Crystal structure of a new mixed-metal coordin­ation polymer consisting of NiII piperidine-di­thio­carbamate and penta­nuclear CuI—I cluster units

Himoto, K.; Horii, T.; Oda, S.; Suzuki, S.; Sugimoto, K.; Okubo, T.; Maekawa, M.; Kuroda-Sowa, T.

doi:10.1107/S2056989018000750

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 1
An ORTEP view of the title compound, showing the mononuclear Ni^II dithiocarbamate unit Ni^II(Pip-dtc)₂, the pentanuclear Cu^I cluster unit Cu₅I₅(CH₃CH₂CN) and the chloroform molecule with 50% probability level ellipsoids. H atoms have been omitted for clarity. [Symmetry codes: (i) x, −y + $[1\over2]$ , z; (ii) −x, −y + 1, −z; (iii) x, −y + $[3\over2]$ , z.]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 2| February 2018| Pages 233-236

https://doi.org/10.1107/S2056989018000750

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