Figure 2
Outline of the unit cell with axes showing all molecular entities in the crystal. Details of the hydrogen bonds found for the [Ru(L)3]2+ unit are also shown. Dashed lines indicate the mutual N—H⋯N array between two symmetric complexes through one of the heteroaryl-imidazole ligands and two hydrogen bonds with water molecules. Symmetry codes: (i) −x + 1, −y + 2, −z + 2; (ii) x + , −y + , z − ; (iii) −x + 1, −y + 1, −z + 2; (iv) −x + 1, −y + 2, −z + 1. Water H atoms were not found, see text for details. Atoms of the PF6− anion in the upper right corner have symmetry code (ii). |