
C41 | 0.3896 (4) | 0.3416 (2) | 0.08872 (16) | 0.0353 (7) | |
H41 | 0.3594 | 0.2664 | 0.0844 | 0.042* | |
C42 | 0.2986 (4) | 0.3719 (3) | 0.04405 (16) | 0.0346 (7) | |
H42 | 0.2092 | 0.3183 | 0.0097 | 0.041* | |
C43 | 0.3392 (3) | 0.4808 (2) | 0.05005 (15) | 0.0279 (6) | |
C44 | 0.4744 (4) | 0.5551 (2) | 0.09968 (17) | 0.0325 (6) | |
H44 | 0.5079 | 0.6307 | 0.1046 | 0.039* | |
C45 | 0.5596 (4) | 0.5178 (2) | 0.14181 (16) | 0.0319 (6) | |
H45 | 0.6523 | 0.5694 | 0.1753 | 0.038* | |
C46 | 0.2421 (4) | 0.5236 (3) | 0.00764 (15) | 0.0313 (6) | |
O41 | 0.2731 (3) | 0.62182 (19) | 0.02170 (13) | 0.0428 (6) | |
N42 | 0.1222 (3) | 0.4499 (2) | −0.04437 (15) | 0.0390 (6) | |
H42A | 0.0620 | 0.4713 | −0.0701 | 0.047* | |
H42B | 0.1037 | 0.3801 | −0.0529 | 0.047* | |
N51 | 0.6258 (4) | 0.9683 (2) | 0.61213 (16) | 0.0460 (7) | |
C51 | 0.5455 (5) | 1.0340 (3) | 0.61289 (19) | 0.0459 (8) | |
H51 | 0.5017 | 1.0398 | 0.5698 | 0.055* | |
C52 | 0.5234 (4) | 1.0931 (3) | 0.67293 (18) | 0.0406 (7) | |
H52 | 0.4627 | 1.1370 | 0.6710 | 0.049* | |
C53 | 0.5905 (4) | 1.0883 (3) | 0.73626 (17) | 0.0344 (6) | |
C54 | 0.6730 (4) | 1.0196 (3) | 0.73642 (19) | 0.0397 (7) | |
H54 | 0.7194 | 1.0129 | 0.7788 | 0.048* | |
C55 | 0.6854 (4) | 0.9609 (3) | 0.6724 (2) | 0.0447 (8) | |
H55 | 0.7398 | 0.9128 | 0.6722 | 0.054* | |
C56 | 0.5693 (4) | 1.1562 (3) | 0.80151 (18) | 0.0405 (7) | |
O51 | 0.4479 (3) | 1.1764 (3) | 0.79954 (15) | 0.0655 (9) | |
N52 | 0.6846 (3) | 1.1943 (2) | 0.85867 (15) | 0.0406 (6) | |
H52A | 0.6762 | 1.2358 | 0.8973 | 0.049* | |
H52B | 0.7693 | 1.1779 | 0.8578 | 0.049* | |
N61 | 1.0108 (4) | −0.1655 (3) | 0.36132 (16) | 0.0445 (7) | |
C61 | 1.0359 (4) | −0.2371 (3) | 0.3113 (2) | 0.0429 (8) | |
H61 | 1.0812 | −0.2845 | 0.3245 | 0.052* | |
C62 | 1.0002 (4) | −0.2467 (3) | 0.24140 (19) | 0.0377 (7) | |
H62 | 1.0214 | −0.2988 | 0.2078 | 0.045* | |
C63 | 0.9329 (3) | −0.1788 (2) | 0.22133 (17) | 0.0317 (6) | |
C64 | 0.9026 (4) | −0.1056 (3) | 0.27224 (17) | 0.0355 (7) | |
H64 | 0.8538 | −0.0592 | 0.2602 | 0.043* | |
C65 | 0.9444 (4) | −0.1010 (3) | 0.34117 (19) | 0.0429 (8) | |
H65 | 0.9250 | −0.0494 | 0.3759 | 0.051* | |
C66 | 0.9038 (4) | −0.1824 (2) | 0.14579 (15) | 0.0292 (6) | |
O61 | 0.9960 (3) | −0.20254 (18) | 0.10943 (12) | 0.0367 (5) | |
N62 | 0.7810 (3) | −0.1622 (2) | 0.12232 (14) | 0.0365 (6) | |
H62A | 0.7600 | −0.1624 | 0.0788 | 0.044* | |
H62B | 0.7194 | −0.1484 | 0.1501 | 0.044* | |
C71 | 0.678 (2) | 0.5974 (12) | 0.5795 (11) | 0.106 (6) | 0.4 |
H71A | 0.5657 | 0.5518 | 0.5749 | 0.127* | 0.4 |
H71B | 0.7317 | 0.6140 | 0.6286 | 0.127* | 0.4 |
C72 | 0.742 (3) | 0.526 (3) | 0.5390 (12) | 0.095 (8) | 0.4 |
H72A | 0.7252 | 0.4627 | 0.5554 | 0.142* | 0.4 |
H72B | 0.6874 | 0.5028 | 0.4899 | 0.142* | 0.4 |
H72C | 0.8553 | 0.5657 | 0.5442 | 0.142* | 0.4 |
O71 | 0.6780 (16) | 0.6932 (13) | 0.5727 (8) | 0.122 (4) | 0.4 |
H71 | 0.7702 | 0.7335 | 0.5731 | 0.182* | 0.4 |
C81 | 0.9012 (14) | 0.5036 (8) | 0.5864 (8) | 0.111 (4) | 0.6 |
H81A | 1.0100 | 0.5458 | 0.5836 | 0.133* | 0.6 |
H81B | 0.8927 | 0.5336 | 0.6346 | 0.133* | 0.6 |
C82 | 0.802 (2) | 0.531 (2) | 0.5447 (13) | 0.137 (10) | 0.6 |
H82A | 0.8318 | 0.6097 | 0.5598 | 0.205* | 0.6 |
H82B | 0.8111 | 0.5068 | 0.4963 | 0.205* | 0.6 |
H82C | 0.6926 | 0.4945 | 0.5478 | 0.205* | 0.6 |
O81 | 0.8947 (8) | 0.4053 (5) | 0.5805 (5) | 0.096 (2) | 0.6 |
H81 | 0.8285 | 0.3619 | 0.5439 | 0.145* | 0.6 |
U11 | U22 | U33 | U12 | U13 | U23 | |
Co1 | 0.0294 (2) | 0.02770 (19) | 0.02199 (19) | 0.01389 (16) | 0.00461 (15) | 0.00611 (14) |
N1 | 0.0332 (14) | 0.0347 (13) | 0.0328 (14) | 0.0136 (11) | 0.0090 (11) | 0.0081 (11) |
C1 | 0.0347 (16) | 0.0326 (15) | 0.0265 (14) | 0.0175 (13) | 0.0046 (12) | 0.0083 (12) |
S1 | 0.0337 (4) | 0.0697 (6) | 0.0498 (5) | 0.0260 (4) | 0.0163 (4) | 0.0288 (5) |
N2 | 0.0343 (14) | 0.0376 (14) | 0.0356 (14) | 0.0141 (12) | 0.0046 (11) | 0.0108 (11) |
C2 | 0.0342 (16) | 0.0330 (15) | 0.0262 (14) | 0.0159 (13) | 0.0082 (12) | 0.0062 (12) |
S2 | 0.0331 (4) | 0.0516 (5) | 0.0533 (5) | 0.0102 (4) | 0.0159 (4) | 0.0018 (4) |
N11 | 0.0324 (13) | 0.0331 (13) | 0.0239 (12) | 0.0164 (11) | 0.0043 (10) | 0.0046 (10) |
C11 | 0.0336 (16) | 0.0433 (17) | 0.0279 (15) | 0.0198 (14) | 0.0010 (12) | 0.0025 (13) |
C12 | 0.0338 (16) | 0.0438 (17) | 0.0324 (16) | 0.0222 (14) | 0.0035 (13) | 0.0052 (13) |
C13 | 0.0317 (15) | 0.0335 (15) | 0.0280 (14) | 0.0158 (12) | 0.0096 (12) | 0.0076 (12) |
C14 | 0.0315 (15) | 0.0343 (15) | 0.0309 (15) | 0.0143 (13) | 0.0042 (12) | 0.0018 (12) |
C15 | 0.0279 (14) | 0.0366 (15) | 0.0291 (15) | 0.0160 (12) | 0.0039 (12) | 0.0040 (12) |
C16 | 0.0351 (16) | 0.0368 (16) | 0.0313 (15) | 0.0191 (13) | 0.0081 (13) | 0.0071 (13) |
O11 | 0.0372 (12) | 0.0475 (13) | 0.0394 (13) | 0.0247 (11) | 0.0120 (10) | 0.0059 (10) |
N12 | 0.0380 (16) | 0.0531 (18) | 0.059 (2) | 0.0232 (15) | 0.0022 (14) | −0.0179 (15) |
N21 | 0.0387 (14) | 0.0302 (12) | 0.0260 (12) | 0.0180 (11) | 0.0053 (10) | 0.0077 (10) |
C21 | 0.0348 (15) | 0.0316 (15) | 0.0303 (15) | 0.0142 (12) | 0.0100 (12) | 0.0114 (12) |
C22 | 0.0349 (15) | 0.0271 (14) | 0.0331 (15) | 0.0111 (12) | 0.0062 (13) | 0.0098 (12) |
C23 | 0.0326 (15) | 0.0275 (13) | 0.0221 (13) | 0.0129 (12) | −0.0001 (11) | 0.0043 (11) |
C24 | 0.0494 (18) | 0.0315 (15) | 0.0247 (14) | 0.0163 (14) | 0.0112 (13) | 0.0099 (12) |
C25 | 0.0534 (19) | 0.0260 (14) | 0.0271 (15) | 0.0166 (14) | 0.0117 (14) | 0.0095 (12) |
C26 | 0.0344 (15) | 0.0293 (14) | 0.0258 (14) | 0.0125 (12) | 0.0018 (12) | 0.0047 (11) |
O21 | 0.0643 (16) | 0.0288 (11) | 0.0333 (12) | 0.0224 (11) | 0.0129 (11) | 0.0078 (9) |
N22 | 0.0535 (17) | 0.0324 (13) | 0.0403 (16) | 0.0196 (13) | 0.0216 (13) | 0.0089 (12) |
N31 | 0.0322 (13) | 0.0379 (13) | 0.0251 (12) | 0.0176 (11) | 0.0065 (10) | 0.0110 (10) |
C31 | 0.0301 (15) | 0.0414 (16) | 0.0276 (15) | 0.0181 (13) | 0.0084 (12) | 0.0123 (12) |
C32 | 0.0330 (15) | 0.0416 (16) | 0.0261 (14) | 0.0173 (13) | 0.0089 (12) | 0.0140 (12) |
C33 | 0.0306 (14) | 0.0342 (15) | 0.0263 (14) | 0.0144 (12) | 0.0052 (12) | 0.0084 (12) |
C34 | 0.0385 (17) | 0.0498 (19) | 0.0305 (16) | 0.0278 (15) | 0.0095 (13) | 0.0117 (14) |
C35 | 0.0370 (16) | 0.0507 (18) | 0.0258 (15) | 0.0248 (15) | 0.0125 (12) | 0.0133 (13) |
C36 | 0.0348 (16) | 0.0392 (16) | 0.0290 (15) | 0.0186 (13) | 0.0046 (12) | 0.0096 (13) |
O31 | 0.0434 (13) | 0.0684 (16) | 0.0370 (13) | 0.0367 (13) | 0.0098 (10) | 0.0210 (12) |
N32 | 0.0450 (17) | 0.084 (2) | 0.0408 (16) | 0.0394 (17) | 0.0153 (13) | 0.0352 (17) |
N41 | 0.0368 (13) | 0.0313 (12) | 0.0251 (12) | 0.0172 (11) | 0.0041 (10) | 0.0064 (10) |
C41 | 0.0502 (19) | 0.0257 (14) | 0.0261 (15) | 0.0162 (13) | −0.0004 (13) | 0.0030 (11) |
C42 | 0.0422 (17) | 0.0320 (15) | 0.0250 (14) | 0.0150 (13) | −0.0010 (13) | 0.0040 (12) |
C43 | 0.0324 (14) | 0.0336 (14) | 0.0232 (13) | 0.0167 (12) | 0.0107 (11) | 0.0102 (11) |
C44 | 0.0349 (16) | 0.0276 (14) | 0.0361 (16) | 0.0114 (12) | 0.0084 (13) | 0.0122 (12) |
C45 | 0.0311 (15) | 0.0305 (14) | 0.0310 (15) | 0.0097 (12) | 0.0042 (12) | 0.0085 (12) |
C46 | 0.0379 (16) | 0.0378 (16) | 0.0254 (14) | 0.0198 (13) | 0.0107 (12) | 0.0126 (12) |
O41 | 0.0587 (15) | 0.0357 (12) | 0.0384 (13) | 0.0232 (11) | 0.0045 (11) | 0.0144 (10) |
N42 | 0.0413 (15) | 0.0409 (15) | 0.0371 (15) | 0.0212 (13) | −0.0002 (12) | 0.0125 (12) |
N51 | 0.0463 (17) | 0.0402 (16) | 0.0415 (17) | 0.0134 (13) | 0.0096 (14) | −0.0006 (13) |
C51 | 0.052 (2) | 0.048 (2) | 0.0357 (18) | 0.0201 (17) | 0.0089 (16) | 0.0080 (15) |
C52 | 0.0428 (18) | 0.0433 (18) | 0.0354 (17) | 0.0198 (15) | 0.0057 (14) | 0.0079 (14) |
C53 | 0.0294 (15) | 0.0380 (16) | 0.0328 (16) | 0.0112 (13) | 0.0090 (12) | 0.0070 (13) |
C54 | 0.0361 (17) | 0.0373 (17) | 0.0421 (18) | 0.0120 (14) | 0.0060 (14) | 0.0097 (14) |
C55 | 0.0404 (18) | 0.0334 (17) | 0.054 (2) | 0.0139 (15) | 0.0079 (16) | 0.0049 (15) |
C56 | 0.0352 (17) | 0.052 (2) | 0.0369 (17) | 0.0205 (15) | 0.0128 (14) | 0.0110 (15) |
O51 | 0.0451 (15) | 0.109 (3) | 0.0438 (15) | 0.0458 (17) | 0.0086 (12) | 0.0024 (16) |
N52 | 0.0380 (15) | 0.0519 (17) | 0.0300 (14) | 0.0213 (13) | 0.0050 (12) | 0.0045 (12) |
N61 | 0.0411 (16) | 0.0533 (17) | 0.0388 (16) | 0.0142 (14) | 0.0039 (13) | 0.0217 (14) |
C61 | 0.0440 (19) | 0.0446 (19) | 0.046 (2) | 0.0190 (16) | 0.0059 (16) | 0.0236 (16) |
C62 | 0.0389 (17) | 0.0339 (16) | 0.0440 (18) | 0.0154 (14) | 0.0089 (14) | 0.0166 (14) |
C63 | 0.0259 (14) | 0.0318 (15) | 0.0349 (16) | 0.0087 (12) | 0.0021 (12) | 0.0117 (12) |
C64 | 0.0352 (16) | 0.0432 (17) | 0.0314 (16) | 0.0195 (14) | 0.0058 (13) | 0.0118 (13) |
C65 | 0.0422 (18) | 0.051 (2) | 0.0350 (17) | 0.0186 (16) | 0.0071 (14) | 0.0112 (15) |
C66 | 0.0314 (14) | 0.0265 (13) | 0.0289 (14) | 0.0106 (12) | 0.0056 (12) | 0.0081 (11) |
O61 | 0.0379 (12) | 0.0409 (12) | 0.0349 (12) | 0.0194 (10) | 0.0093 (10) | 0.0109 (10) |
N62 | 0.0386 (14) | 0.0471 (15) | 0.0296 (13) | 0.0219 (13) | 0.0083 (11) | 0.0135 (12) |
C71 | 0.125 (14) | 0.056 (8) | 0.129 (15) | 0.016 (9) | 0.034 (12) | 0.038 (9) |
C72 | 0.12 (2) | 0.091 (15) | 0.071 (12) | 0.022 (16) | 0.041 (14) | 0.036 (11) |
O71 | 0.108 (9) | 0.155 (12) | 0.136 (11) | 0.059 (9) | 0.054 (9) | 0.077 (10) |
C81 | 0.091 (7) | 0.065 (6) | 0.169 (13) | 0.017 (5) | 0.006 (8) | 0.051 (7) |
C82 | 0.096 (13) | 0.088 (10) | 0.167 (17) | −0.029 (9) | −0.051 (11) | 0.070 (11) |
O81 | 0.064 (4) | 0.073 (4) | 0.132 (7) | 0.014 (3) | 0.001 (4) | 0.023 (4) |
Co1—N1 | 2.074 (3) | C41—H41 | 0.9500 |
Co1—N2 | 2.079 (3) | C42—C43 | 1.378 (4) |
Co1—N31 | 2.179 (2) | C42—H42 | 0.9500 |
Co1—N11 | 2.181 (2) | C43—C44 | 1.391 (4) |
Co1—N41 | 2.183 (2) | C43—C46 | 1.511 (4) |
Co1—N21 | 2.185 (2) | C44—C45 | 1.384 (4) |
N1—C1 | 1.160 (4) | C44—H44 | 0.9500 |
C1—S1 | 1.635 (3) | C45—H45 | 0.9500 |
N2—C2 | 1.162 (4) | C46—O41 | 1.227 (4) |
C2—S2 | 1.631 (3) | C46—N42 | 1.338 (4) |
N11—C11 | 1.337 (4) | N42—H42A | 0.8800 |
N11—C15 | 1.339 (4) | N42—H42B | 0.8800 |
C11—C12 | 1.387 (4) | N51—C55 | 1.319 (5) |
C11—H11 | 0.9500 | N51—C51 | 1.338 (5) |
C12—C13 | 1.385 (4) | C51—C52 | 1.370 (5) |
C12—H12 | 0.9500 | C51—H51 | 0.9500 |
C13—C14 | 1.387 (4) | C52—C53 | 1.381 (5) |
C13—C16 | 1.508 (4) | C52—H52 | 0.9500 |
C14—C15 | 1.388 (4) | C53—C54 | 1.391 (5) |
C14—H14 | 0.9500 | C53—C56 | 1.499 (4) |
C15—H15 | 0.9500 | C54—C55 | 1.393 (5) |
C16—O11 | 1.236 (4) | C54—H54 | 0.9500 |
C16—N12 | 1.325 (4) | C55—H55 | 0.9500 |
N12—H12A | 0.8800 | C56—O51 | 1.235 (4) |
N12—H12B | 0.8800 | C56—N52 | 1.330 (4) |
N21—C25 | 1.336 (4) | N52—H52A | 0.8800 |
N21—C21 | 1.343 (4) | N52—H52B | 0.8800 |
C21—C22 | 1.384 (4) | N61—C61 | 1.333 (5) |
C21—H21 | 0.9500 | N61—C65 | 1.339 (5) |
C22—C23 | 1.382 (4) | C61—C62 | 1.379 (5) |
C22—H22 | 0.9500 | C61—H61 | 0.9500 |
C23—C24 | 1.387 (4) | C62—C63 | 1.384 (4) |
C23—C26 | 1.512 (4) | C62—H62 | 0.9500 |
C24—C25 | 1.383 (4) | C63—C64 | 1.381 (5) |
C24—H24 | 0.9500 | C63—C66 | 1.510 (4) |
C25—H25 | 0.9500 | C64—C65 | 1.385 (5) |
C26—O21 | 1.221 (4) | C64—H64 | 0.9500 |
C26—N22 | 1.328 (4) | C65—H65 | 0.9500 |
N22—H22A | 0.8800 | C66—O61 | 1.247 (4) |
N22—H22B | 0.8800 | C66—N62 | 1.309 (4) |
N31—C31 | 1.330 (4) | N62—H62A | 0.8800 |
N31—C35 | 1.341 (4) | N62—H62B | 0.8800 |
C31—C32 | 1.388 (4) | C71—O71 | 1.351 (19) |
C31—H31 | 0.9500 | C71—C72 | 1.44 (4) |
C32—C33 | 1.386 (4) | C71—H71A | 0.9900 |
C32—H32 | 0.9500 | C71—H71B | 0.9900 |
C33—C34 | 1.392 (4) | C72—H72A | 0.9800 |
C33—C36 | 1.515 (4) | C72—H72B | 0.9800 |
C34—C35 | 1.375 (4) | C72—H72C | 0.9800 |
C34—H34 | 0.9500 | O71—H71 | 0.8400 |
C35—H35 | 0.9500 | C81—O81 | 1.300 (11) |
C36—O31 | 1.238 (4) | C81—C82 | 1.37 (2) |
C36—N32 | 1.314 (4) | C81—H81A | 0.9900 |
N32—H32A | 0.8800 | C81—H81B | 0.9900 |
N32—H32B | 0.8800 | C82—H82A | 0.9800 |
N41—C41 | 1.336 (4) | C82—H82B | 0.9800 |
N41—C45 | 1.336 (4) | C82—H82C | 0.9800 |
C41—C42 | 1.385 (4) | O81—H81 | 0.8400 |
N1—Co1—N2 | 178.32 (11) | C45—N41—Co1 | 123.6 (2) |
N1—Co1—N31 | 90.01 (10) | N41—C41—C42 | 123.4 (3) |
N2—Co1—N31 | 88.33 (10) | N41—C41—H41 | 118.3 |
N1—Co1—N11 | 89.42 (10) | C42—C41—H41 | 118.3 |
N2—Co1—N11 | 90.36 (10) | C43—C42—C41 | 119.2 (3) |
N31—Co1—N11 | 92.30 (9) | C43—C42—H42 | 120.4 |
N1—Co1—N41 | 91.91 (10) | C41—C42—H42 | 120.4 |
N2—Co1—N41 | 89.74 (10) | C42—C43—C44 | 117.8 (3) |
N31—Co1—N41 | 178.04 (10) | C42—C43—C46 | 123.6 (3) |
N11—Co1—N41 | 88.09 (9) | C44—C43—C46 | 118.5 (3) |
N1—Co1—N21 | 88.74 (10) | C45—C44—C43 | 119.3 (3) |
N2—Co1—N21 | 91.53 (10) | C45—C44—H44 | 120.4 |
N31—Co1—N21 | 89.72 (9) | C43—C44—H44 | 120.4 |
N11—Co1—N21 | 177.27 (10) | N41—C45—C44 | 123.0 (3) |
N41—Co1—N21 | 89.95 (9) | N41—C45—H45 | 118.5 |
C1—N1—Co1 | 158.0 (2) | C44—C45—H45 | 118.5 |
N1—C1—S1 | 178.5 (3) | O41—C46—N42 | 122.7 (3) |
C2—N2—Co1 | 169.1 (3) | O41—C46—C43 | 120.3 (3) |
N2—C2—S2 | 178.5 (3) | N42—C46—C43 | 117.0 (3) |
C11—N11—C15 | 117.6 (3) | C46—N42—H42A | 120.0 |
C11—N11—Co1 | 120.6 (2) | C46—N42—H42B | 120.0 |
C15—N11—Co1 | 121.68 (19) | H42A—N42—H42B | 120.0 |
N11—C11—C12 | 122.8 (3) | C55—N51—C51 | 117.6 (3) |
N11—C11—H11 | 118.6 | N51—C51—C52 | 123.1 (3) |
C12—C11—H11 | 118.6 | N51—C51—H51 | 118.4 |
C13—C12—C11 | 119.5 (3) | C52—C51—H51 | 118.4 |
C13—C12—H12 | 120.2 | C51—C52—C53 | 119.2 (3) |
C11—C12—H12 | 120.2 | C51—C52—H52 | 120.4 |
C12—C13—C14 | 117.9 (3) | C53—C52—H52 | 120.4 |
C12—C13—C16 | 118.5 (3) | C52—C53—C54 | 118.4 (3) |
C14—C13—C16 | 123.6 (3) | C52—C53—C56 | 118.5 (3) |
C13—C14—C15 | 119.1 (3) | C54—C53—C56 | 123.1 (3) |
C13—C14—H14 | 120.4 | C53—C54—C55 | 117.8 (3) |
C15—C14—H14 | 120.4 | C53—C54—H54 | 121.1 |
N11—C15—C14 | 123.1 (3) | C55—C54—H54 | 121.1 |
N11—C15—H15 | 118.5 | N51—C55—C54 | 123.7 (3) |
C14—C15—H15 | 118.5 | N51—C55—H55 | 118.1 |
O11—C16—N12 | 122.0 (3) | C54—C55—H55 | 118.1 |
O11—C16—C13 | 119.4 (3) | O51—C56—N52 | 122.9 (3) |
N12—C16—C13 | 118.6 (3) | O51—C56—C53 | 118.8 (3) |
C16—N12—H12A | 120.0 | N52—C56—C53 | 118.2 (3) |
C16—N12—H12B | 120.0 | C56—N52—H52A | 120.0 |
H12A—N12—H12B | 120.0 | C56—N52—H52B | 120.0 |
C25—N21—C21 | 117.2 (3) | H52A—N52—H52B | 120.0 |
C25—N21—Co1 | 118.8 (2) | C61—N61—C65 | 116.8 (3) |
C21—N21—Co1 | 123.5 (2) | N61—C61—C62 | 124.0 (3) |
N21—C21—C22 | 122.9 (3) | N61—C61—H61 | 118.0 |
N21—C21—H21 | 118.5 | C62—C61—H61 | 118.0 |
C22—C21—H21 | 118.5 | C61—C62—C63 | 118.6 (3) |
C23—C22—C21 | 119.4 (3) | C61—C62—H62 | 120.7 |
C23—C22—H22 | 120.3 | C63—C62—H62 | 120.7 |
C21—C22—H22 | 120.3 | C64—C63—C62 | 118.3 (3) |
C22—C23—C24 | 117.9 (3) | C64—C63—C66 | 122.2 (3) |
C22—C23—C26 | 118.7 (3) | C62—C63—C66 | 119.4 (3) |
C24—C23—C26 | 123.4 (3) | C63—C64—C65 | 119.0 (3) |
C25—C24—C23 | 119.0 (3) | C63—C64—H64 | 120.5 |
C25—C24—H24 | 120.5 | C65—C64—H64 | 120.5 |
C23—C24—H24 | 120.5 | N61—C65—C64 | 123.3 (3) |
N21—C25—C24 | 123.5 (3) | N61—C65—H65 | 118.4 |
N21—C25—H25 | 118.3 | C64—C65—H65 | 118.4 |
C24—C25—H25 | 118.3 | O61—C66—N62 | 123.4 (3) |
O21—C26—N22 | 122.2 (3) | O61—C66—C63 | 119.9 (3) |
O21—C26—C23 | 119.9 (3) | N62—C66—C63 | 116.7 (3) |
N22—C26—C23 | 117.9 (3) | C66—N62—H62A | 120.0 |
C26—N22—H22A | 120.0 | C66—N62—H62B | 120.0 |
C26—N22—H22B | 120.0 | H62A—N62—H62B | 120.0 |
H22A—N22—H22B | 120.0 | O71—C71—C72 | 127.2 (19) |
C31—N31—C35 | 117.4 (3) | O71—C71—H71A | 105.5 |
C31—N31—Co1 | 119.99 (19) | C72—C71—H71A | 105.5 |
C35—N31—Co1 | 122.6 (2) | O71—C71—H71B | 105.5 |
N31—C31—C32 | 123.3 (3) | C72—C71—H71B | 105.5 |
N31—C31—H31 | 118.3 | H71A—C71—H71B | 106.1 |
C32—C31—H31 | 118.3 | C71—C72—H72A | 109.5 |
C33—C32—C31 | 118.8 (3) | C71—C72—H72B | 109.5 |
C33—C32—H32 | 120.6 | H72A—C72—H72B | 109.5 |
C31—C32—H32 | 120.6 | C71—C72—H72C | 109.5 |
C32—C33—C34 | 118.2 (3) | H72A—C72—H72C | 109.5 |
C32—C33—C36 | 123.5 (3) | H72B—C72—H72C | 109.5 |
C34—C33—C36 | 118.3 (3) | C71—O71—H71 | 109.5 |
C35—C34—C33 | 118.9 (3) | O81—C81—C82 | 125.4 (14) |
C35—C34—H34 | 120.6 | O81—C81—H81A | 106.0 |
C33—C34—H34 | 120.6 | C82—C81—H81A | 106.0 |
N31—C35—C34 | 123.4 (3) | O81—C81—H81B | 106.0 |
N31—C35—H35 | 118.3 | C82—C81—H81B | 106.0 |
C34—C35—H35 | 118.3 | H81A—C81—H81B | 106.3 |
O31—C36—N32 | 123.0 (3) | C81—C82—H82A | 109.5 |
O31—C36—C33 | 118.8 (3) | C81—C82—H82B | 109.5 |
N32—C36—C33 | 118.2 (3) | H82A—C82—H82B | 109.5 |
C36—N32—H32A | 120.0 | C81—C82—H82C | 109.5 |
C36—N32—H32B | 120.0 | H82A—C82—H82C | 109.5 |
H32A—N32—H32B | 120.0 | H82B—C82—H82C | 109.5 |
C41—N41—C45 | 117.3 (3) | C81—O81—H81 | 109.5 |
C41—N41—Co1 | 118.0 (2) |
D—H···A | D—H | H···A | D···A | D—H···A |
C11—H11···S1i | 0.95 | 3.03 | 3.676 (3) | 127 |
C14—H14···O31ii | 0.95 | 2.62 | 3.532 (4) | 162 |
C15—H15···O81ii | 0.95 | 2.60 | 3.454 (7) | 149 |
N12—H12A···N51 | 0.88 | 2.09 | 2.936 (4) | 160 |
N12—H12B···O31ii | 0.88 | 2.12 | 2.879 (4) | 144 |
C25—H25···O41iii | 0.95 | 2.47 | 3.100 (4) | 124 |
N22—H22A···S2iv | 0.88 | 2.60 | 3.439 (3) | 160 |
N22—H22B···O61v | 0.88 | 2.26 | 3.005 (4) | 142 |
C32—H32···O11vi | 0.95 | 2.47 | 3.399 (4) | 165 |
N32—H32A···N61vii | 0.88 | 2.14 | 2.965 (4) | 156 |
N32—H32B···O11vi | 0.88 | 2.14 | 2.952 (4) | 153 |
C41—H41···O21iv | 0.95 | 2.32 | 3.113 (4) | 140 |
C42—H42···O61iv | 0.95 | 2.63 | 3.547 (4) | 163 |
N42—H42A···S1iii | 0.88 | 2.68 | 3.523 (3) | 161 |
N42—H42B···O61iv | 0.88 | 2.22 | 3.063 (4) | 159 |
N52—H52A···O41viii | 0.88 | 2.09 | 2.921 (4) | 157 |
N52—H52B···O61ii | 0.88 | 2.06 | 2.882 (4) | 155 |
C62—H62···S1ix | 0.95 | 2.89 | 3.734 (3) | 148 |
N62—H62A···O21 | 0.88 | 2.03 | 2.854 (4) | 156 |
N62—H62B···O51vi | 0.88 | 1.94 | 2.775 (4) | 159 |
O71—H71···O31ii | 0.84 | 2.20 | 3.020 (13) | 167 |
O81—H81···O11vi | 0.84 | 2.37 | 2.855 (7) | 118 |
O81—H81···N32 | 0.84 | 2.58 | 3.062 (8) | 118 |
Symmetry codes: (i) x−1, y, z; (ii) −x+2, −y+1, −z+1; (iii) −x+1, −y+1, −z; (iv) −x+1, −y, −z; (v) −x+2, −y, −z; (vi) −x+1, −y+1, −z+1; (vii) −x+2, −y, −z+1; (viii) −x+1, −y+2, −z+1; (ix) x, y−1, z. |
Acknowledgements
This project was supported by the Deutsche Forschungsgemeinschaft (project No. NA 720/5–1) and the State of Schleswig-Holstein. We thank Professor Dr Wolfgang Bensch for access to his experimental facilities.
References
Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany. Google Scholar
Đaković, M., Jagličić, Z., Kozlevčar, B. & Popović, Z. (2010). Polyhedron, 29, 1910–1917. Google Scholar
Gao, E.-Q., Liu, P.-P., Wang, Y.-Q., Yue, Q. & Wang, Q.-L. (2009). Chem. Eur. J. 15, 1217–1226. Web of Science CSD CrossRef PubMed CAS Google Scholar
Groom, C. R., Bruno, I. J., Lightfoot, M. P. & Ward, S. C. (2016). Acta Cryst. B72, 171–179. Web of Science CSD CrossRef IUCr Journals Google Scholar
Ma, Y., Zhang, J. Y., Cheng, A.-L., Sun, Q., Gao, E.-Q. & Liu, C.-M. (2009). Inorg. Chem. 48, 6142–6151. Web of Science CSD CrossRef PubMed CAS Google Scholar
Näther, C., Wöhlert, S., Boeckmann, J., Wriedt, M. & Jess, I. (2013). Z. Anorg. Allg. Chem. 639, 2696–2714. Google Scholar
Neumann, T., Jess, I. & Näther, C. (2016). Acta Cryst. E72, 922–925. CSD CrossRef IUCr Journals Google Scholar
Palion-Gazda, J., Machura, B., Lloret, F. & Julve, M. (2015). Cryst. Growth Des. 15, 2380–2388. CAS Google Scholar
Sekiya, R. & Nishikiori, S. (2005). Chem. Lett. 34, 1076–1077. Web of Science CSD CrossRef CAS Google Scholar
Sekiya, R., Nishikiori, S. & Kuroda, R. (2009). CrystEngComm, 11, 2251–2253. Web of Science CSD CrossRef CAS Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Sheldrick, G. M. (2015). Acta Cryst. C71, 3–8. Web of Science CrossRef IUCr Journals Google Scholar
Stoe (2008). X-AREA, X-RED32 and X-SHAPE. Stoe & Cie, Darmstadt, Germany. Google Scholar
Werner, J., Rams, M., Tomkowicz, Z. & Näther, C. (2014). Dalton Trans. 43, 17333–17342. Web of Science CSD CrossRef CAS PubMed Google Scholar
Werner, J., Rams, M., Tomkowicz, Z., Runčevski, T., Dinnebier, R. E., Suckert, S. & Näther, C. (2015a). Inorg. Chem. 54, 2893–2901. Web of Science CSD CrossRef CAS PubMed Google Scholar
Werner, J., Runčevski, T., Dinnebier, R. E., Ebbinghaus, S. G., Suckert, S. & Näther, C. (2015b). Eur. J. Inorg. Chem. pp. 3236–3245. Web of Science CSD CrossRef Google Scholar
Werner, J., Tomkowicz, Z., Rams, M., Ebbinghaus, S. G., Neumann, T. & Näther, C. (2015c). Dalton Trans. 44, 14149–14158. Web of Science CSD CrossRef CAS PubMed Google Scholar
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920–925. Web of Science CrossRef CAS IUCr Journals Google Scholar
Wöhlert, S., Tomkowicz, Z., Rams, M., Ebbinghaus, S. G., Fink, L., Schmidt, M. U. & Näther, C. (2014). Inorg. Chem. 53, 8298–8310. Web of Science PubMed Google Scholar
Yang, G., Zhu, H.-G., Liang, B.-H. & Chen, X.-M. (2001). J. Chem. Soc. Dalton Trans. pp. 580–585. Web of Science CSD CrossRef Google Scholar
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.