Figure 3
The molecular packing in (I): (a) a view of the supramolecular dimer sustained by amine-N—H⋯N(imine) and amine-N—H⋯S(thiolate) hydrogen bonds between the independent molecules, shown as blue and orange dashed lines, respectively, (b) a view of the supramolecular chain whereby the dimers in (a) are connected via amine-N—H⋯S(thiolate) hydrogen bonds and (c) a view of the unit-cell contents shown in projection down the c axis. The π–π and C—H⋯π interactions are shown as purple and pink dashed lines, respectively. |