Synthesis, detailed geometric analysis and bond-valence method evaluation of the strength of π-arene bonding of two isotypic cationic prehnitene tin(II) complexes: [{1,2,3,4-(CH3)4C6H2}2Sn2Cl2][MCl4]2 (M = Al and Ga)

Merkelbach, J.; Frank, W.

doi:10.1107/S2056989019008508

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

IUCr IT WDC

home archive editors for authors for readers submit open access

view article

Figure 1
Asymmetric units of the crystal structures of 1 (top) and 2 (bottom) displaying the atom-labelling schemes, and in transparent mode the symmetry-related second half completing the dimeric building block that defines the repeating units of the coordination polymeric, secondary structure of the compounds[(symmetry code (i) 1 − x, −y, 1 − z]. The direction of secondary bonding to atoms of the neighbouring moieties is indicated by thin sticks. Displacement ellipsoids are drawn at the 50% probability level, hydrogen atoms are drawn with an arbitrary radius.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 75| Part 7| July 2019| Pages 1051-1056

https://doi.org/10.1107/S2056989019008508

Open

access

Follow Acta Cryst. E

Search IUCr Journals		doi		Advanced search
Author		volume	page