Figure 1
The different coordination modes in the M(pds)(nab)2 family. (I): {[Cd(pds)(Bpy)2}n, P (Harvey et al., 2001a ); (II): {[Hg(pds)(Bpy)2}n, P21/n (Díaz de Vivar et al., 2005 ); (III): Cd(pds)(Phen)2(H2O) P (Harvey et al., 2001b ); (IV): Zn(pds)(Phen)2(H2O), P (Harvey et al., 2011 ); (V) : Cd(pds)(DMPhen)2, C2/c (Harvey et al., 2001b ; Marsh, 2004 , and this work); (VI) : Zn(pds)(TMPhen)2, P (this work); (VII) : Cd(pds)(TMPhen)2, Pbcn (this work). Ligand code: Bpy = 2,2′-bipyridine; Phen = 1,10-phenanthroline, DMPhen = 2,9-dimethyl-1,10-phenanthroline, TMPhen = 3,4,7,8-tetramethyl-1,10-phenanthroline. |