Crystal structures of two new six-coordinate iron(III) complexes with 1,2-bis(diphenyl­phosphane) ligands

McNeil Jr, D.L.; Beckford, D.J.; Kneebone, J.L.; Carpenter, S.H.; Brennessel, W.W.; Neidig, M.L.

doi:10.1107/S2056989018006898

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 1
Displacement ellipsoid plot of 1 drawn at the 50% probability level with hydrogen atoms omitted. The full cation of the title formula is generated by a crystallographic inversion center (1 − x, 1 − y, 1 − z) at atom Fe1. The full anion is generated by a crystallographic twofold axis (−x, y, $[{3\over 2}]$ − z), which includes atom Fe2. The symmetry-equivalent atoms of the dichloromethane solvent molecule are generated by a crystallographic twofold axis (1 − x, y, $[{3\over 2}]$ − z) that contains atom C27.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 6| June 2018| Pages 803-807

https://doi.org/10.1107/S2056989018006898

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