Spontaneous enanti­omorphism in poly-phased alkaline salts of tris­(oxalato)ferrate(III): crystal structure of cubic NaRb5[Fe(C2O4)3]2

Piro, O.E.; Echeverría, G.A.; Baran, E.J.

doi:10.1107/S2056989018008022

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

IUCr IT WDC

home archive editors for authors for readers submit open access

view article

Figure 1
View of NaRb₅[Fe(C₂O₄)₃]₂ showing the atom labels and displacement ellipsoids at the 50% probability level. For clarity, only the minimum number of oxygen ligands around each metal ion has been labelled. The rest of the environmental oxygen atoms are generated through the symmetry operations of the corresponding point groups: C₃ (Fe), C₂ (Rb1), C₃ (Rb2) and D₃ (Na). Iron–oxalate bonds are indicated by double lines and alkali metal–oxygen contacts by single lines. Symmetry codes: (i) −y + 1, z + $[{1\over 2}]$ , −x + $[{1\over 2}]$ ; (ii) y − $[{1\over 2}]$ , −z + $[{3\over 2}]$ , −x + 1; (iii) −y + $[{5\over 4}]$ , −x + $[{5\over 4}]$ , −z + $[{1\over 4}]$ .

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 7| July 2018| Pages 905-909

https://doi.org/10.1107/S2056989018008022

Open

access

Follow Acta Cryst. E

Search IUCr Journals		doi		Advanced search
Author		volume	page